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    • 3. 发明申请
    • PROCESS FOR PRODUCING POLYOXYETHYLENE SORBITAN FATTY ACID ESTER
    • 生产聚氧乙烯磺酸脂肪酸酯的方法
    • US20100311996A1
    • 2010-12-09
    • US12864737
    • 2009-01-28
    • Kazuaki WakitaSusumu TanakaKeiichi Maruyama
    • Kazuaki WakitaSusumu TanakaKeiichi Maruyama
    • C07C67/24
    • C08G65/2615A23L27/86C08G65/30
    • An object of the present invention is to provide a process for producing a polyoxyethylene sorbitan fatty acid ester in which the bitterness just after the production is suppressed and also an increase in the bitterness with the lapse of time is suppressed.The process for producing a polyoxyethylene sorbitan fatty acid ester of the invention includes reacting an ester (component A) of a fatty acid having 10 to 22 carbon atoms and a monohydric alcohol having 1 to 3 carbon atoms with at least either (component B) of sorbitol and sorbitan to form a sorbitan fatty acid ester and adding ethylene oxide to the sorbitan fatty acid ester, thereby producing a polyoxyethylene sorbitan fatty acid ester, which is characterized that the following steps (a) to (d) are contained: (a) the component B is provided in the form of a 50 to 90% by weight aqueous solution and mixed with the component A and dehydration was performed until a water content in the system reaches 1.0% by weight or less based on the total weight of the components A and B; (b) 1 to 10% by weight of a monohydric alcohol having 1 to 3 carbon atoms and 0.1 to 1.0% by weight of an alkali catalyst based on the total weight of the components A and B are added at 50 to 90° C.; (c) a transesterification reaction is performed under a nitrogen stream at a reaction temperature of 140 to 190° C. to thereby obtain a sorbitan fatty acid ester; (d) ethylene oxide is added thereto at a reaction temperature of 70 to 130° C.
    • 本发明的目的是提供一种制造聚合物脱水山梨糖醇脂肪酸酯的方法,其中抑制刚刚生产后的苦味,并且抑制了随着时间的流逝而引起的苦味的增加。 本发明的聚氧乙烯脱水山梨糖醇脂肪酸酯的制造方法包括将具有10〜22个碳原子的脂肪酸的酯(A成分)与碳原子数1〜3的一元醇与(B成分) 山梨糖醇酐和脱水山梨糖醇形成山梨糖醇酐脂肪酸酯,并向脱水山梨醇脂肪酸酯中加入环氧乙烷,由此制备聚氧乙烯山梨糖醇酐脂肪酸酯,其特征在于包含以下步骤(a)至(d):(a) 组分B以50至90重量%的水溶液的形式提供并与组分A混合,并进行脱水,直到系统中的水含量基于组分的总重量达到1.0重量%或更少 A和B; (b)在50至90℃下加入1至10重量%的具有1至3个碳原子的一元醇和0.1至1.0重量%的碱催化剂,基于组分A和B的总重量。 ; (c)在氮气流下,在140〜190℃的反应温度下进行酯交换反应,得到脱水山梨醇脂肪酸酯; (d)在70〜130℃的反应温度下加入环氧乙烷
    • 6. 发明授权
    • Process for producing polyoxyethylene sorbitan fatty acid ester
    • 生产聚氧乙烯山梨糖醇酐脂肪酸酯的方法
    • US08334397B2
    • 2012-12-18
    • US12864737
    • 2009-01-28
    • Kazuaki WakitaSusumu TanakaKeiichi Maruyama
    • Kazuaki WakitaSusumu TanakaKeiichi Maruyama
    • C07C51/00
    • C08G65/2615A23L27/86C08G65/30
    • A process for producing a polyoxyethylene sorbitan fatty acid ester in which the bitterness just after the production and the bitterness with the lapse of time is suppressed. The process of the invention includes reacting an ester (component A) of a fatty acid having 10 to 22 carbon atoms and a monohydric alcohol having 1 to 3 carbon atoms with at least either (component B) of sorbitol and sorbitan to form a sorbitan fatty acid ester and adding ethylene oxide to the sorbitan fatty acid ester, thereby producing a polyoxyethylene sorbitan fatty acid ester, which is characterized that the following steps (a) to (d) are contained: (a) the component B is provided in the form of a 50 to 90% by weight aqueous solution and mixed with the component A and dehydration was performed until a water content in the system reaches 1.0% by weight or less based on the total weight of the components A and B; (b) 1 to 10% by weight of a monohydric alcohol having 1 to 3 carbon atoms and 0.1 to 1.0% by weight of an alkali catalyst based on the total weight of the components A and B are added at 50 to 90° C.; (c) a transesterification reaction is performed under a nitrogen stream at a reaction temperature of 140 to 190° C. to thereby obtain a sorbitan fatty acid ester; (d) ethylene oxide is added thereto at a reaction temperature of 70 to 130° C.
    • 制造聚合物脱水山梨糖醇脂肪酸酯的方法,其中刚刚生产后的苦味和经过了时间的苦味被抑制。 本发明的方法包括将具有10-22个碳原子的脂肪酸的酯(组分A)和具有1至3个碳原子的一元醇与山梨糖醇和脱水山梨糖醇中的至少一种(组分B)反应以形成脱水山梨糖醇脂肪 酸酐,并将环氧乙烷加入脱水山梨糖醇脂肪酸酯中,由此制备聚氧乙烯山梨糖醇酐脂肪酸酯,其特征在于包含以下步骤(a)至(d):(a)组分B以 的50〜90重量%的水溶液并与组分A混合,并进行脱水,直到系统中的水含量基于组分A和B的总重量达到1.0重量%或更少; (b)在50至90℃下加入1至10重量%的具有1至3个碳原子的一元醇和0.1至1.0重量%的碱催化剂,基于组分A和B的总重量。 ; (c)在氮气流下,在140〜190℃的反应温度下进行酯交换反应,得到脱水山梨醇脂肪酸酯; (d)在70〜130℃的反应温度下加入环氧乙烷
    • 7. 发明授权
    • Method, server and program product for delivering messages
    • 用于传递消息的方法,服务器和程序产品
    • US07949715B2
    • 2011-05-24
    • US11360968
    • 2006-02-23
    • Keiichi Maruyama
    • Keiichi Maruyama
    • G06F15/16
    • H04L51/00
    • There is provided a method, a system and a program product for delivering on-target messages needed for a user, without omissions. A method for delivering a plurality of delivery messages in a delivery message database to one or more clients, comprising the steps of: delivering one or more delivery messages for a first delivery which are extracted from the delivery message database to at least one of the one or more clients, monitoring reading statuses of each of the one or more delivery messages for the first delivery, generating correlation data indicating a correlation between the plurality of delivery messages based on a result of monitoring the reading statuses, and delivering one or more delivery messages for a second delivery which are not included in the one or more delivery messages for a first delivery and are extracted from the delivery message database based on the correlation data.
    • 提供了一种方法,系统和程序产品,用于提供用户所需的目标消息,而不会有遗漏。 一种用于将传送消息数据库中的多个传递消息递送到一个或多个客户端的方法,包括以下步骤:将从传送消息数据库提取的一个或多个传送消息递送到第一传送消息数据库中的至少一个, 监视所述一个或多个传送消息中的每一个的读取状态以用于所述第一传送;基于监视所述读取状态的结果生成指示所述多个传送消息之间的相关性的相关数据,以及传送一个或多个传送消息 用于第二递送,其不包括在用于第一递送的一个或多个递送消息中,并且基于相关数据从传送消息数据库中提取。
    • 8. 发明申请
    • Method, server and program product for delivering messages
    • 用于传递消息的方法,服务器和程序产品
    • US20070055733A1
    • 2007-03-08
    • US11360968
    • 2006-02-23
    • Keiichi Maruyama
    • Keiichi Maruyama
    • G06F15/16
    • H04L51/00
    • There is provided a method, a system and a program product for delivering on-target messages needed for a user, without omissions. A method for delivering a plurality of delivery messages in a delivery message database to one or more clients, comprising the steps of: delivering one or more delivery messages for a first delivery which are extracted from the delivery message database to at least one of the one or more clients, monitoring reading statuses of each of the one or more delivery messages for the first delivery, generating correlation data indicating a correlation between the plurality of delivery messages based on a result of monitoring the reading statuses, and delivering one or more delivery messages for a second delivery which are not included in the one or more delivery messages for a first delivery and are extracted from the delivery message database based on the correlation data.
    • 提供了一种方法,系统和程序产品,用于提供用户所需的目标消息,而不会有遗漏。 一种用于将传送消息数据库中的多个传递消息递送到一个或多个客户端的方法,包括以下步骤:将从传送消息数据库提取的一个或多个传送消息递送到第一传送消息数据库中的至少一个, 监视所述一个或多个传送消息中的每一个的读取状态以用于所述第一传送;基于监视所述读取状态的结果生成指示所述多个传送消息之间的相关性的相关数据,以及传送一个或多个传送消息 用于第二递送,其不包括在用于第一递送的一个或多个递送消息中,并且基于相关数据从传送消息数据库中提取。