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    • 4. 发明申请
    • Negative electrode material for non-aqueous electrolyte secondary battery, method for producing the same and non-aqueous electrolyte secondary battery
    • 非水电解质二次电池用负极材料及其制造方法以及非水电解质二次电池
    • US20070122708A1
    • 2007-05-31
    • US11642472
    • 2006-12-20
    • Harunari ShimamuraTakayuki NakamotoHideaki OhyamaYasuhiko Bito
    • Harunari ShimamuraTakayuki NakamotoHideaki OhyamaYasuhiko Bito
    • H01M4/58
    • H01M4/38H01M4/0402H01M4/366H01M4/386H01M4/387H01M4/42H01M4/58H01M10/0525H01M2004/021H01M2004/027
    • A negative electrode material for a non-aqueous electrolyte secondary battery of the present invention is a negative electrode material for a non-aqueous electrolyte secondary battery capable of reversibly absorbing and desorbing lithium, and it includes a solid phase A and a solid phase B that have different compositions and has a structure in which the surface around the solid phase A is entirely or partly covered by the solid phase B. The solid phase A contains at least one element selected from the group consisting of silicon, tin and zinc, and the solid phase B contains the above-described at least one element contained in the solid phase A, and at least one element selected from the group consisting of Group IIA elements, transition elements, Group IIB elements, Group IIIB elements and Group IVB elements. The atomic arrangement and structure (e.g., crystal structure or amorphous structure) of at least one solid phase selected from the group consisting of the solid phase A and the solid phase B are controlled. It is possible to provide a negative electrode material for a non-aqueous electrolyte secondary battery in which deterioration due to charge/discharge cycle characteristics is suppressed, by using such a material as a negative electrode material for a non-aqueous electrolyte secondary battery. It is also possible to provide a non-aqueous electrolyte secondary battery having excellent charge/discharge cycle characteristics, by including such a negative electrode material for a non-aqueous electrolyte secondary battery.
    • 本发明的非水电解质二次电池用负极材料是能够可逆地吸收和解吸锂的非水电解质二次电池用负极材料,具有固相A和固相B, 具有不同的组成并且具有其中固相A周围的表面完全或部分被固相B覆盖的结构。固相A含有选自硅,锡和锌中的至少一种元素,并且 固相B包含上述固相A中所含的至少一种元素,以及选自由IIA族元素,过渡元素,IIB族元素,IIIB族元素和IVB族元素组成的组中的至少一种元素。 控制选自固相A和固相B的至少一种固相的原子排列和结构(例如,晶体结构或无定形结构)。 通过使用这种材料作为非水电解质二次电池的负极材料,可以提供通过抑制由于充放电循环特性而导致的劣化的非水电解质二次电池用负极材料。 通过包括这种非水电解质二次电池用负极材料,也可以提供充放电循环特性优异的非水电解质二次电池。
    • 5. 发明申请
    • Energy device and method for producing the same
    • 能量装置及其制造方法
    • US20050118504A1
    • 2005-06-02
    • US10985543
    • 2004-11-10
    • Kazuyoshi HondaKiichiro OishiYasuhiko BitoTakayuki Nakamoto
    • Kazuyoshi HondaKiichiro OishiYasuhiko BitoTakayuki Nakamoto
    • B05D5/12H01M4/04H01M4/1395H01M4/38H01M4/66H01M10/052H01M10/36H01M4/58
    • H01M4/661H01M4/0426H01M4/1395H01M4/38H01M4/386H01M10/052Y10T29/49115
    • An auxiliary film-forming source containing a main component element of a collector and a negative active material film-forming source for forming a negative active material thin film are placed adjacent to each other so that parts of film-forming particles from the respective sources are mixed with each other. The collector is moved relatively from the auxiliary film-forming source side to the negative active material film-forming source side, whereby a negative active material thin film containing silicon as a main component is formed on the collector by a vacuum film-forming process. A composition gradient layer, in which a composition distribution of a main component element of the collector and silicon constituting the negative active material is varied smoothly, is formed at the interface between the negative active material thin film and the collector. Even when the silicon particles in the negative active material expand/contract during charging/discharging, the composition gradient layer alleviates the strain involved in the expansion/contraction of the silicon particles, so that peeling at the interface between the negative active material thin film and the collector is suppressed, and the adhesion strength is enhanced. Consequently, cycle characteristics are enhanced.
    • 包含集电体的主要成分元素的辅助成膜源和用于形成负极活性物质薄膜的负极活性物质成膜源彼此相邻放置,使得来自各个源的成膜颗粒的部分为 相互混合 集电体从辅助成膜源侧相对移动到负极活性物质成膜源侧,由此通过真空成膜工艺在集电体上形成含有硅作为主要成分的负极活性物质薄膜。 在负极活性物质薄膜和集电体之间的界面处形成组成梯度层,其中集电体的主要成分元素的组成分布和构成负极活性物质的硅平滑地变化。 即使当负极活性物质中的硅颗粒在充电/放电期间膨胀/收缩时,组成梯度层也减轻了涉及硅颗粒膨胀/收缩的应变,从而在负极活性物质薄膜和 集电体被抑制,粘合强度提高。 因此,循环特性得到提高。
    • 7. 发明授权
    • Removal and installation device for external and internal snap rings
    • 外部和内部卡环的拆卸和安装设备
    • US07007357B2
    • 2006-03-07
    • US10479482
    • 2001-06-07
    • Takayuki Nakamoto
    • Takayuki Nakamoto
    • B23P19/04
    • B25B7/04B25B7/12B25B7/18B25B27/205Y10T29/53622Y10T29/5363
    • A removal and installation device for external and internal snap rings that can switch between shaft and hole modes by simple operation and produces better controllability, workability, serviceability and easiness in handling is provided. A rotary plate is rotated in a positive direction, a left side lever is turned as a shaft part is rotated integrally with the rotary plate, right and left side levers are crossed substantially in an X shape, the crossed parts supported by the shaft part, realizing the hole mode. The rotary plate is rotated in reverse direction, the left side lever is turned in a reverse direction as the shaft part is rotated in a reverse direction integrally with the rotary plate, both pivot parts of the right and left side levers arranged substantially in a V shape supported by the shaft part so that both projected working tools are parallel, realizing the shaft mode.
    • 提供外部和内部卡环的拆卸和安装装置,其可以通过简单的操作在轴和孔模式之间切换,并且提供更好的可控性,可操作性,可维护性和易于处理。 旋转板沿正方向旋转,随着轴部与旋转板一体地旋转,左侧杠杆转动,左右侧杠杆基本上跨越X形,由轴部支撑的交叉部分, 实现孔模式。 旋转板沿相反方向转动,左侧杠杆沿着与转动盘一体地相反方向转动的方向向相反方向转动,左右侧杠杆的两个枢轴部分基本上设置在V 形状由轴部支撑,使得两个投影的工作工具平行,实现轴模式。
    • 10. 发明授权
    • Device for attaching/detaching shaft snap ring and hole snap ring
    • 用于安装/拆卸轴卡环和孔扣环的装置
    • US5542167A
    • 1996-08-06
    • US391030
    • 1995-02-21
    • Takayuki Nakamoto
    • Takayuki Nakamoto
    • B25B7/04B25B27/20B23P19/04
    • B25B7/04B25B27/205Y10T29/5363
    • A device for attaching/detaching a snap ring, which can be set up in either of types for shaft and hole applications only by one operation of turning right and left leading portions removably inserted in holes at both ends of a snap ring. Leading portions connected to right and left grasp levers and operating levers are turned around the connecting axes such that locking projections of the leading portions are both directed inward or outward, and rotational shafts removably connected with the leading portions are rotated, so that a right movable pin meshing with a gear portion of one rotational shaft is engaged with a pin hole of the right operating lever and an engaging hole of the right grasp lever while a left movable pin is engaged with a pin hole of the left operating lever and an engaging hole of the left grasp lever, as a result of which the device is set up in the type for shaft application; or a left movable pin is engaged with the pin hole of the left operating lever and an engaging hole of the right grasp lever while a right movable pin is engaged with the pin hole of the right operating lever and an engaging hole of the left grasp lever, as a result of which the device is set up in the type for hole application.
    • 一种用于安装/拆卸卡环的装置,其可以仅通过将可拆卸地插入卡环的两端的孔中的左右前导部的一个操作设置在用于轴和孔应用的类型中。 连接到左右抓握杆和操作杆的引导部分围绕连接轴线转动,使得引导部分的锁定突起都向内或向外指向,并且与引导部分可移除地连接的旋转轴旋转,使得可动 与一个旋转轴的齿轮部分的销啮合与右操作杆的销孔和右把手杆的接合孔接合,而左可动销与左操作杆的销孔接合,并且接合孔 的左侧把手杆,因此该装置设置在轴应用的类型中; 或左活动销与左操作杆的销孔和右把手杆的接合孔接合,而右可动销与右操作杆的销孔接合,并且左抓握杆的接合孔 ,因此该装置被设置在孔应用的类型中。