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    • 1. 发明申请
    • HYDROGEN SEPARATION DEVICE AND METHOD FOR OPERATING SAME
    • 氢分离装置及其操作方法
    • US20140271450A1
    • 2014-09-18
    • US14344611
    • 2012-09-12
    • Takao IshikawaKazuhiro Yamamura
    • Takao IshikawaKazuhiro Yamamura
    • C01B3/50
    • C01B3/508B01D65/08B01D71/022B01D2256/16B01D2257/108B01D2311/10C01B3/503C22C5/04C22C27/02C22C30/00H01M8/04955H01M8/0687Y02E60/50
    • It is an objective of the invention to provide a method for operating hydrogen separation devices which is capable of efficiently suppressing hydrogen embrittlement in a hydrogen separation alloy membrane and to provide a hydrogen separation device that performs favorably during repeated starting/stopping operations thereof. There is provided a method for operating a hydrogen separation device for separating hydrogen from a mixture hydrogen gas using a membrane separation technique with a hydrogen separation alloy membrane. The method comprises the successive steps of: stopping supply of the mixture hydrogen gas to the hydrogen separation alloy membrane with a temperature of the membrane within a range from 300 to 600° C.; supplying an oxidizing gas over a predetermined duration to at least an upstream side of the membrane with a temperature of the membrane within a range from 300 to 600° C.; and lowering the temperature of the membrane to below 200° C.
    • 本发明的目的是提供一种操作氢分离装置的方法,其能够有效地抑制氢分离合金膜中的氢脆化,并提供在其重复的起动/停止操作期间有利地执行的氢分离装置。 提供了一种使用具有氢分离合金膜的膜分离技术来操作氢分离装置用于从氢气混合物中分离氢的方法。 该方法包括以下连续步骤:在300〜600℃的范围内,停止向氢分离合金膜供给混合氢气。 将膜的温度在300-600℃的范围内,将预定时间内的氧化气体供给到膜的至少上游侧; 并将膜的温度降低到200℃以下。
    • 8. 发明申请
    • HYDROGEN SEPARATION ALLOY AND METHOD FOR PRODUCING SAME
    • 氢分离合金及其生产方法
    • US20120138196A1
    • 2012-06-07
    • US13389618
    • 2011-05-31
    • Kazuhiro YamamuraMasahiro Tobise
    • Kazuhiro YamamuraMasahiro Tobise
    • C22F1/18C22C27/02
    • B01D71/022B01D67/0074B01D2323/12B01D2325/04C01B3/503C01B3/505C22C27/02C22F1/00C22F1/16C22F1/18
    • Disclosed is a hydrogen separation alloy which is adoptable to a product having a large surface area of a side where hydrogen permeates and which has such a metallographic structure as to improve hydrogen permeability and to improve hydrogen-embrittlement resistance. The hydrogen separation alloy used herein is represented by the compositional formula: Nb100−(α+β)M1αM2β where M1 is at least one element selected from the group consisting of Ti, Zr and Hf; M2 is at least one element selected from the group consisting of Ni, Co, Cr, Fe, Cu and Zn; 10≦α≦60, 10≦β≦50, and α+β≦80. The alloy contains inevitable impurities. And the alloy includes two phases, i.e., an Nb-M1 phase serving as a hydrogen-permeable phase, and a M2-M1 phase serving as a hydrogen-embrittlement-resistant phase. The hydrogen-permeable phase and the hydrogen-embrittlement-resistant phase have an elongated structure resulting from rolling. The hydrogen-permeable phase occupies 35% to 70% of an arbitrary 10 μm×10 μm region in a 50 μm×50 μm observation plane of a cross section of the alloy under an electron microscopic observation, the cross section is taken in a direction of thickness reduced by the rolling and in a direction of rolling and flattening.
    • 公开了一种氢分离合金,其可以用于氢渗透的一侧的大表面积的产品,并且具有提高氢渗透性和提高耐氢脆性的金相组织。 本文使用的氢分离合金由组成式表示:Nb100-(α+&bgr;)M1αM2&bgr; 其中M1是选自Ti,Zr和Hf中的至少一种元素; M2是选自Ni,Co,Cr,Fe,Cu和Zn中的至少一种元素; 10≦̸α≦̸ 60,10和nlE;&bgr;≦̸ 50和α+&bgr;≦̸ 80。 该合金含有不可避免的杂质。 该合金包括两相,即用作氢可渗透相的Nb-M1相和用作耐氢脆相的M2-M1相。 氢渗透相和耐氢脆相具有由轧制产生的细长结构。 在电子显微镜观察的合金的截面的50μm×50μm的观察平面中,氢渗透相占据任意10μm×10μm的任意的10μm×10μm的35%〜70%,横截面为 的厚度通过轧制和轧制和扁平化的方向减小。
    • 10. 发明授权
    • Hydrogen separation alloy and method for producing same
    • 氢分离合金及其制造方法
    • US09266071B2
    • 2016-02-23
    • US13389618
    • 2011-05-31
    • Kazuhiro YamamuraMasahiro Tobise
    • Kazuhiro YamamuraMasahiro Tobise
    • C22C27/02B01D71/02B01D67/00C22F1/00C22F1/16C22F1/18C01B3/50
    • B01D71/022B01D67/0074B01D2323/12B01D2325/04C01B3/503C01B3/505C22C27/02C22F1/00C22F1/16C22F1/18
    • Disclosed is a hydrogen separation alloy which is adoptable to a product having a large surface area of a side where hydrogen permeates and which has such a metallographic structure as to improve hydrogen permeability and to improve hydrogen-embrittlement resistance. The hydrogen separation alloy used herein is represented by the compositional formula: Nb100−(α+β)M1αM2β where M1 is at least one element selected from the group consisting of Ti, Zr and Hf; M2 is at least one element selected from the group consisting of Ni, Co, Cr, Fe, Cu and Zn; 10≦α≦60, 10≦β≦50, and α+β≦80. The alloy contains inevitable impurities. And the alloy includes two phases, i.e., an Nb-M1 phase serving as a hydrogen-permeable phase, and a M2-M1 phase serving as a hydrogen-embrittlement-resistant phase. The hydrogen-permeable phase and the hydrogen-embrittlement-resistant phase have an elongated structure resulting from rolling. The hydrogen-permeable phase occupies 35% to 70% of an arbitrary 10 μm×10 μm region in a 50 μm×50 μm observation plane of a cross section of the alloy under an electron microscopic observation, the cross section is taken in a direction of thickness reduced by the rolling and in a direction of rolling and flattening.
    • 公开了一种氢分离合金,其可以用于氢渗透的一侧的大表面积的产品,并且具有提高氢渗透性和提高耐氢脆性的金相组织。 本文使用的氢分离合金由组成式表示:Nb100-(α+&bgr;)M1αM2&bgr; 其中M1是选自Ti,Zr和Hf中的至少一种元素; M2是选自Ni,Co,Cr,Fe,Cu和Zn中的至少一种元素; 10≦̸α≦̸ 60,10和nlE;&bgr;≦̸ 50和α+&bgr;≦̸ 80。 该合金含有不可避免的杂质。 该合金包括两相,即用作氢可渗透相的Nb-M1相和用作耐氢脆相的M2-M1相。 氢渗透相和耐氢脆相具有由轧制产生的细长结构。 在电子显微镜观察的合金的截面的50μm×50μm的观察平面中,氢渗透相占据任意10μm×10μm的任意的10μm×10μm的35%〜70%,横截面为 的厚度通过轧制和轧制和扁平化的方向减小。