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1. 发明申请

US20060060502A1 Bulk bi-metallic catalysts made from precursors containing an organic agent 有权
公开(公告)号：US20060060502A1
公开(公告)日：2006-03-23
申请号：US11227726
申请日：2005-09-14
申请人： Stuart Soled , Sabato Miseo , Zhiguo Hou
发明人： Stuart Soled , Sabato Miseo , Zhiguo Hou
IPC分类号： C10G45/04 , C10G45/44 , C10G47/02 , C10G45/60 , C07C5/02 , B01J27/02 , B01J31/00 , B01J27/043
CPC分类号： B01J35/002 , B01J23/88 , B01J23/883 , B01J23/888 , B01J27/188 , B01J27/24 , B01J35/1014 , B01J35/1038 , B01J37/0018 , B01J37/03 , B01J37/20 , B01J37/28 , C10G45/08 , C10G45/38 , C10G45/50 , C10G45/60 , C10G47/02 , C10G49/04 , C10G49/08 , C10G65/02 , C10G65/12
摘要： Bulk bi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.

2. 发明申请

US20060060503A1 Bulk Ni-Mo-W catalysts made from precursors containing an organic agent 有权
公开(公告)号：US20060060503A1
公开(公告)日：2006-03-23
申请号：US11227727
申请日：2005-09-14
申请人： Stuart Soled , Sabato Miseo , Zhiguo Hou
发明人： Stuart Soled , Sabato Miseo , Zhiguo Hou
IPC分类号： C10G45/04 , C10G47/02 , C10G45/44 , C10G45/60 , C07C5/02 , B01J27/24 , B01J27/02 , B01J27/043 , B01J27/051 , B01J27/047
CPC分类号： C10G65/12 , B01J23/8885 , B01J27/24 , B01J35/002 , B01J35/1014 , B01J35/1038 , B01J37/0018 , B01J37/03 , B01J37/20 , C10G45/08 , C10G45/48 , C10G45/60 , C10G47/02 , C10G47/06 , C10G49/04 , C10G65/02
摘要： Novel bulk tri-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.

3. 发明申请

US20060293544A1 Partially decomposed catalyst and hydrocarbon oxidation processes using the same 有权
标题翻译：部分分解的催化剂和烃氧化方法使用它们
公开(公告)号：US20060293544A1
公开(公告)日：2006-12-28
申请号：US11434717
申请日：2006-05-16
申请人： Jihad Dakka , Sabato Miseo , Stuart Soled , Jose Santiesteban , Joseph Baumgartner , Michiel Van Vliet , Roger Sheldon
发明人： Jihad Dakka , Sabato Miseo , Stuart Soled , Jose Santiesteban , Joseph Baumgartner , Michiel Van Vliet , Roger Sheldon
IPC分类号： C07C27/00
CPC分类号： B01J31/2243 , B01J23/76 , B01J2231/70 , B01J2531/16 , B01J2531/847 , C07C68/00 , C07C69/96
摘要： The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof. The invention is also related to a process for manufacturing of a catalyst comprising mixing L-arginine, a Cu-based compound, water, and optionally another metal-based compound to form a solution; impregnating the solution onto a silica support to form a catalyst precursor; and partially decomposing the L-arginine to form the catalyst so that at least 5% of L-arginine remains in the catalyst.
摘要翻译：本发明涉及烃氧化方法。该方法包括在自由基引发剂和催化剂的存在下使一种或多种烃与氧源接触。催化剂包含位于催化剂载体上的有机金属络合物，并通过有机金属络合物的部分分解获得。例如，该方法可用于从二甲氧基甲烷生产碳酸二甲酯。本发明还涉及包含二氧化硅载体和有机金属络合物的部分分解的催化剂，其中至少5％的有机化合物保留在催化剂中。有机金属络合物包括有机化合物和金属基化合物，其中金属选自铜，镍及其组合。本发明还涉及制造催化剂的方法，其包括将L-精氨酸，Cu基化合物，水和任选的其它金属类化合物混合以形成溶液; 将溶液浸渍到二氧化硅载体上以形成催化剂前体; 并部分分解L-精氨酸以形成催化剂，使得至少5％的L-精氨酸保留在催化剂中。

4. 发明申请

US20100012554A1 Selective Catalysts For Naphtha Hydrodesulfurization 有权
标题翻译：选择性催化剂用于石脑油加氢脱硫
公开(公告)号：US20100012554A1
公开(公告)日：2010-01-21
申请号：US12087980
申请日：2007-01-12
申请人： Chuansheng Bai , Stuart Soled , Sabato MIseo , Jonathan McConnachie
发明人： Chuansheng Bai , Stuart Soled , Sabato MIseo , Jonathan McConnachie
IPC分类号： C10G29/22 , B01J31/02 , C10G29/20
CPC分类号： B01J23/882 , B01J21/08 , B01J29/0341 , B01J31/04 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J37/0203 , B01J37/20 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2300/80 , C10G2400/02
摘要： Naphtha is selectively hydrodesulfurized with retention of olefin content. More particularly, a CoMo metal hydrogenation component is loaded on a silica or modified silica support in the presence of an organic additive to produce a catalyst which is then used for hydrodesulfurizing naphtha while retaining olefins.
摘要翻译：石脑油选择性加氢脱硫，保留烯烃含量。更具体地说，在有机添加剂的存在下，将CoMo金属氢化组分负载在二氧化硅或改性二氧化硅载体上以产生催化剂，然后将其用于加氢脱硫石脑油同时保留烯烃。

5. 发明申请

US20070082811A1 Method of preparing a hydrotreating catalyst on a support containing a rare earth metal 有权
标题翻译：在含有稀土金属的载体上制备加氢处理催化剂的方法
公开(公告)号：US20070082811A1
公开(公告)日：2007-04-12
申请号：US11238930
申请日：2005-09-29
申请人： Stuart Soled , Sabato Miseo , Joseph Baumgartner , Christine Kliewer , Jeffrey Elks
发明人： Stuart Soled , Sabato Miseo , Joseph Baumgartner , Christine Kliewer , Jeffrey Elks
IPC分类号： B01J23/00
CPC分类号： B01J23/8871 , B01J23/888 , B01J37/0203 , B01J37/0205 , B01J37/20
摘要： This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids.
摘要翻译：本发明涉及用于烃进料加氢处理的负载型多金属催化剂，以及制备这种催化剂的方法。催化剂由至少一种VIII族金属和第Ⅵ族金属的催化剂前体和选自氨基醇和氨基酸的有机试剂制备。

6. 发明申请

US20070227949A1 Hydrotreating Catalyst Containing a Group V Metal 有权
标题翻译：含有V族金属的加氢精制催化剂
公开(公告)号：US20070227949A1
公开(公告)日：2007-10-04
申请号：US11579391
申请日：2005-04-19
申请人： Sonja Eijsbouts , Stuart Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Stuart Soled , Sabato Miseo
IPC分类号： C10G45/08 , B01J23/887 , B01J37/20
CPC分类号： B01J23/8877 , B01J37/0009 , B01J37/0236 , B01J37/20 , C10G45/08
摘要： The present invention pertains to a sulfur-containing catalyst composition suitable for the hydrotreating of hydro-carbon feeds which comprises a Group VIB metal component selected from molybdenum, tungsten, and mixtures thereof, a Group V metal component selected from vanadium, niobium, tantalum, and mixtures thereof, and a Group VIII metal component selected from nickel, cobalt, iron, and mixtures thereof, the metal components (calculated as oxides) making up at least 50 wt. % of the catalyst, wherein the molar ratio between the metal components satisfies the following formula: (Group VIB+Group V):(Group VIII)=0.5-2:1. This catalyst has been found to show a high activity in sulfur removal in combination with good aromatics removal properties.
摘要翻译：本发明涉及适用于加氢处理含氢催化剂组合物的含氢催化剂组合物，该组合物包含选自钼，钨及其混合物的VIB族金属组分，选自钒，铌，钽，和它们的混合物，以及选自镍，钴，铁及其混合物的VIII族金属组分，所述金属组分（以氧化物计）占组合物的至少50重量％。％的催化剂，其中金属组分之间的摩尔比满足下式：（VIB + V族）（VIII族）= 0.5-2:1。已经发现该催化剂显示出除去高硫的高活性，同时具有良好的芳族化合物去除性能。

7. 发明申请

US20070090023A1 Hydroprocessing using hydrothermally-prepared bulk multimetallic catalysts 有权
标题翻译：使用水热制备的大量多金属催化剂进行加氢处理
公开(公告)号：US20070090023A1
公开(公告)日：2007-04-26
申请号：US11586397
申请日：2006-10-25
申请人： Stuart Soled , Sabato Miseo , Sonja Eijsbouts , Frans Plantenga
发明人： Stuart Soled , Sabato Miseo , Sonja Eijsbouts , Frans Plantenga
IPC分类号： B01J23/00 , C10G45/00 , C10G45/08
CPC分类号： B01J23/888 , B01J23/002 , B01J23/85 , B01J35/002 , B01J37/0072 , B01J37/0236 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G47/04 , C10G2300/202 , C10G2300/207 , C10G2400/04 , C10G2400/10 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/56
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing at leas one Group VIII metal and at least one Group VIB metal. The catalyst is prepared hydrothermally.
摘要翻译：本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。该催化剂是含有一种Ⅷ族金属和至少一种ⅥB族金属的大量催化剂。催化剂水热制备。

8. 发明申请

US20070084754A1 Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts 有权
标题翻译：散装双金属催化剂，制造块状双金属催化剂的方法和使用散装双金属催化剂的加氢处理
公开(公告)号：US20070084754A1
公开(公告)日：2007-04-19
申请号：US11586399
申请日：2006-10-25
申请人： Stuart Soled , Sabato Miseo , Sonja Eijsbouts , Frans Plantenga
发明人： Stuart Soled , Sabato Miseo , Sonja Eijsbouts , Frans Plantenga
IPC分类号： C10G45/00 , C10G17/00
CPC分类号： C10G45/08 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/038 , B01J37/20
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst comprising a Group VIII metal and a Group VIB metal.
摘要翻译：本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。该催化剂是包含VIII族金属和VIB族金属的本体催化剂。

9. 发明申请

US20050277545A1 Bulk metal hydrotreating catalyst used in the production of low sulfur diesel fuels 有权
标题翻译：用于生产低硫柴油燃料的散装金属加氢处理催化剂
公开(公告)号：US20050277545A1
公开(公告)日：2005-12-15
申请号：US11096501
申请日：2005-04-01
申请人： Stuart Shih , Stuart Soled , Sabato Miseo
发明人： Stuart Shih , Stuart Soled , Sabato Miseo
IPC分类号： B01J23/20 , B01J23/28 , B01J23/847 , B01J23/882 , B01J23/887 , C10G45/08
CPC分类号： B01J23/8877 , B01J23/28 , B01J23/8474 , B01J23/882 , C10G45/08
摘要： The instant invention relates to a bulk metal hydrotreating catalyst used for hydrotreating diesel boiling range feedstreams to produce low sulfur diesel products.
摘要翻译：本发明涉及用于加氢处理柴油沸程的原料流以生产低硫柴油产品的散装金属加氢处理催化剂。

10. 发明申请

US20050065384A1 Hydrogenation of oxo aldehydes to oxo alcohols in the presence of a nickel-molybdenum catalyst 失效
标题翻译：在镍 - 钼催化剂存在下，将羰基醛氢化成羰基合成醇
公开(公告)号：US20050065384A1
公开(公告)日：2005-03-24
申请号：US10938252
申请日：2004-09-10
申请人： Ramzi Saleh , Stuart Soled , Sabato Miseo , Hyung Woo
发明人： Ramzi Saleh , Stuart Soled , Sabato Miseo , Hyung Woo
IPC分类号： C07C29/141 , C07C29/14
CPC分类号： C07C29/141 , C07C31/125
摘要： A reduced or partially reduced nickel-molybdenum catalyst prepared by a process having the steps of 1) reacting nickel carbonate and molybdenum oxide precursors to form nickel molybdate and 2) treating the nickel molybdate under reducing conditions to form the reduced or partially reduced nickel-molybdenum catalyst. There is also a process for making the catalyst. There is also a process for using the catalyst in the hydrogenation of an oxo aldehyde, thereby forming an oxo alcohol of high selectivity. There is also a process for forming an oxo alcohol from the hydroformylation/hydrogenation of an olefinic feedstream. There is also a process for forming an oxo alcohol by contacting formates, dimers, trimers, and organic acids with hydrogen in the presence of a reduced or partially reduced nickel-molybdenum catalyst. The foregoing processes are also useful with a catalyst having the general formula YxZ wherein Y is nickel and/or cobalt and Z is molybdenum and/or tungsten; and wherein x ranges between about 0.25 to about 4.0. There are also reduced or partially reduced catalysts of the general formula NixMo or YxZ wherein x ranges between about 0.25 to about 4.0 and wherein oxide precursors of the catalysts are substantially free of ammonium groups.
摘要翻译：通过具有以下步骤的方法制备的还原或部分还原的镍 - 钼催化剂：具有以下步骤：1）使碳酸镍和氧化钼前体反应形成钼酸镍，和2）在还原条件下处理钼酸镍以形成还原或部分还原的镍 - 钼催化剂。还有一种制备催化剂的方法。还有一种使用催化剂加氢羰基醛的方法，从而形成高选择性的羰基合成醇。还有从烯烃进料流的加氢甲酰化/氢化形成羰基合成醇的方法。还有一种通过在还原或部分还原的镍 - 钼催化剂存在下使甲酸盐，二聚体，三聚体和有机酸与氢接触来形成羰基合成醇的方法。上述方法对于具有通式Y x Z的催化剂也是有用的，其中Y是镍和/或钴，Z是钼和/或钨; 并且其中x在约0.25至约4.0之间。还有还原或部分还原的通式为NixMo或YxZ的催化剂，其中x为约0.25至约4.0，并且其中催化剂的氧化物前体基本上不含铵基团。

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