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    • 2. 发明授权
    • Fluorine-containing copolymer
    • 含氟共聚物
    • US5856417A
    • 1999-01-05
    • US958165
    • 1997-10-27
    • Teruo TakakuraAtsushi FunakiNaomi Ichikuni
    • Teruo TakakuraAtsushi FunakiNaomi Ichikuni
    • C08F214/22C08F214/26C08F16/24
    • C08F214/22C08F214/26
    • A fluorine-containing copolymer comprising:(a) from 0.05 to 20 mol % of polymer units based on at least one fluorinated comonomer selected from the group consisting of fluorinated comonomers of the following formulae (1), (2) and (3):X--R.sup.f --CY.dbd.CH.sub.2 (1)X--R.sup.f --O--CF.dbd.CF.sub.2 (2)CF.sub.3 --(CF.sub.2).sub.n --(O--CF(CF.sub.3)--CF.sub.2).sub.m --O--CF.dbd.CF.sub.2 (3)wherein Y is a fluorine atom or a hydrogen atom, R.sup.f is a C.sub.2-12 bivalent fluorinated organic group, X is a fluorine atom, a chlorine atom or a hydrogen atom, n is an integer of from 0 to 3, and m is an integer of from 1 to 4,(b) from 30 to 85 mol % of polymer units based on tetrafluoroethylene,(c) from 1 to 30 mol % of polymer units based on propylene, and(d) from 5 to 68.5 mol % of polymer units based on vinylidene fluoride.
    • 一种含氟共聚物,其包含:(a)0.05至20摩尔%的基于至少一种选自以下式(1),(2)和(3)的氟化共聚单体的氟化共聚单体的聚合物单元: X-Rf-CY = CH2(1)X-Rf-O-CF = CF2(2)CF3-(CF2)n-(O-CF(CF3)-CF2)mO-CF = CF2(3) 氟原子或氢原子,Rf为C2-12二价氟代有机基团,X为氟原子,氯原子或氢原子,n为0〜3的整数,m为 1〜4,(b)30〜85摩尔%的基于四氟乙烯的聚合物单元,(c)1〜30摩尔%的基于丙烯的聚合物单元,和(d)5〜68.5摩尔% 偏氟乙烯。
    • 6. 发明授权
    • Method for producing a fluorinated polymer
    • 氟化聚合物的制造方法
    • US5494984A
    • 1996-02-27
    • US325437
    • 1994-11-09
    • Atsushi FunakiTeruo TakakuraKazuo KatoKazuo HamazakiHaruhisa Miyake
    • Atsushi FunakiTeruo TakakuraKazuo KatoKazuo HamazakiHaruhisa Miyake
    • C08F2/06C08F2/18C08F2/38C08F14/18
    • C08F14/18
    • A method for producing a fluorinated polymer containing fluoroolefin units as the main constituting units, wherein CF.sub.3 (CF.sub.2).sub.n CH.sub.2 CH.sub.3 or CF.sub.3 (CF.sub.2).sub.n H, wherein n is an integer of from 1 to 8), the is used as the polymerization medium, and CF.sub.2 ClCF.sub.2 CHClF and/or CF.sub.3 CF.sub.2 CHCl.sub.2 as a chain transfer agent.Using the polymerization medium which is less likely to bring about an environmental destruction, it is possible to obtain a fluorinated polymer excellent in the heat resistance, solvent resistance, chemical resistance, etc. Further, the above chain transfer agent has good compatibility with the polymerization medium which scarcely brings about the environmental destruction, whereby it is possible to efficiently produce a fluorinated polymer excellent in the heat resistance and solvent resistance. This chain transfer agent has affinity to the resulting polymer and to the polymerization medium and has excellent handling efficiency for post treatment such as granulation or drying.
    • PCT No.PCT / JP94 / 00420 Sec。 371日期:1994年11月9日 102(e)日期1994年11月9日PCT 1994年3月16日PCT公布。 WO94 / 21696 PCT公开号 日本特开2002-1949号公报。一种含有氟代烯烃单元作为主要构成单元的含氟聚合物的制造方法,其中,CF 3(CF 2)n CH 2 CH 3或CF 3(CF 2)n H,其中n为1〜8的整数) 用作聚合介质,CF2ClCF2CHClF和/或CF3CF2CHCl2作为链转移剂。 使用不太可能引起环境破坏的聚合介质,可以获得耐热性,耐溶剂性,耐化学性等优异的氟化聚合物。此外,上述链转移剂与聚合物具有良好的相容性 介质几乎不会导致环境破坏,从而可以有效地制备耐热性和耐溶剂性优异的氟化聚合物。 该链转移剂对所得聚合物和聚合介质具有亲和性,并且对于后处理如造粒或干燥具有优异的处理效率。