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    • 3. 发明申请
    • Porphyrin compositions
    • 卟啉组合物
    • US20060152149A1
    • 2006-07-13
    • US11326949
    • 2006-01-06
    • Kyle LitzJames CellaQing Ye
    • Kyle LitzJames CellaQing Ye
    • H01J1/62C08F230/04C07F15/00
    • C07D487/22
    • Novel metal porphyrin compositions useful as organic phosphors are provided. The novel compositions are prepared from commercially available porphyrin-containing starting materials. In one instance a novel palladium-containing porphyrin composition having a number average molecular weight of greater than 12,000 grams per mole was prepared from 5,10,15,20-tetrakis(3′,5′-di(hydroxy)phenyl)-21H-23H-porphyrin by reaction first with palladium(II) acetylacetonate, followed by reaction with 2-bromo-2-methylpropionyl bromide, and subsequent group transfer reaction of the alpha-bromo ester groups with 9,9-dioctyl-2-vinylfluorene in the presence of CuBr as a radical initiator. The product polymer exhibited a number average molecular weight of 12,884 grams per mole, a weight average molecular weight of 14,338 grams per mole, and a robust red phosphorescent emission. Porphyrin containing copoylmers comprising structural units derived from 9,9-dioctyl-2-vinylfluorene and 9-anthracenylmethyl methacrylate were prepared in a similar fashion.
    • 提供了可用作有机磷光体的新型金属卟啉组合物。 该新型组合物由市售的含卟啉原料制备。 在一种情况下,从5,10,15,20-四(3',5'-二(羟基)苯基)-21H(5')中制备数均分子量大于12,000克/摩尔的新颖的含钯卟啉组合物 -23H-卟啉通过首先与乙酰丙酮钯(II)反应,随后与2-溴-2-甲基丙酰溴反应,随后将α-溴酯基与9,9-二辛基-2-乙烯基芴的组转移反应 存在CuBr作为自由基引发剂。 产物聚合物的数均分子量为12,884克/摩尔,重均分子量为14,338克/摩尔,并具有坚固的红色磷光发射。 含有衍生自9,9-二辛基-2-乙烯基芴和9-蒽基甲基甲基丙烯酸酯的结构单元的含卟啉的共聚酰基酯以类似的方式制备。
    • 4. 发明申请
    • Thermally crosslinked polymers
    • 热交联聚合物
    • US20050258407A1
    • 2005-11-24
    • US11189911
    • 2005-07-26
    • James CellaRachid Kerboua
    • James CellaRachid Kerboua
    • C08G64/04F21V9/00
    • C08G64/045
    • Crosslinking between polymer chains having olefin groups occurs by heating the polymer chains in the presence of a catalyst. Mixtures of polymer and catalyst can be dried and cast into films at ambient temperatures and remain non-crosslinked and soluble for extended periods. However, upon heating of the polymer to temperatures of about 300° C. or greater in the presence of a catalyst, the polymer chains of the film are cured to produce an insoluble crosslinked matrix. The sudden and relatively complete nature of the crosslinking between the polymers under specific conditions is particularly useful to allow chromophores poled in a noncrosslinked polymer mixture to retain their uniform orientation after crosslinking has occurred.
    • 在具有烯烃基团的聚合物链之间的交联通过在催化剂存在下加热聚合物链而发生。 聚合物和催化剂的混合物可以在环境温度下干燥并浇注成膜,并保持非交联并长时间溶解。 然而,当在催化剂存在下将聚合物加热到约300℃或更高的温度时,该膜的聚合物链被固化以产生不溶的交联基质。 在特定条件下聚合物之间交联的突然且相对完整的性质特别有用,以使非交联聚合物混合物中的发色团保持其交联发生后的均匀取向。
    • 5. 发明申请
    • OPTOELECTRONIC DEVICES WITH MULTILAYERED STRUCTURES
    • 具有多层结构的光电器件
    • US20070225464A1
    • 2007-09-27
    • US11748195
    • 2007-05-14
    • Larry LewisKelly ChichakJames CellaJoseph Shiang
    • Larry LewisKelly ChichakJames CellaJoseph Shiang
    • C08G77/04C08L83/04
    • C08G77/58G02B1/043C08L83/04
    • Optoelectronic devices include polysiloxanes derived from hydrosilation of an organometallic compound of formula L2MZ, wherein L and Z are independently bidentate ligands; at least one of L and Z comprises alkenyl, alkenylaryl, alkenyloxy, alkenyloxyaryl, alkynyl, alkynylaryl, alkynyloxy, alkynyloxyaryl, substituted alkenyl, substituted alkenylaryl, substituted alkenyloxy, substituted alkenyloxyaryl, substituted alkynyl, substituted alkynylaryl, substituted alkynyloxy, substituted alkynyloxyaryl, acrylate, methacrylate, or a combination thereof; and M is Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Ga, Ge, In, Sn, Sb, Tl, Pd, Bi, Po, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu.
    • 光电器件包括衍生自式L 2 MZ的有机金属化合物的硅氢化的聚硅氧烷,其中L和Z独立地是二齿配体; L和Z中的至少一个包括烯基,烯基芳基,烯氧基,烯基氧基芳基,炔基,炔基芳基,炔氧基,炔氧基芳基,取代的烯基,取代的烯基芳基,取代的烯氧基,取代的烯基氧基芳基,取代的炔基,取代的炔基芳基,取代的炔氧基,取代的炔氧基芳基,丙烯酸酯, 甲基丙烯酸酯或其组合; 并且M是Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Hf,Ta,W,Re,Os,Ir,Pt,Au,Hg,Ga,Ge,In,Sn,Sb, ,Pd,Bi,Po,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb或Lu。