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    • 7. 发明授权
    • Block copolymers and use thereof
    • 嵌段共聚物及其用途
    • US08211576B2
    • 2012-07-03
    • US10573783
    • 2004-09-24
    • Toru OnoderaShigeru SasakiDaizaburo Yashiki
    • Toru OnoderaShigeru SasakiDaizaburo Yashiki
    • B01D71/80C08G65/40C08G75/23
    • H01M8/1058B01D71/80C08G65/40C08G75/23C08J5/2256C08J2371/12H01M4/8605H01M8/1025H01M8/1027H01M8/1032Y10S525/906
    • A block copolymer comprising at least one segment having an acid group which is represented by the following formula (1) and at least one segment substantially free from acid groups which comprises repeating units represented by the following formula (2) is provided: (wherein, m represents an integer of 10 or more, Ar1, Ar2 and Ar3 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms or aryloxy group having 6 to 10 carbon atoms, at least one of Ar1 and Ar2 having an acid group, and Ar3 may have an acid group or may be free from acid groups. Y represents —CO— or —SO2—, and Y's may be different from each other.) (wherein, n represents an integer of 10 or more, Ar4 and Ar5 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, aryloxy group having 6 to 10 carbon atoms or flouro group. Z represents —CO— or —SO2—, and Z's may be different from each other). The block copolymer exerts more excellent performances as the polymer electrolyte in fuel cells and the like.
    • 提供了包含至少一个具有由下式(1)表示的酸基的片段和至少一个基本上不含酸基的片段的嵌段共聚物,该片段包含由下式(2)表示的重复单元:(其中, m表示10以上的整数,Ar 1,Ar 2和Ar 3各自独立地表示任选被具有1〜10个碳原子的烷基,具有1〜10个碳原子的烷氧基,2〜6个碳原子的芳基, 10个碳原子或具有6〜10个碳原子的芳氧基,具有酸基的Ar1和Ar2中的至少一个和Ar3可以具有酸基或可以不含酸基,Y表示-CO-或-SO2-, 并且Y可以彼此不同。)(其中,n表示10以上的整数,Ar 4和Ar 5各自独立地表示任选被具有1〜10个碳原子的烷基取代的二价芳基,烷氧基havi 具有1至10个碳原子,具有6至10个碳原子的芳基,具有6至10个碳原子的芳氧基或氟基。 Z表示-CO-或-SO 2 - ,Z可以彼此不同)。 嵌段共聚物作为燃料电池等中的高分子电解质具有更优异的性能。
    • 8. 发明申请
    • Block copolymers and use thereof
    • 嵌段共聚物及其用途
    • US20070083010A1
    • 2007-04-12
    • US10573783
    • 2004-09-24
    • Toru OnoderaShigeru SasakiDaizaburo Yashiki
    • Toru OnoderaShigeru SasakiDaizaburo Yashiki
    • C08F297/02
    • H01M8/1058B01D71/80C08G65/40C08G75/23C08J5/2256C08J2371/12H01M4/8605H01M8/1025H01M8/1027H01M8/1032Y10S525/906
    • A block copolymer comprising at least one segment having an acid group which is represented by the following formula (1) and at least one segment substantially free from acid groups which comprises repeating units represented by the following formula (2) is provided: (wherein, m represents an integer of 10 or more, Ar1, Ar2 and Ar3 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms or aryloxy group having 6 to 10 carbon atoms, at least one of Ar1 and Ar2 having an acid group, and Ar3 may have an acid group or may be free from acid groups. Y represents —CO— or —SO2—, and Y's may be different from each other.) (wherein, n represents an integer of 10 or more, Ar4 and Ar5 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, aryloxy group having 6 to 10 carbon atoms or fluoro group. Z represents —CO— or —SO2—, and Z's may be different from each other). The block copolymer exerts more excellent performances as the polymer electrolyte in fuel cells and the like.
    • 提供了包含至少一个具有由下式(1)表示的酸基的片段和至少一个基本上不含酸基的片段的嵌段共聚物,该片段包含由下式(2)表示的重复单元:(其中, m表示10以上的整数,Ar 1,Ar 2和Ar 3各自独立地表示任选被 碳原子数1〜10的烷基,碳原子数1〜10的烷氧基,碳原子数6〜10的芳基或碳原子数6〜10的芳氧基,Ar 1〜 具有酸基的Ar 2和Ar 3可以具有酸基或可以不含酸基,Y表示-CO-或-SO 2 (其中,n表示10以上的整数,Ar 4和Ar 5表示各自独立地表示) 二价芳族基团 任选被具有1至10个碳原子的烷基,具有1至10个碳原子的烷氧基,具有6至10个碳原子的芳基,具有6至10个碳原子的芳氧基或氟基团取代。 Z表示-CO-或-SO 2 - ,Z可以彼此不同)。 嵌段共聚物作为燃料电池等中的高分子电解质具有更优异的性能。