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    • 2. 发明授权
    • Atmospheric pressure ionization mass spectrometer
    • 大气压电离质谱仪
    • US5485016A
    • 1996-01-16
    • US231847
    • 1994-04-25
    • Takashi IrieYasuhiro MitsuiKazuaki MizokamiKatsumi Kuriyama
    • Takashi IrieYasuhiro MitsuiKazuaki MizokamiKatsumi Kuriyama
    • G01N27/62H01J49/04H01J49/10H01J49/26
    • H01J49/168H01J49/0422H01J49/145
    • A mass spectrometer for analyzing trace impurities on a level between ppt and ppb contained in silicon material gas such as monosilane gas. The mass spectrometer includes an ion formation region, reaction region, and mass analysis region. Ion formation gas is introduced into the ion formation region and sample gas (silicon material gas) is introduced into the reaction region. The ion formation region ionizes ion formation gas by an ionizer and forms primary ions. When the pressure of ion formation gas is made higher than the pressure of sample gas, the ion formation gas flows into the reaction region from the ion formation region together with primary ions and is mixed with the sample gas. In the reaction region, an ion-molecule reaction is produced between the primary ions and trace impurities contained in the sample gas and the trace impurities contained in the sample gas are ionized. The ion intensity of trace impunities, the concentration of trace impurities in the sample gas is determined using a calibration curve. When the gas pressure in the reaction region is kept at almost 1 atmosphere, the reaction is promoted and when the ion-molecule reaction time is optimized according to the size of the reaction region and the voltage condition, impurities on a level between ppt and ppb can be detected and determined.
    • 用于分析硅材料气体(如硅烷气体)中含有的ppt和ppb之间的痕量杂质的质谱仪。 质谱仪包括离子形成区域,反应区域和质量分析区域。 将离子形成气体引入离子形成区域,并将样品气体(硅材料气体)引入反应区域。 离子形成区域通过离子发生器离子化形成气体并形成初级离子。 当离子形成气体的压力高于样品气体的压力时,离子形成气体与一次离子一起从离子形成区域流入反应区域,并与样品气体混合。 在反应区域中,在原料离子和样品气体中含有的微量杂质之间产生离子分子反应,并将样品气体中所含的痕量杂质离子化。 使用校准曲线确定痕量缺陷的离子强度,样品气体中微量杂质的浓度。 当反应区域的气体压力保持在大致1气道时,促进反应,当根据反应区域的大小和电压条件优化离子分子反应时间时,ppt与ppb之间的杂质 可以被检测和确定。