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1. 发明授权

US6057479A Process for preparing indan derivatives 失效
标题翻译：制备茚满衍生物的方法
公开(公告)号：US6057479A
公开(公告)日：2000-05-02
申请号：US91229
申请日：1998-07-09
申请人： Shuichi Mitamura , Yasuhisa Asano , Tamejiro Hiyama , Hiroshi Kajiro
发明人： Shuichi Mitamura , Yasuhisa Asano , Tamejiro Hiyama , Hiroshi Kajiro
IPC分类号： C07C213/02 , C07C215/44 , C12P7/18 , C12P7/26 , C12P13/00 , C12P41/00 , C07C211/42
CPC分类号： C12P13/001 , C07C213/02 , C07C215/44 , C12P41/002 , C12P7/18 , C12P7/26 , C07B2200/07 , C07C2102/08
摘要： This invention relates to a process for preparing indan derivatives and comprises a process for preparing cis-1-amino-2-indanol by treating (.+-.)indan-1,2-diol and/or its 2-formate derivative with specific microbes to give optically active 2-hydroxy-1-indanone, converting the optically active 2-hydroxy-1-indanone to its oxime, and treating the oxime with hydrogen or a hydrogen donor in the presence of a heterogeneous hydrogenation catalyst, a process for preparing optically active 2-hydroxy-1-indanone and/or optically active indan-1,2-diol by treating (.+-.)indan-1,2-diol and/or its 2-formate derivative with specific microbes, and a process for preparing cis-1-amino-2-indanol by treating the oxime of 2-hydroxy-1-indanone with hydrogen or a hydrogen donor in the presence of a heterogeneous hydrogenation catalyst.
摘要翻译： PCT No.PCT / JP97 / 00040 Sec。 371日期：1998年7月9日 102（e）日期1998年7月9日PCT 1997年1月10日PCT PCT。公开号WO97 / 25436 日期1997年7月17日本发明涉及一种制备茚满衍生物的方法，包括通过处理（+/-）茚满-1,2-二醇和/或其2- 甲酸酯衍生物与特定的微生物反应得到光学活性的2-羟基-1-茚满酮，将光学活性的2-羟基-1-二氢茚酮转化成其肟，并在异相氢化催化剂存在下用氢或氢供体处理肟，通过用（+/-）茚满-1,2-二醇和/或其2-甲酸酯衍生物处理具有特异性的方法制备光学活性2-羟基-1-茚满酮和/或光学活性茚满-1,2-二醇的方法微生物和通过在异相氢化催化剂存在下用氢或氢供体处理2-羟基-1-二氢茚酮的肟而制备顺式-1-氨基-2-茚醇的方法。

2. 发明授权

US4659744A Fluorocarbon anion exchangers and processes for their preparation 失效
标题翻译：氟碳阴离子交换剂及其制备方法
公开(公告)号：US4659744A
公开(公告)日：1987-04-21
申请号：US624029
申请日：1984-06-25
申请人： Kiyohide Matsui , Yoshiyuki Kikuchi , Tamejiro Hiyama , Etsuko Tobita , Kiyosi Kondo , Akira Akimoto , Toru Seita , Hiroyuki Watanabe
发明人： Kiyohide Matsui , Yoshiyuki Kikuchi , Tamejiro Hiyama , Etsuko Tobita , Kiyosi Kondo , Akira Akimoto , Toru Seita , Hiroyuki Watanabe
IPC分类号： C25B13/08 , C08F8/44 , C08J5/22 , B01J41/14 , C08F8/02
CPC分类号： C08J5/2237 , C08F8/44 , C08J2327/12
摘要： A fluorocarbon anion exchanger which is composed of a fluorocarbon polymer comprising a perfluorocarbon main chain and a pendant chain attached to the main chain, characterized in that the pendant chainhas a terminal group represented by the formula: ##STR1##
摘要翻译：一种氟碳阴离子交换剂，其由包含全氟化碳主链和附着于所述主链的侧链的碳氟聚合物组成，其特征在于所述侧链具有由下式表示的端基：（I）

3. 发明申请

US20090179196A1 Pyrene-Based Organic Compound, Transistor Material and Light-Emitting Transistor Device 审中-公开
标题翻译：芘基有机化合物，晶体管材料和发光晶体管器件
公开(公告)号：US20090179196A1
公开(公告)日：2009-07-16
申请号：US12225370
申请日：2007-03-20
申请人： Chihaya Adachi , Takahito Oyamada , Hiroyuki Uchiuzou , Seiji Akiyama , Takayoshi Takahashi , Kumiko Takenouchi , Masaki Shimizu , Tamejiro Hiyama , Etsuya Okamoto
发明人： Chihaya Adachi , Takahito Oyamada , Hiroyuki Uchiuzou , Seiji Akiyama , Takayoshi Takahashi , Kumiko Takenouchi , Masaki Shimizu , Tamejiro Hiyama , Etsuya Okamoto
IPC分类号： H01L51/54 , C07D409/14 , C07D209/86 , C07D409/04 , C07C15/02 , C07C15/12 , C07C15/24 , C07C211/54 , C07D401/04 , C07D213/06 , C07D333/08 , C07D307/36
CPC分类号： C07C17/12 , C07C15/38 , C07C15/62 , C07C17/263 , C07C17/2635 , C07C22/08 , C07C25/24 , C07C45/00 , C07C2603/50 , C07F5/025 , C07F9/4056 , C07F15/0093 , C09K11/06 , C09K2211/1011 , C09K2211/1044 , C09K2211/1074 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0054 , H01L51/0558 , H01L51/5012 , H01L51/52 , H01L51/5203 , H01L51/5296 , H05B33/14 , C07C25/22 , C07C47/546
摘要： The object is to provide a light-emitting transistor material which is high in both luminescent property and mobility when used as a light-emitting transistor device.A light-emitting transistor device is provided in which light emission of a specific pyrene-based organic compound is used for a light-emitting layer of a transistor device.
摘要翻译：本发明的目的是提供一种当用作发光晶体管器件时发光特性和迁移率高的发光晶体管材料。提供了一种发光晶体管器件，其中特定芘类有机化合物的发光用于晶体管器件的发光层。

4. 发明授权

US5276154A Optically active esters of 7-substituted 3,5-difunctionalized 6-heptenoic acids 失效
标题翻译： 7-取代的3,5-二官能化的6-庚烯酸的光学活性酯
公开(公告)号：US5276154A
公开(公告)日：1994-01-04
申请号：US748076
申请日：1991-08-21
申请人： Tamejiro Hiyama , Tatsuya Minami , Takeshi Hanamoto , Guntoori B. Reddy
发明人： Tamejiro Hiyama , Tatsuya Minami , Takeshi Hanamoto , Guntoori B. Reddy
IPC分类号： C07C67/343 , C07C69/732 , C07C69/738 , C07D209/10 , C07D309/30 , C07D215/14 , C07D215/233
CPC分类号： C07C69/738 , C07C67/343 , C07C69/732
摘要： The present invention provides optically active esters of 7-substituted 3,5-difunctionalized 6-heptenoic acids represented by the following formula: ##STR1## wherein R is a substituted or unsubstituted aromatic group, a substituted or unsubstituted heteroaromatic group or a substituted vinyl group;Ar is a condensed aromatic group;X.sup.1 and Y.sup.1 are not the same and each is a hydrogen atom or a hydroxyl group, or may be combined to represent an oxygen atom which forms a carbonyl group together with the carbon atom to which X.sup.1 and Y.sup.1 are attached; andX.sup.2 and Y.sup.2 are not the same and each is a hydrogen atom or a hydroxyl group, or may be combined to represent an oxygen atom which forms a carbonyl group together with the carbon atom to which X.sup.2 and Y.sup.2 are attached,or enantiomers thereof.The present invention further provides processes for preparing the above optically active esters and 7-substituted (3R, 5S, 6E)-3,5-dihydroxy-6-hepten-1,5-olides.These esters are useful as synthetic intermediates for preparing the above lactones having an inhibitory activity of HMG-CoA reductase as well as a sex attractant pheromone of beetles, endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane.
摘要翻译：本发明提供由下式表示的7-取代的3,5-二官能的6-庚烯酸的光学活性酯：（*化学结构*）其中R是取代或未取代的芳族基团，取代或未取代的杂芳族基团或取代乙烯基; Ar是稠合芳族基团; X1和Y1不相同，各自为氢原子或羟基，或者可以组合形成与X1和Y1所连接的碳原子一起形成羰基的氧原子; X2和Y2不相同，各自为氢原子或羟基，或者可以与X2和Y2所连接的碳原子一起形成羰基的氧原子或其对映异构体。本发明还提供了制备上述光学活性酯和7-取代的（3R，5S，6E）-3,5-二羟基-6-庚烯-1,5-二醇的方法。这些酯可用作制备具有HMG-CoA还原酶抑制活性的上述内酯的合成中间体以及甲虫的性引诱信息素，内切1,3-二甲基-2,9-二氧杂双环（3.3.1）壬烷。

5. 发明授权

US5369109A Optically active esters of 7-substituted 3,5-difunctionalized 6-heptenoic acids 失效
标题翻译： 7-取代的3,5-二官能化的6-庚烯酸的光学活性酯
公开(公告)号：US5369109A
公开(公告)日：1994-11-29
申请号：US77454
申请日：1993-06-17
申请人： Tamejiro Hiyama , Tatsuya Minami , Takeshi Hanamoto , Guntoori B. Reddy
发明人： Tamejiro Hiyama , Tatsuya Minami , Takeshi Hanamoto , Guntoori B. Reddy
IPC分类号： C07C67/343 , C07C69/732 , C07C69/738 , C07D209/10 , C07D309/30 , A01N43/40 , C07C69/73 , C07D215/06 , C07D471/04
CPC分类号： C07C69/738 , C07C67/343 , C07C69/732
摘要： The present invention provides optically active esters of 7-substituted 3,5-difunctionalized 6-heptenoic acids represented by the following formula: ##STR1## wherein R is a substituted or unsubstituted aromatic group, a substituted or unsubstituted heteroaromatic group or a substituted vinyl group;Ar is a condensed aromatic group;X.sup.1 and Y.sup.1 are not the same and each is a hydrogen atom or a hydroxyl group; andX.sup.2 and Y.sup.2 are not the same and each is a hydrogen atom or a hydroxyl group or enantiomers thereof.
摘要翻译：本发明提供由下式表示的7-取代的3,5-二官能的6-庚烯酸的光学活性酯：所述芳族基团，取代或未取代的杂芳基或取代的乙烯基; Ar是稠合芳族基团; X1和Y1不相同，各自为氢原子或羟基; X2和Y2不相同，各自为氢原子或羟基或其对映异构体。

6. 发明授权

US4661231A Fluorocarbon polymers and processes for their preparation 失效
标题翻译：氟碳聚合物及其制备方法
公开(公告)号：US4661231A
公开(公告)日：1987-04-28
申请号：US792860
申请日：1985-10-30
申请人： Kiyohide Matsui , Yoshiyuki Kikuchi , Tamejiro Hiyama , Etsuko Tobita , Kiyoshi Kondo
发明人： Kiyohide Matsui , Yoshiyuki Kikuchi , Tamejiro Hiyama , Etsuko Tobita , Kiyoshi Kondo
IPC分类号： C08F8/44 , C08J5/22 , C25B9/00 , B01D13/00
CPC分类号： C08J5/2237 , C08F8/44 , C08J2327/12
摘要： A fluorocarbon polymer comprising a perfluorocarbon main chain and a pendant chain attached to the main chain, characterized in that the pendant chain has a quaternary ammonium type terminal group.

7. 发明申请

US20090069577A1 Silicon-Based Cross-Coupling Reagent and Production Method of Organic Compound Using the Same 有权
标题翻译：硅基交联试剂及其使用的有机化合物的制备方法
公开(公告)号：US20090069577A1
公开(公告)日：2009-03-12
申请号：US11918261
申请日：2005-11-21
申请人： Yoshiaki Nakao , Tamejiro Hiyama
发明人： Yoshiaki Nakao , Tamejiro Hiyama
IPC分类号： C07D333/02 , C07F7/08 , C07F7/02 , C07C33/34 , C07C255/01 , C07C69/76
CPC分类号： C07C253/30 , C07B37/04 , C07C17/263 , C07C29/32 , C07C33/20 , C07C41/30 , C07C45/68 , C07C67/343 , C07C69/76 , C07C201/12 , C07C255/07 , C07C255/41 , C07F7/081 , C07F7/0814 , C07F7/1804 , C12C11/02 , Y02P20/582 , C07C25/02 , C07C25/13 , C07C25/06 , C07C25/18 , C07C22/08 , C07C25/24 , C07C33/30 , C07C33/24 , C07C47/548 , C07C49/794 , C07C49/807 , C07C47/55 , C07C205/06 , C07C43/215 , C07C43/205
摘要： In one embodiment of the present invention, a silicon-based cross-coupling reagent is disclosed which is a highly stable tetraorganosilicon compound allowing for a cross-coupling reaction under mild reaction conditions without using fluoride ions, transition metal promoter, or strong bases, and the residue of the silicon reagent can be recovered and reused. The silicon-based cross-coupling reagent is a silicon compound in which an o-hydroxymethylphenyl group is connected to a silicon atom for intramolecular activation.
摘要翻译：在本发明的一个实施方案中，公开了一种硅基交联偶联剂，其是高度稳定的四有机硅化合物，其允许在温和的反应条件下进行交叉偶联反应而不使用氟离子，过渡金属促进剂或强碱，以及可以回收和再利用硅试剂的残留物。硅基交联偶联剂是其中邻羟基甲基苯基连接到硅原子用于分子内活化的硅化合物。

8. 发明授权

US5061398A Optically active lactone derivative, intermediate therefor, process for producing the intermediate, liquid-crystal composition, and liquid-crystal display device 失效
标题翻译：光学活性衍生物，其中间体，制备中间体，液晶组合物和液晶显示装置的方法
公开(公告)号：US5061398A
公开(公告)日：1991-10-29
申请号：US515915
申请日：1990-04-27
申请人： Sadao Takehara , Takeshi Kuriyama , Kayoko Nakamura , Tadao Shoji , Toru Fujisawa , Masashi Osawa , Tamejiro Hiyama , Tetsuo Kusumoto , Akiko Nakayama , Kiyoharu Nishide
发明人： Sadao Takehara , Takeshi Kuriyama , Kayoko Nakamura , Tadao Shoji , Toru Fujisawa , Masashi Osawa , Tamejiro Hiyama , Tetsuo Kusumoto , Akiko Nakayama , Kiyoharu Nishide
IPC分类号： G02F1/13 , C07C255/37 , C07D307/33 , C09K19/34 , C09K19/54
CPC分类号： C07D307/33 , C09K19/2021 , C09K19/3405 , C09K2019/3075
摘要： An optically active lactone derivative represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a straight-chain or branched alkyl, alkoxyl, alkanoyloxy, alkoxycarbonyl, alkoxyalkyl, alkoxyalkanoyloxy, or alkoxyalkoxyl group having 1 to 20 carbon atoms or an optically active group of each of the above kinds, R.sup.2 represents a straight-chain or branched alkyl group having 1 to 20 carbon atoms, ##STR2## or trans-1,4-cyclohexylene group of the formula and the asymmetric carbon atoms at the 2- and 4-positions in the lactone ring each independently is of the (S) or (R) configuration, an intermediate therefor, a process for producing the intermediate, a liquid-crystal composition, and a liquid-crystal display device.

9. 发明授权

US4481366A Process for the preparation of a trifluorovinylsilane, and fluorine-containing polymer and process for its preparation 失效
标题翻译：制备三氟乙烯基硅烷和含氟聚合物的方法及其制备方法
公开(公告)号：US4481366A
公开(公告)日：1984-11-06
申请号：US572247
申请日：1984-01-20
申请人： Tamejiro Hiyama , Kiyoharu Nishide
发明人： Tamejiro Hiyama , Kiyoharu Nishide
IPC分类号： C07F7/08 , C08F30/08 , C07C7/08
CPC分类号： C07F7/0827 , C08F30/08
摘要： A process for preparing a trifluorovinylsilane represented by the general formula:(CF.sub.2 .dbd.CF).sub.n SiR.sub.4-n (I)where each R independently represents an alkyl group, an aryl group or an aralkyl group, and n is an integer of 1 to 4, which comprises the reaction of chlorotrifluoroethylene with a chlorosilane represented by the general formula:Cl.sub.n SiR.sub.4-n (II)where R and n are as defined above, in the presence of an alkyllithium. Also disclosed is a fluorine-containing polymer represented by the general formula: ##STR1## where each of x and m is an integer other than O, y is an integer including O, and each of R.sup.1, R.sup.2 and R.sup.3 is a lower alkyl group, an aryl group or an aralkyl group, which is prepared by polymerization of a trifluorovinyl silane (I) with active fluoride-ion generating catalyst.
摘要翻译：一种制备由以下通式表示的三氟乙烯基硅烷的方法：（CF 2 = CF）n SiR 4-n（I）其中每个R独立地表示烷基，芳基或芳烷基，n是1至4的整数，其包括在三烷基锂存在下氯三氟乙烯与由以下通式表示的氯代硅烷的反应：其中R和n如上所定义。还公开了由以下通式表示的含氟聚合物：其中x和m各自为O以外的整数，y为包括O的整数，R 1，R 2和R 3各自为低级烷基，芳基或芳烷基，其通过三氟乙烯基硅烷（I）与活性氟离子产生催化剂的聚合制备。

10. 发明授权

US07960571B2 Silicon-based cross-coupling reagent and production method of organic compound using the same 有权
标题翻译：硅基交联偶联剂及其制备方法的有机化合物
公开(公告)号：US07960571B2
公开(公告)日：2011-06-14
申请号：US11918261
申请日：2005-11-21
申请人： Yoshiaki Nakao , Tamejiro Hiyama
发明人： Yoshiaki Nakao , Tamejiro Hiyama
IPC分类号： C07D333/10
CPC分类号： C07C253/30 , C07B37/04 , C07C17/263 , C07C29/32 , C07C33/20 , C07C41/30 , C07C45/68 , C07C67/343 , C07C69/76 , C07C201/12 , C07C255/07 , C07C255/41 , C07F7/081 , C07F7/0814 , C07F7/1804 , C12C11/02 , Y02P20/582 , C07C25/02 , C07C25/13 , C07C25/06 , C07C25/18 , C07C22/08 , C07C25/24 , C07C33/30 , C07C33/24 , C07C47/548 , C07C49/794 , C07C49/807 , C07C47/55 , C07C205/06 , C07C43/215 , C07C43/205
摘要： In one embodiment of the present invention, a silicon-based cross-coupling reagent is disclosed which is a highly stable tetraorganosilicon compound allowing for a cross-coupling reaction under mild reaction conditions without using fluoride ions, transition metal promoter, or strong bases, and the residue of the silicon reagent can be recovered and reused. The silicon-based cross-coupling reagent is a silicon compound in which an o-hydroxymethylphenyl group is connected to a silicon atom for intramolecular activation.
摘要翻译：在本发明的一个实施方案中，公开了一种硅基交联偶联剂，其是高度稳定的四有机硅化合物，其允许在温和的反应条件下进行交叉偶联反应而不使用氟离子，过渡金属促进剂或强碱，以及可以回收和再利用硅试剂的残留物。硅基交联偶联剂是其中邻羟基甲基苯基连接到硅原子用于分子内活化的硅化合物。

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