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1. 发明授权

US5395433A Reversible thermosensitive coloring composition, recording medium, recording method, and image display apparatus using the recording medium 失效
标题翻译：可逆热敏着色组合物，记录介质，记录方法和使用记录介质的图像显示装置
公开(公告)号：US5395433A
公开(公告)日：1995-03-07
申请号：US159456
申请日：1993-11-30
申请人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
发明人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
IPC分类号： B41M5/30 , B41M5/333 , C09D11/00
CPC分类号： B41M5/305 , B41M5/3335 , B41M5/3336
摘要： A reversible thermosensitive coloring composition is composed of (i) an electron-donor coloring compound and (ii) an electron-acceptor compound selected from the group consisting of an organic phosphoric acid compound, an aliphatic carboxylic acid, and a phenolic compound, each having a straight chain or branched chain alkyl group or alkyenyl group having 12 or more carbon atoms, the electron-donor coloring compound and the electron-acceptor compound being capable of reacting to induce color formation in the reversible thermosensitive coloring composition at the eutectic temperature thereof. The electron-donor coloring compound and the electron-acceptor compound, when fused and colored in a mixed state, with application of heat thereto, followed by rapidly cooling the fused mixture, exhibit an exothermic peak in a temperature elevation process in a differential scanning calorific analysis or in a differential thermal analysis. A recording medium and display medium using the above reversible thermosensitive coloring composition, a recording method of using the recording medium, a display method of using the display medium, a display method of using the display medium, and a display apparatus using the display medium are disclosed.
摘要翻译：可逆热敏着色组合物由（i）电子给体着色化合物和（ii）选自有机磷酸化合物，脂肪族羧酸和酚类化合物的电子受体化合物组成，各自具有具有12个或更多个碳原子的直链或支链烷基或链烯基，电子给体着色化合物和电子受体化合物能够在其共晶温度下在可逆热敏着色组合物中引起颜色形成。电子给体着色化合物和电子受体化合物在混合状态下熔融并着色时，施加热量，然后快速冷却熔融混合物，在差示扫描热量的升温过程中显示放热峰分析或差示热分析。使用上述可逆热敏着色组合物的记录介质和显示介质，使用记录介质的记录方法，使用显示介质的显示方法，使用显示介质的显示方法和使用显示介质的显示装置，披露

2. 发明授权

US06656879B2 Method of reversible selective manifestation of different states of functional element 失效
标题翻译：功能元素不同状态的可逆选择性表现方法
公开(公告)号：US06656879B2
公开(公告)日：2003-12-02
申请号：US08070859
申请日：1993-06-03
申请人： Kyoji Tsutsui , Takehito Yamaguchi , Hideaki Ema , Masaru Shimada , Hiroshi Goto , Ichiro Sawamura , Eiichi Kawamura , Keishi Kubo , Shoji Maruyama , Hiroki Kuboyama , Keishi Taniguchi
发明人： Kyoji Tsutsui , Takehito Yamaguchi , Hideaki Ema , Masaru Shimada , Hiroshi Goto , Ichiro Sawamura , Eiichi Kawamura , Keishi Kubo , Shoji Maruyama , Hiroki Kuboyama , Keishi Taniguchi
IPC分类号： B41M520
CPC分类号： B41M5/305
摘要： A method of reversible selective manifestation of different states of a functional element is disclosed. The functional element is composed of at least two compounds and is capable of alternatively assuming (a) a first state in which the two compounds interact to form a regular aggregate structure, or (b) a second state in which the two compounds do not interact, and at least one of the two compounds is in an aggregate or crystallized state. The respective conditions for attaining one of the two states can be reversibly and extremely speedily controlled, for instance, by use of a heat application device.
摘要翻译：公开了一种功能元件的不同状态的可逆选择性表现的方法。功能元件由至少两种化合物组成，并且能够替代地（a）第一种状态，其中两种化合物相互作用形成规则的聚集体结构，或（b）两种化合物不相互作用的第二种状态，并且两种化合物中的至少一种处于聚集或结晶状态。用于实现两种状态中的一种状态的各个条件可以可逆地且极其快速地控制，例如通过使用热施加装置。

3. 发明授权

US5432534A Reversible thermosensitive coloring composition, recording medium, recording method, and image display apparatus using the recording medium 失效
公开(公告)号：US5432534A
公开(公告)日：1995-07-11
申请号：US338112
申请日：1994-11-09
申请人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
发明人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
IPC分类号： B41M5/30 , B41M5/333 , B41M5/26 , B41J2/32 , B41J2/435 , B41J2/475
CPC分类号： B41M5/305 , B41M5/3335 , B41M5/3336
摘要： A reversible thermosensitive coloring composition is composed of (i) an electron-donor coloring compound and (ii) an electron-acceptor compound selected from the group consisting of an organic phosphoric acid compound, an aliphatic carboxylic acid, and a phenolic compound, each having a straight chain or branched chain alkyl group or alkyenyl group having 12 or more carbon atoms, the electron-donor coloring compound and the electron-acceptor compound being capable of reacting to induce color formation in the reversible thermosensitive coloring composition at the eutectic temperature thereof. The electron-donor coloring compound and the electron-acceptor compound, when fused and colored in a mixed state, with application of heat thereto, followed by rapidly cooling the fused mixture, exhibit an exothermic peak in a temperature elevation process in a differential scanning calorific analysis or in a differential thermal analysis. A recording medium and display medium using the above reversible thermosensitive coloring composition, a recording method of using the recording medium, a display method of using the display medium, a display method of using the display medium, and a display apparatus using the display medium are disclosed.

4. 发明授权

US5296439A Reversible thermosensitive coloring recording medium, recording method, and image display apparatus using the recording medium 失效
标题翻译：可逆热敏着色记录介质，记录方法和使用记录介质的图像显示装置
公开(公告)号：US5296439A
公开(公告)日：1994-03-22
申请号：US813181
申请日：1991-12-24
申请人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
发明人： Shoji Maruyama , Hiroshi Goto , Eiichi Kawamura , Masaru Shimada , Keishi Kubo , Kyoji Tsutsui , Hideaki Ema , Takehito Yamaguchi , Hiroki Kuboyama , Ichiro Sawamura , Keishi Taniguchi
IPC分类号： B41M5/30 , B41M5/333
CPC分类号： B41M5/305 , B41M5/3335 , B41M5/3336
摘要： A reversible thermosensitive coloring composition is composed of (i) an electron-donor coloring compound and (ii) an electron-acceptor compound selected from the group consisting of an organic phosphoric acid compound, an aliphatic carboxylic acid, and a phenolic compound, each having a straight chain or branched chain alkyl group or alkenyl group having 12 or more carbon atoms, the electron-donor coloring compound and the electron-acceptor compound being capable of reacting to induce color formation in the reversible thermosensitive coloring composition at the eutectic temperature thereof. The electron-donor coloring compound and the electron-acceptor compound, when fused and colored in a mixed state, with application of heat thereto, followed by rapidly cooling the fused mixture, exhibit an exothermic peak in a temperature elevation process in a differential scanning calorific anlaysis or in a differential thermal analysis. A recording medium and display medium using the above reversible thermosensitive coloring composition, a recording method of using the recording medium, a display method of using the display medium, a display method of using the display medium, and a display apparatus using the display medium are disclosed.
摘要翻译：可逆热敏着色组合物由（i）电子给体着色化合物和（ii）选自有机磷酸化合物，脂肪族羧酸和酚类化合物的电子受体化合物组成，各自具有具有12个或更多个碳原子的直链或支链烷基或烯基，电子给体着色化合物和电子受体化合物能够在其共晶温度下在可逆热敏着色组合物中引起颜色形成。电子给体着色化合物和电子受体化合物在混合状态下熔融并着色时，施加热量，然后快速冷却熔融混合物，在差示扫描热量的升温过程中显示放热峰或差示热分析。使用上述可逆热敏着色组合物的记录介质和显示介质，使用记录介质的记录方法，使用显示介质的显示方法，使用显示介质的显示方法和使用显示介质的显示装置，披露

5. 发明授权

US5521138A Reversible thermosensitive coloring composition, and recording medium using the same 失效
标题翻译：可逆热敏着色组合物和使用其的记录介质
公开(公告)号：US5521138A
公开(公告)日：1996-05-28
申请号：US902834
申请日：1992-06-23
申请人： Masaru Shimada , Hiroshi Goto , Eiichi Kawamura , Shoji Maruyama , Keishi Kubo , Kyoji Tsutsui
发明人： Masaru Shimada , Hiroshi Goto , Eiichi Kawamura , Shoji Maruyama , Keishi Kubo , Kyoji Tsutsui
IPC分类号： B41M5/30 , B41M5/26
CPC分类号： B41M5/305
摘要： A reversible thermosensitive coloring composition is composed of an electron-donor coloring compound; an electron-acceptor compound which is capable of producing a colored material with a regularly aggregated structure in the electron-doner coloring compound at a color development initiation temperature to obtain a color development state, and is capable of crystallizing out of the colored material at a decolorization initiation temperature which is lower than the color development initiation temperature; and an organic compound serving as a decolorization-accelerating agent capable of inducing the destruction of the regularly aggregated structure of the colored material to accelerate the decolorization of the composition. A reversible thermosensitive coloring recording medium is composed of a support and a recording layer formed thereon, which contains the above-mentioned reversible thermosensitive coloring composition.
摘要翻译：可逆热敏着色组合物由电子给体着色化合物组成; 电子受体化合物，其能够在显色开始温度下在电子给体着色化合物中产生具有规则聚集结构的着色材料，以获得显色状态，并且能够在着色材料中以脱色开始温度低于显色开始温度; 以及用作能够引起着色材料的规则聚集结构的破坏的脱色促进剂的有机化合物，以加速组合物的脱色。可逆热敏着色记录介质由其上形成的载体和记录层组成，其中含有上述可逆热敏着色组合物。

6. 发明授权

US5641724A Reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof 失效
标题翻译：可逆热敏着色组合物和使用其的热敏记录介质
公开(公告)号：US5641724A
公开(公告)日：1997-06-24
申请号：US536452
申请日：1995-09-29
申请人： Takehito Yamaguchi , Kyoji Tsutsui , Masaru Shimada
发明人： Takehito Yamaguchi , Kyoji Tsutsui , Masaru Shimada
IPC分类号： B41M5/28 , B41M5/30 , B41M5/327 , B41M5/333 , B41M5/337 , B41M5/42 , B41M5/035
CPC分类号： B41M5/3275 , B41M5/305 , B41M5/3333
摘要： This invention generally relates to a reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof which have high light-resisting characteristics, wherein coloring and decolorizing can be repeated suitably. A reversible thermosensitive coloring composition of this invention comprises an electron donating chromophoric compound and an electron accepting compound, which has a colored state and a decolorized state based on a heated temperature and a difference between cooling speeds after being heated, said electron donating chromophoric compound including a compound having a general formula (I) ##STR1##
摘要翻译：本发明一般涉及具有高耐光特性的可逆热敏着色组合物和使用其的热敏记录介质，其中着色和脱色可以适当地重复。本发明的可逆热敏着色组合物包括供电发色团和受电子化合物，其具有基于加热温度和加热后的冷却速度之差的着色状态和脱色状态，所述给电子发色化合物包括具有通式（I）的化合物

7. 发明授权

US5868821A Thermally reversible color forming composition and thermally reversible recording medium using the thermally reversible color forming composition 失效
标题翻译：使用热可逆成色组合物的热可逆成色组合物和热可逆记录介质
公开(公告)号：US5868821A
公开(公告)日：1999-02-09
申请号：US791747
申请日：1997-01-30
申请人： Masafumi Torii , Shoji Maruyama , Fumio Kawamura , Hiromi Furuya , Kyoji Tsutsui , Katsuhisa Kamio , Katsushi Sugiyama , Kazuo Hosoda , Masatake Kawashima , Masafumi Moriya , Hiroaki Matsui , Masaru Shimada
发明人： Masafumi Torii , Shoji Maruyama , Fumio Kawamura , Hiromi Furuya , Kyoji Tsutsui , Katsuhisa Kamio , Katsushi Sugiyama , Kazuo Hosoda , Masatake Kawashima , Masafumi Moriya , Hiroaki Matsui , Masaru Shimada
IPC分类号： B41M5/333 , C09D11/02
CPC分类号： B41M5/3335 , B41M5/305
摘要： A thermally reversible color forming composition which includes an electron-donating chromophoric compound and an electron-accepting compound, by which formation and deletion of a color image may be carried out by adjusting thermal energy applied to the composition, wherein the electron-accepting compound is a carboxylic acid compound having the following general formula (1):R.sub.1 --X--R.sub.2 --COOH (1)in which, X represents a divalent group having at least one hetero atom, R.sub.1 represents a hydrocarbon group having at least one hetero atom, R.sub.2 represents an aliphatic hydrocarbon group, which may be substituted and whose principle chain contains less than 6 carbon atoms.
摘要翻译：一种热可逆成色组合物，其包括给电子发色化合物和电子接受性化合物，通过调节施加到组合物上的热能可以进行彩色图像的形成和缺失，其中电子接受性化合物是具有以下通式（1）的羧酸化合物：其中，X表示具有至少一个杂原子的二价基团，R 1表示至少具有一个杂原子的烃基，R1-X-R2-COOH（1） R 2表示脂族烃基，其可以被取代，并且其原子链含有少于6个碳原子。

8. 发明授权

US5585320A Reversible thermosensitive coloring recording method, recording medium and recording apparatus for the recording method 失效
公开(公告)号：US5585320A
公开(公告)日：1996-12-17
申请号：US449746
申请日：1995-05-25
申请人： Kyoji Tsutsui , Takehito Yamaguchi
发明人： Kyoji Tsutsui , Takehito Yamaguchi
IPC分类号： B41J2/32 , B41M5/28 , B41M5/34 , B41M5/30 , B41M5/40
CPC分类号： B41M5/34 , B41J2/32 , B41M5/28
摘要： A reversible thermosensitive coloring recording method for producing multi-color images by use of a reversible thermosensitive coloring recording medium which is composed of a support and a reversible thermosensitive coloring recording layer containing a plurality of reversible thermosensitive coloring compositions, each coloring composition being independently present separated from the other coloring compositions, and capable of reversibly forming a color development state with a different color in a predetermined color development temperature range, and a decolorization state in a predetermined decolorization temperature range by the application of heat thereto and maintaining the above two states at room temperature, the decolorization temperature range being located lower in terms of temperature than the color development temperature range therefor, comprises the steps of: temporarily applying heat to the recording medium to a color development temperature at which at least two of the coloring compositions are colored or to a temperature higher than the color development temperature to obtain a mixed coloring state, and decolorizing at least one of the coloring compositions which have been colored, thereby producing multi-color images.

9. 发明授权

US5552364A Reversible theromosensitive coloring recording method, recording medium and recording apparatus for the recording method 失效
标题翻译：可逆热敏着色记录方法，记录介质和用于记录方法的记录装置
公开(公告)号：US5552364A
公开(公告)日：1996-09-03
申请号：US28229
申请日：1993-03-09
申请人： Kyoji Tsutsui , Takehito Yamaguchi
发明人： Kyoji Tsutsui , Takehito Yamaguchi
IPC分类号： B41J2/32 , B41M5/28 , B41M5/34
CPC分类号： B41M5/34 , B41J2/32 , B41M5/28
摘要： A reversible thermosensitive coloring recording method for producing multi-color images by use of a reversible thermosensitive coloring recording medium which is composed of a support and a reversible thermosensitive coloring recording layer containing a plurality of reversible thermosensitive coloring compositions, each coloring composition being independently present separated from the other coloring compositions, and capable of reversibly forming a color development state with a different color in a predetermined color development temperature range, and a decolorization state in a predetermined decolorization temperature range by the application of heat thereto and maintaining the above two states at room temperature, the decolorization temperature range being located lower in terms of temperature than the color development temperature range therefor, comprises the steps of: temporarily applying heat to the recording medium to a color development temperature at which at least two of the coloring compositions are colored or to a temperature higher than the color development temperature to obtain a mixed coloring state, and decolorizing at least one of the coloring compositions which have been colored, thereby producing multi-color images.
摘要翻译：一种可逆热敏着色记录方法，用于通过使用由支持体和包含多个可逆热敏着色组合物的可逆热敏着色记录层组成的可逆热敏着色记录介质来生产多色图像，每个着色组合物独立存在分离并且能够在预定的显色温度范围内可逆地形成具有不同颜色的显色状态，并且通过施加热量使预定的脱色温度范围内的脱色状态保持在上述两种状态在室温下，脱色温度范围位于比显色温度范围低的温度范围内，包括以下步骤：暂时向记录介质施加热量至显色温度着色组合物着色或高于显色温度的温度以获得混合着色状态，并使着色组合物中的至少一种脱色，从而产生多色图像。

10. 发明授权

US5534907A Reversible thermosensitive coloring recording method, recording medium and recording apparatus for the recording method 失效
公开(公告)号：US5534907A
公开(公告)日：1996-07-09
申请号：US451071
申请日：1995-05-25
申请人： Kyoji Tsutsui , Takehito Yamaguchi
发明人： Kyoji Tsutsui , Takehito Yamaguchi
IPC分类号： B41J2/32 , B41M5/28 , B41M5/34 , B41J2/325 , B41M5/30
CPC分类号： B41M5/34 , B41J2/32 , B41M5/28
摘要： A reversible thermosensitive coloring recording method for producing multi-color images by use of a reversible thermosensitive coloring recording medium which is composed of a support and a reversible thermosensitive coloring recording layer containing a plurality of reversible thermosensitive coloring compositions, each coloring composition being independently present separated from the other coloring compositions, and capable of reversibly forming a color development state with a different color in a predetermined color development temperature range, and a decolorization state in a predetermined decolorization temperature range by the application of heat thereto and maintaining the above two states at room temperature, the decolorization temperature range being located lower in terms of temperature than the color development temperature range therefor, comprises the steps of: temporarily applying heat to the recording medium to a color development temperature at which at least two of the coloring compositions are colored or to a temperature higher than the color development temperature to obtain a mixed coloring state, and decolorizing at least one of the coloring compositions which have been colored, thereby producing multi-color images.

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