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1. 发明授权

US4910326A .beta.-ketonitrils 失效
标题翻译： β-酮腈
公开(公告)号：US4910326A
公开(公告)日：1990-03-20
申请号：US166306
申请日：1988-03-10
申请人： Sumimoto Shinzaburo , Ichiro Ishizuka , Hiroyuki Kai , Shiro Ueda , Akira Takase
发明人： Sumimoto Shinzaburo , Ichiro Ishizuka , Hiroyuki Kai , Shiro Ueda , Akira Takase
IPC分类号： A01N43/80 , C07D261/14 , C07D271/06 , C07D271/07
CPC分类号： C07D271/06 , C07C255/00 , C07D261/14 , C07D271/07
摘要： A fluorinated .beta.-ketonitrile of the formula: ##STR1## in which: R is alkyl having plural fluorines and R.sup.1 is hydrogen or alkyl.

2. 发明授权

US4797492A Polyfluoroalkylisoxazolylamines 失效
标题翻译：多氟烷基异恶唑胺
公开(公告)号：US4797492A
公开(公告)日：1989-01-10
申请号：US921415
申请日：1986-10-22
申请人： Shinzaburo Sumimoto , Ichiro Ishizuka , Hiroyuki Kai , Shiro Ueda , Akira Takase
发明人： Shinzaburo Sumimoto , Ichiro Ishizuka , Hiroyuki Kai , Shiro Ueda , Akira Takase
IPC分类号： A01N43/80 , C07D261/14 , C07D271/06 , C07D271/07
CPC分类号： C07D271/06 , C07C255/00 , C07D261/14 , C07D271/07
摘要： A novel compound useful as an intermediate for synthesizing pesticides and medicines of the formula: ##STR1## in which: R is alkyl having plural florines; R.sup.1 is hydrogen, alkyl, halogen or optionally substituted phenyl; and R.sup.2 is hydrogen or alkyl, or a salt thereof.

3. 发明授权

US4186144A Process for the production of cyanopinacolone 失效
标题翻译：氰考酚酸的生产工艺
公开(公告)号：US4186144A
公开(公告)日：1980-01-29
申请号：US897001
申请日：1978-04-17
申请人： Tsutomu Sugasawa , Tatsuo Toyoda , Kazuyuki Sasakura , Shiro Ueda , Akira Takase , Katsuto Okuno , Ichiro Ishizuka , Shinzaburo Sumimoto
发明人： Tsutomu Sugasawa , Tatsuo Toyoda , Kazuyuki Sasakura , Shiro Ueda , Akira Takase , Katsuto Okuno , Ichiro Ishizuka , Shinzaburo Sumimoto
IPC分类号： C07D261/14 , A01N43/80 , C07C45/00 , C07C45/63 , C07C49/16 , C07C67/00 , C07C253/00 , C07C253/16 , C07C255/17 , C07C121/34
CPC分类号： C07C255/00 , C07C45/63
摘要： Cyanopinacolone is produced by reacting pinacolone with about 1.0 to about 1.2 molar equivalents of chlorine in methanol and further reacting the resulting monochloropinacolone with about 1.0 to about 1.2 molar equivalents of an alkali metal cyanide in methanol.
摘要翻译：通过频哪酮与约1.0至约1.2摩尔当量的甲醇中的氯反应制备亚氨基乐康酮，并使所得一氯一可乐酮与约1.0至约1.2摩尔当量的碱金属氰化物在甲醇中反应。

4. 发明授权

US4888044A 3-perfluoroalkyl-5-substituted-oxy-isoxazole derivatives, process for preparing the same, and herbicides containing the same 失效
标题翻译： 3-全氟烷基-5-取代的 - 氧 - 异恶唑衍生物，其制备方法和含有它们的除草剂
公开(公告)号：US4888044A
公开(公告)日：1989-12-19
申请号：US88214
申请日：1987-08-24
申请人： Shinzaburo Sumimoto , Ichiro Ishizuka , Shiro Ueda , Hiroyuki Kai , Kinya Ide
发明人： Shinzaburo Sumimoto , Ichiro Ishizuka , Shiro Ueda , Hiroyuki Kai , Kinya Ide
IPC分类号： A01N43/80 , C07D261/12 , C07D413/04 , C07D413/12
CPC分类号： C07D413/04 , A01N43/80 , C07D261/12 , C07D413/12
摘要： A novel herbicidal compound of the formula: ##STR1## in which R is OH, C.sub.1 -C.sub.3 alkoxy or R.sup.3 -N-R.sup.4 ; R.sub.f is C.sub.1 -C.sub.3 perfluoroalkyl; R.sup.1 is hydrogen, C.sub.1 -C.sub.6 alkyl or optionally substituted phenyl; R.sup.2 is hydrogen or C.sub.1 -C.sub.3 alkyl; n is an integer of 0 to 2; R.sup.3 is hydrogen or C.sub.1 -C.sub.3 alkyl; R.sup.4 is C.sub.1 -C.sub.6 alkyl, optionally substituted phenylalkyl where alkyl contains 1 to 3 carbons or optionally substituted phenyl; or R.sup.3 and R.sup.4 together with the nitrogen atom to which they are attached form a cyclic amino group; or a salt thereof. A process for preparing the compound (I) and a herbicide containing the compound (I) are also disclosed.

5. 发明授权

US5082947A 3-perfluoroalkyl-5-hydroxyisoxazoles 失效
标题翻译： 3-全氟烷基-5-羟基氧杂环己烷
公开(公告)号：US5082947A
公开(公告)日：1992-01-21
申请号：US541178
申请日：1990-06-19
申请人： Shinzaburo Sumimoto , Ichiro Ishizuka , Shiro Ueda , Hiroyuki Kai
发明人： Shinzaburo Sumimoto , Ichiro Ishizuka , Shiro Ueda , Hiroyuki Kai
IPC分类号： C07D261/12 , C07D261/14
CPC分类号： C07D261/14 , C07D261/12
摘要： A novel compound useful as an intermediate for synthesizing pesticides and medicine of the formula: ##STR1## in which: R is perfluoroalkyl, R.sup.1 is hydrogen, alkyl or optionally substituted phenyl, or a salt thereof.
摘要翻译：用作合成农药和药物的中间体的新化合物，其分子式为：其中：R为全氟烷基，R 1为氢，烷基或任选取代的苯基或其盐。

6. 发明授权

US4256899A Process for the production of 3-amino-5-t-butylisoxazole 失效
标题翻译：制备3-氨基-5-叔丁基异恶唑的方法
公开(公告)号：US4256899A
公开(公告)日：1981-03-17
申请号：US82405
申请日：1979-10-05
申请人： Yasuo Makisumi , Akira Murabayashi , Akira Takase , Ichiro Ishizuka , Shinzaburo Sumimoto
发明人： Yasuo Makisumi , Akira Murabayashi , Akira Takase , Ichiro Ishizuka , Shinzaburo Sumimoto
IPC分类号： C07D261/12 , C07D261/14
CPC分类号： C07D261/12 , C07D261/14
摘要： 3-Amino-5-t-butylisoxazole is prepared by reacting pivaloylacetonitrile with hydroxylamine in aqueous medium under basic conditions and treating the reaction products with an acid. The process is economical and industrial.
摘要翻译： 3-氨基-5-叔丁基异恶唑通过在碱性条件下在水介质中使新戊酰基乙腈与羟胺反应并用酸处理反应产物来制备。这个过程是经济实惠的。

7. 发明授权

US4111680A Herbicidal compositions containing 3-isoxazolylurea derivatives 失效
标题翻译：含有3-异丙唑基衍生物的除草剂组合物
公开(公告)号：US4111680A
公开(公告)日：1978-09-05
申请号：US836238
申请日：1977-09-23
申请人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
发明人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
IPC分类号： C07D261/14 , C07D261/20 , A01N9/22
CPC分类号： C07D261/14 , C07D261/20
摘要： Isoxazole derivatives represented by the formula: ##STR1## wherein R represents hydrogen, alkyl group, or aryl group, R.sup.1 represents hydrogen, or alkyl group, R.sup.2 represents acyl group, a ##STR2## group [R.sup.3 and R.sup.4 each represent hydrogen, alkyl group, alkenyl group, alkynyl group, aralkyl group, aryl group, alkoxy group, or alkylthio group; or optionally R.sup.3 and R.sup.4 are combined with each other directly or indirectly including another hetero atom (nitrogen, oxygen, or sulfur) to form a nitrogen-containing ring], or a --CO--Y--R.sup.5 group[R.sup.5 represents alkyl group, alkenyl group, alkynyl group, aralkyl group, or aryl group, and Y represents oxygen, or sulfur], and X represents hydrogen, alkyl group, or halogen, or R and X are optionally combined each other to form an alkylene group, said alkyl group, aralkyl group, and aryl group each being optionally substituted with one or more members selected from halogen, alkyl group, alkoxy group, nitro group, and hydroxy group, are prepared by 11 routes. The isoxazole derivatives are useful as herbicides.
摘要翻译：由下式表示的异恶唑衍生物：其中R表示氢，烷基或芳基，R 1表示氢或烷基，R 2表示酰基，基团[R 3和R 4各自表示氢，烷基烯基，炔基，芳烷基，芳基，烷氧基或烷硫基; 或任选的R 3和R 4彼此直接或间接地包含另外的杂原子（氮，氧或硫）以形成含氮环]或-CO-Y-R 5基[R 5表示烷基，烯基基团，炔基，芳烷基或芳基，Y表示氧或硫]，X表示氢，烷基或卤素，或R和X任选地相互结合形成亚烷基，所述烷基芳烷基，芳基，芳基，可以被选自卤素，烷基，烷氧基，硝基，羟基中的一个以上的任意一个取代。异恶唑衍生物可用作除草剂。

8. 发明授权

US4028376A 3-Alkylisoxazole derivatives and herbicides containing them 失效
标题翻译：含有它们的3-烷基异恶唑衍生物和除草剂
公开(公告)号：US4028376A
公开(公告)日：1977-06-07
申请号：US615883
申请日：1975-09-23
申请人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
发明人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
IPC分类号： A01N47/18 , A01N43/80 , A01N47/36 , C07D261/14 , C07D261/20 , C07D1/14
CPC分类号： C07D261/14 , C07D261/20
摘要： 3-ALKYLISOXAZOLE DERIVATIVES REPRESENTED BY THE FORMULA: ##STR1## wherein R represents C.sub.3 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl, R.sup.1 represents hydrogen or C.sub.1 -C.sub.6 alkyl, R.sup.2 represents ##STR2## [in which R.sup.3 and R.sup.4 each represent hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.7 alkenyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.7 alkoxycarbonyl or C.sub.1 -C.sub.6 alkylthio, or ##STR3## represents morpholino, pyrrolidino or piperidino, and Y represents oxygen or sulfur] or --CO--Y--R.sup.5 [in which R.sup.5 represents C.sub.1 -C.sub.6 alkyl and Y is as defined above] and X represents hydrogen, halogen or C.sub.1 -C.sub.6 alkyl, or R and X are combined to form C.sub.3 -C.sub.6 alkylene, being useful as herbicides, are prepared by several routes.
摘要翻译：其中R表示C 3 -C 6烷基或C 3 -C 6环烷基，R 1表示氢或C 1 -C 6烷基，R 2表示其中R 3和R 4各自表示氢，C 1 -C 6烷基，C 1 -C 6烷氧基， C2-C7链烯基，C1-C6烷氧基，C2-C7烷氧基羰基或C1-C6烷硫基，或表示吗啉代，吡咯烷子基或哌啶子基，Y表示氧或硫]或-CO-Y-R5 [其中R5表示C1-C6烷基和 Y如上所定义），X表示氢，卤素或C 1 -C 6烷基，或R和X组合形成可用作除草剂的C 3 -C 6亚烷基，是通过若干途径制备的。

9. 发明授权

US4594203A Method for producing a thermoplastic polymeric sheet 失效
标题翻译：热塑性聚合物片材的制造方法
公开(公告)号：US4594203A
公开(公告)日：1986-06-10
申请号：US588963
申请日：1984-03-13
申请人： Satoru Hagiwara , Ichiro Ishizuka , Kazuo Okabe
发明人： Satoru Hagiwara , Ichiro Ishizuka , Kazuo Okabe
IPC分类号： B29C47/88 , B29C71/04
CPC分类号： B29C47/888 , B29C47/0021 , B29C47/8845 , B29C47/887 , B29C47/8875 , B29C47/0019
摘要： The present invention relates to a method for producing a thermoplastic polymeric sheet, wherein a molten thermoplastic polymer is extruded from an extrusion die in the form of a sheet onto a moving quenching member, with an electric potential difference being established between the surface of the moving quenching member and the extrusion die, whereby the polymer is caused to electrostatically solidify and adhered to the surface of the quenching member. The contact area of the polymeric sheet with the moving quenching member is held in an atmosphere of a gas which posesses better insulating properties than standard air. Thus the present invention provides a useful method that can produce, at higher speeds than conventional method, polymer sheets of high surface quality which avoid the operational problems encountered in the conventional methods.
摘要翻译：本发明涉及一种用于制造热塑性聚合物片材的方法，其中将熔融的热塑性聚合物从片状的挤出模头挤出到移动的淬火构件上，在移动的表面之间建立电位差淬火构件和挤出模头，由此使聚合物静电固化并粘附到淬火构件的表面。聚合物片与移动淬火构件的接触面积保持在比标准空气更好的绝缘性气体的气氛中。因此，本发明提供了一种有用的方法，其可以以比常规方法更高的速度产生高表面质量的聚合物片材，其避免了常规方法中遇到的操作问题。

10. 发明授权

US4116671A 3-Isoxazolylcarbamate derivatives 失效
标题翻译： 3-异恶唑基氨基甲酸酯衍生物
公开(公告)号：US4116671A
公开(公告)日：1978-09-26
申请号：US836237
申请日：1977-09-23
申请人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
发明人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
IPC分类号： C07D261/14 , C07D261/20 , A01N9/28
CPC分类号： C07D261/14 , C07D261/20
摘要： Isoxazole derivatives represented by the formula: ##STR1## wherein R represents hydrogen, alkyl group, or aryl group, R.sup.1 represents hydrogen, or alkyl group, R.sup.2 represents acyl group, a ##STR2## group [R.sup.3 and R.sup.4 each represent hydrogen, alkyl group, alkenyl group, alkynyl group, aralkyl group, aryl group, alkoxy group, or alkylthio group; or optionally R.sup.3 and R.sup.4 are combined with each other directly or indirectly including another hetero atom (nitrogen, oxygen, or sulfur) to form a nitrogen-containing ring], or a--CO--Y--R.sup.5group [R.sup.5 represents alkyl group, alkenyl group, alkynyl group, aralkyl group, or aryl group, and Y represents oxygen, or sulfur], and X represents hydrogen, alkyl group, or halogen, or R and X are optionally combined each other to form an alkylene group, said alkyl group, aralkyl group, and aryl group each being optionally substituted with one or more members selected from halogen, alkyl group, alkoxy group, nitro group, and hydroxy group, are prepared by eleven routes. The isoxazole derivatives are useful as herbicides.

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