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    • 3. 发明授权
    • Process for the electrodeposition of chrome plate using
fluorine-containing wetting agents
    • 使用含氟润湿剂电镀铬板的方法
    • US4006064A
    • 1977-02-01
    • US657014
    • 1976-02-10
    • Hans NiederprumHeinz Gunter KleinJohann Nikolaus Meussdoerffer
    • Hans NiederprumHeinz Gunter KleinJohann Nikolaus Meussdoerffer
    • C25D3/10
    • C25D3/10
    • In the electrodeposition of a chrome layer wherein the chrome is deposited from an electrolyte solution containing a hexavalent chromium compound in the presence of a fluorine-based surfactant, the improvement which comprises employing as the fluorine-based surfactant a quaternary ammonium perfluoralkane sulfonate of the formula[R.sub.F SO.sub.3 ].sup.- [NR.sup.1 R.sup.2 R.sup.3 R.sup.4 ].sup.+in which R.sup.1,R.sup.2, R.sup.3 and R.sup.4 each individually is alkyl, alkenyl, cycloalkyl or aralkyl of up to 18 carbon atoms, or two or three of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 together with the nitrogen atom to which they are attached form a heterocyclic ring, and R.sub.F is a perfluorinated alkyl radical with 6 to 12 carbon atoms.Additives such as Na.sub.2 CO.sub.3, NaHCO.sub.3, Na.sub.2 CrO.sub.4, K.sub.2 CrO.sub.4, Na.sub.2 Cr.sub.2 O.sub.7 and K.sub.2 Cr.sub.2 O.sub.7 or water may also be admixed with the quaternary ammonium perfluoralkane sulfonate.
    • 在铬层的电沉积中,其中铬在含氟六价铬化合物的电解液中在氟基表面活性剂的存在下沉积,包括使用式为氟基表面活性剂的季铵全氟烷基磺酸盐 其中R 1,R 2,R 3和R 4分别是至多18个碳原子的烷基,烯基,环烷基或芳烷基,或者R 1,R 2,R 3和R 4中的两个或三个 与它们所连接的氮原子一起形成杂环,RF是具有6至12个碳原子的全氟化烷基。