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    • 8. 发明授权
    • N-substituted amino acid derivatives
    • N-取代氨基酸衍生物
    • US4054668A
    • 1977-10-18
    • US619125
    • 1975-10-02
    • Osamu KirinoTadashi OoishiNobuyuki KamedaToshiro KatoAkira FujinamiToshiaki Ozaki
    • Osamu KirinoTadashi OoishiNobuyuki KamedaToshiro KatoAkira FujinamiToshiaki Ozaki
    • A01N37/44C07C101/28A01N9/24A01N9/30C07C103/48
    • A01N37/44
    • Novel N-substituted amino acid derivatives of the formula: ##STR1## wherein R.sub.1 is an alkenyl group having 2 to 5 carbon atoms, a halogen-substituted alkenyl group having 2 to 5 carbon atoms or an alkynyl group having 2 to 5 carbon atoms, R.sub.2 is a methyl or ##STR2## group in which R.sub.2 ' is an alkyl group having 1 to 4 carbon atoms or a halogen-substituted alkyl group having 1 to 4 carbon atoms; and R.sub.3 is a hydrogen atom, an alkyl having 1 to 20 carbon atoms, cycloalkyl having 3 to 6 carbon atoms, benzyl, hydroxyethyl or methoxyethyl group, and inorganic or organic acid addition salts thereof, which possess useful soil fungicidal activities and can be produced by reacting a sarcosine derivative of the formula:CH.sub.3 HNCH.sub.2 COOR.sub.3 (II)wherein R.sub.3 is as defined above, with a halogen compound of the formula:R.sub.1 -- X (III)wherein R.sub.1 is as defined above and X is a halogen atom, or by reacting an N-substituted glycine derivative of the formula: ##STR3## wherein R.sub.1 and R.sub.3 are as defined above, with an acyl compound of the formula: ##STR4## wherein R.sub.2 ' is as defined above and X is a halogen atom.
    • 式(I)的新型N-取代氨基酸衍生物:其中R 1是具有2至5个碳原子的烯基,具有2至5个碳原子的卤素取代的烯基或具有2至5个炔基的新的N-取代的氨基酸衍生物 碳原子,R2是甲基或者基团,其中R2'是具有1至4个碳原子的烷基或具有1至4个碳原子的卤素取代的烷基; R3为氢原子,碳原子数1〜20的烷基,碳原子数为3〜6的环烷基,苄基,羟乙基或甲氧基乙基,以及无机或有机酸加成盐,具有有效的土壤杀真菌活性, 通过使下式的肌氨酸衍生物:
    • 10. 发明授权
    • Amide phosphorothiolate derivatives and their use as pesticides
    • 酰胺二硫代磷酸衍生物及其作为农药的用途
    • US4394379A
    • 1983-07-19
    • US113133
    • 1980-01-17
    • Osamu KirinoMasachika HiranoHisami TakedaToshiro Kato
    • Osamu KirinoMasachika HiranoHisami TakedaToshiro Kato
    • A01N57/14A01N57/30C07F9/165C07F9/24C07F9/40
    • C07F9/1651A01N57/14A01N57/30C07F9/2408
    • Amide phosphorothiolate derivatives of the formula, ##STR1## wherein X is an oxygen or sulfur atom, Y is an oxygen or sulfur atom or imino group, R.sub.1 and R.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 alkyl group, R.sub.3 is a C.sub.1 -C.sub.4 alkyl group, R.sub.4 is a hydrogen atom or methyl group, R.sub.5 is a C.sub.1 -C.sub.3 alkyl, methoxy or ethoxy group, Z is a hydrogen atom, a methyl group or chlorine atom and n is 1 or 2, a process for producing said derivatives characterized by reacting the salt of thiophosphoric ester represented by the formula, ##STR2## wherein X, Y, R.sub.1 and R.sub.2 are as defined above and M is a sodium or potassium atom or ammonium group, with a haloacetamide derivative of the formula, ##STR3## wherein R.sub.3, R.sub.4, R.sub.5, Z and n are as defined above and W is a halogen atom, and a combined insecticide, acaricide, nematocide and/or fungicide containing said derivatives as an active ingredient.
    • 下式的酰亚胺硫代衍生物,其中X是氧或硫原子,Y是氧或硫原子或亚氨基,可以相同或不同的R 1和R 2各自为C 1 -C 3烷基 R3为C1-C4烷基,R4为氢原子或甲基,R5为C1-C3烷基,甲氧基或乙氧基,Z为氢原子,甲基或氯原子,n为1或2 制备所述衍生物的方法,其特征在于使由下式表示的硫代磷酸酯的盐,其中X,Y,R 1和R 2如上所定义,M是钠或钾原子或铵基,与卤代乙酰胺 衍生物,其中R3,R4,R5,Z和n如上所定义,W是卤素原子,以及含有所述衍生物作为活性成分的杀虫剂,杀螨剂,杀线虫剂和/或杀真菌剂的组合物。