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1. 发明授权

US5969069A Water-activatable polymers and printable constructions 失效
标题翻译：水可活化的聚合物和可印刷的结构
公开(公告)号：US5969069A
公开(公告)日：1999-10-19
申请号：US701767
申请日：1996-08-26
申请人： Shiaonung Su , H. Paul Barker , Ghanshyam H Popat , Frederick N. Miekka , Raymond G. Kubit , Robert Valadez
发明人： Shiaonung Su , H. Paul Barker , Ghanshyam H Popat , Frederick N. Miekka , Raymond G. Kubit , Robert Valadez
IPC分类号： B41J2/01 , B41M3/00 , B41M5/00 , B41M5/025 , B41M5/50 , B41M5/52 , B41M7/00 , B44C1/165 , B44C1/17 , B44C1/175 , C08F220/18 , C08F20/10
CPC分类号： C08F220/18 , B41M3/006 , B41M5/0256 , B41M5/5254 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752 , B41M5/504 , B41M5/508 , B41M7/0036
摘要： Water dispersible, hydrophilic, repulpable, water-activatable, acrylic polymers are provided. The polymers are non-tacky when dry, but become tacky when wet, and exhibit high peel strength on a variety of substrates. The polymers comprise an acrylic-based polymer prepared by emulsion polymerization of 40 to 70% by weight of one or more alkyl acrylates, the alkyl group of which has from 4 to 8 carbon atoms; 10 to 20% by weight of methacrylate; 2 to 15% by weight of vinyl acetate; and 10 to 25 percent by weight of methacrylic acid and/or acrylic acid; and a positive amount up to about 30% by weight of methyl methacrylate. Some embodiments also include a short chain hydroxyalkyl methacrylate. Also provided are ink jet-imprintable, water-activatable constructions comprising a layer of water-activatable polymer, coated on a release liner or other surface. Optionally, a water-resistant transparent film layer is disposed between the polymer and release liner or used in place of the release liner. The constructions are suitable for use in ink jet printers and can be used to transfer an image to a substrate.
摘要翻译：提供水可分散的，亲水的，可重复使用的，水可活化的丙烯酸聚合物。干燥时，聚合物是非粘性的，但在湿润时变得发粘，并且在各种基材上表现出高的剥离强度。聚合物包含通过乳液聚合制备的丙烯酸类聚合物，其通过40至70重量％的一种或多种丙烯酸烷基酯，其烷基具有4至8个碳原子; 10〜20重量％的甲基丙烯酸酯; 2〜15重量％的乙酸乙烯酯; 和10-25重量％的甲基丙烯酸和/或丙烯酸; 和高达约30重量％的甲基丙烯酸甲酯的正量。一些实施方案还包括甲基丙烯酸短链羟烷基酯。还提供了喷墨可打印的可水激活的结构，其包含涂覆在剥离衬垫或其它表面上的可水可水解聚合物层。任选地，在聚合物和剥离衬垫之间设置防水透明膜层，或者用于代替剥离衬垫。这些结构适用于喷墨打印机，并且可用于将图像转印到基底上。

2. 发明授权

US06824839B1 Water-activated polymers and adhesive image transfer technique 失效
标题翻译：水活化聚合物和胶粘剂图像转移技术
公开(公告)号：US06824839B1
公开(公告)日：2004-11-30
申请号：US09030664
申请日：1998-02-25
申请人： Ghanshyam H. Popat , Fred Miekka , Raymond Kubit , Robert Valadez , Gustav Ray , Shiaonung Su , H. Paul Barker
发明人： Ghanshyam H. Popat , Fred Miekka , Raymond Kubit , Robert Valadez , Gustav Ray , Shiaonung Su , H. Paul Barker
IPC分类号： B41M500
CPC分类号： B41M3/006 , B41M5/0256 , B41M5/504 , B41M5/508 , B41M5/5254 , B41M7/00 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752 , C08F220/18
摘要： An image transfer assembly (12) receives an image printed from an ink jet printer. The assembly (12) provides a device to transfer the printed image onto an image-receiving surface. The assembly (12) has a flexible substrate (16) on one side, and an upper surface (20) on the other side that is substantially permeable to ink jet printer ink and that is non-tacky prior to printing. The assembly (12) has an adhesive or polymer layer (14) in between the upper surface (20) and the flexible substrate (16). After printing with a water-based ink jet printer ink, the user may apply the assembly (12) to a substrate, such as a window or other surface, and remove the flexible substrate (16), thereby leaving the layer (14) that bears the image on the substrate. In one of several alternative embodiments, the layer (14) is divided into discrete zones that are separated from one another along boundaries.
摘要翻译：图像转印组件（12）接收从喷墨打印机打印的图像。组件（12）提供了将印刷图像转印到图像接收表面上的装置。组件（12）在一侧具有柔性基板（16）和另一侧上表面（20），其基本上可透过喷墨打印机油墨并且在打印之前是非粘性的。组件（12）在上表面（20）和柔性衬底（16）之间具有粘合剂或聚合物层（14）。在使用水性喷墨打印机油墨进行打印之后，用户可以将组件（12）施加到诸如窗户或其他表面的基底上，并且移除柔性基底（16），从而使层（14）承载基板上的图像。在几个替代实施例中的一个中，层（14）被划分成沿着边界彼此分开的离散区域。

3. 发明授权

US6080261A Adhesive image transfer technique 失效
标题翻译：胶粘剂图像转印技术
公开(公告)号：US6080261A
公开(公告)日：2000-06-27
申请号：US892187
申请日：1997-07-14
申请人： Ghanshyam H. Popat , Fred Miekka , Raymond G. Kubit , Robert Valadez
发明人： Ghanshyam H. Popat , Fred Miekka , Raymond G. Kubit , Robert Valadez
IPC分类号： B41M3/00 , B41M5/025 , B41M5/52 , B41M7/00 , B44C1/17 , C08F220/18 , B32B31/04
CPC分类号： C08F220/18 , B41M3/006 , B41M5/0256 , B41M5/5254 , B44C1/1737 , B41M7/00 , B41M7/009
摘要： An ink jet printer image transfer sheet having a non-porous flexible base layer, an ink absorbing adhesive layer coated onto said base layer and an ink jet printing ink porous detackifying outer layer. A method for transferring an ink jet printed image to a substrate.
摘要翻译：一种具有无孔柔性基底层，涂覆在所述基底层上的吸墨粘合剂层和喷墨印刷油墨多孔防粘外层的喷墨打印机图像转印片。一种将喷墨印刷图像转印到基板上的方法。

4. 发明授权

US06946023B2 Smear-resistant ink compositions 有权
标题翻译：防油墨组合物
公开(公告)号：US06946023B2
公开(公告)日：2005-09-20
申请号：US10165663
申请日：2002-06-06
申请人： Thomas Mammen , Robert Valadez
发明人： Thomas Mammen , Robert Valadez
IPC分类号： C09D11/00
CPC分类号： C09D11/32 , C09D11/50
摘要： In general, a smear-resistant ink composition according to the present invention comprises: (1) water; (2) at least one glycol selected from the group consisting of diethylene glycol, ethylene glycol, glycerol, and propylene glycol; (3) a pyrrolidone selected from the group consisting of 2-pyrrolidone and 3-pyrrolidone; and (4) at least one colorant that produces a detectable fluorescent color when the ink composition is applied to paper. Preferably, the pyrrolidone is 2-pyrrolidone. In one preferred embodiment, the at least one glycol comprises diethylene glycol and ethylene glycol. In another preferred embodiment, the at least one glycol comprises diethylene glycol, ethylene glycol, and propylene glycol. The composition can comprise other ingredients, such as a basic color stabilizer, a resin, a resin modifier that is a carbonate salt, a biocide, and a nonionic surfactant. The colorants can be formulated to produce a pink, yellow, blue, green, purple, or orange color; other colors are possible.
摘要翻译：通常，根据本发明的防污油墨组合物包括：（1）水; （2）至少一种选自二甘醇，乙二醇，甘油和丙二醇的二醇; （3）选自2-吡咯烷酮和3-吡咯烷酮的吡咯烷酮; 和（4）当将油墨组合物施加到纸上时产生可检测荧光颜色的至少一种着色剂。优选地，吡咯烷酮是2-吡咯烷酮。在一个优选的实施方案中，至少一种二醇包括二甘醇和乙二醇。在另一个优选的实施方案中，至少一种二醇包括二甘醇，乙二醇和丙二醇。组合物可以包含其它成分，例如碱性颜色稳定剂，树脂，作为碳酸盐的树脂改性剂，杀生物剂和非离子表面活性剂。着色剂可配制成粉红色，黄色，蓝色，绿色，紫色或橙色; 其他颜色也是可以的。

5. 发明授权

US07084191B2 Ink composition resistant to solvent evaporation 失效
标题翻译：油墨组合物耐溶剂蒸发
公开(公告)号：US07084191B2
公开(公告)日：2006-08-01
申请号：US10325138
申请日：2002-12-20
申请人： Thomas Mammen , Robert Valadez
发明人： Thomas Mammen , Robert Valadez
IPC分类号： C09D11/16 , C08L91/00
CPC分类号： C09D11/16
摘要： The present invention is directed to an ink composition resistant to solvent evaporation which may be employed for use in retractable permanent marker pens. Generally, the ink composition of the present invention comprises n-propanol, a pyrrolidone, a tryglyceride, a terpene phenolic resin, and at least one colorant to yield a detectable color when the ink composition is applied to a writable substrate. Additionally, the ink composition may further comprise at least one of polyether modified dimethylpolysiloxane copolymer and silicone glycol surfactant. Optionally, the ink composition may further comprise water.
摘要翻译：本发明涉及一种耐溶剂蒸发的油墨组合物，其可用于可伸缩永久性标记笔中。通常，本发明的油墨组合物包含正丙醇，吡咯烷酮，甘油三酯，萜烯酚醛树脂和至少一种着色剂，以便当将油墨组合物施加到可写基材时产生可检测的颜色。另外，油墨组合物还可以包含聚醚改性的二甲基聚硅氧烷共聚物和硅氧烷二醇表面活性剂中的至少一种。任选地，油墨组合物还可以包含水。

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