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    • 6. 发明授权
    • Mixed ionic conductors
    • 混合离子导体
    • US5387330A
    • 1995-02-07
    • US913958
    • 1992-07-17
    • Noboru TaniguchiJunji NiikuraKazuhito HatohTakaharu Gamo
    • Noboru TaniguchiJunji NiikuraKazuhito HatohTakaharu Gamo
    • C01F17/00C04B35/00C04B35/50C30B29/22H01B1/06H01M8/12G01N27/406G01N27/407
    • C01F17/0018C04B35/50H01M8/126C01P2002/34C01P2002/52C01P2004/61C01P2004/62C01P2006/10C01P2006/40Y02E60/525Y02P70/56
    • The present invention relates to a mixing ion conductive material for use in an electrochemical device such as a fuel cell or a sensor and more particularly to the super ion conductive material based on protons or oxide cations and also to a synthesizing method of the mixing ion conductive material.A mixing ion conductive oxide which has a proton conductivity and/or oxide cation conductivity and has a composition comprising 1 mol of barium oxide, 1-x mol of cerium oxide and x mol of gadolinium oxide; wherein 1>x>0.1. When x=0.2, the mixing ion conductive material shows a conductivity shown in FIG. 2. The oxide sintered body mentioned above has a density higher than 96.5% of the theoretical density and a grain size of 0.1 to 10 micron. The synthesizing method of the oxide sintered body is characterized by that the powders for use in the final heat treatment is crushed into a particle size less than 3 micron and is subjected to a vacuum drying process. Further, the sintering temperature is specified to a temperature between 1635.degree. C. and 1665.degree. C.
    • 本发明涉及用于诸如燃料电池或传感器的电化学装置中的混合离子传导材料,更具体地涉及基于质子或氧化物阳离子的超离子导电材料,还涉及一种混合离子导电 材料。 具有质子传导性和/或氧化物阳离子导电性并具有1摩尔氧化钡,1摩尔氧化铈和x摩尔氧化钆的组成的混合离子传导性氧化物; 其中1> x> 0.1。 当x = 0.2时,混合离子传导材料显示出如图1所示的电导率。 上述氧化物烧结体的密度高于理论密度的96.5%,粒径为0.1〜10微米。 氧化物烧结体的合成方法的特征在于,用于最终热处理的粉末粉碎成小于3微米的粒度,并进行真空干燥处理。 此外,烧结温度规定为1635℃至1665℃之间的温度。