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1. 发明授权

US5534595A Syndiotactic propylene copolymer, preparation of the same, and resin composition containing the same 失效
标题翻译：间同立构丙烯共聚物，其制备方法和含有它们的树脂组合物
公开(公告)号：US5534595A
公开(公告)日：1996-07-09
申请号：US468316
申请日：1995-06-06
申请人： Tadashi Asanuma , Hiroshi Matsuzawa , Tateyo Sasaki , Kaoru Kawanishi
发明人： Tadashi Asanuma , Hiroshi Matsuzawa , Tateyo Sasaki , Kaoru Kawanishi
IPC分类号： C08F8/00 , C08F4/642 , C08F210/06
CPC分类号： C08F8/00
摘要： Disclosed is a syndiotactic propylene copolymer containing 0.01 to 40 mol % of olefin units containing --OH group in the side chain. Of absorption peaks attributed to the methyl groups of the propylene units on an absorption spectrum by .sup.13 C-NMR of the copolymer, the intensity of an absorption peak observed at about 20.2 ppm is 0.3 or more of the intensity of absorption peaks of all the methyl groups attributed to the propylene units. The copolymer is produced by copolymerizing propylene and an alkenylsilane or alkenylborane compound in the presence of a catalyst system comprising an asymmetric ligands-having transition metal compound and an aluminoxane, followed by heat-treating the resulting propylene-alkenylsilane copolymer in the presence of a trialkylamine oxide and KF.HF or oxidizing and decomposing the resulting propylene-alkenylborane compound copolymer. Also disclosed is a resin composition comprising the copolymer and other polyolefin(s).
摘要翻译：公开了含侧链中含有-OH基的烯烃单元为0.01〜40摩尔％的间同立构丙烯共聚物。归因于丙烯单元的甲基的吸收峰在共聚物的13 C-NMR吸收光谱上，在约20.2ppm处观察到的吸收峰的强度为所有甲基的吸收峰的强度的0.3以上归因于丙烯单元。共聚物通过在包含不对称配体的过渡金属化合物和铝氧烷的催化剂体系的存在下共聚丙烯和烯基硅烷或烯基硼烷化合物，然后在三烷基胺存在下热处理所得的丙烯 - 链烯基硅烷共聚物氧化物和KF.HF，或氧化和分解得到的丙烯 - 烯基硼烷化合物共聚物。还公开了包含共聚物和其它聚烯烃的树脂组合物。

2. 发明授权

US5225507A Polymer and polypropylene resin composition 失效
标题翻译：聚合物和聚丙烯树脂组合物
公开(公告)号：US5225507A
公开(公告)日：1993-07-06
申请号：US628357
申请日：1990-12-17
申请人： Tadashi Asanuma , Kaoru Kawanishi , Hiroshi Matsuzawa , Yukari Nishimori
发明人： Tadashi Asanuma , Kaoru Kawanishi , Hiroshi Matsuzawa , Yukari Nishimori
IPC分类号： C08F30/08 , C08F210/00 , C08F230/08 , C08L23/10 , C08L23/14 , C08L29/00 , C08L43/04 , C08L53/00
CPC分类号： C08L23/142 , C08F210/00 , C08F230/08 , C08L23/10 , C08L53/00 , C08L2207/12 , C08L2314/06 , C08L43/04 , Y10S526/943
摘要： There is disclosed a homoplymer of an alkenylsilane having a syndiotactic structure and a copolymer of the alkenylsilane and an .alpha.-olefin. The polymer and the copolymer can be prepared by subjecting the alkenylsilane or the alkenylsilane and the .alpha.-olefin to addition polymerization in the presence of a transition metal compound having asymmetirically interconnected ligands or preferably in the presence of the transition metal compound and aluminoxane. The polymer and the copolymer can be used as a nucleating agent for a crystalline polypropylene.

3. 发明授权

US06255425B1 Syndiotactic polypropylene copolymer and extruded polypropylene articles 失效
标题翻译：间同立构聚丙烯共聚物和挤出聚丙烯制品
公开(公告)号：US06255425B1
公开(公告)日：2001-07-03
申请号：US08182348
申请日：1994-01-18
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Osamu Uchida , Tutomu Iwatani , Shigeru Kimura , Takeo Inoue
IPC分类号： C08F21006
CPC分类号： C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/10 , Y10S526/916 , Y10T428/1345 , Y10T428/1352 , Y10T428/1397 , C08F210/16 , C08F2500/16 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： A syndiotactic polypropylene copolymer is disclosed which comprises 70 to 99.9 mole % of propylene and 0.1 to 30 mole % of an olefin other than propylene; in the 13C-NMR spectrum of the syndiotactic polypropylene copolymer, a ratio of the intensity of a peak at about 20.2 ppm to the sum of the intensities of the total peaks attributable to methyl groups in propylene units at about 19-22 ppm being 0.3 or more. Also disclosed are extrusion-molded high-transparency articles, especially films and sheets and blown films, obtained by the extrusion of a polypropylene substantially having a syndiotactic structure.
摘要翻译：公开了间同立构聚丙烯共聚物，其包含70-99.9摩尔％的丙烯和0.1-30摩尔％的除丙烯以外的烯烃; 在间同立构聚丙烯共聚物的13 C-NMR光谱中，约20.2ppm处的峰强度与归属于丙烯单元的甲基的总峰的强度的总和的比例为约为19-22ppm，为0.3或更多。还公开了挤出成型的高透明度制品，特别是通过挤出基本上具有间同立构结构的聚丙烯获得的薄膜和片材和吹塑薄膜。

4. 发明授权

US5132157A Stretched films of polyproplene 失效
标题翻译：聚丙烯薄膜
公开(公告)号：US5132157A
公开(公告)日：1992-07-21
申请号：US525726
申请日：1990-05-21
申请人： Tadashi Asanuma , Kazuhiko Yamamoto , Tateyo Sasaki , Takeo Inoue , Takayuki Yamada
发明人： Tadashi Asanuma , Kazuhiko Yamamoto , Tateyo Sasaki , Takeo Inoue , Takayuki Yamada
IPC分类号： B29C55/02 , B29C55/00 , B29C59/02 , B29K23/00 , B29L7/00 , C08J5/18
CPC分类号： C08J5/18 , B29C55/005 , B29C59/022 , B29K2023/12 , B29K2995/0026 , B29K2995/0072 , C08J2323/10 , Y10S428/91 , Y10T156/1002 , Y10T156/1023 , Y10T428/24355 , Y10T428/24479 , Y10T428/26 , Y10T428/269 , Y10T428/31 , Y10T428/31938
摘要： A stretched film of polypropylene which is excellent in transparency, substantially free of an antiblocking agent and at least uniaxially stretched and which is characterized in that it has uniformly distributed projections having a height ranging from 0.05 to 0.50 .mu. and a width ranging from 10 to 100 .mu. at least on the surface thereof as well as a method for preparing the foregoing stretched film of polypropylene which comprises the steps of forming, into a sheet, polypropylene which comprises a nucleating agent in an amount selected so that the crystallization temperature of polypropylene is increased by 1.degree.to 10.degree. C. by the addition thereof and then stretching the sheet at a temperature ranging from 140.degree. to 165.degree. C. are herein disclosed.

5. 发明授权

US5591817A Molded articles of syndiotactic polypropylene and method for preparing same 失效
标题翻译：间同立构聚丙烯的成型制品及其制备方法
公开(公告)号：US5591817A
公开(公告)日：1997-01-07
申请号：US210082
申请日：1994-03-18
申请人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Tetusnosuke Shiomura
发明人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Tetusnosuke Shiomura
IPC分类号： C08J5/00 , B29C35/00 , B29C67/24 , B29C71/02 , B29K23/00 , B29K105/32 , C08F4/642 , C08F110/06 , C08F10/06
CPC分类号： B29C67/24 , B29K2023/12 , B29K2995/0026 , C08F110/06 , Y10T428/26
摘要： A molded article of a syndiotactic polypropylene having excellent transparency in which a melting point attributed to the polypropylene having the syndiotactic structure measured at a heating rate of 10.degree. C./minute by differential scanning thermal analysis is represented by a substantially single peak, the aforesaid molded article being prepared by heating, melting and then hot-molding a homopolymer of propylene or a copolymer of propylene and a small amount of another olefin, which have a substantially syndiotactic structure, or a mixture of the homopolymer or the copolymer and a small amount of a polypropylene having a substantially isotactic structure, followed by quenching, or, after these steps, additionally subjecting the above molded article to a heat treatment at a temperature of less than its melting point. A method for preparing the above molded article is also disclosed here.
摘要翻译：间隔立构聚丙烯的模塑制品具有优异的透明性，其中通过差示扫描热分析以10℃/分钟的加热速率测量的具有间同立构结构的聚丙烯的熔点由基本上单峰表示，上述通过将具有基本上间同立构结构的丙烯或丙烯与少量的另一种烯烃的共聚物或均聚物或共聚物的混合物和少量的均聚物进行加热，熔融，然后热模塑，的具有基本上全同立构结构的聚丙烯，然后淬火，或者在这些步骤之后，另外对上述模塑制品在低于其熔点的温度进行热处理。此处也公开了制备上述模制品的方法。

6. 发明授权

US5200131A Method for molding syndiotactic polypropylene 失效
标题翻译：模塑聚丙烯聚丙烯的方法
公开(公告)号：US5200131A
公开(公告)日：1993-04-06
申请号：US679522
申请日：1991-04-02
申请人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
发明人： Tadashi Asanuma , Tateyo Sasaki , Mitsuru Ito , Shigeru Kimura , Takeo Inoue
IPC分类号： C08J5/18 , C08J7/02 , C08L23/10 , D01F6/06
CPC分类号： D01F6/06 , C08J5/18 , C08J7/02 , C08J2323/10 , C08L2207/12 , C08L23/10 , Y10S526/943
摘要： A method for molding a polypropylene or a propylene copolymer having a syndiotactic structure which comprises the steps of melting, molding, if desired, quenching and then stretching a propylene homopolymer or a copolymer of propylene and a small amount of ethylene or another .alpha.-olefin which has a substantially syndiotactic structure, or a mixture of the same and a small amount of a polypropylene having a substantially isotactic structure. The molded and stretched article can be heated at a temperature of a molding temperature or more, while a load is applied to the article. Furthermore, the molded and stretched article, if desired, can be treated with a hydrocarbon vapor, while a load is applied to the article. The molded article obtained by the method of the present invention has a novel crystalline structure.

7. 发明授权

US5637367A Transparent impact-resistant molded articles 失效
标题翻译：透明耐冲击成型制品
公开(公告)号：US5637367A
公开(公告)日：1997-06-10
申请号：US124531
申请日：1993-09-22
申请人： Tadashi Asanuma , Tateyo Sasaki , Shosuke Nakanishi , Takeo Inoue
发明人： Tadashi Asanuma , Tateyo Sasaki , Shosuke Nakanishi , Takeo Inoue
IPC分类号： B29C49/00 , C08L23/08 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , B29D23/00
CPC分类号： C08L23/12 , B29C49/0005 , C08L23/10 , C08L23/142 , C08L23/16 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/00 , B29K2023/12 , B29K2995/0026 , B29K2995/0089 , B29L2031/7158 , C08L2203/10 , C08L2207/12 , C08L23/0815 , C08L23/14 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397
摘要： A molded article obtained by blow molding a propylene having a substantially syndiotactic structure or a resin composition comprising a polypropylene having a substantially syndiotactic structure and a copolymer of ethylene and propylene, and a multi-layer molded article obtained from this resin composition in which at least one surface of the molded article is a polypropylene layer having the substantially syndiotactic structure.
摘要翻译：通过吹塑具有基本上间同立构结构的丙烯或包含具有基本上间同立构结构的聚丙烯和乙烯和丙烯的共聚物的树脂组合物和由该树脂组合物获得的多层模塑制品而获得的模制品，其中至少模制品的一个表面是具有基本上间同立构结构的聚丙烯层。

8. 发明授权

US5266641A Butene-1 copolymers and resin compositions containing the same 失效
标题翻译：丁烯-1共聚物和含有它们的树脂组合物
公开(公告)号：US5266641A
公开(公告)日：1993-11-30
申请号：US013175
申请日：1993-01-29
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Tateyo Sasaki , Tutomu Iwatani , Nobutaka Uchikawa , Kouji Kitabayashi
IPC分类号： C08F210/06 , C08F210/08 , C08L23/14
CPC分类号： C08F210/08 , C08F210/06
摘要： Copolymers of butene-1 and propylene, having specific physical properties and substantially a syndiotactic structure; and easily heat-sealable polypropylene resin compositions comprising 5-50 parts by weight of one of the copolymers and 95-50 parts by weight of a stereoregular crystalline propylene-ethylene copolymer or propylene ethylene-C.sub.4-12 -.alpha.-olefin copolymer having specific compositions and melt flow index.
摘要翻译：具有特定物理性质和基本上间同立构结构的丁烯-1和丙烯的共聚物; 和易于热封的聚丙烯树脂组合物，其包含5-50重量份的一种共聚物和95-50重量份的具有特定组成的立构规整结晶丙烯 - 乙烯共聚物或丙烯乙烯-C4-12-α-烯烃共聚物和熔体流动指数。

9. 发明授权

US5232992A Molded articles of syndiotactic polypropylene and method for preparing same 失效
标题翻译：合成聚丙烯的成型制品及其制备方法
公开(公告)号：US5232992A
公开(公告)日：1993-08-03
申请号：US593734
申请日：1990-10-05
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Takeo Inoue
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Takeo Inoue
IPC分类号： B29C67/24 , B29C71/02 , C08J5/00 , C08K3/00 , C08K5/00 , C08L23/10
CPC分类号： C08J5/00 , B29C67/24 , C08K3/0008 , C08K5/0008 , C08K5/0083 , C08L23/10 , B29C71/02 , B29K2023/12 , C08J2323/10 , C08L2205/02 , C08L2207/12
摘要： According to the present invention, molded articles can be provided in which a melting point attributed to a syndiotactic polypropylene and measured at a temperature rise rate of 10.degree. C./minute by differential scanning thermal analysis is indicated by a substantially single peak, the aforesaid molded articles being obtained by heating, melting and molding a substantially syndiotactic homopolymer of propylene, a substantially syndiotactic copolymer of propylene and a small amount of another olefin, or a mixture of these polymers and a small amount of a substantially isotactic polypropylene, and then subjecting the molded products to a heat treatment. Furthermore, a method for preparing the above-mentioned molded articles is also provided. The molded articles have high stiffness and impact resistance.
摘要翻译：根据本发明，可以提供通过差示扫描热分析以10℃/分钟的升温速度测定归因于间同立构聚丙烯的熔点的成型体，其基本上由单峰表示，上述通过加热，熔融和模制丙烯基本上间同立构的均聚物，丙烯和少量另一种烯烃的基本上间同立构共聚物，或这些聚合物和少量的基本上为全同立构的聚丙烯的混合物而获得的模塑制品，成型产品进行热处理。此外，还提供了制备上述模制品的方法。模制品具有高刚度和抗冲击性。

10. 发明授权

US5428127A Preparation process of syndiotactic polyproplene 失效
标题翻译：间同立构聚丙烯的制备方法
公开(公告)号：US5428127A
公开(公告)日：1995-06-27
申请号：US339298
申请日：1994-11-10
申请人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Norihide Inoue , Osamu Uchida , Tutomu Iwatani
发明人： Tadashi Asanuma , Tetsunosuke Shiomura , Nobutaka Uchikawa , Tateyo Sasaki , Norihide Inoue , Osamu Uchida , Tutomu Iwatani
IPC分类号： C08F6/00 , C08F4/60 , C08F4/642 , C08F4/6592 , C08F6/02 , C08F6/06 , C08F8/00 , C08F10/00 , C08F6/28
CPC分类号： C08F6/02
摘要： Disclosed herein is a process for preparing a syndiotactic polypropylene comprising washing with a hydrocarbon solvent a polymer obtained by polymerizing propylene in the presence of a catalyst comprising a transition metal compound having an asymmetric ligand. The slurry of the polymer obtained by the polymerization is treated with a .beta.-dicarboxy compound and an alcohol or with an alcohol containing hydrochloric acid gasunder non-aqueous conditions prior to the washing with a hydrocarbon solvent so that the residue of the catalyst used in the polymerization reaction may be rendered soluble in the hydrocarbon solvent, the properties of the resulting syndiotactic polypropylene are improved greatly.
摘要翻译：本文公开了一种制备间同立构聚丙烯的方法，包括用烃溶剂洗涤在含有具有不对称配体的过渡金属化合物的催化剂存在下聚合丙烯而获得的聚合物。在用烃溶剂洗涤之前，通过聚合获得的聚合物的浆料用β-二羧基化合物和醇或含有盐酸气体的醇在非水性条件下处理，使得在聚合反应可溶于烃溶剂，所得间同立构聚丙烯的性能大大提高。

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