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1. 发明授权

US3461140A Production of ethylene oxide 失效
标题翻译：生产乙烯氧化物
公开(公告)号：US3461140A
公开(公告)日：1969-08-12
申请号：US43872565
申请日：1965-03-10
申请人： BASF AG
发明人： TITZENTHALER ECKART
IPC分类号： B01J23/66 , C07D301/10 , C07D1/14
CPC分类号： C07D301/10 , B01J23/66 , Y02P20/52

2. 发明授权

US3845079A Method of producing ethylene oxide in conjunction with other alpha-oxides 失效
标题翻译：与其他氧化铝连接生产乙烯氧化物的方法
公开(公告)号：US3845079A
公开(公告)日：1974-10-29
申请号：US31939272
申请日：1972-12-29
申请人： FARBEROV M , EPSHTEIN D , BOBYLEV B
发明人： BOBYLEV B , EPSHTEIN D , FARBEROV M
IPC分类号： C07D301/19 , C07D1/08 , C07D1/14
CPC分类号： C07D301/19
摘要： 1. A METHOD OF PRODUCING ETHYLENE OXIDE TOGETHER WITH OTHER A-OXIDES, COMPRISSING THE STEPS OF EPOXIDIZING ETHYLENE WITH AN ORGANIC HYDROPEROXIDE IN THE PRESENCE OF A CATALYST COMPRISING A COMPOUND OFF A METAL FROM GROUPS V AND VI OF THE PERIODIC TABLE, IN A MEDIUM OF A HYDROCARBON SOLVENT, THE ETHYLENE BEING UNDER A PRESSURE OFF FROM 50 TO 300 ATM. AND A TEMPERATURE OF 70-160* C., UNTIL 10 TO 85 PERCENT OF HYDROPEROXIDE IS CONVERTED TO FORM ETHYLENE OXIDE; REMOVING AT LEAST PARTIALLY THE UNREACTED ETHYLENE FROM THE REACTION PRODUCTS; ADDING ANOTHER OLEFIN OR A MIXTURE OF OLEFINS HAVING A HIGHER REACTIVITY THAN ETHYLENE TO THE REMAINING REACTION MIXTURE, AND EPOXIDIZING SAID REAGENT WITH THE UNREACTED HYDROPEROXIDE UNTIL 95-100 PERCENT OF THE ORIGINAL AMOUNT OF THE UNREACTED HYDROPEROXIDE IS CONVERTED, UNDER A PRESSURE OF 1 TO 60 ATM., AND AT A TEMPERATURE OF 20-160* C., IN THE PRESENCE OF SAID CATALYST.

3. 发明授权

US3745092A Recovery and purification of ethylene oxide by distillation and absorption 失效
标题翻译：通过蒸馏和吸收来回收和纯化乙烯氧化物
公开(公告)号：US3745092A
公开(公告)日：1973-07-10
申请号：US3745092D
申请日：1971-01-11
申请人： SHELL OIL CO
发明人： VANDERWATER R
IPC分类号： C07D303/04 , C07D301/10 , C07D301/32 , C07D1/14
CPC分类号： C07D301/32 , C07D301/10
摘要： ETHYLENE OXIDE, PRODUCED BY THE DIRECT, CATALYTIC OXIDATION OF ETHYLENE, IN ADMIXTURE WITH INERT GASES, LOW MOLECULAR WEIGHT HYDROCARBONS, AND OXIDES OF CARBON, IS ABSORBED IN AN AQUEOUS STREAM AND STRIPPED THEREFROM TO PRODUCE A GASEOUS STRIPPING ZONE OVERHEAD. THE STRIPPING ZONE OVERHEAD IS COOLED, CONDENSING MOST OF THE WATER AND A PORTION OF THE ETHYLENE OXIDE CONTAINED THEREIN. THE COOLED STRIPPING ZONE OVERHEAD IS PHASE SEPARATED, THE VAPOR BEING CONTACTED WITH A LEAN AQUEOUS ABSORBENT IN A

SCRUBBING ZONE TO RECOVER SUBSTANTIALLY ALL OF THE ETHYLENE OXIDE FROM THE NON-CONDENSABLE GASES. THE LIQUID FROM THE PHASE. SEPARATOR AND THE ETHYLENE OXIDE-RICH AQUEOUS ABSORBATE ARE JOINED AND FED TO AN ETHYLENE OXIDE PURIFICATION ZONE, IN WHICH HIGH PURITY ETHYLENE OXIDE IS RECOVERED.

4. 发明授权

US3894059A Process for the oxidation of olefines 失效
标题翻译：烯烃氧化方法
公开(公告)号：US3894059A
公开(公告)日：1975-07-08
申请号：US35543773
申请日：1973-04-30
申请人： PETROCARBON DEV LTD
发明人： SELVARATNAM THILLYAMPALAM
IPC分类号： C07C27/00 , C07C29/124 , C07C29/66 , C07C31/20 , C07C31/34 , C07C67/00 , C07D301/26 , C07D1/04 , C07D1/12 , C07D1/14
CPC分类号： C07C29/66 , C07D301/26 , C07C31/36 , C07C29/106 , C07C31/202 , C07C31/205
摘要： Processes are provided for the oxidation of olefinically unsaturated compounds to oxirane compounds, vic-glycols and vichalohydrins in which the olefinically unsaturated compound, carbon dioxide water and hypohalite are brought into intimate contact so as to form vic-halohydrin, and if desired, exposing the vic-halohydrin to aqueous bicarbonate so as to form oxirane compound and/or vic-glycol. Bicarbonate is formed as by-product in the production of vic-halohydrin and this bicarbonate may be used to convert the vic-halohydrin to oxirane compound or vicglycol. Also carbon dioxide is formed as by-product during the conversion and this is advantageously used to provide carbon dioxide required for the production of the vic-halohydrin. Similarly, the hypohalite is conveniently formed by electrolysis of metal halide derived as by-product of the conversion of vichalohydrin to oxirane compound or vic-glycol.
摘要翻译：提供了将烯属不饱和化合物氧化成环氧乙烷化合物，维 - 乙二醇和邻 - 卤代醇的方法，其中使烯属不饱和化合物，二氧化碳水和次卤酸盐紧密接触形成vic-卤代醇，如果需要，将维 - 卤代醇暴露于含水碳酸氢盐中，以形成环氧乙烷化合物和/或维 - 乙二醇。碳酸氢盐在制备邻 - 卤代醇时作为副产物形成，并且该碳酸氢盐可用于将邻 - 卤代醇转化为环氧乙烷化合物或维 - 乙二醇。在转化期间二氧化碳也作为副产物形成，并且有利地用于提供生产维 - 卤代醇所需的二氧化碳。类似地，次卤酸盐可以方便地通过电解金属卤化物而形成，金属卤化物作为副产物转化为环氧乙烷化合物或维 - 乙二醇。

5. 发明授权

US3523957A Process for producing an olefinic oxide 失效
标题翻译：生产氧化烯的方法
公开(公告)号：US3523957A
公开(公告)日：1970-08-11
申请号：US3523957D
申请日：1966-12-07
申请人： LUMMUS CO
发明人： TSAO UTAH
IPC分类号： C07D301/32 , C07D1/14
CPC分类号： C07D301/32

6. 发明授权

US4028376A 3-Alkylisoxazole derivatives and herbicides containing them 失效
标题翻译：含有它们的3-烷基异恶唑衍生物和除草剂
公开(公告)号：US4028376A
公开(公告)日：1977-06-07
申请号：US615883
申请日：1975-09-23
申请人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
发明人： Hisajiro Yukinaga , Shinzaburo Sumimoto , Ichiro Ishizuka , Jitsuo Sugita
IPC分类号： A01N47/18 , A01N43/80 , A01N47/36 , C07D261/14 , C07D261/20 , C07D1/14
CPC分类号： C07D261/14 , C07D261/20
摘要： 3-ALKYLISOXAZOLE DERIVATIVES REPRESENTED BY THE FORMULA: ##STR1## wherein R represents C.sub.3 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl, R.sup.1 represents hydrogen or C.sub.1 -C.sub.6 alkyl, R.sup.2 represents ##STR2## [in which R.sup.3 and R.sup.4 each represent hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.7 alkenyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.7 alkoxycarbonyl or C.sub.1 -C.sub.6 alkylthio, or ##STR3## represents morpholino, pyrrolidino or piperidino, and Y represents oxygen or sulfur] or --CO--Y--R.sup.5 [in which R.sup.5 represents C.sub.1 -C.sub.6 alkyl and Y is as defined above] and X represents hydrogen, halogen or C.sub.1 -C.sub.6 alkyl, or R and X are combined to form C.sub.3 -C.sub.6 alkylene, being useful as herbicides, are prepared by several routes.
摘要翻译：其中R表示C 3 -C 6烷基或C 3 -C 6环烷基，R 1表示氢或C 1 -C 6烷基，R 2表示其中R 3和R 4各自表示氢，C 1 -C 6烷基，C 1 -C 6烷氧基， C2-C7链烯基，C1-C6烷氧基，C2-C7烷氧基羰基或C1-C6烷硫基，或表示吗啉代，吡咯烷子基或哌啶子基，Y表示氧或硫]或-CO-Y-R5 [其中R5表示C1-C6烷基和 Y如上所定义），X表示氢，卤素或C 1 -C 6烷基，或R和X组合形成可用作除草剂的C 3 -C 6亚烷基，是通过若干途径制备的。

7. 发明授权

US3798898A Gas turbine prime mover 失效
标题翻译：气体涡轮增压器
公开(公告)号：US3798898A
公开(公告)日：1974-03-26
申请号：US19186971
申请日：1971-10-22
申请人： DELAHAYE J
发明人： DELAHAYE J
IPC分类号： B01J19/00 , C07C51/215 , F02C6/10 , F02C3/00 , C07D1/14
CPC分类号： F02C6/10 , C07C51/215 , C07C63/16 , C07C53/08
摘要： A gas turbine prime mover is comprised of at least one air compressor, a combustion chamber, an oxidation reactor and an expansion turbine. Turbine power is developed by compressing air in said at least one air compressor, injecting a portion of said compressed air directly into the combustion chamber of the expansion turbine wherein combustion is taking place, injecting remaining compressed air into a chemical oxidation reactor wherein an oxidation reaction is taking place, injecting residual gases of the said oxidation reaction into the said combustion chamber, and thence driving a turbine utilizing the products of the said combustion reaction as the working medium for the said turbine.
摘要翻译：燃气轮机原动机由至少一个空气压缩机，燃烧室，氧化反应器和膨胀涡轮组成。通过在所述至少一个空气压缩机中压缩空气来发展涡轮发电，将一部分所述压缩空气直接喷入到其中发生燃烧的膨胀涡轮机的燃烧室中，将剩余的压缩空气注入到化学氧化反应器中，其中氧化反应正在进行，将所述氧化反应的残余气体注入所述燃烧室，然后利用所述燃烧反应的产物驱动涡轮机作为所述涡轮机的工作介质。

8. 发明授权

US3654318A Method of preparing ethylene oxide 失效
标题翻译：制备乙烯氧化物的方法
公开(公告)号：US3654318A
公开(公告)日：1972-04-04
申请号：US3654318D
申请日：1970-06-23
申请人： AIR PROD & CHEM
发明人： KUCIRKA JOHN F
IPC分类号： B01J23/50 , C07D1/14
CPC分类号： B01J23/50
摘要： A CATALYST COMPOSITION, CONVENIENTLY DESIGNATED AS SILVER ALUMINATE MONOHYDRATE, FUNCTIONS AS A CATALYST FOR THE SYNTHESIS OF ETHYLENE OXIDE FROM OXYGEN AND ETHYLENE. THE CATALYST HAD 65$5% SILVER, A PORE VOLUME OF 0.6 TO 1.5 CC./G., AND A SURFACE AREA OF 100-600 M.2/G. THE CATALYST IS SO ACTIVE THAT ACCEPTABLE CONVERSIONS ARE OBTAINED BELOW 192*C., THE CRITICAL TEMPERATURE OF ETHYLENE OXIDE.

9. 发明授权

US3603085A Process for the production of ethylene oxide 失效
标题翻译：生产乙烯氧化物的方法
公开(公告)号：US3603085A
公开(公告)日：1971-09-07
申请号：US3603085D
申请日：1968-02-16
申请人： SNAM PROGETTI
发明人： PARMEGIANI MARIO , CLEMENTI ANACLETO
IPC分类号： B01J19/00 , F02C3/00 , C07D1/14
CPC分类号： B01J19/0013 , B01J2219/00063 , B01J2219/00065 , B01J2219/00103
摘要： A process for producing ethylene oxide wherein a portion of the gases produced in the process are combusted with supplementary fuel to produce products of combustion that drive a gas turbineair compressor. The compressed air from the air compressor is returned to the ethylene oxide reactor to be used in the production of ethylene oxide.

10. 发明授权

US3644432A Process for recovering ethylene oxide 失效
标题翻译：回收乙烯氧化物的方法
公开(公告)号：US3644432A
公开(公告)日：1972-02-22
申请号：US3644432D
申请日：1969-09-30
申请人： HALCON INTERNATIONAL INC
发明人： HOCH ROBERT , GILMAN HAROLD
IPC分类号： C07D301/32 , C07D1/14
CPC分类号： C07D301/32
摘要： THIS INVENTION RELATES TO A PROCESS FOR THE RECOVERY OF ETHYLENE OXIDE FROM THE RICH CYCLE GAS RESULTING FROM THE VAPOR PHASE REACTION OF ETHYLENE WITH MOLECULAR OXYGEN UNDER ETHYLENE OXIDE FORMING CONDITIONS. RECOVERY IS EFFECTED BY SCRUBBING THE RICH CYCLE GAS WITH A NON-AQUEOUS LIQUID ABSORBENT IN A DRY SYSTEM AT CRYOGENIC CONDTIONS AND THEREAFTER STRIPPING THE ASORBENT FROM ETHYLENE OXIDE ABSORBATE WHICH IS THEN REFINED TO THE DESIRED PRODUCT. ADVANTAGES OF THE PROCESS RESIDE IN THE ELIMINATION OF THE USUAL GYCOL MAKE ACCOMPANYING RECOVERY IN AN AQUEOUS SYSTEM AND IN THE ABTENTION OF HIGH ETHYLENE OXIDE CONCENTRATIONS IN THE LIQUID PHASE. THE INVENTIVE PROCESS MAY ADVANTAGEOUSLY PROVIDE AN ABOSORBENT INVENTORY FOR CONTINOUS PROCESS OPERATION BY CONDENSATION AND RECYCLING OF OVERHEAD ABSORBENT FROM THE STRIPPER. THE INVENTION IS OF PARTICULAR VALUE IN AN ETHANE BALLASTEDHIGH PURITY OXYGEN SYSTEM UTILIZING LIQID ETHANE AS ABSORBENT; THE HIGH ETHANE PARTIAL PRESSURES MAY BE AVAILED OF TO RAISE THE TEMPERATURE LEVEL OF THE REFRIGERATION REQUIRED AND THEREBY REDUCE ITS COST.

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