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1. 发明授权

US5352379A Liquid crystal composition, liquid crystal element and process for the preparation of liquid crystal element 失效
标题翻译：液晶组成物，液晶元件及制备液晶元件的方法
公开(公告)号：US5352379A
公开(公告)日：1994-10-04
申请号：US894659
申请日：1992-06-05
申请人： Shinichi Nishiyama , Hideo Hama , Tooru Yamanaka , Yukio Miyachi
发明人： Shinichi Nishiyama , Hideo Hama , Tooru Yamanaka , Yukio Miyachi
IPC分类号： C09K19/20 , C09K19/02 , C09K19/22 , C09K19/30 , C09K19/32 , C09K19/42 , C09K19/46 , G02F1/13 , C09K19/12
CPC分类号： C09K19/0266 , C09K19/322 , C09K19/46 , C09K2019/325
摘要： The liquid crystal composition of the present invention comprises 1-99 wt. % of an antiferroelectric liquid crystal compound such as a compound represented by the following formula [A-8] and 99-1 wt. % of a cholesteric liquid crystal compound such as a compound represented by the following formula [B-2]. ##STR1## By the use of the liquid crystal composition of the invention, a liquid crystal element improved in liquid crystal properties such as contrast can be prepared.
摘要翻译：本发明的液晶组合物包含1-99重量％％的反铁电液晶化合物，例如由下式[A-8]表示的化合物和99-1重量％％的由下式[B-2]表示的化合物的胆甾醇型液晶化合物。通过使用本发明的液晶组合物，可以制备提高液晶性能如对比度的液晶元件。图像A [8] [B-2]

2. 发明授权

US5389287A Antiferroelectric liquid crystal composite material, process for preparing the same, and liquid crystal element using the same 失效
标题翻译：反铁电液晶复合材料及其制备方法和使用该反铁电液晶复合材料的液晶元件
公开(公告)号：US5389287A
公开(公告)日：1995-02-14
申请号：US90820
申请日：1993-07-13
申请人： Shinichi Nishiyama , Mitsuko Nagai , Hideo Hama , Tooru Yamanaka
发明人： Shinichi Nishiyama , Mitsuko Nagai , Hideo Hama , Tooru Yamanaka
IPC分类号： C09K19/02 , C09K19/32 , C09K19/42 , C09K19/54 , C09K19/52 , G02F1/13
CPC分类号： C09K19/0266 , C09K19/322 , C09K19/42 , C09K19/544 , C09K2019/325 , C09K2019/326
摘要： An antiferroelectric liquid crystal composite material comprising an organic polymer and an antiferroelectric liquid crystal material, both being in the dispersed state; a process for preparing a liquid crystal element including a step of mixing an organic polymer and an antiferroelectric liquid crystal material; and a liquid crystal element having such a structure that the above-mentioned antiferroelectric liquid crystal composite material is sandwiched between a pair of electrodes are provided. According to the present invention, there can be obtained a liquid crystal element which is available at a low price, quick in the electrooptical response, free from occurrence of switching failure and is able to make a large display screen.
摘要翻译：包含分散状态的有机聚合物和反铁电液晶材料的反铁电液晶复合材料; 一种制备液晶元件的方法，包括混合有机聚合物和反铁电液晶材料的步骤; 以及具有上述反铁电液晶复合材料夹在一对电极之间的结构的液晶元件。根据本发明，可以获得一种液晶元件，其以低价格可用，电光响应快，不发生开关故障，并且能够制作大的显示屏。

3. 发明授权

US5356561A Carboxylate compounds, liquid crystal compositions and liquid crystal elements containing said compounds and method of optical modulation using said elements 失效
标题翻译：含有所述化合物的羧酸酯化合物，液晶组合物和液晶元素以及使用所述元素进行光学调制的方法
公开(公告)号：US5356561A
公开(公告)日：1994-10-18
申请号：US813032
申请日：1991-12-24
申请人： Toyoji Shimizu , Shinichi Nishiyama , Nobuyuki Doi , Shoichi Miyakoshi , Tooru Yamanaka , Katsuo Taniguchi , Hideo Hama
发明人： Toyoji Shimizu , Shinichi Nishiyama , Nobuyuki Doi , Shoichi Miyakoshi , Tooru Yamanaka , Katsuo Taniguchi , Hideo Hama
IPC分类号： C07C69/757 , C07C69/773 , C07C69/90 , C09K19/02 , C09K19/32 , C07C69/76
CPC分类号： C09K19/0266 , C07C69/757 , C07C69/90 , C09K19/322 , C09K2019/325
摘要： In accordance with the present invention, there are provided carboxylate compounds represented by the following formula [A] and liquid crystal material comprising said compounds ##STR1## wherein R is a group selected from the group consisting of alkyl, alkoxy and halogenated alkyl group of 3-20 carbon atoms, X and Y represent each a group selected from the group consisting of --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --S--S--, ##STR2## or a single bond, A and B represent each a group selected from the group consisting of specific divalent aromatic and alicyclic group such as phenylene, cyclohexylene and tetrahydronaphthalene and R* is an optically active group of 4-20 carbon atoms containing at least one asymmetric carbon atom (hydrogen atoms attached to the carbon atoms of said optically active group may be substituted with halogen atoms), and m and n are each an integer of 0-2, with the proviso that both m and n do not become 0 at the same time.
摘要翻译：根据本发明，提供由下式[A]表示的羧酸酯化合物和包含所述化合物[A]的液晶材料，其中R是选自烷基，烷氧基和卤代烷基 3-20个碳原子的基团，X和Y各自表示选自-COO - ， - OCO - ， - CH 2 CH 2 - ， - CH 2 O - ， - OCH 2 - ，-SS-，或单键，A和B分别表示选自亚苯基，亚环己基和四氢萘中的特定二价芳族和脂环族的基团，R *是含有至少一个不对称碳原子的4-20个碳原子的光学活性基团（与所述光学活性基团的碳原子连接的氢原子可以被卤素原子取代），m和n分别为0-2的整数，条件是m和n两者不同时成为0 。

4. 发明授权

US5246622A Liquid crystal racemic mixture, liquid crystal composition and liquid crystal element, process for manufacturing liquid crystal element, and uses of liquid crystal element 失效
标题翻译：液晶混合液体，液晶组合物和液晶元件，制造液晶元件的方法和液晶元件的使用
公开(公告)号：US5246622A
公开(公告)日：1993-09-21
申请号：US731978
申请日：1991-07-18
申请人： Toyoji Shimizu , Katsuo Taniguchi , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi , Hideo Hama
发明人： Toyoji Shimizu , Katsuo Taniguchi , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi , Hideo Hama
IPC分类号： C09K19/02 , C09K19/28 , C09K19/30 , C09K19/32
CPC分类号： C09K19/0266 , C09K19/28 , C09K19/3068 , C09K19/322 , C09K2019/325
摘要： The liquid crystal racemic mixture of the invention is represented by the formula [I]:Z--(X.A).sub.m (Y.B).sub.n COOR.sup.1 [I]wherein R1 is a specific group of alkyl, alkoxy or halogenated alkyl, X and Y are either one of the following group: --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --COCH.sub.2 --, --CH.sub.2 CO-- and --S--S--, or a single bond, A and B are each a specific bivalent group such as 1,4-phenylene group, Z is a group selected from the group consisting of ##STR1## (wherein R.sub.2 is an alkyl group, an alkoxy group or a halogenated alkyl group), and m and n are an integer of 0 to 2 (m and N not being simultaneously 0). The liquid crystal composition of the invention comprises the racemic mixture as described above. Moreover, the liquid crystal element of the invention comprises a liquid crystal material containing the liquid crystal racemic mixture as described above.

5. 发明授权

US5445888A Hydrazine compound, process for the preparation of the same, and nonlinear optical organic material 失效
标题翻译：肼化合物，其制备方法和非线性光学有机材料
公开(公告)号：US5445888A
公开(公告)日：1995-08-29
申请号：US177713
申请日：1994-01-05
申请人： Tsuneaki Koike , Hideo Hama , Tooru Yamanaka
发明人： Tsuneaki Koike , Hideo Hama , Tooru Yamanaka
IPC分类号： C07C243/28 , C07C243/30 , C07C281/02 , C07C323/60 , C07D213/77 , C07D239/42 , G02F1/361 , B32B9/04
CPC分类号： C07D213/77 , C07C243/28 , C07C243/30 , C07C281/02 , C07C323/60 , C07D239/42 , G02F1/3611 , Y10S428/913 , Y10T428/1041 , Y10T428/261 , Y10T428/31504
摘要： A novel hydrazine compound represented by the formula (I) is disclosed. ##STR1## Also disclosed are a process for preparing the novel hydrazine compound comprising reacting a specific hydrazine compound and a specific acid halide, a nonlinear optical organic material comprising the hydrazine compound represented by the above formula (I), and a nonlinear optical organic element comprising the nonlinear optical organic material. The nonlinear optical organic material shows excellent nonlinear optical effect, and the material is favorably applied to nonlinear optical organic elements such as an optical wavelength conversion element and an electrooptical element.
摘要翻译：公开了由式（I）表示的新型肼化合物。（I）还公开了一种制备新型肼化合物的方法，包括使特定的肼化合物和特定的酰卤反应，包含由上式（I）表示的肼化合物的非线性光学有机材料和非线性光学有机元件包括非线性光学有机材料。非线性光学有机材料显示出优异的非线性光学效果，并且该材料有利地应用于诸如光学波长转换元件和电光学元件的非线性光学有机元件。

6. 发明授权

US6007737A Liquid crystal compositions 失效
标题翻译：液晶组成
公开(公告)号：US6007737A
公开(公告)日：1999-12-28
申请号：US952732
申请日：1997-11-25
申请人： Shinichi Nishiyama , Yuichirou Tatsuki , Takahiro Fujiyama , Chiho Hirano , Hideo Hama , Tohru Yamanaka
发明人： Shinichi Nishiyama , Yuichirou Tatsuki , Takahiro Fujiyama , Chiho Hirano , Hideo Hama , Tohru Yamanaka
IPC分类号： C09K19/02 , C09K19/52 , C09K19/20 , C09K19/32
CPC分类号： C09K19/0266 , C09K19/0225
摘要： The first smectic liquid crystal composition of the invention has a voltage gradation parameter L of less than 0.6, said parameter being defined by the equation L=S.sub.H /S.sub.O with the proviso that: a liquid crystal cell filled with a liquid crystal composition is placed between a pair of polarizing plates arranged in the crossed Nicols state; a voltage is applied to the liquid crystal cell to form a hysteresis curve showing a correlation between the voltage and a transmittance; and a tangent line I.sub.R of the hysteresis curve within a region wherein the transmittance steeply increases intersects a tangent line I.sub.F of the hysteresis curve within a region which is adjacent to the voltage-steep increase region and which is on the higher-voltage side at an intersection point P. In the above equation, S.sub.O is an area of a rectangular triangle having as an oblique side a straight line PQ which has, as both ends, the intersection point P and an intersection point Q of an axis of ordinate (V=0) and the hysteresis curve; and S.sub.H is an area of a region enclosed with the straight line PQ, the hysteresis curve and a constant-voltage straight line which passes the intersection point P. The second liquid crystal composition of the invention has a parameter G of 0 to 0.3, said parameter G being defined by the following equation with the proviso that when an absolute value .vertline.V.vertline. of a voltage V applied in the same manner as described above is increased to the predetermined value .vertline.V.vertline..sub.min, the light quantity T becomes a maximum value T.sub.max ; ##EQU1## In the above equation, S is an area of a region enclosed with the hysteresis curve, T.sub.min is a minimum value of the transmittance; and T.sub.0 is a transmittance given when no voltage is applied.
摘要翻译： PCT No.PCT / JP96 / 01478。 371日期：1997年11月25日 102（e）1997年11月25日日期PCT提交1996年5月31日PCT公布。公开号WO96 / 38513 日本1996年12月5日本发明的第一层间液晶组合物具有小于0.6的电压等级参数L，所述参数由式L = SH / SO定义，条件是：填充有液体的液晶单元将晶体组成放置在以正交尼科尔斯状态布置的一对偏振板之间; 向液晶单元施加电压，形成表示电压与透射率的相关性的滞后曲线。并且在透射率急剧增加的区域内的滞后曲线的切线IR与滞后曲线的切线IF在与电压陡峭增加区域相邻的区域内相交，并且位于高电压侧的区域在上述等式中，SO是具有倾斜侧的直线PQ的矩形三角形的区域，该直线PQ的两端具有交点P和纵轴的交点Q（V = 0）和滞后曲线; SH是通过交点P的直线PQ，滞后曲线和恒定电压直线所包围的区域的区域。本发明的第二液晶组合物的参数G为0〜0.3，所述参数G由以下等式定义，条件是当绝对值| V |时以与上述相同的方式施加的电压V增加到预定值| V | min，光量T变为最大值Tmax; 在上述等式中，S是用滞后曲线包围的区域的面积，Tmin是透射率的最小值; 而T0是当没有施加电压时给出的透射率。

7. 发明授权

US5589966A Antiferroelectric liquid crystal light modulation device 失效
标题翻译：反铁电液晶光调制装置
公开(公告)号：US5589966A
公开(公告)日：1996-12-31
申请号：US237120
申请日：1994-05-03
申请人： Hideo Hama , Yukari Sakai
发明人： Hideo Hama , Yukari Sakai
IPC分类号： G02F1/1347 , G02F1/141 , G02F1/31
CPC分类号： G02F1/141 , G02F1/13471 , G02F1/31 , G02F2001/1412 , G02F2203/07
摘要： The liquid crystal light modulation device of the present invention comprising a liquid crystal element consisting of one of plural liquid crystal cells and a voltage signal input means electrically connected with the liquid crystal element, wherein each liquid crystal cell contains a chiral smectic liquid crystal material layer and when a voltage signal is input to the liquid crystal element, the polarization direction of a light transmitted by the liquid crystal element is changed by approx. 90.degree. as compared with the state where the voltage signal is not input to the liquid crystal element enables a change of a light path and an open-close (on-off) operation of a light path at a high speed (optical switching time: not longer than 1 msec).
摘要翻译：本发明的液晶光调制装置包括由多个液晶单元中的一个组成的液晶元件和与液晶元件电连接的电压信号输入装置，其中每个液晶单元包含手性近晶液晶材料层并且当向液晶元件输入电压信号时，由液晶元件透射的光的偏振方向改变大约。 90°与电压信号未输入到液晶元件的状态相比，可以高速地改变光路的光路和开 - 关（开 - 关）操作（光切换时间：不超过1毫秒）。

8. 发明授权

US5113273A Liquid crystal display device 失效
公开(公告)号：US5113273A
公开(公告)日：1992-05-12
申请号：US496030
申请日：1990-03-20
申请人： Akihiro Mochizuki , Hideo Hama , Mitsuaki Hirose
发明人： Akihiro Mochizuki , Hideo Hama , Mitsuaki Hirose
IPC分类号： G02F1/133 , G02F1/1333 , G02F1/137 , G02F1/141 , G09G3/36
CPC分类号： G02F1/133345 , G02F1/141
摘要： A liquid crystal display device comprising a layer of a ferroelectric liquid crystal material sandwiched between opposed first and second electrodes. The display device further comprises a dielectric layer as a capacitative element which is electrically connected through an electrically conductive connecting means to the first electrode so that the dielectric layer and the liquid crystal material are connected in parallel with regard to an external electric source. The display device provides a large area and high information content display, high contrast ratio display, and high gradation display, together with a stabilized memory effect.

9. 发明授权

US07553524B2 Liquid crystal display device 失效
标题翻译：液晶显示装置
公开(公告)号：US07553524B2
公开(公告)日：2009-06-30
申请号：US10587069
申请日：2005-01-19
申请人： Naoko Sawatari , Masato Okabe , Hideo Hama
发明人： Naoko Sawatari , Masato Okabe , Hideo Hama
IPC分类号： C09K19/02 , G02F1/141
CPC分类号： G02F1/141 , G02F1/133788 , G02F2001/133773 , Y10T428/10 , Y10T428/1005
摘要： The invention provides a liquid crystal display using a ferroelectric liquid crystal, which can give mono-domain alignment of the ferroelectric liquid crystal without forming alignment defects which is so remarkably good in alignment stability that the alignment thereof can be maintained even if the temperature of the liquid crystal is raised to the phase transition point or higher. The present invention provides a liquid crystal display comprising a ferroelectric liquid crystal sandwiched between two substrates, wherein an electrode and a photo alignment layer are each successively formed a constituent material of the respective photo alignment layer is a photoreactive material which generates a photoreaction to give anisotropy to the photo alignment layer; and the constituent material of the respective photo alignment layer has different composition from each other with the ferroelectric liquid crystal sandwiched therebetween.
摘要翻译：本发明提供了一种使用铁电液晶的液晶显示器，其可以赋予铁电液晶的单畴取向，而不会形成取向稳定性非常好的取向缺陷，即使其中的液晶升高至相变点以上。本发明提供一种液晶显示装置，其特征在于，具备夹在两个基板之间的铁电液晶，其中依次形成电极和光取向层，各自的光取向层的构成材料是产生光反应以产生各向异性的光反应性材料到光取向层; 并且各个光取向层的构成材料在其间夹有铁电液晶的方式彼此不同。

10. 发明授权

US5922242A Liquid crystal display 失效
标题翻译：液晶显示器
公开(公告)号：US5922242A
公开(公告)日：1999-07-13
申请号：US858811
申请日：1997-05-19
申请人： Tatsuo Saishu , Kohki Takatoh , Hideo Hama , Yukari Sakai
发明人： Tatsuo Saishu , Kohki Takatoh , Hideo Hama , Yukari Sakai
IPC分类号： G02F1/137 , C09K19/02 , G02F1/133 , G02F1/1337 , G02F1/141 , G09F9/35 , C09K19/52 , C09K19/32
CPC分类号： C09K19/0266 , G02F1/141 , G02F2001/133773 , G02F2001/1412 , G02F2203/30
摘要： An LCD which having a high response speed, a wide viewing angle and a high contrast and capable of displaying high-quality gray-scale images at normal temperature. The LCD comprises an array substrate, a counter substrate opposing the array substrate, pixel electrodes arranged on the the array substrate in rows and columns, each connected to an active element, a first orientation film provided on the pixel electrodes, a counter electrode opposing the pixel electrodes, arranged on the counter substrate, a second orientation film provided on the counter electrode, rubbed in a direction slightly inclined to a direction in which the first orientation has been rubbed, and a layer of antiferroelectric liquid crystal sealed in a gap between the first and second orientation films, the antiferroelectric liquid crystal being a smectic liquid crystal which contains an antiferroelectric liquid crystal compound represented by R.sup.1 (O)--Zm--Y--E--COO--C*HX--R.sup.4. The liquid crystal exhibits transmittance which increases monotonically with applied voltage and exhibits a memory margin M ranging from -1 to 0 at normal temperature. The memory margin M is given as M=(V.sub.10 -V'.sub.90)/(V.sub.90 -V.sub.10).
摘要翻译：具有高响应速度，宽视角和高对比度并能够在常温下显示高质量灰度图像的LCD。 LCD包括阵列基板，与阵列基板相对的对置基板，排列在阵列基板上的行和列各自连接到有源元件的像素电极，设置在像素电极上的第一取向膜，与配置在对置基板上的像素电极，设置在对电极上的第二取向膜，沿着与第一取向被摩擦的方向稍微倾斜的方向摩擦，以及密封在第一取向之间的间隙中的反铁电液晶层第一和第二取向膜，反铁电液晶是含有由R1（O）-Zm-YE-COO-C * HX-R4表示的反铁电液晶化合物的近晶液晶。液晶显示透射率随施加电压单调增加，并且在正常温度下表现出从-1到0的记忆容限M. 存储器裕度M被给出为M =（V10-V'90）/（V90-V10）。

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