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    • 1. 发明授权
    • Method to incorporate, and a device having, oxide enhancement dopants
using gas immersion laser doping (GILD) for selectively growing an
oxide layer
    • 使用气体浸渍激光掺杂(GILD)来选择生长氧化物层的掺入方法和具有氧化物增强掺杂剂的器件
    • US5885904A
    • 1999-03-23
    • US799235
    • 1997-02-14
    • Sunil MehtaEmi IshidaXiao-Yu Li
    • Sunil MehtaEmi IshidaXiao-Yu Li
    • H01L21/311H01L21/316H01L21/461H01L21/31
    • H01L21/02238H01L21/02255H01L21/0231H01L21/02312H01L21/31138H01L21/31144H01L21/31662
    • A method for forming a uniform and reliable oxide layer on the surface of a semiconductor substrate using projection gas immersion laser doping (P-GILD) is provided. A semiconductor substrate is immersed in an oxide enhancing compound containing atmosphere. The oxide enhancing compound containing atmosphere may include phosphorus, arsenic, boron or an equivalent. A 308 nm excimer laser is then applied to a portion of the substrate to induce incorporation of the oxide enhancing compound into a portion of the substrate. The deposition depth is dependent upon the strength of the laser energy directed at the surface of the substrate. A uniform and reliable oxide layer is then formed on the surface of the substrate by heating the substrate. The laser may be applied with a reflective reticle or mask formed on the substrate. An E.sup.2 PROM memory cell having a program junction region in a silicon substrate is also provided. An oxide layer is positioned between a program junction and a floating gate. The oxide layer is formed by a single or multiple thermal oxidation step(s) to have at least a first oxide thickness due to a GILD oxide enhancing compound underlying a region of the oxide having at least the first oxide thickness.
    • 提供了使用投影气体浸渍激光掺杂(P-GILD)在半导体衬底的表面上形成均匀且可靠的氧化物层的方法。 将半导体衬底浸入含氧化物增强化合物的气氛中。 含氧化物增强化合物的气氛可以包括磷,砷,硼或等价物。 然后将308nm准分子激光器施加到衬底的一部分以诱导氧化物增强化合物掺入衬底的一部分中。 沉积深度取决于指向衬底表面的激光能量的强度。 然后通过加热衬底在衬底的表面上形成均匀且可靠的氧化物层。 可以在基板上形成反射型掩模版或掩模来施加激光。 还提供了具有硅衬底中的程序接合区的E2PROM存储单元。 氧化物层位于程序结和浮动栅之间。 通过单个或多个热氧化步骤形成氧化物层,以至少具有第一氧化物厚度,这是由于至少具有第一氧化物厚度的氧化物区域下面的GILD氧化物增强化合物。
    • 4. 发明授权
    • Method and apparatus incorporating nitrogen selectively for differential
oxide growth
    • 选择性地掺入氮用于差异氧化物生长的方法和装置
    • US5904575A
    • 1999-05-18
    • US799153
    • 1997-02-14
    • Emi IshidaXiao-Yu LiSunil D. Mehta
    • Emi IshidaXiao-Yu LiSunil D. Mehta
    • H01L21/265H01L21/266H01L21/316H01L21/8234H01L27/115H01L21/31H01L21/469
    • H01L21/02238H01L21/02255H01L21/0231H01L21/02312H01L21/26506H01L21/266H01L21/31662H01L21/823462H01L27/115Y10S148/126Y10S438/981
    • A method for forming an oxide on the surface of a semiconductor substrate. The method includes the steps of: placing the semiconductor substrate in an atmosphere containing an atmosphere of an oxide growth inhibiting compound; applying laser energy to at least a first portion of the substrate; and forming the oxide on the surface of the substrate by heating the substrate. In a further aspect of the invention, the method comprises applying laser energy through a patterned, reflective reticle. Alternatively, prior to the step of placing, a reflective mask layer may be applied to the surface of the semiconductor substrate. In addition, the invention comprises an EEPROM memory cell having a program junction region in a semiconductor substrate. The cell comprises at least a first program junction provided in the silicon substrate and a floating gate having a portion positioned over the program junction. In addition, an oxide layer is positioned between the program junction and the floating gate, the gate oxide formed by a single thermal oxidation step to have at least a first oxide thickness and a second oxide thickness due to gas immersion laser doped nitrogen underlying a region of the oxide having said at least first oxide thickness.
    • 一种在半导体衬底的表面上形成氧化物的方法。 该方法包括以下步骤:将半导体衬底放置在含有氧化物生长抑制化合物气氛的气氛中; 将激光能量施加到所述衬底的至少第一部分; 以及通过加热衬底在衬底的表面上形成氧化物。 在本发明的另一方面,该方法包括通过图案化的反射光罩施加激光能量。 或者,在放置步骤之前,可以将反射掩模层施加到半导体衬底的表面。 此外,本发明包括一个在半导体衬底中具有编程结区的EEPROM存储单元。 该单元包括设置在硅衬底中的至少第一程序段和具有位于程序结上方的部分的浮动栅极。 此外,氧化物层位于程序结和浮置栅极之间,栅极氧化物通过单个热氧化步骤形成,以由于气体浸没激光掺杂氮在下面的区域具有至少第一氧化物厚度和第二氧化物厚度 的具有所述至少第一氧化物厚度的氧化物。