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1. 发明授权

US5462905A Exhaust gas purifying catalyst 失效
标题翻译：废气净化催化剂
公开(公告)号：US5462905A
公开(公告)日：1995-10-31
申请号：US105932
申请日：1993-08-13
申请人： Tetsuo Nagami , Yoshitsugu Ogura , Masahiko Ogai , Yoshiaki Fukushima , Shinji Inagaki , Kazuhiro Fukumoto , Kouji Banno , Yuji Sakakibara , Yasuo Takada , Takashi Ohta , Akane Okada , Yukimura Yamada , Kiyotaka Hayashi , Shinji Matsuura , Kazuyuki Kuroda
发明人： Tetsuo Nagami , Yoshitsugu Ogura , Masahiko Ogai , Yoshiaki Fukushima , Shinji Inagaki , Kazuhiro Fukumoto , Kouji Banno , Yuji Sakakibara , Yasuo Takada , Takashi Ohta , Akane Okada , Yukimura Yamada , Kiyotaka Hayashi , Shinji Matsuura , Kazuyuki Kuroda
IPC分类号： B01D53/86 , B01D53/94 , B01J21/08 , B01J29/03
CPC分类号： B01J29/0308 , B01D53/9418 , B01D53/9445 , B01D53/945 , B01D53/9481 , B01J21/08 , B01J29/0325 , B01J35/1061 , B01D2255/1021 , B01D2255/912 , B01D2255/9202 , Y02T10/22
摘要： An exhaust gas purifying catalyst is characterized in that at least one kind of catalyst metal is loaded on a layered porous silica or a layered porous silica-metal oxide. The exhaust gas purifying catalyst is used as an oxidation catalyst for purifying hydrocarbon and carbon monoxide, or a reduction catalyst for purifying nitrogen oxides (NO.sub.x), which is suitable for purifying exhaust gases in automobiles. An exhaust gas purifying apparatus includes the above exhaust gas purifying catalyst and an absorbent for trapping hydrocarbon components, in which aromatic HC such as trimethylbenzene and the like are effectively trapped.
摘要翻译：废气净化催化剂的特征在于，在层状多孔质二氧化硅或层状多孔二氧化硅 - 金属氧化物上载持至少一种催化剂金属。废气净化催化剂用作净化烃和一氧化碳的氧化催化剂，或者用于净化汽车中的废气的氮氧化物（NOx）的还原催化剂。废气净化装置包括上述废气净化催化剂和用于捕获烃成分的吸收剂，其中芳族HC如三甲基苯等被有效地捕获。

2. 发明授权

US5382558A Heat resistant layered porous silica and process for producing the same 失效
标题翻译：耐热层状多孔二氧化硅及其制造方法
公开(公告)号：US5382558A
公开(公告)日：1995-01-17
申请号：US087440
申请日：1993-07-02
申请人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okada , Kazuhiro Fukumoto , Kazuyuki Kuroda
发明人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okada , Kazuhiro Fukumoto , Kazuyuki Kuroda
IPC分类号： B01J20/10 , B01J21/08 , B01J23/04 , B01J29/04 , B01J35/04 , B01J20/28
CPC分类号： B01J35/04 , B01J20/10 , B01J21/08 , B01J23/04 , B01J29/049
摘要： A heat resistant layered porous silica having a honeycomb porous structure comprises a plurality of waved or bent sheet layers of crystalline layered silicate superposed one after another, and the neighboring sheets are partially bonded by siloxane bonding. The spacing between the neighboring sheet layers is narrowed toward the bonded portions and expanded at other portions to thereby form fine pores. The layered porous silica contains alkali metal ions in an amount of 0.2% by weight or less and has a specific surface area of 1,000 m.sup.2 /g or more.The layered porous silica has a large specific surface area, and exhibits an excellent heat resistance and adsorption of organic substances such as fuel.
摘要翻译：具有蜂窝状多孔结构的耐热性层状多孔二氧化硅，包括多个叠层的多个波状或弯曲的结晶层状硅酸盐层，相邻的片材通过硅氧烷键部分地结合。相邻片层之间的间隔朝向接合部变窄，在其他部分膨胀，形成细孔。层状多孔二氧化硅含有0.2重量％以下的碱金属离子，比表面积为1000m 2 / g以上。层状多孔二氧化硅具有大的比表面积，并表现出优异的耐热性和有机物质如燃料的吸附。

3. 发明授权

US5707598A Porous material composed of layered silica and metal oxide and a process for manufacturing the same 失效
公开(公告)号：US5707598A
公开(公告)日：1998-01-13
申请号：US192962
申请日：1994-02-07
申请人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okada , Chuzo Kato , Kazuyuki Kuroda
发明人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okada , Chuzo Kato , Kazuyuki Kuroda
IPC分类号： C01B33/12 , B01J20/10 , B01J21/08 , B01J23/04 , B01J29/00 , B01J29/04 , B01J35/04 , C01B33/20 , C01B33/32 , C01B33/44 , C01B33/26
CPC分类号： B01J20/10 , B01J21/08 , B01J23/04 , B01J29/049 , B01J35/04 , Y10T428/24149 , Y10T428/249969 , Y10T428/24997
摘要： A porous material composed of many SiO.sub.4 tetrahedra sheets having interlayer bridges of SiO.sub.2. It has pores having a diameter of 10 .ANG. or above, and possesses the properties of a solid acid formed by the isomorphous substitution of metal atoms for Si of SiO.sub.4 frameworks. It is made by a process including introducing an organic substance into interlayer space of crystals of layered silicates to expand the spacing between crystal layers, as well as forming bridges of SiO.sub.2 therebetween, bringing the intercalated compounds into contact with a metal salt to link metal atoms to the SiO.sub.4 frameworks, and firing the products. The material can withstand a temperature of 800.degree. C., has a pore diameter larger than that of zeolites, etc., and is useful in making an adsorbent or catalyst for molecules having a high molecular weight, such as a catalyst for the catalytic cracking of petroleum.

4. 发明授权

US5508081A Porous material composed of layered silica and metal oxide and a process for manufacturing the same 失效
标题翻译：由层状二氧化硅和金属氧化物构成的多孔材料及其制造方法
公开(公告)号：US5508081A
公开(公告)日：1996-04-16
申请号：US192933
申请日：1994-02-07
申请人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okata , Chuzo Kato , Kazuyuki Kuroda
发明人： Shinji Inagaki , Yoshiaki Fukushima , Akane Okata , Chuzo Kato , Kazuyuki Kuroda
IPC分类号： C01B33/12 , B01J20/10 , B01J21/08 , B01J23/04 , B01J29/00 , B01J29/04 , B01J35/04 , C01B33/20 , C01B33/32 , C01B33/44 , B32B3/12
CPC分类号： B01J20/10 , B01J21/08 , B01J23/04 , B01J29/049 , B01J35/04 , Y10T428/24149 , Y10T428/249969 , Y10T428/24997
摘要： A porous material composed of many SiO.sub.4 tetrahedra sheets having interlayer bridges of SiO.sub.2. It has pores having a diameter of 10 .ANG. or above, and possesses the properties of a solid acid formed by the isomorphous substitution of metal atoms for Si of SiO.sub.4 frameworks. It is made by a process including introducing an organic substance into interlayer space of crystals of layered silicates to expand the spacing between crystal layers, as well as forming bridges of SiO.sub.2 therebetween, bringing the intercalated compounds into contact with a metal salt to link metal atoms to the SiO.sub.4 frameworks, and firing the products. The material can withstand a temperature of 800.degree. C., has a pore diameter larger than that of zeolites, etc., and is useful in making an adsorbent or catalyst for molecules having a high molecular weight, such as a catalyst for the catalytic cracking of petroleum.
摘要翻译：由具有SiO 2层间桥的许多SiO 4四面体片组成的多孔材料。它具有直径为10或更大的孔，并且具有通过金属原子对SiO 4骨架的Si的同晶取代而形成的固体酸的性质。它是通过包括将有机物质引入到层状硅酸盐晶体的层间空间中以扩大晶体层之间的间距，以及在其间形成二氧化硅之间的过程，使插入的化合物与金属盐接触以连接金属原子到SiO4框架，并烧制产品。该材料可以承受800℃的温度，孔径大于沸石等的孔径，并且可用于制备具有高分子量的分子的吸附剂或催化剂，例如用于催化裂化的催化剂的石油。

5. 发明申请

US20070023289A1 Mesoporous film, laser emission assembly, and process for producing mesoporous film 审中-公开
标题翻译：介孔膜，激光发射组件，以及生产介孔膜的工艺
公开(公告)号：US20070023289A1
公开(公告)日：2007-02-01
申请号：US11437787
申请日：2006-05-22
申请人： Hirokatsu Miyata , Masatoshi Watanabe , Takashi Noma , Kazuyuki Kuroda , Takashi Suzuki , Ayumu Fukuoka
发明人： Hirokatsu Miyata , Masatoshi Watanabe , Takashi Noma , Kazuyuki Kuroda , Takashi Suzuki , Ayumu Fukuoka
IPC分类号： E04B1/70
CPC分类号： C01B37/02 , B01J20/28033 , B01J20/28083 , B82Y30/00 , C01B33/124 , H01S5/10
摘要： A novel structure is provided in which mesopores are oriented. Further a mesoporous film is provided which has two-branched diffraction peaks at intervals or 180° according to in-plane X-ray diffraction.
摘要翻译：提供了一种新颖的结构，其中介孔取向。此外，提供了根据平面内X射线衍射，间隔或180°具有双支链衍射峰的介孔膜。

6. 发明授权

US5028351A Process for preparing organic smectite by solid-solid reaction 失效
标题翻译：固相反应制备有机蒙皂石的方法
公开(公告)号：US5028351A
公开(公告)日：1991-07-02
申请号：US515305
申请日：1990-04-27
申请人： Chuzo Kato , Kazuyuki Kuroda , Makoto Ogawa
发明人： Chuzo Kato , Kazuyuki Kuroda , Makoto Ogawa
IPC分类号： C04B33/00 , B28C1/10 , C01B33/40 , C01B33/44
CPC分类号： C01B33/44
摘要： A process for preparing organic smectite applied for thickener, protective colloid, dispersant and binder. The present invention features the process for preparing the organic smectite by mixing smectite incluidng 0 to 20% by weight of interlayer water in the interlayer spaces of said smectite with organic cation-supplying substance selected from at least one of aliphatic alkylamine salts, aromatic amine salts and basic organic compound having pyridine nucleus, and/or basic organic molecule in a mixing ratio of the latter to the former of 10 to 500 milliequivalents per 100 g smectite, and stirring the resulting mixture at a temperature of 5.degree. to 50.degree. C. under an applied pressure of 0.5 to 10 kg/cm.sup.2 to cause a solid-solid reaction. By the process of the present invention, exchangeable organic cations and/or basic organic molecules as a guest substance are intercalated int he interlayer spaces of the smectite as a host substance, thus the hydrophilic smectite can convert to the organic smectite by a more simplified solid-solid reaction than a liquid-liquid reaction.
摘要翻译：一种制备有机蒙皂石的方法，用于增稠剂，保护胶体，分散剂和粘合剂。本发明的特征在于通过将含有0-20％重量的层间水的蒙皂石与所述蒙皂石的层间空间中的有机阳离子供应物质混合，所述有机阳离子供体物质选自以下中的至少一种：脂族烷基胺盐，芳族胺盐和具有吡啶核的碱性有机化合物和/或碱性有机分子，其混合比例相对于每100克蒙皂石的10-500毫当量的混合比，并在5℃至50℃的温度下搅拌所得混合物。在0.5〜10kg / cm2的施加压力下进行固体 - 固体反应。通过本发明的方法，作为客体物质的交换性有机阳离子和/或碱性有机分子以蒙脱石的层间空间作为主体物质嵌入，因此亲水性绿土可以通过更简单的固体转化为有机蒙皂石固液反应比液 - 液反应。

7. 发明申请

US20080207785A1 PROCESS FOR FORMING MESOSTRUCTURED MATERIAL AND PROCESS FOR CONTROLLING ORIENTATION OF TUBULAR MESOPORES 有权
标题翻译：用于形成结构材料的方法和用于控制管状体的方向的方法
公开(公告)号：US20080207785A1
公开(公告)日：2008-08-28
申请号：US12109028
申请日：2008-04-24
申请人： Hirokatsu Miyata , Kazuyuki Kuroda
发明人： Hirokatsu Miyata , Kazuyuki Kuroda
IPC分类号： C08J9/00
CPC分类号： C01B37/00 , C01B37/02 , Y10T428/24562 , Y10T428/24661 , Y10T428/24744 , Y10T428/249953 , Y10T428/249974
摘要： A mesostructured material, which has plural tubular pores and is arranged on a polymer surface, characterized in that the pores are uniaxially oriented. The mesostructured material can be developed to functional devices.
摘要翻译：一种介孔结构材料，其具有多个管状孔并且布置在聚合物表面上，其特征在于，孔是单轴取向的。介观结构材料可以开发成功能性器件。

8. 发明申请

US20060204758A1 Mesostructured film, mesoporous material film, and production methods for the same 失效
标题翻译：中等结构膜，介孔材料膜及其制备方法
公开(公告)号：US20060204758A1
公开(公告)日：2006-09-14
申请号：US10544109
申请日：2004-08-05
申请人： Hirokatsu Miyata , Yasuhiro Kawashima , Kazuyuki Kuroda
发明人： Hirokatsu Miyata , Yasuhiro Kawashima , Kazuyuki Kuroda
IPC分类号： B32B9/04
CPC分类号： G21K1/06 , C01B37/02 , Y10T428/24322 , Y10T428/24496 , Y10T428/249967 , Y10T428/249969 , Y10T428/31504
摘要： A mesostructured film is provided having a structure in which surfactant molecular assemblies are regularly arranged three-dimensionally. A polymer compound thin film is formed on the substrate surface through spin coating or the like, and a rotating roller wrapped with a cloth is pressed against the polymer film for rubbing in one direction. The polymer material includes polyimide, polyamide, and polystyrene. The substrate includes a silica glass substrate and a silicon substrate. The mesostructured film can be formed by retaining the substrate in an aqueous solution containing a surfactant, silicon alkoxide, and acid. After being retained in the solution, the substrate is heated at about 60 to 120° C. for several hours to several days for reaction. The surfactant includes C18H37 (OCH2CH2)200H and C16H33 (OCH2CH2) 200H. The alkoxide included tetraethoxysilane, tetramethoxysilane, and tetrapropoxysilane. Hydrochloric acid, nitric acid, or sulfuric acid is used as a catalyst.
摘要翻译：提供了具有其中表面活性剂分子组件被三维规则地排列的结构的介孔结构膜。通过旋涂等在基材表面上形成高分子化合物薄膜，将用布覆盖的旋转辊按压在聚合物膜上以在一个方向上摩擦。聚合物材料包括聚酰亚胺，聚酰胺和聚苯乙烯。基板包括石英玻璃基板和硅基板。可以通过将基材保持在含有表面活性剂，硅醇盐和酸的水溶液中来形成介孔结构膜。保留在溶液中后，将基底在约60至120℃加热数小时至数天以进行反应。表面活性剂包括C 18 H 23（OCH 2 CH 2）2 O 20 H和C 16 H 33（OCH 2 CH 2）20 H 2 O 醇盐包括四乙氧基硅烷，四甲氧基硅烷和四丙氧基硅烷。使用盐酸，硝酸或硫酸作为催化剂。

9. 发明授权

US06846546B2 Mesostructured materials, silica mesostructured materials, preparation methods thereof and control method of mesopore orientation 失效
标题翻译：中孔结构材料，二氧化硅介孔结构材料，其制备方法和中孔取向控制方法
公开(公告)号：US06846546B2
公开(公告)日：2005-01-25
申请号：US09478884
申请日：2000-01-07
申请人： Kazuyuki Kuroda , Hirokatsu Miyata
发明人： Kazuyuki Kuroda , Hirokatsu Miyata
IPC分类号： C08J7/12 , C01B33/12 , C01B37/00 , C01B37/02 , B32B3/20 , B01J20/10 , B01J21/14 , B32B3/00 , B32B3/26
CPC分类号： C01B37/00 , C01B37/02 , Y10T428/24562 , Y10T428/24661 , Y10T428/24744 , Y10T428/249953 , Y10T428/249974
摘要： A mesostructured material, which has plural tubular mesopores and is arranged on a polymer surface, characterized in that the mesopores are oriented in on direction parallel to the surface. The mesostructured material can be developed to functional devices.
摘要翻译：一种介质结构材料，其具有多个管状介孔并且布置在聚合物表面上，其特征在于，所述中孔在平行于所述表面的方向上取向。介观结构材料可以开发成功能性器件。

10. 发明申请

US20050048264A1 Structure with oriented tubular pores 失效
标题翻译：具有定向管状孔的结构
公开(公告)号：US20050048264A1
公开(公告)日：2005-03-03
申请号：US10958245
申请日：2004-10-06
申请人： Hirokatsu Miyata , Kazuyuki Kuroda
发明人： Hirokatsu Miyata , Kazuyuki Kuroda
IPC分类号： C08J7/12 , C01B33/12 , C01B37/00 , C01B37/02 , B32B3/00
CPC分类号： C01B37/00 , C01B37/02 , Y10T428/24562 , Y10T428/24661 , Y10T428/24744 , Y10T428/249953 , Y10T428/249974
摘要： A mesostructured material, which has plural tubular pores and is arranged on a polymer surface, characterized in that the pores are uniaxially oriented. The mesostructured material can be developed to functional devices.
摘要翻译：一种介孔结构材料，其具有多个管状孔并且布置在聚合物表面上，其特征在于，孔是单轴取向的。介观结构材料可以开发成功能性器件。

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