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1. 发明申请

US20120318717A1 HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME 有权
标题翻译：烃油的加氢催化剂及其生产方法，以及使用相同的油气加氢方法
公开(公告)号：US20120318717A1
公开(公告)日：2012-12-20
申请号：US13581997
申请日：2011-03-22
申请人： Shinichi Inoue , Yukitaka Wada , Akihiro Mutou , Takeo Ono
发明人： Shinichi Inoue , Yukitaka Wada , Akihiro Mutou , Takeo Ono
IPC分类号： B01J31/38 , C10G45/10
CPC分类号： B01J31/38 , B01J21/04 , B01J21/063 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J35/002 , B01J35/0026 , B01J35/0033 , B01J35/1019 , B01J35/1038 , B01J35/1047 , B01J35/1061 , B01J35/1085 , B01J37/0207 , B01J37/0219 , B01J37/0221 , B01J37/06 , C10G45/08
摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.
摘要翻译：提供：具有加氢脱硫活性的烃油的加氢处理催化剂，其另外通过以下方式进一步提高：在含有氧化铝水合物颗粒的水溶胶的同时并连续地将含有钛的酸性化合物的水溶液和含有碱性化合物的水溶液加入到含有水合氧化铝颗粒的水溶胶中 10至100℃，pH为4.5至6.5; 洗涤所得物以除去污染的离子; 在脱水后形成洗涤后的产品，使其具有可形成的水分含量; 干燥结果; 用含有至少一种周期表6族金属化合物，至少一种周期表第8-10族金属化合物，至少一种磷化合物和至少一种类型的磷化合物的催化组分水溶液浸渍干燥产物的糖; 并干燥所得物; 催化剂的制造方法; 以及使用该催化剂的烃油的加氢脱硫处理方法。

2. 发明授权

US09776180B2 Hydrotreating catalyst for hydrocarbon oil and method for producing same, and hydrocarbon oil hydrotreating method using same 有权
公开(公告)号：US09776180B2
公开(公告)日：2017-10-03
申请号：US13581997
申请日：2011-03-22
申请人： Shinichi Inoue , Yukitaka Wada , Akihiro Mutou , Takeo Ono
发明人： Shinichi Inoue , Yukitaka Wada , Akihiro Mutou , Takeo Ono
IPC分类号： B01J23/85 , B01J31/38 , B01J21/04 , B01J21/06 , B01J23/883 , B01J35/00 , B01J35/10 , B01J37/02 , C10G45/08 , B01J37/06 , B01J23/88 , B01J27/19 , B01J23/882
CPC分类号： B01J31/38 , B01J21/04 , B01J21/063 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J35/002 , B01J35/0026 , B01J35/0033 , B01J35/1019 , B01J35/1038 , B01J35/1047 , B01J35/1061 , B01J35/1085 , B01J37/0207 , B01J37/0219 , B01J37/0221 , B01J37/06 , C10G45/08
摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

3. 发明授权

US07691781B2 Layered porous titanium oxide, process for producing the same, and catalyst comprising the same 有权
标题翻译：层状多孔氧化钛，其制造方法，以及含有它们的催化剂
公开(公告)号：US07691781B2
公开(公告)日：2010-04-06
申请号：US10584453
申请日：2003-12-25
申请人： Shinichi Inoue , Akihiro Mutou , Yukitaka Wada , Hidehiko Kudou , Tateo Ono , Hisashi Nomura
发明人： Shinichi Inoue , Akihiro Mutou , Yukitaka Wada , Hidehiko Kudou , Tateo Ono , Hisashi Nomura
IPC分类号： B01J23/00 , C01G23/047
CPC分类号： C01G23/0532 , B01J21/063 , B01J27/19 , B01J35/002 , B01J37/0215 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C10G45/00
摘要： This invention provides layered porous titanium oxide comprising an inorganic oxide as a core and titanium oxide deposited on the surface of the inorganic oxide, wherein the titanium localization index B/A represented by the ratio of the proportion of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) determined by X-ray photoelectron spectroscopy (XPS) [B=Ti XPS/(Ti XPS+M XPS)] to the bulk mixing molar ratio of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) [A=Ti/(Ti+M)] is 1.6 or more and the titanium oxide is deposited on the surface of the inorganic oxide so as to be chemically and/or microscopically united to the inorganic oxide and also provides a process for producing the same and a catalyst comprising the same. The layered porous titanium oxide of this invention has a regulated pore structure, a large specific surface area, and excellent mechanical strength and is useful as a catalyst or a catalyst carrier.
摘要翻译：本发明提供了以无机氧化物为芯和沉积在无机氧化物表面上的氧化钛的层状多孔氧化钛，其中钛定位指数B / A以钛（Ti）的比例与无机氧化物的组成金属（M）和通过X射线光电子能谱（XPS）测定的钛（Ti）[B = Ti XPS /（Ti XPS + M XPS）]与钛（Ti）的体积混合摩尔比相对于无机氧化物的组成金属（M）和钛（Ti）[A = Ti /（Ti + M）]的总和为1.6以上，氧化钛沉积在无机氧化物的表面上，在化学和/或显微镜下与无机氧化物结合，并提供其制备方法和包含该方法的催化剂。本发明的层状多孔氧化钛具有调节的孔结构，大的比表面积和优异的机械强度，并且可用作催化剂或催化剂载体。

4. 发明申请

US20070140952A1 Layered porous titanium oxide, process for producing the same, and catalyst comprising the same 有权
标题翻译：层状多孔氧化钛，其制造方法，以及含有它们的催化剂
公开(公告)号：US20070140952A1
公开(公告)日：2007-06-21
申请号：US10584453
申请日：2003-12-25
申请人： Shinichi Inoue , Akihiro Mutou , Yukitaka Wada , Hidehiko Kudou , Tateo Ono , Hisashi Nomura
发明人： Shinichi Inoue , Akihiro Mutou , Yukitaka Wada , Hidehiko Kudou , Tateo Ono , Hisashi Nomura
IPC分类号： C01G23/047
CPC分类号： C01G23/0532 , B01J21/063 , B01J27/19 , B01J35/002 , B01J37/0215 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C10G45/00
摘要： This invention provides layered porous titanium oxide comprising an inorganic oxide as a core and titanium oxide deposited on the surface of the inorganic oxide, wherein the titanium localization index B/A represented by the ratio of the proportion of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) determined by X-ray photoelectron spectroscopy (XPS) [B=TiXPS/(TiXPS+MXPS)] to the bulk mixing molar ratio of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) [A=Ti/(Ti+M)] is 1.6 or more and the titanium oxide is deposited on the surface of the inorganic oxide so as to be chemically and/or microscopically united to the inorganic oxide and also provides a process for producing the same and a catalyst comprising the same. The layered porous titanium oxide of this invention has a regulated pore structure, a large specific surface area, and excellent mechanical strength and is useful as a catalyst or a catalyst carrier.
摘要翻译：本发明提供了以无机氧化物为芯和沉积在无机氧化物表面上的氧化钛的层状多孔氧化钛，其中钛定位指数B / A以钛（Ti）的比例与无机氧化物的组分金属（M）和通过X射线光电子能谱（XPS）测定的钛（Ti）[B = Ti XPS + M （Ti）与无机氧化物的组成金属（M）和钛（Ti）[A = Ti /（Ti + M））的总和的体积混合摩尔比 ]为1.6以上，并且氧化钛沉积在无机氧化物的表面上，以便化学和/或显微结合到无机氧化物上，并且还提供其制备方法和包含其的催化剂。本发明的层状多孔氧化钛具有调节的孔结构，大的比表面积和优异的机械强度，并且可用作催化剂或催化剂载体。

5. 发明授权

US06376423B2 Catalyst for preparation of synthesis gas and process for preparing carbon monoxide 失效
标题翻译：用于制备合成气的催化剂和一氧化碳的制备方法
公开(公告)号：US06376423B2
公开(公告)日：2002-04-23
申请号：US09254634
申请日：1999-03-11
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
IPC分类号： B01J2340
CPC分类号： C01B3/40 , B01J23/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed are a catalyst for producing a synthesis gas using a carbon-containing organic compound as a raw material and a process for producing carbon monoxide. The catalyst for producing a synthesis gas is composed of a carrier formed of a metal oxide and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier and is characterized in that the catalyst has a specific surface area of 25 m2/g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the supported catalytic metal is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide. The process for producing carbon monoxide includes a step of reacting a carbon-containing organic compound with carbon dioxide in a pressurized condition to produce a synthesis gas, and a step of concentrating carbon monoxide in the thus obtained synthesis gas and is characterized in that the above-described catalyst is used as a catalyst in the synthesis gas producing step.
摘要翻译：公开了使用含碳有机化合物作为原料的合成气的制造催化剂和一氧化碳的制造方法。用于生产合成气的催化剂由金属氧化物和选自铑，钌，铱，钯和铂的至少一种催化金属形成的载体组成，并载持在载体上，其特征在于催化剂具有比表面积面积为25m 2 / g以下，其中，载体金属氧化物的金属离子的电负性为13.0以下，以金属为基准的负载催化金属的量为0.0005〜0.1摩尔％在载体金属氧化物上。生产一氧化碳的方法包括在加压状态下使含碳有机化合物与二氧化碳反应以产生合成气的步骤，以及将一氧化碳浓缩在所得合成气中的步骤，其特征在于上述在合成气生产步骤中使用描述的催化剂作为催化剂。

6. 发明授权

US06387843B1 Method of preparing Rh- and/or Ru-catalyst supported on MgO carrier and reforming process using the catalyst 有权
标题翻译：制备负载在MgO载体上的Rh-和/或Ru-催化剂的方法和使用该催化剂的重整方法
公开(公告)号：US06387843B1
公开(公告)日：2002-05-14
申请号：US09825966
申请日：2001-04-05
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura
IPC分类号： B01J2358
CPC分类号： B01J37/0018 , B01J21/10 , B01J23/462 , B01J23/464 , B01J37/0009
摘要： A method of preparing a catalyst, including molding a mixture of magnesium oxide with a binder selected from carbon, fatty acids having 12-22 carbon atoms, magnesium salts of fatty acids having 12-22 carbon atoms, carboxymethyl cellulose, a magnesium salt of carboxymethyl cellulose and polyvinyl alcohol and calcining the molded mixture to obtain a carrier having a specific surface area of 5 m2/g of less. The carrier is impregnated with an aqueous solution containing Rh and/or Ru compounds for loading a catalytic metal component and then dried and calcined. The catalyst is used for reforming a lower hydrocarbon gas with steam and carbon dioxide or with carbon dioxide to produce a synthesis gas.
摘要翻译：一种制备催化剂的方法，包括将氧化镁与选自碳，12-22个碳原子的脂肪酸，含12-22个碳原子的脂肪酸镁盐，羧甲基纤维素，羧甲基镁盐，纤维素和聚乙烯醇，并煅烧模制的混合物以获得比表面积为5m 2 / g以下的载体。用含有Rh和/或Ru化合物的水溶液浸渍载体以负载催化金属组分，然后干燥和煅烧。催化剂用于用蒸汽和二氧化碳或二氧化碳重整低级烃气体以产生合成气。

7. 发明授权

US06340437B1 Process for preparing synthesis gas by autothermal reforming 有权
标题翻译：通过自热重整制备合成气的方法
公开(公告)号：US06340437B1
公开(公告)日：2002-01-22
申请号：US09254636
申请日：1999-03-11
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
IPC分类号： C07C102
CPC分类号： B01J23/40 , C01B3/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed is a process for producing a synthesis gas by an autothermal reforming method including a step of partially oxidizing a carbon-containing organic compound to produce a high temperature mixed gas, and a synthesis producing step of reacting the unreacted carbon-containing organic compound contained in the high temperature mixed gas with carbon dioxide and/or steam, wherein a catalyst having a considerably suppressed carbon deposition activity is used as a catalyst for the synthesis gas producing step. The catalyst is characterized in that the catalyst comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m2/g or less, in that metal ion of the carrier metal oxide has electronegativity of 13.0 or less, and in that the amount of the catalytic metal supported is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide.
摘要翻译：公开了一种通过自热重整法制备合成气的方法，该方法包括将含碳有机化合物部分氧化以产生高温混合气体的步骤，以及合成制备步骤，使含有具有二氧化碳和/或蒸汽的高温混合气体，其中具有显着抑制的碳沉积活性的催化剂用作合成气生产步骤的催化剂。催化剂的特征在于催化剂包含由金属氧化物形成的载体和至少一种选自铑，钌，铱，钯和铂的催化金属并负载在载体上，因为催化剂具有比表面积 25m 2 / g以下，载体金属氧化物的金属离子的电负性为13.0以下，并且，以金属为基准，载体的载体量为0.0005〜0.1摩尔％金属氧化物。

8. 发明授权

US06312660B1 Process for preparing synthesis gas 有权
标题翻译：合成气的制备方法
公开(公告)号：US06312660B1
公开(公告)日：2001-11-06
申请号：US09254635
申请日：1999-03-11
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
IPC分类号： C01B326
CPC分类号： C01B3/40 , B01J23/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed is a process for producing a synthesis gas by reacting a carbon-containing organic compound with steam and/or carbon dioxide using a catalyst whose carbon deposition activity is considerably suppressed. The catalyst is characterized in that it comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m2/g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the catalytic metal is 0.0005-0.1 mole %, in terms of metal, based on the carrier metal oxide.
摘要翻译：公开了一种通过使碳含量有机化合物与蒸汽和/或二氧化碳反应的催化剂，其碳沉积活性受到显着抑制而制备合成气的方法。该催化剂的特征在于其包含由金属氧化物形成的载体和至少一种选自铑，钌，铱，钯和铂的催化金属并负载在载体上，因为催化剂的比表面积为25 m 2 / g以下，其中载体金属氧化物的金属离子的电负性为13.0以下，催化剂金属的量为0.0005〜0.1摩尔％，以金属计，基于载体金属氧化物。

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