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    • 1. 发明授权
    • Toner, developing device, image forming apparatus, and image forming method using the toner
    • 调色剂,显影装置,图像形成装置和使用调色剂的图像形成方法
    • US07638250B2
    • 2009-12-29
    • US11685838
    • 2007-03-14
    • Takahiro HondaHiroyuki FushimiOsamu Uchinokura
    • Takahiro HondaHiroyuki FushimiOsamu Uchinokura
    • G03G9/08
    • G03G9/08795G03G9/08755G03G9/08786G03G9/08797G03G9/09725G03G9/0975
    • A toner is provided including a colorant; a binder resin (A) which is a polyester resin having no tetrahydrofuran insoluble component, and having a molecular weight distribution such that components having a molecular weight of not greater than 500 are included in an amount of not greater than 4% by weight and a peak is present in a molecular weight range of from 3,000 to 9,000 when measured by gel permeation chromatography (GPC); and a binder resin (B) which is a polyester resin having no tetrahydrofuran insoluble component, and including units of a polycarboxylic acid and a diol having the specific formula; wherein at least one of the binder resins (A) and (B) is prepared in the presence of the specific titanium-containing catalyst, and wherein a weight ratio ((A)/(B)) of the binder resin (A) to the binder resin (B) is from 60/40 to 85/15.
    • 提供了包括着色剂的调色剂; 作为不具有四氢呋喃不溶成分的聚酯树脂的粘合剂树脂(A),其分子量分布使得分子量不大于500的组分的含量不大于4重量%,并且 当通过凝胶渗透色谱(GPC)测量时,峰存在于3,000至9,000的分子量范围内; 和不含四氢呋喃不溶成分的聚酯树脂的粘合剂树脂(B),具有上述具体结构的多元羧酸和二醇的单元; 其中,所述粘合剂树脂(A)和(B)中的至少一种在所述特定的含钛催化剂的存在下制备,并且其中所述粘合剂树脂(A)的重量比((A)/(B)) 粘合剂树脂(B)为60/40〜85/15。
    • 2. 发明申请
    • TONER, DEVELOPING DEVICE, IMAGE FORMING APPARATUS, AND IMAGE FORMING METHOD USING THE TONER
    • 调色剂,显影装置,图像形成装置和使用色调剂的图像形成方法
    • US20070218389A1
    • 2007-09-20
    • US11685838
    • 2007-03-14
    • Takahiro HondaHiroyuki FushimiOsamu Uchinokura
    • Takahiro HondaHiroyuki FushimiOsamu Uchinokura
    • G03G9/08
    • G03G9/08795G03G9/08755G03G9/08786G03G9/08797G03G9/09725G03G9/0975
    • A toner is provided including a colorant; a binder resin (A) which is a polyester resin having no tetrahydrofuran insoluble component, and having a molecular weight distribution such that components having a molecular weight of not greater than 500 are included in an amount of not greater than 4% by weight and a peak is present in a molecular weight range of from 3,000 to 9,000 when measured by gel permeation chromatography (GPC); and a binder resin (B) which is a polyester resin having no tetrahydrofuran insoluble component, and including units of a polycarboxylic acid and a diol having the specific formula; wherein at least one of the binder resins (A) and (B) is prepared in the presence of the specific titanium-containing catalyst, and wherein a weight ratio ((A)/(B)) of the binder resin (A) to the binder resin (B) is from 60/40 to 85/15.
    • 提供了包括着色剂的调色剂; 作为不具有四氢呋喃不溶成分的聚酯树脂的粘合剂树脂(A),其分子量分布使得分子量不大于500的组分的含量不大于4重量%,并且 当通过凝胶渗透色谱(GPC)测量时,峰存在于3,000至9,000的分子量范围内; 和不含四氢呋喃不溶成分的聚酯树脂的粘合剂树脂(B),具有上述具体结构的多元羧酸和二醇的单元; 其中,所述粘合剂树脂(A)和(B)中的至少一种在所述特定的含钛催化剂的存在下制备,并且其中所述粘合剂树脂(A)的重量比((A)/(B)) 粘合剂树脂(B)为60/40〜85/15。
    • 3. 发明授权
    • Electrostatic image developing toner, toner kit and image forming apparatus
    • 静电图像显影调色剂,调色剂套件和成像设备
    • US08007976B2
    • 2011-08-30
    • US12091301
    • 2006-11-01
    • Hideki SugiuraHiroyuki FushimiOsamu UchinokuraTakahiro HondaMasami TomitaHyo ShuKen Umehara
    • Hideki SugiuraHiroyuki FushimiOsamu UchinokuraTakahiro HondaMasami TomitaHyo ShuKen Umehara
    • G03G15/04
    • G03G9/08755G03G9/0806G03G9/0819G03G9/08753G03G9/08795G03G9/08797G03G9/091G03G9/0912G03G9/0914G03G9/0922
    • A toner is provided that comprises a colorant and a binder resin, wherein the binder resin comprises a polyester resin that is prepared by a polycondensation reaction in the presence of at least a titanium-containing catalyst expressed by General Formula (II) or (II), the toner has a volume average particle diameter of 2.0 μm to 10.0 μm and a ratio Dv/Dn within a range of 1.00 to 1.40, in which Dv represents a volume average particle diameter and Dn represents a number average particle diameter, Ti(—X)m(—OH)n  General Formula (I) O═Ti(—X)p(—OR)q  General Formula (II) in General Formulas (I) and (II), X represents a residue of a mono-alkanolamine of 2 to 12 carbon atoms or a polyalkanolamine from which a hydrogen atom of one hydroxyl group is removed; other hydroxyl group(s) and still other hydroxyl group(s), within the polyalkanolamine molecule that has a directly bonding Ti atom, may polycondense to form a ring structure; other hydroxyl group(s) and still other hydroxyl group(s) may polycondense intermolecularly to form a repeating structure; and the polymerization degree is 2 to 5 in a case of forming the repeating structure; R represents one of a hydrogen atom and alkyl groups of 1 to 8 carbon atoms that may have 1 to 3 ether bonds; “m” is an integer of 1 to 4; “n” is an integer of 0 to 3; the sum of “m” and “n” is 4; “p” is an integer of 1 or 2; “q” is an integer of 0 or 1; the sum of “p” and “q” is 2; and in a case that “m” and “p” is 2 or more, the respective Xs may be identical or different each other.
    • 提供了包含着色剂和粘合剂树脂的调色剂,其中粘合剂树脂包括通过缩聚反应在至少由通式(II)或(II)表示的含钛催化剂存在下制备的聚酯树脂, 调色剂的体积平均粒径为2.0μm〜10.0μm,Dv / Dn的比例在1.00〜1.40的范围内,其中Dv表示体积平均粒径,Dn表示数均粒径,Ti( - X)m(-OH)n通式(I)O = Ti(-X)p(-OR)q通式(I)和(II)中的通式(II) 2至12个碳原子的链烷醇胺或去除一个羟基的氢原子的聚烷醇胺; 在具有直接键合Ti原子的聚链烷醇胺分子内的其它羟基和其它羟基可以缩聚形成环结构; 其他羟基和其他羟基可以分子间缩聚形成重复结构; 在形成重复结构的情况下聚合度为2〜5; R表示氢原子和可以具有1〜3个醚键的1〜8个碳原子的烷基; “m”为1〜4的整数, “n”为0〜3的整数, “m”和“n”之和为4; “p”是1或2的整数; “q”是0或1的整数; “p”和“q”之和为2; 在“m”和“p”为2以上的情况下,各X可以相同也可以不同。