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1. 发明授权

US08110296B2 Multifunctional hard material coating 有权
标题翻译：多功能硬质材料涂层
公开(公告)号：US08110296B2
公开(公告)日：2012-02-07
申请号：US12221690
申请日：2008-08-06
申请人： Sven Ulrich , Michael Stüber , Harald Leiste , Helmut Holleck
发明人： Sven Ulrich , Michael Stüber , Harald Leiste , Helmut Holleck
IPC分类号： B32B9/00
CPC分类号： C23C14/06 , C04B35/5611 , C04B35/58014 , C04B2235/3418 , C23C14/0676 , Y10T428/24355 , Y10T428/252
摘要： In a multi-functional hard material coating of a substrate wherein the hard material coating comprises a single phase crystalline structure including metastable mixed crystals of at least two hard material components which are not soluble in each other and comprise at least one metallic hard material and an ionic hard material whereby the advantages of metallic and ionic hard material components are combined.
摘要翻译：在基质的多功能硬质材料涂层中，其中所述硬质材料涂层包括单相晶体结构，其包括至少两种彼此不溶的硬质材料成分的亚稳态混合晶体，并且包含至少一种金属硬质材料和离子硬质材料，从而结合了金属和离子硬质材料组分的优点。

2. 发明申请

US20090061156A1 Multifunctional hard material coating 有权
标题翻译：多功能硬质材料涂层
公开(公告)号：US20090061156A1
公开(公告)日：2009-03-05
申请号：US12221690
申请日：2008-08-06
申请人： Sven Ulrich , Michael Stuber , Harald Leiste , Helmut Holleck
发明人： Sven Ulrich , Michael Stuber , Harald Leiste , Helmut Holleck
IPC分类号： B32B18/00 , B32B15/04 , B32B17/06 , B32B9/04 , C23C14/34 , C23C16/513
CPC分类号： C23C14/06 , C04B35/5611 , C04B35/58014 , C04B2235/3418 , C23C14/0676 , Y10T428/24355 , Y10T428/252
摘要： In a multi-functional hard material coating of a substrate wherein the hard material coating comprises a single phase crystalline structure including metastable mixed crystals of at least two hard material components which are not soluble in each other and comprise at least one metallic hard material and an ionic hard material whereby the advantages of metallic and ionic hard material components are combined.
摘要翻译：在基质的多功能硬质材料涂层中，其中所述硬质材料涂层包括单相晶体结构，其包括至少两种彼此不溶的硬质材料成分的亚稳态混合晶体，并且包含至少一种金属硬质材料和离子硬质材料，从而结合了金属和离子硬质材料组分的优点。

3. 发明授权

US6110329A Method of manufacturing a composite material 失效
标题翻译：制造复合材料的方法
公开(公告)号：US6110329A
公开(公告)日：2000-08-29
申请号：US215392
申请日：1998-12-18
申请人： Helmut Holleck , Michael Stuber
发明人： Helmut Holleck , Michael Stuber
IPC分类号： C23C14/02 , C23C14/06 , C23C14/35
CPC分类号： C23C14/0605 , C23C14/027
摘要： In a method of manufacturing a composite material structure consisting of a substrate with a layer of essentially pure sp.sup.2 - and sp.sup.3 -hybridized carbon with a sp.sup.3 -hybridized carbon proportion which increases toward the surface of the carbon layer, the carbon layer is deposited on the substrate by a PVD process using a magnetron sputtering apparatus in a process chamber in which an argon partial pressure of 0.6 to 1.0 pa is maintained and, during the carbon deposition, a bias voltage is maintained which is increased with increasing thickness of the layer from 0 to 300 volts.
摘要翻译：在制备复合材料结构的方法中，所述复合材料结构由具有基本上纯的sp2-和sp3杂化的碳的基底组成，其中sp3-杂化的碳比例朝向碳层的表面增加，碳层沉积在通过使用磁控溅射装置的PVD工艺在基板中保持0.6至1.0Pa的氩分压，并且在碳沉积期间保持偏压，该偏置电压随着层的厚度从0增加而增加至300伏。

4. 发明授权

US4835062A Protective coating for metallic substrates 失效
标题翻译：金属基材的保护涂层
公开(公告)号：US4835062A
公开(公告)日：1989-05-30
申请号：US836628
申请日：1986-03-05
申请人： Helmut Holleck
发明人： Helmut Holleck
IPC分类号： C23C14/06 , C23C28/04
CPC分类号： C23C28/044
摘要： A protective coating for metallic substrates consists of a plurality of layers having a total thickness ranging from 0.1 to 10.mu., an individual thickness for each layer ranging from 0.5 to 40 nm, and a total number of layers which does not exceed 20,000, each layer being comprised of one kind of at least two kinds of crystalline hard substances and being arranged in a sequentially alternating order with respect to the others, the crystalline hard substances having phase interfaces with respect to one another which are at least crystallographically partially coherent. In an alternate embodiment, the protective coating is a single layer which is a superfinely dispersed mixture of the crystalline hard substances. The multi-layered embodiment is provided by a method which includes positioning the metallic substrate in a physical vapor deposition apparatus; providing at least two cathodes in the apparatus, each cathode being comprised of a different kind of crystalline hard substance; continuously moving the metallic substrate sequentially past each cathode; and causing the vapor deposition of the crystalline hard substances on the metallic substrate as a protective coating having a plurality of layers. The single-layered embodiment is provided by an alternate method in which one cathode is provided and is comprised of at least two kinds of crystalline hard substances. These protective coatings have a resistance to wear which exceeds that for a coating comprised of any one of the crystalline hard substances alone.
摘要翻译：用于金属基底的保护涂层由总厚度为0.1-10μm的多个层组成，每一层的单独厚度为0.5〜40nm，层数总和不超过20,000层由一种至少两种结晶硬质物质组成，并以相对于其它物质顺序交替排列的方式，所述结晶硬物质相互之间具有至少在晶体学部分相干的相界面。在替代实施例中，保护涂层是单层，其是结晶硬物质的超细分散混合物。多层实施例通过包括将金属基板定位在物理气相沉积设备中的方法来提供; 在设备中提供至少两个阴极，每个阴极由不同种类的结晶硬物质组成; 连续地将金属基板顺序地移动通过每个阴极; 并且使金属基体上的结晶硬物质气相沉积为具有多个层的保护涂层。单层实施例由提供一种阴极并由至少两种结晶硬物质构成的替代方法提供。这些保护涂层具有耐磨性，其超过单独使用任何一种结晶硬质物质的涂层。

5. 发明授权

US4432794A Hard alloy comprising one or more hard phases and a binary or multicomponent binder metal alloy 失效
标题翻译：包含一种或多种硬相和二元或多组分粘合剂金属合金的硬质合金
公开(公告)号：US4432794A
公开(公告)日：1984-02-21
申请号：US286376
申请日：1981-07-17
申请人： Helmut Holleck
发明人： Helmut Holleck
IPC分类号： C22C29/06 , C22C29/08 , C22C29/10 , C22C32/00 , B22F3/16 , C22C14/00 , C22C27/00 , C22C28/00
CPC分类号： C22C32/0052 , C22C29/06 , C22C29/067
摘要： A hard alloy including at least one hard phase and a binary or multicomponent binder metal alloy, in which the hard substance comprises a finely dispersed, homogeneous distribution in the binder metal. The hard phase comprises a carbide of a Group IVb, Vb or VIb transition metal, and the binder metal alloy comprises a solid alloy of a Group IVb, Vb or VIb transition metal, with Re, Ru, Rh, Pd, Os, Ir, or Pt.
摘要翻译：包括至少一种硬相和二元或多组分粘合剂金属合金的硬质合金，其中所述硬质物质包含在所述粘合剂金属中的细分散均匀分布。硬质相包括IVb族，Vb族或VIb族过渡金属的碳化物，并且该粘合剂金属合金包含IVb族，Vb族或VIb族过渡金属与Re，Ru，Rh，Pd，Os，Ir，或Pt。

6. 发明授权

US5182238A Protective layer of hard material with homogeneous distribution of elements 失效
标题翻译：具有均质分布元素的硬质材料保护层
公开(公告)号：US5182238A
公开(公告)日：1993-01-26
申请号：US335601
申请日：1989-04-10
申请人： Helmut Holleck
发明人： Helmut Holleck
IPC分类号： C23C14/06 , C23C14/35
CPC分类号： C23C14/0641 , C23C14/0635 , Y10T428/31678 , Y10T428/31815
摘要： A primarily crystalline, titanium-containing protective layer of hard material with homogeneous distribution of elements on the surfaces of a substrate material. The protective layer comprises a stabilized mixed phase having a crystal structure made of a metallic hard material which is at least one material selected from TiN and TiC and a covalent hard material which is at least one material selected from SiC and Si.sub.3 N.sub.4.
摘要翻译：一种主要结晶的含钛保护层的硬质材料，在基材表面上均匀分布元素。保护层包括具有由金属硬质材料制成的晶体结构的稳定混合相，其为选自TiN和TiC中的至少一种材料，以及选自SiC和Si 3 N 4中的至少一种材料的共价硬质材料。

7. 发明授权

US06245446B1 Wear protection layer 失效
标题翻译：磨损保护层
公开(公告)号：US06245446B1
公开(公告)日：2001-06-12
申请号：US08903682
申请日：1997-07-31
申请人： Veit Schier , Helmut Holleck
发明人： Veit Schier , Helmut Holleck
IPC分类号： B32B1504
CPC分类号： C23C28/044 , B32B18/00 , C04B2237/36 , C04B2237/361 , C04B2237/363 , C04B2237/366 , C04B2237/368 , C04B2237/704 , C23C28/42 , Y10T428/12576
摘要： In a wear protection layer comprising, disposed on a substrate, a plurality of individual layers including a first individual layer of a metallic hard material disposed directly on the substrate, periodically repeated composite arrangements of three individual layers comprising two individual layers of different metallic hard materials and one individual layer consisting of a covalent hard material are disposed on the first individual layer of a metallic hard material whereby the mechanical, physical and chemical properties of the metallic hard materials are combined with the properties of the covalent hard materials.
摘要翻译：在包括设置在基底上的磨损保护层中，包括直接设置在基底上的金属硬质材料的第一单独层的多个单独层，周期性地重复复合布置的三个单独的层，包括两层不同的金属硬质材料并且由金属硬质材料的第一单层设置由共价硬质材料构成的一个单独的层，由此金属硬质材料的机械，物理和化学性质与共价硬质材料的性质相结合。

8. 发明授权

US4481166A Wear resistant hard metal free of tungsten carbide 失效
标题翻译：耐磨硬金属不含金属碳化物
公开(公告)号：US4481166A
公开(公告)日：1984-11-06
申请号：US249891
申请日：1981-04-01
申请人： Helmut Holleck , Fritz Thuemmler , Leo Prakash
发明人： Helmut Holleck , Fritz Thuemmler , Leo Prakash
IPC分类号： C22C1/05 , C22C29/00 , B22F3/00
CPC分类号： C22C29/00 , C22C1/051 , C22C1/053
摘要： A wear-resistant hard metal free of tungsten carbide. The hard metal comprises: molybdenum carbide; a carbide of another transition metal; boron, boron nitride, boron carbide, or a mixture thereof, in an amount of 0.1 to 1% by weight boron, based on the weight of the molybdenum carbide, other transition metal carbide and boron-containing material, and a binder metal selected from the group consisting of metals of the iron group of the Periodic Table of Elements, and alloys thereof.

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