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1. 发明授权

US5180502A Electrolytic ozonizer and method of decomposing ozone-containing waste gas using said ozonizer 失效
标题翻译：电解臭氧发生器和使用所述臭氧发生器分解含臭氧废气的方法
公开(公告)号：US5180502A
公开(公告)日：1993-01-19
申请号：US701014
申请日：1991-05-13
申请人： Yoshinori Nishiki , Isao Sawamoto , Shuji Nakamatsu , Takayuki Shimamune
发明人： Yoshinori Nishiki , Isao Sawamoto , Shuji Nakamatsu , Takayuki Shimamune
IPC分类号： B01D53/86
CPC分类号： B01D53/8675
摘要： The present invention is directed toward an electrolytic ozonier for treating ozone-containing waste gas and a method of treating ozone-containing waste gas using the ozonier, wherein the method includes evolving oxygen and ozone in an anode compartment of an electrolytic cell by electrolysis of water while evolving hydrogen in a cathode compartment; directing the evolved hydrogen into a waste gas treating section that contains a waste gas decomposition catalyst so as to convert the hydrogen to a harmless form by means of the catalyst; bringing the oxygen and ozone into contact with a medium to be treated in an ozone contactor so as to treat the medium; and subsequently directing waste gas containing oxygen and ozone produced as a result of treatment of the medium into the waste gas treating section where they are brought into either direct or indirect contact with the catalyst so that the ozone in the waste gas is converted into a harmless form.
摘要翻译：本发明涉及一种用于处理含臭氧废气的电解臭氧化物和使用该臭氧臭氧物处理含臭氧废气的方法，其中该方法包括通过电解电解在电解槽的阳极室中放出氧气和臭氧同时在阴极室中演化氢气; 将放出的氢气导入含有废气分解催化剂的废气处理段，以便通过催化剂将氢转化成无害形式; 使氧气和臭氧与臭氧接触器中要处理的介质接触，以便处理介质; 并且随后将由于处理介质而产生的含有氧气和臭氧的废气引导到废气处理部分中，在那里它们与催化剂直接或间接接触，使得废气中的臭氧转化为无害的形成。

2. 发明授权

US5114549A Method and apparatus for treating water using electrolytic ozone 失效
标题翻译：使用电解臭氧处理水的方法和装置
公开(公告)号：US5114549A
公开(公告)日：1992-05-19
申请号：US784738
申请日：1991-10-29
申请人： Takayuki Shimamune , Shuji Nakamatsu , Isao Sawamoto , Hiroshi Masuda , Yoshinori Nishiki
发明人： Takayuki Shimamune , Shuji Nakamatsu , Isao Sawamoto , Hiroshi Masuda , Yoshinori Nishiki
IPC分类号： C01B13/10 , C02F1/50 , C02F1/78 , C25B1/13
CPC分类号： C02F1/78 , C25B1/13
摘要： A method and apparatus for water treatment is described, using electrolytic zone, which comprises electrolyzing water to generate an ozone-containing gas in the anode compartment of an electrolytic cell, separating the ozone-containing gas from the anolyte, and contacting the separated ozone-containing gas with the water to be treated said water to be treated being different than the water for electrolysis.

3. 发明授权

US5015354A Bipolar-electrode electrolytic cell 失效
标题翻译：双极电极电解槽
公开(公告)号：US5015354A
公开(公告)日：1991-05-14
申请号：US349617
申请日：1989-05-10
申请人： Yoshinori Nishiki , Isao Sawamoto , Shuji Nakamatsu , Takayuki Shimamune
发明人： Yoshinori Nishiki , Isao Sawamoto , Shuji Nakamatsu , Takayuki Shimamune
IPC分类号： C02F1/46 , C02F1/461 , C25B9/00 , C25B9/04 , C25B9/08 , C25B9/18
CPC分类号： C25B9/04 , C02F1/46109 , C25B9/18 , C02F2001/46128 , C02F2201/46115
摘要： A bipolar-electrode electrolytic cell is disclosed, which is to be used in electrolysis of an electrolytic solution having a high electric resistance and including at least two diaphragms positioned to form a plurality of electrode compartments comprising two outer compartments defined between the side walls of the electrolytic cell and the diaphragms positioned closest to the cell walls having a single electrode and at least one electrode compartment having two same-polar electrodes on both sides thereof, each of said electrodes being placed on a diaphragm such that different-polar electrodes are positioned at opposing sides of the diaphragm, wherein the distance between same-polar electrodes within the same compartment is sufficiently large such that electrolysis therebetween does not substantially occur and wherein two of said electrodes at the terminal ends of the series connected electrolytic cell, an anode and a cathode, being further electrically connected to an anode collector and a cathode collector, respectively, and each of the remaining anode electrodes and cathode electrodes is further connected to a different-polar electrode, respectively, which face the same direction and are placed on adjacent diaphragms.

4. 发明授权

US5589052A Method for electrolyzing water 失效
标题翻译：水电解方法
公开(公告)号：US5589052A
公开(公告)日：1996-12-31
申请号：US759975
申请日：1991-09-17
申请人： Takayuki Shimamune , Shuji Nakamatsu , Isao Sawamoto , Yoshinori Nishiki
发明人： Takayuki Shimamune , Shuji Nakamatsu , Isao Sawamoto , Yoshinori Nishiki
IPC分类号： C25B1/30 , C25B1/04 , C25B1/10 , C25B1/13 , C25B9/00 , C25B9/06 , C25B15/00
CPC分类号： C25B1/10 , C25B1/13 , Y02E60/366
摘要： A method and apparatus for water electrolysis is described, using an electrolytic cell comprising an anode compartment, a cathode compartment, and a diaphragm separating the anode and cathode compartments, comprising the steps of electrolyzing water to evolve oxygen or an ozone-containing oxygen gas in the anode compartment and hydrogen in the cathode compartment, thereby resulting in a net transfer of electrolyte from the anode compartment to the cathode compartment through the diaphragm, and recycling electrolyte from the cathode compartment to the anode compartment.
摘要翻译：描述了一种用于水电解的方法和装置，其使用包括阳极室，阴极室和隔离阳极和阴极室的隔膜的电解池，包括以下步骤：电解水以产生氧气或含臭氧的氧气阳极室和阴极室中的氢气，从而导致电解质从阳极室经隔膜转移到阴极室，并将电解质从阴极室再循环到阳极室。

5. 发明授权

US5437771A Electrolytic cell and processes for producing alkali hydroxide and hydrogen peroxide 失效
标题翻译：电解池和碱氢氧化物和过氧化氢的制备方法
公开(公告)号：US5437771A
公开(公告)日：1995-08-01
申请号：US196442
申请日：1994-02-15
申请人： Takayuki Shimamune , Yasuo Nakajima , Shuji Nakamatsu , Yoshinori Nishiki , Shuhei Wakita
发明人： Takayuki Shimamune , Yasuo Nakajima , Shuji Nakamatsu , Yoshinori Nishiki , Shuhei Wakita
IPC分类号： C25B1/30 , C25B1/46 , C25B1/20 , C25B9/00
CPC分类号： C25B1/46 , C25B1/30
摘要： The electrolytic cell 1 for producing alkali hydroxide or hydrogen peroxide is divided into the anode compartment 3 and the cathode compartment 4 by the cation exchange membrane 2. The cathode compartment 4 is further divided by the anion exchange membrane 6 into the solution compartment 7 containing a concentrated aqueous solution of alkali hydroxide and the gas compartment accommodating the gas cathode 8. The anion exchange membrane 6 prevents the gas cathode 8 from coming into direct or indirect contact with the aqueous solution of alkali hydroxide. This leads to the extended life of the gas cathode. The above-mentioned arrangement is effective in large-sized electrolytic cells. Thus, the present invention can be applied to industrial electrolysis which has never been achieved with the conventional gas electrode.
摘要翻译：用于生产碱金属氢氧化物或过氧化氢的电解池1通过阳离子交换膜2分成阳极室3和阴极室4.阴极室4进一步被阴离子交换膜6分成溶液室7，碱性氢氧化物的浓缩水溶液和容纳气体阴极8的气室。阴离子交换膜6防止气体阴极8与碱金属氢氧化物水溶液直接或间接接触。这导致气体阴极的寿命延长。上述布置在大尺寸电解槽中是有效的。因此，本发明可以应用于以往的气体电极从未实现的工业电解。

6. 发明授权

US4978438A Electrolytic cell 失效
标题翻译：电解池
公开(公告)号：US4978438A
公开(公告)日：1990-12-18
申请号：US352427
申请日：1989-05-16
申请人： Takayuki Shimamune , Yoshinori Nishiki , Shuji Nakamatsu
发明人： Takayuki Shimamune , Yoshinori Nishiki , Shuji Nakamatsu
IPC分类号： C02F1/46 , C02F1/461 , C02F1/467 , C02F1/76 , C25B9/00 , C25B9/08 , C25B9/10
CPC分类号： C02F1/46104 , C02F1/4674 , C02F1/4672 , C02F1/763 , C02F2001/46142 , C02F2201/46115 , C02F2201/46195
摘要： The present invention is directed toward an electrolytic cell for treating fluids with gases that are evolved by electrolysis comprising an anode compartment separated from a cathode compartment by a diaphragm, and a gas-permeable and liquid-impermeable window formed in the anode and the cathode compartment, or formed in the anode or the cathode compartment, wherein the window is formed such that a gas evolved in the anode or cathode compartment or gases evolved in these two compartments are allowed to pass through the window to make contact with a fluid to be treated, said fluid being located outside said electrolytic cell, thereby treating the fluid.

7. 发明授权

US4927800A Electrode catalyst and method for production thereof 失效
标题翻译：电极催化剂及其制造方法
公开(公告)号：US4927800A
公开(公告)日：1990-05-22
申请号：US276703
申请日：1988-11-28
申请人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
发明人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
IPC分类号： C25B1/13 , C25B9/10 , C25B11/04 , C25B11/06 , C25B11/10 , C25B11/16
CPC分类号： C25B11/16 , C25B1/13 , C25B11/0478 , C25B9/10
摘要： An electrode catalyst comprising a lead dioxide electrically deposited layer, the layer having particles containing .beta.-lead dioxide powder dispersed therein, and a method for producing the electrode catalyst are disclosed. The particles contain .beta.-lead dioxide powder and optionally an electrolytic cocatalyst selected from PTFE, agar, gelatin, a perfluoro ion exchange resin and the like. The present electrode catalyst is useful for production of ozone by electrolysis of water and for production of peroxides by electrolysis of aqueous solutions.

8. 发明授权

US4900419A Cathode for electrolysis and process for producing the same 失效
标题翻译：电解阴极及其制造方法
公开(公告)号：US4900419A
公开(公告)日：1990-02-13
申请号：US213047
申请日：1988-06-29
申请人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
发明人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
IPC分类号： C25B11/04 , C25B11/08
CPC分类号： C25B11/0484
摘要： A cathode for electrolysis, particularly of a sodium chloride aqueous solution by an ion-exchange membrane method, and a process for producing the same, the cathode comprising a conductive base having a nickel surface and having provided thereon (a) at least one platinum group component selected from the group consisting of a platinum group metal, a platinum group metal oxide, and a platinum group metal hydroxide, and (b) at least one cerium component selected from the group consisting of cerium, cerium oxide, and cerium hydroxide, retaining a markedly reduced hydrogen overpotential for an extended period of time and exhibiting excellent resistance to impurities in the electrolytic solution.

9. 发明授权

US4935110A Electrode structure and process for fabricating the same 失效
标题翻译：电极结构及其制造方法
公开(公告)号：US4935110A
公开(公告)日：1990-06-19
申请号：US276732
申请日：1988-11-28
申请人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
发明人： Yoshinori Nishiki , Shuji Nakamatsu , Takayuki Shimamune
IPC分类号： C25B1/13 , C25B9/10
CPC分类号： C25B9/10 , C25B1/13
摘要： Electrode structures of solid polymer electrolyte type for use in electrolysis are disclosed, (i) in which an adhering layer containing fine particles loaded with a .beta.-lead dioxide powder is formed on one surface of an ion-exchange membrane serving as a solid polymer electrolyte, and an electrodeposited layer of lead dioxide being formed on the surface of the adhering layer, and (ii) in which an electrodeposited layer of lead dioxide having dispersed therein fine particles loaded with a .beta.-lead dioxide powder is formed electrolytically between an ion-exchange membrane serving as a solid polymer electrolyte and a current collector positioned close to the ion-exchange membrane, to thereby form a unitary assembly. The present electrode structures are useful for production of ozone by electrolysis of water and for production of peroxides by electrolysis of aqueous solutions.

10. 发明授权

US5290406A Method for producing ozone 失效
标题翻译：生产臭氧的方法
公开(公告)号：US5290406A
公开(公告)日：1994-03-01
申请号：US899306
申请日：1992-06-16
申请人： Isao Sawamoto , Takayuki Shimamune , Yoshinori Nishiki
发明人： Isao Sawamoto , Takayuki Shimamune , Yoshinori Nishiki
IPC分类号： C01B13/10 , C02F1/467 , C02F1/78 , C25B1/04 , C25B1/13 , C25B1/30 , C25B15/08 , C25B1/00
CPC分类号： C02F1/4672 , C25B1/13 , C02F1/78 , Y02E60/366
摘要： A method for producing ozone which comprises electrolyzing water using a fluororesin-type ion-exchange membrane as a solid electrolyte thereby to generate an ozone-containing gas, and cooling the gas thereby to remove a fluorine-containing substance present in the gas generated.
摘要翻译：一种生产臭氧的方法，其包括使用氟树脂型离子交换膜作为固体电解质电解水，从而产生含臭氧气体，并冷却气体，从而除去所产生的气体中存在的含氟物质。

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