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1. 发明申请

US20060009579A1 Sealing composition for liquid crystal displays and process for production of liquid crystal display panels 有权
标题翻译：用于液晶显示器的密封组合物和制造液晶显示面板的方法
公开(公告)号：US20060009579A1
公开(公告)日：2006-01-12
申请号：US10528196
申请日：2003-09-19
申请人： Takahisa Miyawaki , Yasushi Mizuta , Fumito Takeuchi , Kenji Itou , Tadashi Kitamura , Hiroyuki Asakura , Kenichi yashiro , Kei Nagata
发明人： Takahisa Miyawaki , Yasushi Mizuta , Fumito Takeuchi , Kenji Itou , Tadashi Kitamura , Hiroyuki Asakura , Kenichi yashiro , Kei Nagata
IPC分类号： C08G59/00 , B32B37/00
CPC分类号： C08G59/18 , C08F283/10 , G02F1/1339
摘要： A liquid crystal sealing agent composition that is a one-component light and heat-curable resin composition containing: (1) a solid epoxy resin having a ring and ball method softening temperature of 40° C. or above; (2) an acrylate monomer and/or a methacrylate monomer, or an oligomer thereof; (3) a thermoplastic polymer having a ring and ball method softening temperature of 50 to 120° C., the thermoplastic polymer being obtained by copolymerizing an acrylate monomer and/or a methacrylate monomer with a monomer copolymerizable therewith; (4) a light-activated radical polymerization initiator; and (5) a latent epoxy curing agent. The light and heat curable liquid crystal sealing agent composition is employable in one drop fill, is excellent in properties of a cured product particularly after first-stage light curing, achieves stable cell gap after cell gap formation, permits prevention of contamination of the liquid crystal in second-stage heat curing, is excellent in curing properties in shaded area, and shows superior bonding reliability.
摘要翻译：一种液晶密封剂组合物，其是单组分的光热可固化树脂组合物，其包含：（1）环球法软化温度为40℃以上的固体环氧树脂; （2）丙烯酸酯单体和/或甲基丙烯酸酯单体或其低聚物; （3）具有环球法软化温度为50〜120℃的热塑性聚合物，所述热塑性聚合物通过使丙烯酸酯单体和/或甲基丙烯酸酯单体与可共聚合的单体共聚而得到; （4）光活化自由基聚合引发剂; 和（5）潜在环氧固化剂。光热固化型液晶密封剂组合物可以在一个滴液填充中使用，特别是在第一阶段光固化之后，固化产物的性能优异，在电池间隙形成之后实现稳定的电池间隙，可以防止液晶的污染在第二阶段热固化中，阴影区域的固化性优异，粘接可靠性优异。

2. 发明授权

US07566377B2 Liquid crystal sealing agent composition and manufacturing method of liquid crystal display panel using the same 有权
标题翻译：液晶密封剂组成及其制造方法采用液晶显示面板
公开(公告)号：US07566377B2
公开(公告)日：2009-07-28
申请号：US10528196
申请日：2003-09-19
申请人： Takahisa Miyawaki , Yasushi Mizuta , Fumito Takeuchi , Kenji Itou , Tadashi Kitamura , Hiroyuki Asakura , Kenichi Yashiro , Kei Nagata
发明人： Takahisa Miyawaki , Yasushi Mizuta , Fumito Takeuchi , Kenji Itou , Tadashi Kitamura , Hiroyuki Asakura , Kenichi Yashiro , Kei Nagata
IPC分类号： B32B38/04 , C08L63/00
CPC分类号： C08G59/18 , C08F283/10 , G02F1/1339
摘要： A liquid crystal sealing agent composition that is a one-component light and heat-curable resin composition containing: (1) a solid epoxy resin having a ring and ball method softening temperature of 40° C. or above; (2) an acrylate monomer and/or a methacrylate monomer, or an oligomer thereof; (3) a thermoplastic polymer having a ring and ball method softening temperature of 50 to 120° C., the thermoplastic polymer being obtained by copolymerizing an acrylate monomer and/or a methacrylate monomer with a monomer copolymerizable therewith; (4) a light-activated radical polymerization initiator; and (5) a latent epoxy curing agent. The light and heat curable liquid crystal sealing agent composition is employable in one drop fill, is excellent in properties of a cured product particularly after first-stage light curing, achieves stable cell gap after cell gap formation, permits prevention of contamination of the liquid crystal in second-stage heat curing, is excellent in curing properties in shaded area, and shows superior bonding reliability.
摘要翻译：一种液晶密封剂组合物，其是单组分的光热可固化树脂组合物，其包含：（1）环球法软化温度为40℃以上的固体环氧树脂; （2）丙烯酸酯单体和/或甲基丙烯酸酯单体或其低聚物; （3）具有环球法软化温度为50〜120℃的热塑性聚合物，所述热塑性聚合物通过使丙烯酸酯单体和/或甲基丙烯酸酯单体与可共聚合的单体共聚而得到; （4）光活化自由基聚合引发剂; 和（5）潜在环氧固化剂。光热固化型液晶密封剂组合物可以在一个滴液填充中使用，特别是在第一阶段光固化之后，固化产物的性能优异，在电池间隙形成之后实现稳定的电池间隙，可以防止液晶的污染在第二阶段热固化中，阴影区域的固化性优异，粘接可靠性优异。

3. 发明申请

US20070096056A1 One component resin composition curable with combination of light and heat and use of the same 审中-公开
标题翻译：通过光和热的组合可固化的单组分树脂组合物及其用途
公开(公告)号：US20070096056A1
公开(公告)日：2007-05-03
申请号：US10580852
申请日：2004-11-25
申请人： Fumito Takeuchi , Takahisa Miyawaki , Kenji Itou , Kenichi Yashiro , Kei Nagata , Souta Itou , Tazo Ikeguchi , Nobuo Sasaki , Makoto Nakahara
发明人： Fumito Takeuchi , Takahisa Miyawaki , Kenji Itou , Kenichi Yashiro , Kei Nagata , Souta Itou , Tazo Ikeguchi , Nobuo Sasaki , Makoto Nakahara
IPC分类号： C09K19/52
CPC分类号： C08F283/10 , C08G59/18 , C08L51/08 , G03F7/0007 , G03F7/027 , G03F7/038 , C08L2666/02
摘要： A one component resin composition curable with a combination of light and heat, which comprises (1) an epoxy resin, (2) an acrylic ester monomer and/or methacrylic ester monomer, or an oligomer thereof, (3) a latent epoxy curing agent, (4) a photo radical initiator, and (5) a compound having two or more thiol groups per molecule, wherein the ingredient (5) is contained in an amount of 0.001 to 5.0 parts by weight per 100 parts by weight of this resin composition. According to the present invention, a one component resin composition curable with a combination of light and heat, which has excellent curability especially in a light-shielded area can be provided. Also, a liquid crystal sealant composition curable with a combination of light and heat, which is applicable to the one-drop-fill method and has excellent curability in light-shielded areas and adhesion reliability, especially high-temperature and high-humidity adhesion reliability, can be provided.
摘要翻译：包含（1）环氧树脂，（2）丙烯酸酯单体和/或甲基丙烯酸酯单体或其低聚物的可光聚合组合的单组分树脂组合物，（3）潜在环氧固化剂，（4）光自由基引发剂，和（5）每分子具有两个以上硫醇基的化合物，其中成分（5）的含量相对于该树脂100重量份为0.001〜5.0重量份组成。根据本发明，可以提供特别是在遮光区域中具有优异固化性的组合可热固化的单组分树脂组合物。另外，适用于一滴填充法而且在遮光区域具有优异的固化性和粘合可靠性，尤其是高温高湿粘合可靠性的光和热组合可固化的液晶密封剂组合物，可以提供。

4. 发明申请

US20100022745A1 ONE COMPONENT RESIN COMPOSITION CURABLE WITH COMBINATION OF LIGHT AND HEAT AND USE OF THE SAME 审中-公开
标题翻译：一种组分树脂组合物，可与光和热的组合固化并使用它们
公开(公告)号：US20100022745A1
公开(公告)日：2010-01-28
申请号：US12572420
申请日：2009-10-02
申请人： Fumito Takeuchi , Takahisa Miyawaki , Kenji Itou , Kenichi Yashiro , Kei Nagata , Souta Itou , Tazo Ikeguchi , Nobuo Sasaki , Makoto Nakahara
发明人： Fumito Takeuchi , Takahisa Miyawaki , Kenji Itou , Kenichi Yashiro , Kei Nagata , Souta Itou , Tazo Ikeguchi , Nobuo Sasaki , Makoto Nakahara
IPC分类号： C08G65/04
CPC分类号： C08F283/10 , C08G59/18 , C08L51/08 , G03F7/0007 , G03F7/027 , G03F7/038 , C08L2666/02
摘要： A one component resin composition curable with a combination of light and heat, which comprises (1) an epoxy resin, (2) an acrylic ester monomer and/or methacrylic ester monomer, or an oligomer thereof, (3) a latent epoxy curing agent, (4) a photo radical initiator, and (5) a compound having two or more thiol groups per molecule, wherein the ingredient (5) is contained in an amount of 0.001 to 5.0 parts by weight per 100 parts by weight of this resin composition. According to the present invention, a one component resin composition curable with a combination of light and heat, which has excellent curability especially in a light-shielded area can be provided. Also, a liquid crystal sealant composition curable with a combination of light and heat, which is applicable to the one-drop-fill method and has excellent curability in light-shielded areas and adhesion reliability, especially high-temperature and high-humidity adhesion reliability, can be provided.
摘要翻译：包含（1）环氧树脂，（2）丙烯酸酯单体和/或甲基丙烯酸酯单体或其低聚物的可光聚合组合的单组分树脂组合物，（3）潜在环氧固化剂，（4）光自由基引发剂，和（5）每分子具有两个以上硫醇基的化合物，其中成分（5）的含量相对于该树脂100重量份为0.001〜5.0重量份组成。根据本发明，可以提供特别是在遮光区域中具有优异固化性的组合可热固化的单组分树脂组合物。另外，可以适用于一滴填充法并且在遮光区域中具有优异的固化性和粘合可靠性，特别是高温高湿附着可靠性的光和热组合可固化的液晶密封剂组合物，可以提供。

5. 发明申请

US20090173438A1 PHOTOCURABLE RESIN COMPOSITION CONTAINING ANTHRAQUINONE DERIVATIVE 有权
标题翻译：含有蒽醌衍生物的光催化树脂组合物
公开(公告)号：US20090173438A1
公开(公告)日：2009-07-09
申请号：US12159130
申请日：2006-12-25
申请人： Fumito Takeuchi , Yasushi Mizuta
发明人： Fumito Takeuchi , Yasushi Mizuta
IPC分类号： B32B37/12 , C08F220/38 , C09J133/04 , C07C69/52
CPC分类号： G02F1/1339 , C07C323/22 , C07C2603/24 , C08F220/38
摘要： Disclosed is a photocurable resin composition which is highly sensitive to ultraviolet light or visible light having a long wavelength, in particular a photocurable resin composition which is useful as a sealing agent. Specifically disclosed is a photocurable resin composition containing a component (a) which is composed of an anthraquinone derivative represented by the formula (I) below, and a component (b) which is composed of a compound having a (meth)acryloyl group in the molecule. The photocurable resin composition is characterized in that a part or the entire of the component (b) further contains an oxiranyl group in the molecule, and the component (a) content is 0.01-10% by mass relative to the component (b) content. [chemical formula 1] (I) (In the formula (I), X represents a phenyl group, an alkyl group having 1-8 carbon atoms, an alcoholic form of the phenyl group or the alkyl group, or a derivative of the alcoholic form.)
摘要翻译：公开了对紫外线或长波长的可见光高度敏感的光固化性树脂组合物，特别是可用作密封剂的光固化性树脂组合物。具体公开了含有由下述通式（I）表示的蒽醌衍生物构成的成分（a）的组分（a）的组分（b），由（甲基）丙烯酰基的化合物分子。光固化性树脂组合物的特征在于，成分（b）的一部分或全部在分子中还含有环氧乙烷基，成分（a）相对于成分（b）含量为0.01〜10质量％。 [化学式1]（I）（式（I）中，X表示苯基，碳原子数为1〜8的烷基，苯基或烷基的醇类或醇的衍生物形成。）

6. 发明授权

US07892388B2 Photocurable resin composition containing anthraquinone derivative 有权
标题翻译：含有蒽醌衍生物的光固化树脂组合物
公开(公告)号：US07892388B2
公开(公告)日：2011-02-22
申请号：US12159130
申请日：2006-12-25
申请人： Fumito Takeuchi , Yasushi Mizuta
发明人： Fumito Takeuchi , Yasushi Mizuta
IPC分类号： B32B37/12 , C08F220/38 , C09J133/04 , C07C69/52
CPC分类号： G02F1/1339 , C07C323/22 , C07C2603/24 , C08F220/38
摘要： Disclosed is a photocurable resin composition which is highly sensitive to ultraviolet light or visible light having a long wavelength, in particular a photocurable resin composition which is useful as a sealing agent. Specifically disclosed is a photocurable resin composition containing a component (a) which is composed of an anthraquinone derivative represented by the formula (I) below, and a component (b) which is composed of a compound having a (meth)acryloyl group in the molecule. The photocurable resin composition is characterized in that a part or the entire of the component (b) further contains an oxiranyl group in the molecule, and the component (a) content is 0.01-10% by mass relative to the component (b) content. [chemical formula 1] (I) (In the formula (I), X represents a phenyl group, an alkyl group having 1-8 carbon atoms, an alcoholic form of the phenyl group or the alkyl group, or a derivative of the alcoholic form.)
摘要翻译：公开了对紫外线或长波长的可见光高度敏感的光固化性树脂组合物，特别是可用作密封剂的光固化性树脂组合物。具体公开了含有由下述通式（I）表示的蒽醌衍生物构成的成分（a）的组分（a）的组分（b），由（甲基）丙烯酰基的化合物分子。光固化性树脂组合物的特征在于，成分（b）的一部分或全部在分子中还含有环氧乙烷基，成分（a）相对于成分（b）含量为0.01〜10质量％。 [化学式1]（I）（式（I）中，X表示苯基，碳原子数为1〜8的烷基，苯基或烷基的醇类或醇的衍生物形成。）

7. 发明授权

US09349895B2 Encapsulating material for solar cell and solar cell module 有权
标题翻译：太阳能电池和太阳能电池组件封装材料
公开(公告)号：US09349895B2
公开(公告)日：2016-05-24
申请号：US13882218
申请日：2011-10-31
申请人： Shigenobu Ikenaga , Fumito Takeuchi , Keiji Watanabe , Tomoaki Ito
发明人： Shigenobu Ikenaga , Fumito Takeuchi , Keiji Watanabe , Tomoaki Ito
IPC分类号： H01L31/048 , C08F210/16 , C08L23/08 , C09D123/08 , C08K5/14 , C08K5/5425 , C08L23/26
CPC分类号： H01L31/0481 , C08F210/16 , C08K5/14 , C08K5/5425 , C08L23/0815 , C08L2023/40 , C08L2023/42 , C08L2203/204 , C08L2205/025 , C09D123/0815 , Y02E10/50 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F210/14
摘要： An encapsulating material for solar cell excellent in a balance among properties including transparency, flexibility, adhesiveness, heat resistance, appearance, crosslinking properties, electrical properties and calender moldability. The encapsulating material includes an ethylene/α-olefin copolymer satisfying the following requirements: (a1) the content ratio of structural units derived from ethylene is from 80 to 90 mol % and the content ratio of structural units derived from α-olefin having 3 to 20 carbon atoms is from 10 to 20 mol %; (a2) MFR is equal to or more than 2 g/10 minutes and less than 10 g/10 minutes as measured under the conditions of a temperature of 190 degrees centigrade and a load of 2.16 kg in accordance with ASTM D1238; (a3) the density is from 0.865 to 0.884 g/cm3 as measured in accordance with ASTM D1505; and (a4) the shore A hardness is from 60 to 85 as measured in accordance with ASTM D2240.
摘要翻译：用于太阳能电池的封装材料在透明性，柔性，粘合性，耐热性，外观，交联性能，电性能和压延成型性等性能之间的平衡优异。包封材料包括满足以下要求的乙烯/α-烯烃共聚物：（a1）由乙烯衍生的结构单元的含量比为80〜90摩尔％，来自α-烯烃的结构单元的含量比为3〜 20个碳原子为10〜20摩尔％。（a2）根据ASTM D1238在190℃的温度和2.16kg的负荷条件下测量的MFR等于或大于2g / 10分钟且小于10g / 10分钟; （a3）根据ASTM D1505测量，密度为0.865至0.884g / cm 3; 和（a4）根据ASTM D2240测量的肖氏A硬度为60至85。

8. 发明授权

US08945701B2 Ethylene resin composition, sealing material for solar cell, and solar cell module utilizing the sealing material 有权
标题翻译：乙烯树脂组合物，太阳能电池用密封材料和利用密封材料的太阳能电池组件
公开(公告)号：US08945701B2
公开(公告)日：2015-02-03
申请号：US13375771
申请日：2010-05-31
申请人： Shigenobu Ikenaga , Takashi Hakuta , Kazuhiro Yarimizu , Hiroshi Mori , Takanobu Murofushi , Hirofumi Zenkoh , Jun Tokuhiro , Fumito Takeuchi
发明人： Shigenobu Ikenaga , Takashi Hakuta , Kazuhiro Yarimizu , Hiroshi Mori , Takanobu Murofushi , Hirofumi Zenkoh , Jun Tokuhiro , Fumito Takeuchi
IPC分类号： H01L31/048 , B32B3/30 , B32B27/32 , C08F10/02 , C08L23/08 , C08L23/26 , C08F255/02 , C08L51/06 , C08K5/00 , C08K5/5425
CPC分类号： C08L23/26 , B32B2457/12 , C08F255/02 , C08K5/005 , C08K5/5425 , C08L51/06 , H01L31/0481 , Y02E10/50 , Y10T428/24504 , C08F230/08
摘要： An ethylene resin composition is provided which has excellent properties including adhesion properties, electrically insulating properties, transparency, moldability and process stability and can be produced without requiring any cross-linking procedure if necessary to improve productivity; and others. The ethylene resin composition contains a modified product produced by modifying an ethylene polymer (A) that meets all of the requirements a) to e) mentioned below with an ethylenically unsaturated silane compound (B). a) The density is 900 to 940 kg/m3. b) The melting peak temperature is 90 to 125 ° C. as determined by DSC. c) The melt flow rate (MFR2) is 0.1 to 100 g/10 minutes as measured at 190 ° C. and a load of 2.16 kg in accordance with JIS K-6721. d) The Mw/Mn ratio is 1.2 to 3.5. e) The content of metal residues is 0.1 to 50 ppm.
摘要翻译：提供一种乙烯树脂组合物，其具有优异的性能，包括粘合性能，电绝缘性能，透明性，成型性和工艺稳定性，并且如果需要，可以生产而不需要任何交联程序来提高生产率; 和别的。乙烯树脂组合物含有通过用烯键式不饱和硅烷化合物（B）改性满足下述所有a）至e）的乙烯聚合物（A）而制备的改性产物。 a）密度为900至940 kg / m3。 b）通过DSC测定，熔融峰温度为90至125℃。 c）根据JIS K-6721，190℃下的熔体流动速率（MFR 2）为0.1〜100g / 10分钟，负荷为2.16kg。 d）Mw / Mn比为1.2〜3.5。 e）金属残留物的含量为0.1〜50ppm。

9. 发明申请

US20120073631A1 ETHYLENE RESIN COMPOSITION, SEALING MATERIAL FOR SOLAR CELL, AND SOLAR CELL MODULE UTILIZING THE SEALING MATERIAL 有权
标题翻译：乙烯树脂组合物，太阳能电池密封材料和利用密封材料的太阳能电池模块
公开(公告)号：US20120073631A1
公开(公告)日：2012-03-29
申请号：US13375771
申请日：2010-05-31
申请人： Shigenobu Ikenaga , Takashi Hakuta , Kazuhiro Yarimizu , Hiroshi Mori , Takanobu Murofushi , Hirofumi Zenkoh , Jun Tokuhiro , Fumito Takeuchi
发明人： Shigenobu Ikenaga , Takashi Hakuta , Kazuhiro Yarimizu , Hiroshi Mori , Takanobu Murofushi , Hirofumi Zenkoh , Jun Tokuhiro , Fumito Takeuchi
IPC分类号： H01L31/048 , B32B3/30 , B32B27/32 , C08F10/02 , C08L23/08
CPC分类号： C08L23/26 , B32B2457/12 , C08F255/02 , C08K5/005 , C08K5/5425 , C08L51/06 , H01L31/0481 , Y02E10/50 , Y10T428/24504 , C08F230/08
摘要： The purpose of the present invention is to provide an ethylene resin composition which has excellent properties including adhesion properties, electrically insulating properties, transparency, moldability and process stability and can be produced without requiring any cross-linking procedure if necessary to improve productivity; and others. The ethylene resin composition contains a modified product produced by modifying an ethylene polymer (A) that meets all of the requirements a) to e) mentioned below with an ethylenically unsaturated silane compound (B). a) The density is 900 to 940 kg/m3. b) The melting peak temperature is 90 to 125 DEG C as determined by DSC. c) The melt flow rate (MFR2) is 0.1 to 100 g/10 minutes as measured at 190° C. and a load of 2.16 kg in accordance with JIS K-6721. d) The Mw/Mn ratio is 1.2 to 3.5. e) The content of metal residues is 0.1 to 50 ppm.
摘要翻译：本发明的目的是提供一种乙烯树脂组合物，其具有优异的性能，包括粘合性，电绝缘性，透明性，成型性和工艺稳定性，并且如果需要，可以制备而不需要任何交联方法来提高生产率; 和别的。乙烯树脂组合物含有通过用烯键式不饱和硅烷化合物（B）改性满足下述所有a）至e）的乙烯聚合物（A）而制备的改性产物。 a）密度为900至940 kg / m3。 b）通过DSC测定，熔融峰温度为90〜125℃。 c）根据JIS K-6721，190℃下的熔体流动速率（MFR 2）为0.1〜100g / 10分钟，负荷为2.16kg。 d）Mw / Mn比为1.2〜3.5。 e）金属残留物的含量为0.1〜50ppm。

10. 发明授权

US09595630B2 Solar cell sealing material, method for manufacturing solar cell sealing material, and solar cell module 有权
标题翻译：太阳能电池密封材料，太阳能电池密封材料的制造方法以及太阳能电池组件
公开(公告)号：US09595630B2
公开(公告)日：2017-03-14
申请号：US14239143
申请日：2012-08-16
申请人： Shigenobu Ikenaga , Fumito Takeuchi , Keiji Watanabe , Tomoaki Ito
发明人： Shigenobu Ikenaga , Fumito Takeuchi , Keiji Watanabe , Tomoaki Ito
IPC分类号： H01L31/0203 , H01L31/18 , C08K5/14 , H01L31/048 , C09D123/08 , C08K5/5425
CPC分类号： H01L31/18 , C08K5/14 , C08K5/5425 , C08L2312/00 , C08L2312/08 , C09D123/0815 , H01L31/0481 , H01L31/0488 , Y02E10/50 , C08F210/16 , C08F2/44 , C08F210/08 , C08F2500/11 , C08L23/0815
摘要： An encapsulating material for solar cell containing an ethylene/α-olefin copolymer satisfying the following a1) and a2), and a specific peroxyketal having a 1-hour half-life temperature in a range of 100 to 135 degrees centigrade; the peroxyketal being contained in an amount of 0.1 to less than 0.8 weight parts relative to 100 weight parts of the ethylene/α-olefin copolymer. a1) the shore A hardness is from 60 to 85 as measured in accordance with ASTM D2240. a2) MFR is from 2 to 50 g/10 minutes as measured under the conditions of a temperature of 190 degrees centigrade and a load of 2.16 kg in accordance with ASTM D1238.
摘要翻译：一种含有满足以下a1）和a2）的乙烯/α-烯烃共聚物的太阳能电池用封装材料，具有1小时半衰期温度在100〜135℃范围内的特定的过氧化缩酮; 相对于100重量份的乙烯/α-烯烃共聚物，过氧化缩酮的含量为0.1至小于0.8重量份。 a1）根据ASTM D2240测量，岸A硬度为60至85。 a2）根据ASTM D1238，在190℃的温度和2.16kg的负荷条件下测量，MFR为2至50g / 10分钟

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