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1. 发明授权

US06911282B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US06911282B2
公开(公告)日：2005-06-28
申请号：US10220885
申请日：2001-03-06
申请人： Shinji Kasamatsu , Harunari Shimamura , Yoshiaki Nitta
发明人： Shinji Kasamatsu , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M4/134 , H01M4/36 , H01M4/38 , H01M4/62 , H01M10/05 , H01M4/58
CPC分类号： H01M4/366 , H01M4/02 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/624 , H01M10/0525 , H01M2004/021 , H01M2004/027
摘要： When the composite particle containing Si or Sn is used for the negative electrode, the ratio of the median diameter “Dc” of the conductive material to the median diameter “Da” of the negative electrode material (Dc/Da) is made from 0.02 to 0.5 in order to improve reduction in electron conductivity, which is attributed to fine division of the particles due to repeated charge/discharge.
摘要翻译：当使用含有Si或Sn的复合颗粒作为负极时，导电材料的中值直径“Dc”与负极材料的中值直径“Da”的比值（Dc / Da）为0.02〜以提高电子传导性的降低，这归因于由于重复的充电/放电导致的微粒的细分。

2. 发明授权

US06605386B1 Non-aqueous electrolyte secondary battery comprising composite particles 有权
标题翻译：包含复合颗粒的非水电解质二次电池
公开(公告)号：US06605386B1
公开(公告)日：2003-08-12
申请号：US09601224
申请日：2000-09-18
申请人： Shinji Kasamatsu , Hiroshi Yoshizawa , Kazuhiro Okamura , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
发明人： Shinji Kasamatsu , Hiroshi Yoshizawa , Kazuhiro Okamura , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M462
CPC分类号： H01M4/38 , H01M4/04 , H01M4/13 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/485 , H01M4/58 , H01M4/5835 , H01M6/10 , H01M10/0525 , H01M10/446 , H01M2010/4292
摘要： A non-aqueous electrolyte secondary battery comprises a positive electrode and a negative electrode capable of intercalating and de-intercalating lithium, a non-aqueous electrolyte and separators or solid electrolytes. The negative electrode contains, as a main component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of the element included in the nuclear particles and another predetermined element which is not an element included in the nuclear particles. To improve the ability of the battery, the composite particles mentioned above can include at least one trace element selected from iron, lead and bismuth. The porosity of a mixture layer at the negative electrode is 10% or more and 50% or less. The amount of the non-aqueous electrolyte, the thickness of the separators or the like is restricted in a specific value. The foregoing construction suppresses occurrence of an internal short circuit between the positive electrode and the negative electrode caused by expansion of the negative electrode materials, thereby achieving a high capacity battery with a superior charge/discharge cycle properties, which is suitable for a high-speed charging.
摘要翻译：非水电解质二次电池包括能够插入和脱嵌锂的正极和负极，非水电解质和隔膜或固体电解质。作为主要成分的负极以作为构成要素的锡，硅，锌中的至少一种的核粒子的至少一部分表面的固体溶液或由包含在核粒子中的元素构成的金属间化合物和不包含在核粒子中的元素的另一规定元素。为了提高电池的能力，上述复合颗粒可以包括至少一种选自铁，铅和铋的痕量元素。负极上的混合层的孔隙率为10％以上且50％以下。非水电解质的量，分离器的厚度等被限制在特定值。上述结构抑制了由负极材料的膨胀引起的正极和负极之间的内部短路的发生，从而实现了具有优良的充放电循环特性的高容量电池，适用于高速充电。

3. 发明授权

US06548208B1 Non-aqueous electrolyte secondary battery and its negative electrode 有权
标题翻译：非水电解质二次电池及其负极
公开(公告)号：US06548208B1
公开(公告)日：2003-04-15
申请号：US09701277
申请日：2001-01-22
申请人： Shinji Kasamatsu , Harunari Shimamura , Yoshiaki Nitta
发明人： Shinji Kasamatsu , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M1024
CPC分类号： H01M10/052 , H01M4/02 , H01M4/04 , H01M4/0402 , H01M4/134 , H01M4/366 , H01M4/386 , H01M4/40 , H01M4/463 , H01M4/466 , H01M4/58 , H01M4/625 , H01M4/626 , H01M2004/027
摘要： A high capacity negative electrode for a non-aqueous electrolyte secondary battery which has low declining rate in discharge capacity caused by charge/discharge cycles by improving the electronic conductivity on the surface of the particles of the negative electrode material. The negative electrode material is formed by coating part of or the entire surface of solid phase A comprising a nucleus particle with the solid phase B. The solid phase A contains silicon as a constituent element. The solid phase B is composed of a solid solution or intermetallic compounds composed of silicon and at least one another element selected from a group comprising of group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements (exclusive of carbon and silicon) of the Periodic Table.
摘要翻译：一种用于非水电解质二次电池的高容量负极，其通过改善负极材料的颗粒的表面上的电子导电性而具有由充电/放电循环引起的放电容量的低下降率。负极材料通过将包含核粒子的固相A的一部分或整个表面与固相B进行涂布而形成。固相A含有硅作为构成元素。固相B由固体溶液或由硅构成的金属间化合物和选自由2族元素，过渡元素，12族元素，13族元素和14族元素组成的组中的至少一种元素组成和硅）。

4. 发明授权

US06824920B1 Non-aqueous electrolyte secondary battery comprising composite particles 失效
标题翻译：包含复合颗粒的非水电解质二次电池
公开(公告)号：US06824920B1
公开(公告)日：2004-11-30
申请号：US09601421
申请日：2000-09-28
申请人： Kazuya Iwamoto , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
发明人： Kazuya Iwamoto , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M438
CPC分类号： H01M4/38 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/42 , H01M10/0525 , H01M10/0568 , H01M10/0569
摘要： The present invention relates to a non-aqueous electrolyte secondary battery. The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an intermetallic compound, which are composed of the element contained in the nuclear particles, and at least one other element except the elements contained in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The electrolyte uses anion lithium salts of organic acid dissolved in organic solvent with high oxidation resistant characteristics. By adopting the above construction, a battery which generates only a small amount of gas during a high temperature storing can be obtained. Furthermore, the batteries enjoy high energy density and a lower reduction rate of discharge capacity when used repeatedly as well as high charge/discharge properties.
摘要翻译：本发明涉及一种非水电解质二次电池。本发明的负极的特征在于，其复合颗粒的构成是将含有锡，硅和锌中的至少一种作为构成元素的至少一部分核粒子的周围表面涂布固溶体或由包含在核粒子中的元素组成的金属间化合物，以及除了选自包含第2族元素，过渡元素，第12族元素，第13族元素的核粒子中的元素以外的至少一种其它元素和除了周期表碳以外的第14组元素。电解质使用溶解于有机溶剂中的有机酸的阴离子锂盐，具有高抗氧化特性。通过采用上述结构，可以获得在高温保存期间仅产生少量气体的电池。此外，当重复使用电池以及高充电/放电性能时，电池具有高的能量密度和较低的放电容量的减小率。

5. 发明授权

US08361658B2 Cathode material and non-aqueous electrolyte secondary battery using it 有权
标题翻译：阴极材料和非水电解质二次电池使用它
公开(公告)号：US08361658B2
公开(公告)日：2013-01-29
申请号：US12775185
申请日：2010-05-06
申请人： Harunari Shimamura , Toshitada Sato , Takayuki Nakamoto , Yasuhiko Bito , Yoshiaki Nitta
发明人： Harunari Shimamura , Toshitada Sato , Takayuki Nakamoto , Yasuhiko Bito , Yoshiaki Nitta
IPC分类号： H01M4/38 , H01M10/40 , H01M4/58
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
摘要翻译：一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，所述固相A分散在固相B中，所述比例（IA / IB）归因于固相B的固相A的最大衍射X射线强度（IA）与归于固相B的最大衍射X射线强度（IB）的折射率相对于衍射线满足0.001≤n1E; IA / IB＆N1; 0.1 通过复合粒子的广角X射线衍射测定得到。

6. 发明授权

US06881518B2 Process for manufacture of negative electrode material for a non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池用负极材料的制造方法
公开(公告)号：US06881518B2
公开(公告)日：2005-04-19
申请号：US10355051
申请日：2003-01-31
申请人： Hideya Kaminaka , Masaru Abe , Noriyuki Negi , Yoshiaki Nitta , Harunari Shimamura , Kazuhiro Okamura
发明人： Hideya Kaminaka , Masaru Abe , Noriyuki Negi , Yoshiaki Nitta , Harunari Shimamura , Kazuhiro Okamura
IPC分类号： H01M4/02 , H01M4/04 , H01M4/13 , H01M4/133 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/58 , H01M4/583 , H01M4/86
CPC分类号： H01M4/58 , B22F2009/041 , B22F2998/00 , H01M4/02 , H01M4/0454 , H01M4/13 , H01M4/133 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/383 , H01M4/583 , H01M2004/8684 , H01M2300/0017 , H01M2300/0082 , H01M2300/0085 , Y10T29/49108 , B22F9/008 , B22F9/04
摘要： A negative electrode material for a nonaqueous electrolyte secondary battery having a high discharge capacity and a good cycle life is made from alloy particles having an average particle diameter of 0.1-50 μm and including Si phase grains 40 and a phase of a solid solution or an intermetallic compound of Si and other element selected from Group 2A elements, transition elements, Group 3B elements, and Group 4B elements from the long form periodic table (for example, an NiSi2 phase 42 and an [NiSi2+NiSi] phase 41) at least partially enveloping the Si phase grains. 5-99 wt % of this material is Si phase grains. The alloy particles can be manufactured by rapid solidification (such as atomization or roller quenching) of a melt including Si and the other element, or by adhering the other element to Si powder by electroless plating or mechanical alloying and then performing heat treatment. Even if rapid solidification is carried out, a negative electrode material having a good discharge capacity and cycle life is obtained without heat treatment.
摘要翻译：由平均粒径为0.1-50μm的合金粒子制成具有高放电容量和良好的循环寿命的非水电解质二次电池用负极材料，其包含Si相粒子40，固溶相或选自元素周期表（例如，NiSi 2相42和[NiSi 2Si + NiSi]相41）至少部分包围Si相晶粒。该材料的5-99重量％是Si相晶粒。可以通过包括Si和另一种元素的熔体的快速凝固（例如雾化或辊筒淬火）制造合金颗粒，或者通过化学镀或机械合金化将另一种元素粘附到Si粉末上，然后进行热处理。即使进行快速凝固，也可以得到没有热处理的具有良好的放电容量和循环寿命的负极材料。

7. 发明授权

US06576366B1 Non-aqueous electrolyte secondary cell, and material for negative electrode used therefor 有权
标题翻译：非水电解质二次电池及用于其的负极材料
公开(公告)号：US06576366B1
公开(公告)日：2003-06-10
申请号：US09673753
申请日：2000-12-06
申请人： Takafumi Fujiwara , Harunari Shimamura , Takayuki Nakamoto , Yoshiaki Nitta
发明人： Takafumi Fujiwara , Harunari Shimamura , Takayuki Nakamoto , Yoshiaki Nitta
IPC分类号： H01M458
CPC分类号： H01M4/46 , H01M4/134 , H01M4/38 , H01M4/386 , H01M10/052 , H01M10/0565
摘要： In cycles of charging and discharging, an excellent capacity maintenance rate is obtained. The charging and discharging cycle characteristic of battery is enhanced. Further, an excellent initial discharging capacity is obtained. A negative electrode, a positive electrode, and a non-aqueous electrolyte are contained. The negative electrode includes an alloy of Si, a first element and a second element. The first element includes at least one element selected from the group consisting of the second group element except Mg in the periodic table, transition elements, twelfth group element, thirteenth group element except B, and fourteenth group element except Si. The second element includes at least one element of B and Mg.
摘要翻译：在充放电循环中，能够获得良好的容量维持率。电池的充放电循环特性得到提高。此外，获得了优异的初始放电容量。包含负极，正极和非水电解质。负极包括Si的合金，第一元素和第二元素。第一元素包括选自周期表中除了Mg以外的第二组元素，过渡元素，第十二组元素，除了B以外的第十三组元素，以及Si以外的第十四组元素中的至少一种元素。第二元素包括B和Mg的至少一个元素。

8. 发明授权

US07736806B2 Cathode material and non-aqueous electrolyte secondary battery using it 有权
标题翻译：阴极材料和非水电解质二次电池使用它
公开(公告)号：US07736806B2
公开(公告)日：2010-06-15
申请号：US10508341
申请日：2003-03-17
申请人： Harunari Shimamura , Toshitada Sato , Takayuki Nakamoto , Yasuhiko Bito , Yoshiaki Nitta
发明人： Harunari Shimamura , Toshitada Sato , Takayuki Nakamoto , Yasuhiko Bito , Yoshiaki Nitta
IPC分类号： H01M4/58 , H01M4/38
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
摘要翻译：一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，所述固相A分散在固相B中，所述比例（IA / IB）归因于固相B的固相A的最大衍射X射线强度（IA）与归于固相B的最大衍射X射线强度（IB）的折射率相对于衍射线满足0.001≤n1E; IA / IB＆N1; 0.1 通过复合粒子的广角X射线衍射测定得到。

9. 发明授权

US06506520B1 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US06506520B1
公开(公告)日：2003-01-14
申请号：US09601273
申请日：2000-09-21
申请人： Kaoru Inoue , Hiroshi Yoshizawa , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
发明人： Kaoru Inoue , Hiroshi Yoshizawa , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M1024
CPC分类号： H01M4/134 , H01M4/02 , H01M4/131 , H01M4/362 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/42 , H01M10/052 , H01M10/44 , H01M2004/027
摘要： A negative electrode is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound, which is composed of, the element included in the nuclear particles, and at least one other element except the elements included in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The present invention is characterized that the lithium content of the nuclear particles of the composite particles is 40-95 atomic percent of the theoretical limit of lithium content of each constituent element of the nuclear particles. Further, the batteries are first charged at a constant current and upon reaching the predetermined voltage, are charged at a constant voltage. The current density during charging are set at not more than 5 mA/cm2 as a in the area where the positive and negative electrodes face each other.
摘要翻译：负极的特征在于其复合颗粒以这样的方式构成，使得至少部分包含锡，硅和锌中的至少一种作为构成元素的核颗粒的周围表面涂覆有固溶体或间 - 金属化合物，其由包含在核粒子中的元素构成，以及除了选自包含第2族元素，过渡元素，第12族元素，第13族元素的族的核粒子中的元素以外的至少一种其它元素，第14组元素除了周期表的碳。本发明的特征在于，复合粒子的核粒子的锂含量为核粒子的各构成元素的锂含量的理论极限的40〜95原子％。此外，电池首先以恒定电流充电并且在达到预定电压时以恒定电压充电。在正极和负极彼此面对的区域中，充电时的电流密度设定为5mA / cm 2以下。

10. 发明授权

US06821675B1 Non-Aqueous electrolyte secondary battery comprising composite particles 失效
标题翻译：包含复合颗粒的非水电解质二次电池
公开(公告)号：US06821675B1
公开(公告)日：2004-11-23
申请号：US09601234
申请日：2000-10-30
申请人： Kenichi Morigaki , Kazuya Iwamoto , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
发明人： Kenichi Morigaki , Kazuya Iwamoto , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M458
CPC分类号： H01M4/366 , H01M2/0275 , H01M4/38 , H01M4/386 , H01M4/387 , H01M6/181 , H01M10/052 , H01M10/0562 , H01M10/0565 , H01M2300/0085
摘要： A negative electrode of a non-aqueous electrolyte secondary battery contains, as main a component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of elements included in the nuclear particle and at least one element, exclusive of the element included in said nuclear particle, selected from a group of elements in a Periodic Table, comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements exclusive of carbon. The batteries of the present invention include non-aqueous electrolytic solution and solid electrolytes comprising polymer gel electrolytes. The construction of the present invention provides a non-aqueous electrolytic secondary battery with which a possibility of the generation of gas is extremely low when stored at high temperatures. It also provides a battery having higher capacity, and superior cycle properties, high-rate charge/discharge properties.
摘要翻译：作为非水电解质二次电池的负极，以作为构成要素的锡，硅，锌中的至少一种的核粒子的至少一部分表面构成的复合粒子作为主要成分，涂覆有固体溶液或由核颗粒中包含的元素组成的金属间化合物和至少一种元素，不包括所述核颗粒中包含的元素，其选自周期表中的元素组，其包含组2 元素，过渡元素，第12族元素，13族元素和不含碳的第14族元素。本发明的电池包括非水电解液和包含聚合物凝胶电解质的固体电解质。本发明的构造提供了一种非水电解二次电池，其在高温下储存时具有产生气体的可能性极低。它还提供具有更高容量和优异的循环性能，高速率充电/放电性能的电池。

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