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1. 发明授权

US5321097A Heat-resistant resin composition 失效
标题翻译：耐热树脂组合物
公开(公告)号：US5321097A
公开(公告)日：1994-06-14
申请号：US054194
申请日：1993-04-30
申请人： Takao Kawaki , Akikazu Amagai , Masahiko Ishikawa , Toshiaki Yamada , Yasuhiro Hirai , Hajime Ban
发明人： Takao Kawaki , Akikazu Amagai , Masahiko Ishikawa , Toshiaki Yamada , Yasuhiro Hirai , Hajime Ban
IPC分类号： C08G18/40 , C08G18/64 , C08L79/08 , C08L81/02 , C08L81/04
CPC分类号： C08L79/08 , C08G18/4081 , C08G18/6438 , C08G18/6453 , C08L81/02
摘要： A heat-resistant resin composition comprising a melt-kneaded product of:(A) at least one member selected from the group consisting of a polyamideimide resin precursor composed mainly of a recurring unit of the formula (1)-a, ##STR1## wherein R is a divalent aromatic group or aliphatic group, R.sup.1 is a hydrogen atom, an alkyl group or a phenyl group, and Ar is a trivalent aromatic group composed of at least one six-membered ring, and a polyamideimide resin composed mainly of a recurring unit of the formula (1)-b, ##STR2## wherein R, R.sup.1 and Ar are as defined in the above formula (1)-a, (B) a polyphenylene sulfide resin, and(C) an organic isocyanate compound having at least two isocyanate groups in the molecule, the amount of said organic isocyanate compound being 0.5 to 5 parts by weight based on 100 parts by weight of the total amount of the compounds (A) and (B).
摘要翻译： 1.一种耐热性树脂组合物，其特征在于，含有以下物质的熔融混炼物：（A）选自主要由式（1）-a，（IMAGE）的重复单元组成的组的聚酰胺酰亚胺树脂前体中的至少一种 1）-a其中R是二价芳族基团或脂族基团，R1是氢原子，烷基或苯基，Ar是由至少一个六元环组成的三价芳族基团和聚酰胺酰亚胺树脂主要由式（1）-b，其中R，R 1和Ar如上述式（1）-a定义的重复单元-b，（B）聚苯硫醚树脂，和（C）分子中具有至少两个异氰酸酯基的有机异氰酸酯化合物，所述有机异氰酸酯化合物的量相对于化合物（A）和（A）的总量的100重量份为0.5〜5重量份， B）。

2. 发明授权

US5543474A Resin composition 失效
标题翻译：树脂组成
公开(公告)号：US5543474A
公开(公告)日：1996-08-06
申请号：US318833
申请日：1994-10-17
申请人： Takao Kawaki , Akikazu Amagai , Toshiaki Yamada , Hidefumi Harada , Hajime Ban , Yuji Takeda , Koji Yamamoto
发明人： Takao Kawaki , Akikazu Amagai , Toshiaki Yamada , Hidefumi Harada , Hajime Ban , Yuji Takeda , Koji Yamamoto
IPC分类号： C08L67/02 , C08L79/08 , C08L81/02 , C08L59/02
CPC分类号： C08L67/02 , C08L79/08 , C08L81/02
摘要： There is provided a resin composition having well balanced moldability, heat resistance and mechanical strength, which comprises (A) all aromatic polyamideimide resin and (B) a Polyester resin, (C) a polyphenylene sulfide resin or (D) a resin capable of forming an anisotropic molten phase, said aromatic polyamideimide resin containing 5 to 95 mol % of a recurring unit of the formula (1) and 5 to 95 mol % of at least one of a recurring unit of the formula (2) and a recurring unit of the formula (3). Said aromatic polyamideimide resin is prepared by conducting a polymerization reaction of an aromatic tricarboxylic acid anhydride and at least any one of all aromatic dicarboxylic acid and an aliphatic dicarboxylic acid with a diisocyanate compound in plural steps in which in the first step the polymerization reaction is conducted in a temperature range of 50.degree. to 110.degree. C. and in the second and subsequent steps the polymerization reaction is conducted in a temperature range of higher than 110.degree. C. but not higher than 200.degree. C. ##STR1## wherein Ar denotes a trivalent aromatic group, Ar.sub.1 denotes a divalent aromatic group, R.sub.1 denotes a divalent aliphatic group, and R denotes a divalent aromatic or aliphatic group.
摘要翻译： PCT No.PCT / JP94 / 00232 Sec。 371日期：1994年10月17日 102（e）日期1994年10月17日PCT 1994年2月16日PCT PCT。出版物WO94 / 19410 日本1994年9月1日提供了具有良好平衡的成型性，耐热性和机械强度的树脂组合物，其包含（A）全芳香族聚酰胺酰亚胺树脂和（B）聚酯树脂，（C）聚苯硫醚树脂或（D）能够形成各向异性熔融相的树脂，所述芳香族聚酰胺酰亚胺树脂含有5〜95摩尔％的式（1）的重复单元和5〜95摩尔％的式（2）的重复单元中的至少一种，和式（3）的重复单元。所述芳香族聚酰胺酰亚胺树脂通过芳族三羧酸酐和至少任意一种芳族二羧酸和脂族二羧酸与二异氰酸酯化合物进行多步反应来制备，其中在第一步中进行聚合反应在50〜110℃的温度范围内，在第二和随后的步骤中，聚合反应在高于110℃但不高于200℃的温度范围内进行。（3）其中Ar表示三价芳族基团，Ar 1表示二价芳族基团，R 1表示二价脂肪族基团，R表示二价芳香族或脂肪族基团。

3. 发明授权

US5387652A Resin composition of polyamideimide and polyphenylene sulfide 失效
标题翻译：聚酰胺酰亚胺和聚苯硫醚的树脂组合物
公开(公告)号：US5387652A
公开(公告)日：1995-02-07
申请号：US124642
申请日：1993-09-22
申请人： Takao Kawaki , Akikazu Amagai , Toshiaki Yamada , Hidefumi Harada , Hajime Ban
发明人： Takao Kawaki , Akikazu Amagai , Toshiaki Yamada , Hidefumi Harada , Hajime Ban
IPC分类号： C08G18/34 , C08L79/08 , C08L81/02 , C08L81/04
CPC分类号： C08L79/08 , C08L81/02
摘要： A resin composition comprising a melt-kneaded product of (A) an aromatic polyamideimide resin (Component A) which is obtained by polymerizing an aromatic tricarboxylic acid anhydride and a diisocyanate in a solvent under conditions where an amide group is substantially formed first and then an imide group is formed, and which has at least one recurring unit of the formula (1), ##STR1## wherein Ar is a trivalent aromatic hydrocarbon group having at least one 6-membered carbon ring, and R is a divalent aromatic hydrocarbon group or an aliphatic hydrocarbon group, and (B) a polyphenylene sulfide resin (Component B); and the molded article obtained by molding said resin composition.
摘要翻译：一种树脂组合物，其包含：（A）芳族聚酰胺酰亚胺树脂（组分A）的熔融捏合产物，其通过在溶剂中在首先基本上形成酰胺基的条件下将芳族三羧酸酐和二异氰酸酯进行聚合而得到，酰亚胺基，其具有至少一个式（1）的重复单元，其中Ar是具有至少一个6元碳环的三价芳族烃基，R是二价芳族化合物烃基或脂肪族烃基，（B）聚苯硫醚树脂（B成分）。和通过模制所述树脂组合物而获得的模塑制品。

4. 发明申请

US20110144285A1 RESIN COMPOSITION 审中-公开
标题翻译：树脂组合物
公开(公告)号：US20110144285A1
公开(公告)日：2011-06-16
申请号：US13058498
申请日：2009-08-10
申请人： Toshiaki Yamada , Hajime Ban , Kenichi Yanagisawa
发明人： Toshiaki Yamada , Hajime Ban , Kenichi Yanagisawa
IPC分类号： C08L79/08 , C08L81/04
CPC分类号： C08G18/343 , C08G18/7621 , C08G73/14 , C08L79/08 , C08L81/02 , C08L81/04 , C08L81/00 , C08L2666/20
摘要： The present invention provides a resin composition with favorable melt fluidity, sliding characteristics, toughness, mechanical strength, etc.The present invention is directed to the resin composition containing an aromatic polyamide imide resin (A) that is obtained with the moisture content in the reaction system at 100 to 5000 ppm during the reaction to polymerize an aromatic tricarboxylate anhydride and a diisocyanate and for which the reduced viscosity in N,N-dimethyl acetamide at 30° C. is 0.15 to 0.40 dL/g, and a polyarylene sulfide resin (B).
摘要翻译：本发明提供具有良好的熔体流动性，滑动特性，韧性，机械强度等的树脂组合物。本发明涉及含有芳族聚酰胺酰亚胺树脂（A）的树脂组合物，该树脂组合物是通过反应中的水分含量获得的在聚合芳族三羧酸酐和二异氰酸酯的反应期间为100〜5000ppm的系统，其中N，N-二甲基乙酰胺在30℃下的比浓粘度为0.15〜0.40dL / g，聚芳硫醚树脂（ B）。

5. 发明授权

US07098273B2 Resin composition 失效
标题翻译：树脂组成
公开(公告)号：US07098273B2
公开(公告)日：2006-08-29
申请号：US10871063
申请日：2004-06-21
申请人： Toshiaki Yamada , Hajime Ban , Hiroyuki Kudo
发明人： Toshiaki Yamada , Hajime Ban , Hiroyuki Kudo
IPC分类号： C08L77/00 , C08L79/08
CPC分类号： C08L79/08 , C08K5/372 , C08L77/00 , C08L81/02 , C08L81/04 , C08L81/00 , C08L2666/20
摘要： An object of the present invention is to improve the compatibility of the resin composition comprising the PAI resin and the PAS resin so as to provide a resin composition which is excellent in flowability when molten, strength, tenacity and heat resistance.A resin composition comprising: (1) 5 to 60 parts by weight of aromatic polyamide imide resin (A) having a weight average molecular weight (Mw) of 1,000 to 100,000 and having an amino group in an amount of 0.00002 to 0.002 mol/g in a molecule, (2) 95 to 40 parts by weight of polyarylene sulfide resin (B), and (3) 0.01 to 10 parts by weight of episulfide compound (C) based on 100 parts by weight of the total of (A) and (B).
摘要翻译：本发明的目的是提高包含PAI树脂和PAS树脂的树脂组合物的相容性，以提供当熔融，强度，韧性和耐热性时流动性优异的树脂组合物。 1.一种树脂组合物，其含有：（1）5〜60重量份的重均分子量（Mw）为1,000〜100,000，氨基的量为0.00002〜0.002mol / g的芳香族聚酰胺酰亚胺树脂（A）在分子中，（2）95〜40重量份的聚芳硫醚树脂（B），和（3）0.01〜10重量份的环硫化合物（C），相对于（A）总计100重量份，和（B）。

6. 发明授权

US09315673B2 Insulated ultrafine powder, method for producing same, and high dielectric constant resin composite material 有权
标题翻译：绝缘超细粉末，其制造方法和高介电常数树脂复合材料
公开(公告)号：US09315673B2
公开(公告)日：2016-04-19
申请号：US13386201
申请日：2010-07-09
申请人： Takahiro Matsumoto , Hirotaka Tsuruya , Hajime Ban , Reiki Akita
发明人： Takahiro Matsumoto , Hirotaka Tsuruya , Hajime Ban , Reiki Akita
IPC分类号： C08K5/56 , H01B1/04 , B82Y30/00 , C09C1/56 , C01B31/02 , C08K7/04 , C08K9/04 , H01B3/00 , H05K1/03
CPC分类号： C09C1/56 , B82Y30/00 , C01B32/05 , C01P2004/03 , C01P2004/16 , C01P2004/32 , C01P2004/64 , C01P2006/40 , C08K7/04 , C08K9/04 , H01B3/004 , H05K1/0373 , H05K2201/0239 , H05K2201/0323 , Y10T428/2982
摘要： Provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed and further adding water thereto and a method for producing the same. Also, provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed, further adding a coupling agent having an alkoxide group and then adding water thereto and a method for producing the same. Further, provided is a high dielectric constant resin composite material obtained by blending the insulated ultrafine powder of the present invention with a resin in a volume ratio (insulated ultrafine powder/resin) falling in a range of 5/95 to 50/50.
摘要翻译：提供一种通过将液体金属醇盐加入到其中分散有包含碳材料的导电超细粉末并进一步加入水的含甲醇的有机溶剂中获得的绝缘超微粉及其制备方法。此外，提供了通过将液体金属醇盐添加到其中分散有包含碳材料的导电性超微粉末的含甲醇的有机溶剂中而进一步添加具有醇盐基团的偶联剂然后向其中加入水而获得的绝缘超细粉末，其制造方法此外，提供了通过将本发明的绝缘超细粉末与体积比（绝缘超细粉末/树脂）的树脂混合在5/95至50/50的范围内而获得的高介电常数树脂复合材料。

7. 发明申请

US20120142836A1 INSULATED ULTRAFINE POWDER, METHOD FOR PRODUCING SAME, AND HIGH DIELECTRIC CONSTANT RESIN COMPOSITE MATERIAL 有权
标题翻译：绝缘超细粉，其制造方法和高介电常数树脂复合材料
公开(公告)号：US20120142836A1
公开(公告)日：2012-06-07
申请号：US13386201
申请日：2010-07-09
申请人： Takahiro Matsumoto , Hirotaka Tsuruya , Hajime Ban , Reiki Akita
发明人： Takahiro Matsumoto , Hirotaka Tsuruya , Hajime Ban , Reiki Akita
IPC分类号： C08K5/56 , H01B1/04 , B82Y30/00
CPC分类号： C09C1/56 , B82Y30/00 , C01B32/05 , C01P2004/03 , C01P2004/16 , C01P2004/32 , C01P2004/64 , C01P2006/40 , C08K7/04 , C08K9/04 , H01B3/004 , H05K1/0373 , H05K2201/0239 , H05K2201/0323 , Y10T428/2982
摘要： Provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed and further adding water thereto and a method for producing the same. Also, provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed, further adding a coupling agent having an alkoxide group and then adding water thereto and a method for producing the same. Further, provided is a high dielectric constant resin composite material obtained by blending the insulated ultrafine powder of the present invention with a resin in a volume ratio (insulated ultrafine powder/resin) falling in a range of 5/95 to 50/50.
摘要翻译：提供一种通过将液体金属醇盐加入到其中分散有包含碳材料的导电超细粉末并进一步加入水的含甲醇的有机溶剂中获得的绝缘超微粉及其制备方法。此外，提供了通过将液体金属醇盐添加到其中分散有包含碳材料的导电性超微粉末的含甲醇的有机溶剂中而进一步添加具有醇盐基团的偶联剂然后向其中加入水而获得的绝缘超细粉末，其制造方法此外，提供了通过将本发明的绝缘超细粉末与体积比（绝缘超细粉末/树脂）的树脂混合在5/95至50/50的范围内而获得的高介电常数树脂复合材料。

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