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1. 发明授权

US08092880B2 Fuel hose 有权
标题翻译：燃油软管
公开(公告)号：US08092880B2
公开(公告)日：2012-01-10
申请号：US11727006
申请日：2007-03-23
申请人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
发明人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
IPC分类号： B32B1/08 , B32B25/00
CPC分类号： B32B1/08 , B32B25/08 , B32B25/14 , B32B27/304 , B32B27/322 , B32B2270/00 , B32B2597/00 , F16L11/04 , F16L11/12 , Y10T428/1383 , Y10T428/1386 , Y10T428/139 , Y10T428/1393
摘要： A fuel hose includes a laminated structure of a tubular resin layer and an adjoining rubber layer, the rubber layer being formed by a rubber composition containing the following (A) to (F) as essential components, and the resin layer being formed by a material containing a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer or a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride-perfluoroalkyl vinyl ether quaterpolymer as a main component: (A) a blend of acrylonitrile-butadiene rubber and polyvinyl chloride; (B) at least one selected from the group consisting of 1,8-diazabicyclo[5.4.0]undecene-7 salt, 1,5-diazabicyclo[4.3.0]nonene-5 salt, 1,8-diazabicyclo[5.4.0]undecene-7 and 1,5-diazabicyclo[4.3.0]nonene-5; (C) zeolite; (D) magnesium oxide; (E) laminar mineral; and (F) basic silica.
摘要翻译：燃料软管包括管状树脂层和相邻的橡胶层的层压结构，橡胶层由含有以下（A）至（F）作为必要成分的橡胶组合物形成，树脂层由材料形成含有四氟乙烯 - 六氟丙烯 - 偏二氟乙烯三元共聚物或四氟乙烯 - 六氟丙烯 - 偏氟乙烯 - 全氟烷基乙烯基四
价四聚物作为主要成分：（A）丙烯腈 - 丁二烯橡胶和聚氯乙烯的共混物; （B）至少一种选自1,8-二氮杂双环[5.4.0]十一碳烯-7盐，1,5-二氮杂双环[4.3.0]壬烯-5盐，1,8-二氮杂双环[5.4。 0]十一碳烯-7和1,5-二氮杂双环[4.3.0]壬烯-5; （C）沸石; （D）氧化镁; （E）层状矿物; 和（F）碱性二氧化硅。

2. 发明授权

US06576313B2 Bonded laminate structure, hose containing the bonded laminate structure, and methods for producing the same 失效
公开(公告)号：US06576313B2
公开(公告)日：2003-06-10
申请号：US10084368
申请日：2002-02-28
申请人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
发明人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
IPC分类号： B32B2708
CPC分类号： B32B17/067 , B32B1/08 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2262/0284 , B32B2266/0292 , B32B2323/04 , B32B2323/10 , B32B2367/00 , B32B2377/00 , B32B2398/20 , B32B2597/00 , F16L11/04 , F16L2011/047 , Y10T156/1089 , Y10T428/139 , Y10T428/1393 , Y10T428/31736 , Y10T428/31786
摘要： A bonded laminate structure which is obtainable by bonding a PBN layer (or PBT layer) to a thermoplastic resin layer without the use of an adhesive material. The bonded laminate structure comprises: a first layer comprising at least one of polybutylene naphthalate (PBN) and polybutylene terephthalate (PBT) as an essential component and having a surface subjected to an electric discharge treatment such as a plasma treatment; and a second layer comprising an amine-rich resin as an essential component and bonded to the surface of the first layer.

3. 发明申请

US20070194481A1 Hose production method 审中-公开
标题翻译：软管生产方法
公开(公告)号：US20070194481A1
公开(公告)日：2007-08-23
申请号：US11635614
申请日：2006-12-08
申请人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
发明人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
IPC分类号： B29C47/06
CPC分类号： F16L11/04 , B29C48/09 , B29C48/151 , B29C48/21 , B29C48/22 , B29C48/49 , B29K2009/06 , B29K2023/16 , B29K2027/06 , B29K2027/16 , B29K2027/18 , B29K2077/00 , B29K2081/04 , B29K2995/0072 , B29L2023/005 , B32B1/08 , B32B25/08 , B32B25/14 , B32B25/16 , B32B27/16 , B32B27/304 , B32B27/322 , B32B2270/00 , B32B2597/00 , F16L2011/047
摘要： A production method of a hose having a laminate structure consisting of three layers of an inner rubber layer, a resin layer, an outer rubber layer coaxially laminated in this order, wherein after the resin layer is extruded on an outer peripheral surface of the inner rubber layer, an outer peripheral surface of the resin layer is subjected to a direct type atmospheric pressure plasma treatment in advance of extrusion of the outer rubber layer.
摘要翻译：一种软管的制造方法，其特征在于，具有层叠结构的层叠结构，所述叠层结构由内层橡胶层，树脂层，外侧橡胶层构成，其中，所述内层橡胶层，树脂层，外侧橡胶层依次同轴地层叠，其中，在将所述树脂层挤出到所述内侧橡胶层，外层橡胶层的挤出之前，对树脂层的外周面进行直接型大气压等离子体处理。

4. 发明申请

US20070248779A1 Fuel hose 有权
标题翻译：燃油软管
公开(公告)号：US20070248779A1
公开(公告)日：2007-10-25
申请号：US11727006
申请日：2007-03-23
申请人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
发明人： Shinji Iio , Kazutaka Katayama , Hiroaki Ito
IPC分类号： B32B1/08
CPC分类号： B32B1/08 , B32B25/08 , B32B25/14 , B32B27/304 , B32B27/322 , B32B2270/00 , B32B2597/00 , F16L11/04 , F16L11/12 , Y10T428/1383 , Y10T428/1386 , Y10T428/139 , Y10T428/1393
摘要： A fuel hose includes a laminated structure of a tubular resin layer and an adjoining rubber layer, the rubber layer being formed by a rubber composition containing the following (A) to (F) as essential components, and the resin layer being formed by a material containing a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer or a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride-perfluoroalkyl vinyl ether quaterpolymer as a main component: (A) a blend of acrylonitrile-butadiene rubber and polyvinyl chloride; (B) at least one selected from the group consisting of 1,8-diazabicyclo[5.4.0]undecene-7 salt, 1,5-diazabicyclo[4.3.0]nonene-5 salt, 1,8-diazabicyclo[5.4.0]undecene-7 and 1,5-diazabicyclo[4.3.0]nonene-5; (C) zeolite; (D) magnesium oxide; (E) laminar mineral; and (F) basic silica.
摘要翻译：燃料软管包括管状树脂层和相邻的橡胶层的层压结构，橡胶层由含有以下（A）至（F）作为必要成分的橡胶组合物形成，树脂层由材料形成含有四氟乙烯 - 六氟丙烯 - 偏二氟乙烯三元共聚物或四氟乙烯 - 六氟丙烯 - 偏氟乙烯 - 全氟烷基乙烯基四
价四聚物作为主要成分：（A）丙烯腈 - 丁二烯橡胶和聚氯乙烯的共混物; （B）至少一种选自1,8-二氮杂双环[5.4.0]十一碳烯-7盐，1,5-二氮杂双环[4.3.0]壬烯-5盐，1,8-二氮杂双环[5.4。 0]十一碳烯-7和1,5-二氮杂双环[4.3.0]壬烯-5; （C）沸石; （D）氧化镁; （E）层状矿物; 和（F）碱性二氧化硅。

5. 发明授权

US06446673B1 Fuel hose of low fuel permeability 有权
标题翻译：燃油软管燃油渗透率低
公开(公告)号：US06446673B1
公开(公告)日：2002-09-10
申请号：US10040496
申请日：2002-01-09
申请人： Shinji Iio , Hiroaki Ito , Yoshimitsu Ishida , Katsutoshi Mizuno , Tomohide Ito
发明人： Shinji Iio , Hiroaki Ito , Yoshimitsu Ishida , Katsutoshi Mizuno , Tomohide Ito
IPC分类号： F16L1100
CPC分类号： F16L11/04 , B32B1/08 , F16L2011/047 , Y10S138/07 , Y10T428/139
摘要： A hose of low fuel permeability has a fuel permeability in a bent state with R50 not more than three times a fuel permeability in a straight state, R50 being a bent state where the hose has its longitudinal axis bent to form an arc having a diameter of 100 mm. Its low fuel permeability is achieved if the resin forming its inner wall layer has a melt viscosity falling within a certain range, which can be obtained by, for example, increasing the degree of polymerization of the resin, or grafting a specific side chain to the main chain in each molecule of the resin, or if the resin has a volume swelling degree falling within a certain range, which can be obtained by copolymerizing a monomer having fuel resistance, or blending a polymer having fuel resistance. The hose maintains its low fuel permeability even if it may be subjected to a large load of bending stress as when it is used to form a fluid conveying line.
摘要翻译：具有低燃料渗透性的软管在弯曲状态下具有燃料渗透性，其中R50在直线状态下不超过燃料渗透性的三倍，R50是弯曲状态，其中软管的纵轴弯曲形成直径为 100毫米。如果形成其内壁层的树脂的熔融粘度落在一定范围内，则可以获得低的燃料渗透性，这可以通过例如增加树脂的聚合度或将特定的侧链接枝到或者树脂的体积溶胀度落入一定范围内，这可以通过使具有耐燃料性的单体共聚，或者混合具有耐燃料性的聚合物而获得。软管保持其低的燃料渗透性，即使它可能受到大量的弯曲应力的负载，因为它用于形成流体输送线。

6. 发明申请

US20050003126A1 Fuel hose 审中-公开
标题翻译：燃油软管
公开(公告)号：US20050003126A1
公开(公告)日：2005-01-06
申请号：US10878570
申请日：2004-06-29
申请人： Hiroaki Ito , Shinji Iio
发明人： Hiroaki Ito , Shinji Iio
IPC分类号： F16L11/04 , B29C47/06 , B29C47/20 , B32B1/08 , B32B7/02 , B32B27/28 , B32B27/30 , B32B27/32 , B32B27/34 , C08K3/02 , C08K5/3462 , C08L23/08 , C08L27/12 , C08L33/02 , C08L33/14 , C08L51/06 , C08L77/00 , F16L11/11 , F16L11/12 , F16L11/00
CPC分类号： B32B7/02 , B32B1/08 , B32B3/28 , B32B25/08 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/322 , B32B27/34 , B32B37/153 , B32B2307/50 , B32B2327/12 , B32B2327/18 , B32B2377/00 , B32B2597/00 , F16L11/11 , F16L11/1185 , F16L11/127 , F16L2011/047 , Y10T428/139
摘要： In a fuel hose composed of an inner single layer or multilayer of a fluororesin and an outer single layer or multilayer of a thermoplastic resin, any two materials for the layers have a ratio 1:40 or below in melt viscosity as expressed in Pa·s. The wall formed by having its inner and outer layers co-extruded is free from any unevenness in thickness that would occur if their materials had a larger ratio in melt viscosity. Thus, it is impermeable to fuel, and has an improved adhesion between its inner and outer layers.
摘要翻译：在由内部单层或多层氟树脂和外单层或多层热塑性树脂组成的燃料软管中，用于这些层的任何两种材料的熔体粘度的比例为1:40或更低，如Pa.s 。通过使其内层和外层共挤出而形成的壁没有任何不均匀的厚度，如果它们的材料的熔体粘度比较大，就会发生。因此，它是不可渗透的燃料，并且其内层和外层之间具有改善的粘合性。

7. 发明授权

US06676165B2 Tank joint parts and a process for manufacturing an annular molded product of resins 有权
标题翻译：油罐接头部件和制造环氧树脂成型体的方法
公开(公告)号：US06676165B2
公开(公告)日：2004-01-13
申请号：US10096837
申请日：2002-03-14
申请人： Shinji Iio , Hiroaki Ito , Atsuo Miyajima , Tomohide Ito
发明人： Shinji Iio , Hiroaki Ito , Atsuo Miyajima , Tomohide Ito
IPC分类号： F16L4702
CPC分类号： B29C45/0013 , B29C45/16 , B29C45/2708 , B29C70/62 , B29C2045/2714 , B29K2105/18 , B29L2031/24 , B60K2015/03453
摘要： A tank joint part has a welding member welded to the outer surface of a fuel tank and a main body formed of a material of low fuel permeability and welded or otherwise joined to the welding member. The welding member is formed of modified polyethylene, which is easily weldable or otherwise joinable to the outer surface of the fuel tank and the main body, and in which very fine particles of a layered mineral are easily dispersible. The mineral is dispersed in layers oriented substantially at right angles to the direction of any possible permeation from the tank joint part. The tank joint part ensures a low fuel permeability and a high bonding strength.
摘要翻译：油箱接头部分具有焊接在燃料箱的外表面上的焊接部件和由燃料透过性低的材料形成的主体，并焊接或以其他方式接合到焊接部件。焊接部件由改性聚乙烯形成，其易于焊接或以其他方式连接到燃料箱和主体的外表面，并且其中非常细的分层矿物颗粒易于分散。矿物分散在基本上与罐接合部分任何可能的渗透方向成直角定向的层中。油罐接头部件确保低燃料渗透性和高粘结强度。

8. 发明授权

US06576312B1 Fuel transporting tube 失效
标题翻译：燃油输送管
公开(公告)号：US06576312B1
公开(公告)日：2003-06-10
申请号：US09439870
申请日：1999-11-12
申请人： Hiroaki Ito , Shinji Iio
发明人： Hiroaki Ito , Shinji Iio
IPC分类号： F16L1104
CPC分类号： F16L11/127 , F16L9/123 , Y10T428/1379 , Y10T428/1393 , Y10T428/24975 , Y10T428/31732 , Y10T428/31743 , Y10T428/31746 , Y10T428/31786 , Y10T428/31797
摘要： A fuel transporting tube including an inner layer which contacts a fuel being transported and which is formed of a polybutylene naphthalate resin, an outer layer which is provided radially outwardly of the inner layer and which is formed of a polyamide resin or a polyolefin resin, and an intermediate layer which is provided between the inner layer and the outer layer and which is formed of a resin to adhere the inner and outer layers to each other.
摘要翻译：一种燃料输送管，其包括与被输送的燃料接触并由聚萘二甲酸丁二醇酯树脂形成的内层，设置在所述内层的径向外侧并由聚酰胺树脂或聚烯烃树脂形成的外层，以及中间层，其设置在内层和外层之间，并且由树脂形成，以将内层和外层彼此粘合。

9. 发明授权

US06467509B1 Fuel hose 有权
标题翻译：燃油软管
公开(公告)号：US06467509B1
公开(公告)日：2002-10-22
申请号：US10143948
申请日：2002-05-14
申请人： Shinji Iio , Hiroaki Ito
发明人： Shinji Iio , Hiroaki Ito
IPC分类号： F16L1100
CPC分类号： F16L11/04 , F16L2011/047 , Y10S138/07
摘要： A fuel hose comprising a rubber layer and a fluororesin layer formed on the inner surface of the rubber layer, in which the adhesion to the fluororesin layer is improved by blending from 2 to 15 phr of a phenol-type resin with the rubber forming the rubber layer. Phenol resins of a specific polymeric structure are particularly preferred as the phenol-type resins. A fluororesin layer formed by melting a fluororesin and allowing it to adhere to the inner surface of the rubber layer by powder coating is particularly preferred. The provision of the fluororesin layer on the inner surface of the rubber layer enables simple and effective adhesion of the thinned fluororesin layer to the rubber layer.
摘要翻译：一种燃料软管，其包括形成在橡胶层内表面上的橡胶层和氟树脂层，其中通过将2至15phr的酚型树脂与形成橡胶的橡胶相混合来改善与氟树脂层的粘合性层。作为酚类树脂，特别优选苯酚树脂。特别优选通过熔融氟树脂而使其通过粉末涂料粘附到橡胶层的内表面而形成的氟树脂层。在橡胶层的内表面上设置氟树脂层能够使薄型氟树脂层与橡胶层简单有效地粘合。

10. 发明授权

US06279615B1 Fuel hose 失效
标题翻译：燃油软管
公开(公告)号：US06279615B1
公开(公告)日：2001-08-28
申请号：US09653199
申请日：2000-08-31
申请人： Shinji Iio , Hiroaki Ito , Takahiro Nishiyama
发明人： Shinji Iio , Hiroaki Ito , Takahiro Nishiyama
IPC分类号： F16L1100
CPC分类号： F16L11/11 , F16L2011/047 , Y10S138/07
摘要： A fuel hose comprises a single layered or multi-layered tubular rubber body and a thin film resin layer formed on the inner circumferential surface of the innermost layer of the tubular rubber body. The resin layer is formed of a resin such that an amount of permeation of 10% ethanol-mixed gasoline is 2 mg/cm2/day (at 60° C.) or less when the thickness of the resin layer is 0.1 mm. A preferred example of such a resin is EVOH with an ethylene content of from 35 to 50 mol % or polybutylene aromatic ester. The fuel hose has necessary flexibility and shows excellent impermeability even to an alcohol-mixed gasoline.
摘要翻译：燃料软管包括单层或多层管状橡胶体和形成在管状橡胶体的最内层的内圆周表面上的薄膜树脂层。树脂层由树脂形成，当树脂层的厚度为0.1mm时，10％乙醇混合汽油的渗透量为2mg / cm 2 /天（60℃）以下。这种树脂的优选实例是乙烯含量为35至50摩尔％的EVOH或聚丁烯芳族酯。燃料软管具有必要的灵活性，即使对于酒精混合汽油也显示出优异的不渗透性。

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