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1. 发明授权

US06824839B1 Water-activated polymers and adhesive image transfer technique 失效
标题翻译：水活化聚合物和胶粘剂图像转移技术
公开(公告)号：US06824839B1
公开(公告)日：2004-11-30
申请号：US09030664
申请日：1998-02-25
申请人： Ghanshyam H. Popat , Fred Miekka , Raymond Kubit , Robert Valadez , Gustav Ray , Shiaonung Su , H. Paul Barker
发明人： Ghanshyam H. Popat , Fred Miekka , Raymond Kubit , Robert Valadez , Gustav Ray , Shiaonung Su , H. Paul Barker
IPC分类号： B41M500
CPC分类号： B41M3/006 , B41M5/0256 , B41M5/504 , B41M5/508 , B41M5/5254 , B41M7/00 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752 , C08F220/18
摘要： An image transfer assembly (12) receives an image printed from an ink jet printer. The assembly (12) provides a device to transfer the printed image onto an image-receiving surface. The assembly (12) has a flexible substrate (16) on one side, and an upper surface (20) on the other side that is substantially permeable to ink jet printer ink and that is non-tacky prior to printing. The assembly (12) has an adhesive or polymer layer (14) in between the upper surface (20) and the flexible substrate (16). After printing with a water-based ink jet printer ink, the user may apply the assembly (12) to a substrate, such as a window or other surface, and remove the flexible substrate (16), thereby leaving the layer (14) that bears the image on the substrate. In one of several alternative embodiments, the layer (14) is divided into discrete zones that are separated from one another along boundaries.
摘要翻译：图像转印组件（12）接收从喷墨打印机打印的图像。组件（12）提供了将印刷图像转印到图像接收表面上的装置。组件（12）在一侧具有柔性基板（16）和另一侧上表面（20），其基本上可透过喷墨打印机油墨并且在打印之前是非粘性的。组件（12）在上表面（20）和柔性衬底（16）之间具有粘合剂或聚合物层（14）。在使用水性喷墨打印机油墨进行打印之后，用户可以将组件（12）施加到诸如窗户或其他表面的基底上，并且移除柔性基底（16），从而使层（14）承载基板上的图像。在几个替代实施例中的一个中，层（14）被划分成沿着边界彼此分开的离散区域。

2. 发明授权

US5969069A Water-activatable polymers and printable constructions 失效
标题翻译：水可活化的聚合物和可印刷的结构
公开(公告)号：US5969069A
公开(公告)日：1999-10-19
申请号：US701767
申请日：1996-08-26
申请人： Shiaonung Su , H. Paul Barker , Ghanshyam H Popat , Frederick N. Miekka , Raymond G. Kubit , Robert Valadez
发明人： Shiaonung Su , H. Paul Barker , Ghanshyam H Popat , Frederick N. Miekka , Raymond G. Kubit , Robert Valadez
IPC分类号： B41J2/01 , B41M3/00 , B41M5/00 , B41M5/025 , B41M5/50 , B41M5/52 , B41M7/00 , B44C1/165 , B44C1/17 , B44C1/175 , C08F220/18 , C08F20/10
CPC分类号： C08F220/18 , B41M3/006 , B41M5/0256 , B41M5/5254 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752 , B41M5/504 , B41M5/508 , B41M7/0036
摘要： Water dispersible, hydrophilic, repulpable, water-activatable, acrylic polymers are provided. The polymers are non-tacky when dry, but become tacky when wet, and exhibit high peel strength on a variety of substrates. The polymers comprise an acrylic-based polymer prepared by emulsion polymerization of 40 to 70% by weight of one or more alkyl acrylates, the alkyl group of which has from 4 to 8 carbon atoms; 10 to 20% by weight of methacrylate; 2 to 15% by weight of vinyl acetate; and 10 to 25 percent by weight of methacrylic acid and/or acrylic acid; and a positive amount up to about 30% by weight of methyl methacrylate. Some embodiments also include a short chain hydroxyalkyl methacrylate. Also provided are ink jet-imprintable, water-activatable constructions comprising a layer of water-activatable polymer, coated on a release liner or other surface. Optionally, a water-resistant transparent film layer is disposed between the polymer and release liner or used in place of the release liner. The constructions are suitable for use in ink jet printers and can be used to transfer an image to a substrate.
摘要翻译：提供水可分散的，亲水的，可重复使用的，水可活化的丙烯酸聚合物。干燥时，聚合物是非粘性的，但在湿润时变得发粘，并且在各种基材上表现出高的剥离强度。聚合物包含通过乳液聚合制备的丙烯酸类聚合物，其通过40至70重量％的一种或多种丙烯酸烷基酯，其烷基具有4至8个碳原子; 10〜20重量％的甲基丙烯酸酯; 2〜15重量％的乙酸乙烯酯; 和10-25重量％的甲基丙烯酸和/或丙烯酸; 和高达约30重量％的甲基丙烯酸甲酯的正量。一些实施方案还包括甲基丙烯酸短链羟烷基酯。还提供了喷墨可打印的可水激活的结构，其包含涂覆在剥离衬垫或其它表面上的可水可水解聚合物层。任选地，在聚合物和剥离衬垫之间设置防水透明膜层，或者用于代替剥离衬垫。这些结构适用于喷墨打印机，并且可用于将图像转印到基底上。

3. 发明授权

US06506445B2 Image transfer sheets and a method of manufacturing the same 有权
标题翻译：图像转印纸及其制造方法
公开(公告)号：US06506445B2
公开(公告)日：2003-01-14
申请号：US09905845
申请日：2001-07-13
申请人： Ghanshyam H. Popat , Shiaonung Su , Thomas Mammen , Frederick Miekka , Andre Saint , Brett Ulrich , Omar Attia
发明人： Ghanshyam H. Popat , Shiaonung Su , Thomas Mammen , Frederick Miekka , Andre Saint , Brett Ulrich , Omar Attia
IPC分类号： B41M312
CPC分类号： C08F220/18 , B41M3/12 , B41M5/0256 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/1741 , B44C1/175 , B44C1/1752 , D06P5/003 , Y10S428/914 , Y10T428/1481 , Y10T428/1486 , Y10T428/1495 , Y10T428/24802 , Y10T428/2486 , Y10T428/24959 , Y10T428/283 , Y10T428/2839
摘要： A versatile method for the manufacturing of image transfer sheets which provide users with cold transferring images without using supplemental heat in the course of image transfer to a wide variety of substrates includes printing an image with water-based ink onto an image transfer sheet that has a coating of water-accepting adhesive. A method of manufacturing image transfer sheets includes first applying a water impermeable layer onto a flexible substrate. A layer of water-activatable adhesive is applied upon the water impermeable layer. The adhesive is then dried in a dryer with dehumidified air. A water permeable detack layer is then applied upon the layer of adhesive. In a particular embodiment, the sheet further includes a water-accepting image holding layer in between the water-accepting adhesive layer and the water impermeable layer. The image holding layer becomes water-resisting when heated to within a range of activation temperatures.
摘要翻译：用于制造图像转印片材的通用方法，其在向多种基底的图像转印过程中不使用补充热量的用户提供冷转印图像包括将具有水性油墨的图像印刷到图像转印片材上，所述图像转印片材具有涂层接水胶。制造图像转印片的方法包括首先将不透水层施加到柔性基底上。将一层水可活化的粘合剂施加在防水层上。然后将粘合剂在具有除湿空气的干燥器中干燥。然后将可透水的防粘层施加在粘合剂层上。在具体实施方案中，片材还包括在受水粘合剂层和不透水层之间的受水图像保持层。当被加热到活化温度的范围内时，图像保持层变得耐水。

4. 发明授权

US06277229B1 Image transfer sheets and a method of manufacturing the same 失效
公开(公告)号：US06277229B1
公开(公告)日：2001-08-21
申请号：US09071785
申请日：1998-05-01
申请人： Ghanshyam H. Popat , Shiaonung Su , Thomas Mammen , Frederick Miekka , Andre Saint , Brett Ulrich , Omar Attia
发明人： Ghanshyam H. Popat , Shiaonung Su , Thomas Mammen , Frederick Miekka , Andre Saint , Brett Ulrich , Omar Attia
IPC分类号： B44C1164
CPC分类号： C08F220/18 , B41M3/12 , B41M5/0256 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/1741 , B44C1/175 , B44C1/1752 , D06P5/003 , Y10S428/914 , Y10T428/1481 , Y10T428/1486 , Y10T428/1495 , Y10T428/24802 , Y10T428/2486 , Y10T428/24959 , Y10T428/283 , Y10T428/2839
摘要： A versatile method of cold transferring images without using supplemental heat in the course of image transfer to a wide variety of substrates includes printing an image with water-based ink onto an image transfer sheet that has a coating of water-accepting adhesive. The sheet is then applied to the substrate to transfer only the portions of the adhesive that bear the image onto the substrate, with the remainder of the adhesive remaining attached to the sheet. A method of manufacturing image transfer sheets includes first applying a water impermeable layer onto a flexible substrate. A layer of water-activatable adhesive is applied upon the water impermeable layer. The adhesive is then dried in a dryer with dehumidified air. A water permeable detack layer is then applied upon the layer of adhesive. A sheet for transferring an image that has been printed onto the sheet with a water-based ink has a flexible backing layer and one or more water-accepting layers with water activatable adhesive that are printed with a printing press and/or coated onto the flexible backing layer. A water-impermeable layer is disposed in between the adhesive and the backing layer. A detack layer may be applied onto the layer of adhesive. A water permeable colored, tinted, or reflective water-permeable layer may be between the detack layer and the water-accepting layer, or a colorant may be added to the detack layer. One embodiment includes a water-permeable layer of cross-linker in between the detack layer the water-accepting layer, wherein said water-accepting layer becomes water-resisting when water-based ink flows through said layer of cross-linker and into said water-accepting layer. In another embodiment, the water-accepting layer includes both adhesive and cross-linker, wherein the water-accepting layer is adapted to become water-resisting when the adhesive and the cross-linker react when the water-accepting layer is heated. In another embodiment, the sheet further includes a water-accepting image holding layer in between the water-accepting adhesive layer and the water impermeable layer. The image holding layer becomes water-resisting when heated to within a range of activation temperatures.

5. 发明授权

US06469118B1 Water-activatable polymers for ink jet-imprintable constructions 有权
标题翻译：用于喷墨可打印结构的水可活化聚合物
公开(公告)号：US06469118B1
公开(公告)日：2002-10-22
申请号：US09569533
申请日：2000-05-12
申请人： Shiaonung Su
发明人： Shiaonung Su
IPC分类号： C08F2010
CPC分类号： C08F220/18 , B41M3/006 , B41M5/0256 , B41M5/504 , B41M5/508 , B41M5/5254 , B41M7/00 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752
摘要： Water-activatable acrylic polymers and image transfer constructions made therewith are provided. The polymers are non-tacky to the touch when dry, but become tacky when activated by water, such as the water in the ink of an ink jet printer. The polymers are acrylic copolymers prepared by emulsion polymerization of a monomer mixture that preferably includes at least one alkyl acrylate, methyl acrylate, vinyl acetate, methacrylic acid and acrylic acid. Image transfer sheets made with the water-activatable polymers include a flexible backing, at least one water-impermeable layer, at least one layer of water-activatable polymers, and a protective detack layer.
摘要翻译：提供水可活化的丙烯酸聚合物和由其制成的图像转印结构。当干燥时，聚合物对触摸不粘，但当被水激活时变得发粘，例如喷墨打印机的墨水中的水。聚合物是通过优选包括至少一种丙烯酸烷基酯，丙烯酸甲酯，乙酸乙烯酯，甲基丙烯酸和丙烯酸的单体混合物的乳液聚合制备的丙烯酸共聚物。用可水可聚合的聚合物制成的图像转印片包括柔性背衬，至少一个不透水层，至少一层可水可活化聚合物和保护性剥离层。

6. 发明授权

US5252662A Low viscosity acrylic hot melt adhesives 失效
标题翻译：低粘度丙烯酸热熔胶
公开(公告)号：US5252662A
公开(公告)日：1993-10-12
申请号：US952074
申请日：1992-09-25
申请人： Shiaonung Su , Yehuda Ozari , Richard R. Vargas , Henry Lum, Jr.
发明人： Shiaonung Su , Yehuda Ozari , Richard R. Vargas , Henry Lum, Jr.
IPC分类号： C09J5/00 , C08F220/18 , C09J4/02 , C09J5/06 , C09J133/04 , C09J133/06 , C09J133/08 , C08F222/06
CPC分类号： C08F220/18 , C09J133/08 , C09J2201/61
摘要： A low viscosity hot melt acrylic pressure sensitive adhesive polymer is formed by bulk polymerization of at least one alkyl acrylate monomer containing from about 4 to 8 carbon atoms in the alkyl group and present in an amount of from about 60 to about 95% by weight of the polymer, from 1 to about 10% by weight of a copolymerizable amide monomer, from 1 to 10% by weight of a copolymerizble carboxylic acid, and a positive amount up to about 6% by weight of the monomers of a copolymerizable anhydride, said polymer formed thermally reversible crosslinks with a metal cation having a valence of from 2 to 4. Viscosity of the polymer is typically from 2 to 8 Pa.s at 150.degree. C. as formed and increases up to 100 Pa.s at 150.degree. C. on addition of the metal cation.
摘要翻译：低粘度热熔丙烯酸压敏粘合剂聚合物通过在烷基中含有约4至8个碳原子的至少一种丙烯酸烷基酯单体进行本体聚合而形成，并以约60至约95重量％聚合物，1至约10重量％的可共聚酰胺单体，1至10重量％的共聚羧酸，和至多约6重量％的可共聚酸酐单体的正极，所述聚合物与价态为2至4的金属阳离子形成热可逆交联。聚合物的粘度通常在150℃下形成2至8Pa.s，并且在150℃下增加至100Pa.s 加入金属阳离子。

7. 发明授权

US06242552B1 Stamp adhesive 有权
标题翻译：邮票胶
公开(公告)号：US06242552B1
公开(公告)日：2001-06-05
申请号：US09443571
申请日：1999-11-19
申请人： Shiaonung Su
发明人： Shiaonung Su
IPC分类号： C08F2214
CPC分类号： C09J133/08 , C08F220/18 , C08F222/14 , C09J2201/606 , C09J2400/283 , Y02P20/582
摘要： General purpose permanent, environmentally benign, pressure-sensitive adhesives and self-adhesive postage stamps and other laminate constructions are provided. In one embodiment, the PSA is an inherently, acrylic copolymer prepared by emulsion polymerization of 27 to 29% di-(2-ethylhexyl) maleate, 19 to 21% vinyl acetate, 40 to 43% ethylhexyl acrylate, 5 to 10% methyl methacrylate, 1% acrylic acid, and 1% methacrylic acid. Notably, no multifunctional monomers having a cyanurate or phosphate moiety are included in the polymer, and the polymer is substantially uncrosslinked.
摘要翻译：提供通用的永久性，环境友好的压敏粘合剂和自粘邮票和其他层压结构。在一个实施方案中，PSA是通过27至29％马来酸二（2-乙基己基）酯，19至21％乙酸乙烯酯，40至43％丙烯酸乙基己酯，5至10％甲基丙烯酸甲酯的乳液聚合制备的固有丙烯酸共聚物，1％丙烯酸和1％甲基丙烯酸。值得注意的是，在聚合物中不包含具有氰脲酸酯或磷酸酯部分的多官能单体，并且聚合物基本上未交联。

8. 发明授权

US6124417A Water-activatable polymers for ink-jet imprintable constructions 失效
标题翻译：用于喷墨可打印结构的可水活化聚合物
公开(公告)号：US6124417A
公开(公告)日：2000-09-26
申请号：US71502
申请日：1998-05-01
申请人： Shiaonung Su
发明人： Shiaonung Su
IPC分类号： B41M3/00 , B41M5/00 , B41M5/025 , B41M5/50 , B41M5/52 , B41M7/00 , B44C1/17 , B44C1/175 , C08F220/18 , C08F220/10
CPC分类号： C08F220/18 , B41M3/006 , B41M5/0256 , B41M5/5254 , B44C1/1712 , B44C1/1733 , B44C1/1737 , B44C1/175 , B44C1/1752 , B41M5/504 , B41M5/508 , B41M7/00
摘要： Water-activatable acrylic polymers and image transfer constructions made therewith are provided. The polymers are non-tacky to the touch when dry, but become tacky when activated by water, such as the water in the ink of an ink jet printer. The polymers are acrylic copolymers prepared by emulsion polymerization of a monomer mixture that preferably includes at least one alkyl acrylate, methyl acrylate, vinyl acetate, methacrylic acid and acrylic acid. Image transfer sheets made with the water-activatable polymers include a flexible backing, at least one water-impermeable layer, at least one layer of water-activatable polymers, and a protective detack layer.
摘要翻译：提供水可活化的丙烯酸聚合物和由其制成的图像转印结构。当干燥时，聚合物对触摸不粘，但当被水激活时变得发粘，例如喷墨打印机的墨水中的水。聚合物是通过优选包括至少一种丙烯酸烷基酯，丙烯酸甲酯，乙酸乙烯酯，甲基丙烯酸和丙烯酸的单体混合物的乳液聚合制备的丙烯酸共聚物。用可水可聚合的聚合物制成的图像转印片包括柔性背衬，至少一个不透水层，至少一层可水可活化聚合物和保护性剥离层。

9. 发明授权

US6136903A Repulpable, pressure-sensitive adhesive compositions 失效
标题翻译：可压缩的压敏粘合剂组合物
公开(公告)号：US6136903A
公开(公告)日：2000-10-24
申请号：US947930
申请日：1997-10-09
申请人： Shiaonung Su , Paul Keller , Graham Yeadon
发明人： Shiaonung Su , Paul Keller , Graham Yeadon
IPC分类号： B32B7/12 , C08F265/04 , C08F265/06 , C08L51/00 , C09J7/02 , C09J133/08 , C09J151/00 , C09J131/00 , C09J135/00
CPC分类号： C09J151/003 , C08F265/04 , C08F265/06 , C09J133/08 , C08L51/00 , Y02P20/582
摘要： Repulpable PSA compositions and constructions that exhibit high adhesive performance on a wide range of substrates are provided. In one embodiment, a PSA composition comprises a blend of two emulsion acrylic copolymers. The first type is a repulpable, emulsion acrylic copolymer that passes TAPPI UM 213. Preferably, the copolymer is prepared by sequential polymerization. The second type of copolymer is a non-repulpable, gpp or removable, repositionable, emulsion acrylic copolymer, also preferably prepared by sequential polymerization. The PSA compositions are inherently tacky and can be used in labels and tapes. In addition, they can be added to other PSAs as external tackifiers.
摘要翻译：提供了在宽范围的基底上表现出高粘合性能的可重复粘合剂组合物和结构。在一个实施方案中，PSA组合物包含两种乳液丙烯酸共聚物的共混物。第一种类型是通过TAPPI UM 213的可重新涂布的乳液丙烯酸共聚物。优选地，通过顺序聚合制备共聚物。第二种类型的共聚物是不可重复使用的，gpp或可拆卸的，可重新定位的乳液丙烯酸共聚物，也优选通过顺序聚合制备。 PSA组合物固有地发粘，可用于标签和胶带。此外，它们可以作为外部增粘剂添加到其他PSA中。

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