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    • 1. 发明授权
    • DLC film, DLC-coated plastic container, and method and apparatus for manufacturing DLC-coated plastic container
    • DLC膜,DLC涂层塑料容器,以及用于制造DLC涂层塑料容器的方法和装置
    • US07166336B1
    • 2007-01-23
    • US10019852
    • 2000-04-21
    • Shigeki MoriYuuji YamashitaTsuyoshi Kage
    • Shigeki MoriYuuji YamashitaTsuyoshi Kage
    • B05D7/22C23C16/26C23C16/507C23C16/609H05H1/46C23C16/27
    • C23C16/045C23C16/26
    • Disclosed is an apparatus for producing DLC film-coated plastic containers, which comprises an outer electrode unit disposed outside a plastic container, an inner electrode disposed inside the plastic container, a duct through which a raw material gas of a carbon source is fed into the plastic container having been degassed, and a high-frequency oscillator for applying a voltage between the outer electrode unit and the inner electrode with a carbon source gas being fed into the container, thereby to generate plasma to form a DLC film on the inner surface of the plastic container. In the apparatus, the outer electrode unit comprises a bottom electrode disposed along the bottom of the plastic container, and a body electrode disposed along the body of the plastic container, and the upper edge of the bottom electrode is positioned below the center between the top and the bottom of the plastic container. DLC films having good oxygen barrier properties, and DLC film-coated plastic containers suitable to oxygen-sensitive drinks and to sparkling drinks are produced by the use of the apparatus. Also disclosed is a method for producing a DLC film on the inner surface of a plastic container by the use of the apparatus.
    • 公开了一种用于制造DLC膜涂塑料容器的设备,其包括设置在塑料容器外部的外电极单元,设置在塑料容器内部的内电极,将碳源的原料气体通过其供给到管 已经脱气的塑料容器和用于在外部电极单元和内部电极之间施加电压的高频振荡器,其中碳源气体被供给到容器中,从而产生等离子体以在内部表面上形成DLC膜 塑料容器。 在该装置中,外部电极单元包括沿着塑料容器的底部设置的底部电极和沿塑料容器主体设置的主体电极,并且底部电极的上部边缘位于顶部 和塑料容器的底部。 具有良好的阻氧性能的DLC膜和适用于氧敏感饮料和汽泡饮料的DLC膜涂塑料容器通过使用该装置产生。 还公开了通过使用该装置在塑料容器的内表面上制造DLC膜的方法。
    • 2. 发明授权
    • Rotary type CVD film forming apparatus for mass production
    • 用于批量生产的旋转型CVD成膜装置
    • US07603962B2
    • 2009-10-20
    • US10516732
    • 2003-06-19
    • Kenichi HamaTsuyoshi KageTakumi KobayashiTakeharu Kawabe
    • Kenichi HamaTsuyoshi KageTakumi KobayashiTakeharu Kawabe
    • C23C16/00
    • C23C16/505C23C16/045C23C16/26C23C16/54
    • A rotary type CVD film forming apparatus for mass production, wherein a film forming chamber is formed by providing one columnar body having a plurality of housing spaces for housing one plastic container each in one said housing space, a plurality of said film forming chambers is arranged on a rotation support body at equal intervals in a circular state, source gas introduction means serving as an external electrode which introduce a source gas that is converted to plasma inside the plastic containers housed in each of said film forming chambers is provided, and high frequency supply means which supply a high frequency to the external electrode of each of said film forming chambers is provided to form a CVD (chemical vapor growing) film on the internal surfaces of said plastic containers.
    • 一种用于批量生产的旋转型CVD膜形成装置,其中通过提供一个具有多个容纳空间的柱状体形成成膜室,每个容纳空间用于将一个塑料容器容纳在一个所述容纳空间中,多个所述成膜室被布置 在旋转支撑体上以等间隔的圆形状态设置用作外部电极的源气体引入装置,其将容纳在每个所述成膜室中的塑料容器内的等离子体转换成等离子体的源气体引入, 提供向每个所述成膜室的外部电极提供高频率的供给装置,以在所述塑料容器的内表面上形成CVD(化学气相生长)膜。
    • 8. 发明申请
    • Method of manufacturing gas barrier film coated plastic container
    • 制造阻气膜涂塑料容器的方法
    • US20060177575A1
    • 2006-08-10
    • US10564746
    • 2004-07-15
    • Keishu TakemotoTsuyoshi KageTakumi KobayashiAkira Shirakura
    • Keishu TakemotoTsuyoshi KageTakumi KobayashiAkira Shirakura
    • C23C16/00
    • C23C16/045
    • A method of manufacturing a gas barrier film coated plastic container with high gas-barrier properties by solving a problem in a conventional method wherein the formation of a gas barrier film is obstructed by water molecules adsorbed in the plastic container and the container with reduced gas-barrier properties is manufactured. The method is characterized by comprising the steps of decreasing a pressure inside the plastic container or decreasing a pressure to the entire part of the plastic container, flowing dry gas as leak gas when vacuum is released to fill the inside of the container with the dry gas for drying the plastic container, replacing the gas inside the plastic container with a material gas or a material gas-containing gas, and plasmatizing the material gas to form the gas barrier film on the inner surface of the plastic container by a CVD method.
    • 通过解决传统方法中阻碍膜的吸附阻碍水分子阻塞的传统方法的问题,制造具有高阻气性的阻气膜涂覆塑料容器的方法, 制造阻隔性能。 该方法的特征在于包括以下步骤:减小塑料容器内部的压力或减小塑料容器的整个部分的压力,当释放真空时将干燥气体作为泄漏气体流动,以用干燥气体填充容器的内部 用于干燥塑料容器,用原料气或含气体气体代替塑料容器内部的气体,并通过CVD法在材料气体的等离子体化之上形成阻气膜。