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1. 发明授权

US4221645A Polycarbonates with end groups containing double bonds which can be crosslinked by UV light 失效
标题翻译：具有端基的聚碳酸酯含有双键，其可以通过UV光交联
公开(公告)号：US4221645A
公开(公告)日：1980-09-09
申请号：US50899
申请日：1979-06-21
申请人： Siegfried Adelmann , Dieter Margotte , Hans J. Rosenkranz , Hugo Vernaleken , Werner Nouvertne , Dieter Freitag
发明人： Siegfried Adelmann , Dieter Margotte , Hans J. Rosenkranz , Hugo Vernaleken , Werner Nouvertne , Dieter Freitag
IPC分类号： C08F299/00 , C08F290/00 , C08F299/02 , C08F299/04 , C08G63/00 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/40 , C08J3/28 , C08F8/00
CPC分类号： C08J3/28 , C08G64/045 , C08J2369/00
摘要： High molecular weight aromatic polycarbonates having molecular weights M.sub.w (weight average) of between about 10,000 and 200,000, which are based on diphenols and monofunctional chain stoppers, which correspond to the general formula ##STR1## in which Z denotes the radical of a diphenol,n denotes an integer from 20 to 400,E denotes ##STR2## m is 0 or 1 and R denotes a hydrogen atom or a C.sub.1 to C.sub.3 alkyl group, and in which between about 0.5 and 5 mol % of Z are radicals of aromatic dihydroxyketones. These polycarbonates share mechanical and thermal properties with known polycarbonates but in addition are suitable for crosslinking, for example in the presence of photoinitiators and optionally photo-reducing agents and under irradiation with UV light. When crosslinked they are resistant to organic solvents and insensitive to stress-cracking, and have particularly good flame-repellent properties when additionally incorporating flameproofing agents.
摘要翻译：分子量Mw（重均分子量）在10,000和200,000之间的高分子量芳族聚碳酸酯，它们基于二酚和单官能链终止剂，其对应于通式（I），其中Z表示二苯酚，n表示20〜400的整数，E表示m为0或1，R表示氢原子或C1〜C3烷基，其中约0.5〜5摩尔％的Z为芳族二羟基酮。这些聚碳酸酯与已知的聚碳酸酯共享机械和热性能，但另外适用于交联，例如在光引发剂和任选的光还原剂的存在下，并且在用UV光照射下。当交联时，它们对有机溶剂具有耐受性并且对应力开裂不敏感，并且当额外加入防火剂时具有特别好的阻燃性能。

2. 发明授权

US4041003A Process for molding aromatic polycarbonates having perfluoroalkanesulphonic acid derivatives as mold release agents 失效
标题翻译：用于模塑具有全氟烷基磺酸衍生物的芳族聚碳酸酯作为脱模剂的方法
公开(公告)号：US4041003A
公开(公告)日：1977-08-09
申请号：US656229
申请日：1976-02-09
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Hans Niederprum , Johann Nikolaus Meussdoerffer , Werner Nouvertne
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Hans Niederprum , Johann Nikolaus Meussdoerffer , Werner Nouvertne
IPC分类号： C08L69/00 , C08K5/36 , C08K5/42 , C08K5/43
CPC分类号： C08K5/42 , C08K5/43
摘要： The present invention is concerned with a process for molding thermoplastic, high molecular weight aromatic polycarbonates the improvement which comprises adding to the aromatic polycarbonate from about 0.001 to 1% by weight of a mold release agent selected from the group consisting of perfluoroalkanesulphonic acid amides, cyclimmonium salts of perfluoroalkanesulphonic acids and ammonium salts of perfluoroalkanesulphonic acids.
摘要翻译：本发明涉及用于模塑热塑性高分子量芳族聚碳酸酯的方法，其改进包括向芳族聚碳酸酯中加入约0.001至1重量％的脱模剂，所述脱模剂选自全氟烷基磺酸酰胺，环戊烯全氟烷基磺酸的盐和全氟烷基磺酸的铵盐。

3. 发明授权

US4007150A Use of perfluoroalkanesulphonic acid amides and/or cyclimmonium salts of perfluoroalkansulphonic acids as mold release agents 失效
标题翻译：全氟烷基磺酰胺和/或全氟烷烃磺酸的环戊基铵盐的使用作为脱模剂
公开(公告)号：US4007150A
公开(公告)日：1977-02-08
申请号：US656226
申请日：1976-02-09
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Hans Niederprum , Johann Nikolaus Meussdoerffer , Werner Nouvertne
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Hans Niederprum , Johann Nikolaus Meussdoerffer , Werner Nouvertne
IPC分类号： C08L69/00 , C08K5/36 , C08K5/42 , C08K5/43
CPC分类号： C08K5/42 , C08K5/43
摘要： The present invention is concerned with molding compositions which contain an aromatic polycarbonate and from about 0.001 to 1% by weight of a mold release agent selected from the group consisting of perfluoroalkanesulphonic acid amides and cyclimmonium salts of perfluoroalkanesulphonic acids.
摘要翻译：本发明涉及含有芳族聚碳酸酯和约0.001至1重量％选自全氟烷基磺酸酰胺和全氟烷基磺酸的环辛基铵的脱模剂的模塑组合物。

4. 发明授权

US4131575A Thermoplastic polycarbonate molding materials with improved mold release 失效
标题翻译：热塑性聚碳酸酯成型材料具有改进的脱模性能
公开(公告)号：US4131575A
公开(公告)日：1978-12-26
申请号：US769725
申请日：1977-02-17
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
IPC分类号： C08K5/103 , C08L69/00
CPC分类号： C08K5/103
摘要： The present invention is concerned with thermoplastic molding materials of high molecular weight, thermoplastic, aromatic polycarbonates based on aromatic dihydroxy compounds and containing from about 0.01 to 0.1% by weight of esters of saturated aliphatic carboxylic acids with 10 to 20 C atoms and 4-hydric to 6-hydric alcohols.
摘要翻译：本发明涉及基于芳族二羟基化合物的高分子量，热塑性芳族聚碳酸酯的热塑性成型材料，并且含有约0.01至0.1重量％的具有10-20个碳原子的饱和脂族羧酸和4-羟基至6-羟基醇。

5. 发明授权

US4065436A Thermoplastic polycarbonate moulding compositions with improved ease of mould release 失效
标题翻译：具有提高脱模容易性的热塑性聚碳酸酯模塑组合物
公开(公告)号：US4065436A
公开(公告)日：1977-12-27
申请号：US710069
申请日：1976-07-30
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
IPC分类号： C08L69/00 , C08K5/00 , C08K5/10 , C08K5/105 , C08L67/00 , H05K3/28
CPC分类号： C08K5/105 , C08K5/10 , H05K3/285 , H05K3/288
摘要： The invention relates to a thermoplastic moulding composition comprising a thermoplastic aromatic polycarbonate based on an aromatic dihydroxy compound and containing 0.01 to 0.5% by weight of an ester of a saturated aliphatic carboxylic acid with 10 to 20 C atoms per molecule and an aromatic hydroxy compound with from 1 to 6 hydroxyl groups.
摘要翻译：本发明涉及一种热塑性模塑组合物，其包含基于芳族二羟基化合物的热塑性芳族聚碳酸酯，并且含有0.01至0.5重量％的每分子具有10至20个C原子的饱和脂族羧酸酯和具有 1至6个羟基。

6. 发明授权

US4143024A Thermoplastic polycarbonate moulding compositions with improved ease of mould release 失效
标题翻译：具有改进的模具释放的热塑性聚碳酸酯成型组合物
公开(公告)号：US4143024A
公开(公告)日：1979-03-06
申请号：US793011
申请日：1977-05-02
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken , Werner Nouvertne
IPC分类号： C08G64/06 , C08K5/10 , H05K3/28 , C08L69/00 , C10M7/24
CPC分类号： C08G64/06 , C08K5/10 , H05K3/285 , H05K3/288
摘要： The invention relates to a thermoplastic moulding composition comprising a high molecular, thermoplastic aromatic polycarbonate based on an aromatic dihydroxy compound and containing 0,01 to 0.5% by weight of an ester of a saturated aliphatic carboxylic acid with 10 to 20 C. atoms per molecule and an aromatic hydroxy compound with from 1 to 6 OH groups.

7. 发明授权

US4230548A Polycarbonates with end groups containing bonds which can be crosslinked by UV light 失效
标题翻译：具有端基的聚碳酸酯含有可以通过UV光交联的键
公开(公告)号：US4230548A
公开(公告)日：1980-10-28
申请号：US34839
申请日：1979-04-30
申请人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken
发明人： Siegfried Adelmann , Dieter Margotte , Hugo Vernaleken
IPC分类号： C08F2/00 , C08F2/48 , C08F290/00 , C08F299/00 , C08F299/04 , C08G63/00 , C08G63/64 , C08G64/00 , C08G64/14 , C08G63/62 , C08J3/28
CPC分类号： C08G63/64 , C08G64/14 , C08K5/07 , C08K5/42
摘要： The present invention relates to high-molecular weight aromatic polycarbonates, based on diphenols and monofunctional chain stoppers, corresponding to the formula (I) ##STR1## in which Z denotes the radical of a diphenol,n denotes an integer from about 20 to 400,E denotes ##STR2## wherein m denotes 0 or 1 andR denotes H or C.sub.1 -C.sub.3 -alkyl.The present invention also relates to a process for the preparation of the polycarbonates of the formula (I) comprising reacting diphenols of the formula (II)HO--Z--OH (II)whereinZ is a divalent aromatic radical, and/or their chlorocarbonic acid esters in accordance with the processes which are known for the preparation of polycarbonates, in a homogeneous or heterogeneous phase system, with compounds of the formula (III) ##STR3## wherein m denotes 0 or 1 andR denotes H or C.sub.1 -C.sub.3 -alkyl.The present invention also relates to a process for cross-linking the polycarbonates of the formula (I) with UV light, after adding a photoinitiator and, optionally, flameproofing and photo-reducing agents. Finally, the present invention relates to the cross-linked polycarbonates obtained via this process.
摘要翻译：本发明涉及对应于其中Z表示二酚的基团的式（I）的式（I）的二酚和单官能链终止剂的高分子量芳族聚碳酸酯，n表示约20的整数至400，E表示，其中m表示0或1，R表示H或C 1 -C 3 - 烷基。本发明还涉及制备式（I）的聚碳酸酯的方法，包括使式（II）的二酚HO-Z-OH（II）其中Z是二价芳族基团和/或它们的氯碳（III）化合物，其中m表示0或1，R表示H或C1（III）的化合物，其在均相或非均相系统中制备聚碳酸酯的方法是酸酯， -C 3-烷基。本发明还涉及在加入光引发剂和任选的阻燃和光还原剂之后使式（I）的聚碳酸酯与UV光交联的方法。最后，本发明涉及通过该方法获得的交联聚碳酸酯。

8. 发明授权

US4046836A Polycarbonate molding materials 失效
标题翻译：聚碳酸酯成型材料
公开(公告)号：US4046836A
公开(公告)日：1977-09-06
申请号：US648992
申请日：1976-01-14
申请人： Siegfried Adelmann , Dieter Margotte , Josef Merten , Hugo Vernaleken
发明人： Siegfried Adelmann , Dieter Margotte , Josef Merten , Hugo Vernaleken
IPC分类号： C08L69/00 , C08L81/00 , C08L81/02 , C08L81/04
CPC分类号： C08L69/00 , Y10S260/24
摘要： This invention relates to thermoplastic polycarbonate molding materials having improved flame resistance and hydrolysis resistance. These materials comprise intimate blends of aromatic high molecular weight polycarbonates and about 0.5 to 50 wt. % of polyphenylene sulphides. This invention also relates to a process for improving the flame resistance and hydrolysis resistance of aromatic polycarbonates by intimately blending them with about 0.5 to 50 wt. % polyphenylene sulphide.
摘要翻译：本发明涉及具有改善的阻燃性和耐水解性的热塑性聚碳酸酯成型材料。这些材料包括芳族高分子量聚碳酸酯的紧密共混物和约0.5至50wt。％的聚苯硫醚。本发明还涉及一种通过将它们与约0.5至50重量％的密切混合来改进芳族聚碳酸酯的耐火性和耐水解性的方法。％聚苯硫醚。

9. 发明授权

US4045382A Molding materials based on polyvinyl chloride and polyphenylene oxide 失效
标题翻译：基于聚氯乙烯和聚苯醚的成型材料
公开(公告)号：US4045382A
公开(公告)日：1977-08-30
申请号：US602950
申请日：1975-08-07
申请人： Hans-Eberhard Braese , Siegfried Adelmann , Dietrich Hardt , Dieter Margotte , Hugo Vernaleken
发明人： Hans-Eberhard Braese , Siegfried Adelmann , Dietrich Hardt , Dieter Margotte , Hugo Vernaleken
IPC分类号： C08L27/00 , C08L1/00 , C08L27/06 , C08L33/00 , C08L33/02 , C08L71/00 , C08L71/12 , C08L7/00
CPC分类号： C08L27/06 , C08L71/123 , C08L71/12
摘要： The invention relates to thermoplastic molding materials, of high heat distortion point, comprising polyvinyl chloride or copolymers of vinyl chloride with other vinyl compounds, and polyphenylene oxides.The molding materials according to the invention comprises a blend consisting ofA. 30 - 90% by weight of polyvinyl chloride or of copolymers of vinyl chloride with up to about 30% by weight based on the weight of the copolymer of one or more other vinyl compounds which are copolymerizable with vinyl chloride, andB. about 10 - 70% by weight of a polyphenylene oxide.Particularly preferred molding materials comprise a blend consisting ofA. 30 - 70% by weight of polyvinyl chloride or of its copolymers with up to about 30% by weight based on the weight of the copolymer of copolymerizable vinyl compounds, andB. about 70 - 30% by weight of a polyphenylene oxide.
摘要翻译：本发明涉及高热变形点的热塑性成型材料，其包括聚氯乙烯或氯乙烯与其它乙烯基化合物的共聚物和聚苯醚。

10. 发明授权

US4310642A Graft polycarbonates, their preparation and their use as moldings 失效
标题翻译：接枝聚碳酸酯，它们的制备及其作为模制品的用途
公开(公告)号：US4310642A
公开(公告)日：1982-01-12
申请号：US77978
申请日：1979-09-24
申请人： Dieter Margotte , Werner Nouvertne , Dieter Neuray , Hugo Vernaleken
发明人： Dieter Margotte , Werner Nouvertne , Dieter Neuray , Hugo Vernaleken
IPC分类号： C08F299/00 , C08F283/02 , C08F290/00 , C08F290/06 , C08F299/02 , C08G64/04 , C08L69/00
CPC分类号： C08G64/045 , C08F283/02 , C08F290/061
摘要： The subject disclosure is concerned with a process for synthesizing soluble thermoplastic graft polymers of polycarbonate and ethylenically unsaturated monomers by polymerizing these monomers and aromatic polycarbonates carrying addition polymerizable end groups in a dilute solution of no more than 30 wt. % of reactants based on the weight of solution. The graft polymers so obtained are also encompassed by the inventive concept.
摘要翻译：本发明涉及通过将这些单体和芳族聚碳酸酯在不超过30重量％的稀溶液中载带可加成聚合端基的聚合法合成聚碳酸酯和烯属不饱和单体的可溶性热塑性接枝聚合物的方法。基于溶液重量的反应物的％。如此获得的接枝聚合物也包括在本发明的概念之中。

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