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1. 发明申请

US20090000658A1 2,2-Bipyridine Ligand, Sensitizing Dye and Dye Sensitized Solar Cell 有权
标题翻译： 2,2-Bipyridine配体，敏化染料和染料敏化太阳能电池
公开(公告)号：US20090000658A1
公开(公告)日：2009-01-01
申请号：US11658780
申请日：2005-07-29
申请人： Shaik Mohammed Zakeeruddin , Cedric Klein , Peng Wang , Michael Graetzel
发明人： Shaik Mohammed Zakeeruddin , Cedric Klein , Peng Wang , Michael Graetzel
IPC分类号： H01L31/00 , C07F15/00 , C07D401/02
CPC分类号： C07F15/0053 , B82Y10/00 , B82Y30/00 , C09B57/10 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01L51/0086 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： A dye sensitized solar cell, comprising a-heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated n-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring′ group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.
摘要翻译：一种染料敏化太阳能电池，其包含Ru，Os或Fe的异位多吡啶络合物。捐赠配体具有延长的共轭n系，增加光吸收率并且使LUMO能级高于锚定配体的LUMO能级。其分子结构包括端基，疏水部分和锚定基团的压实化合物可以与染料共同吸附在光电阳极的半导体金属氧化物层上，形成密集的混合自组装单层。

2. 发明申请

US20090176162A1 LITHIUM RECHARGEABLE ELECTROCHEMICAL CELL 审中-公开
标题翻译：锂可充电电化学细胞
公开(公告)号：US20090176162A1
公开(公告)日：2009-07-09
申请号：US12296211
申请日：2007-04-06
申请人： Ivan Exnar , Qing Wang , Michael Gratzel , Shaik Mohammed Zakeeruddin , Ladislav Kavan
发明人： Ivan Exnar , Qing Wang , Michael Gratzel , Shaik Mohammed Zakeeruddin , Ladislav Kavan
IPC分类号： H01M6/16 , H01M4/60 , H01M4/62 , H01M4/52 , H01M4/50 , H01M4/58 , H01M4/48
CPC分类号： H01M10/0525 , H01B1/122 , H01M4/13 , H01M4/5825 , H01M10/0562 , H01M10/0565 , H01M10/0567 , H01M10/058 , H01M2300/0025
摘要： This invention concerns a lithium rechargeable electrochemical cell containing electrochemical redox active compounds in the electrolyte. The cell is composed of two compartments, where the cathodic compartment comprises a cathodic lithium insertion material and one or more of p-type redox active compound(s) in the electrolyte; the anodic compartment comprises an anodic lithium insertion material and one or more of n-type redox active compound(s) in the electrolyte. These two compartments are separated by a separator and the redox active compounds are confined only in each compartment. Such a rechargeable electrochemical cell is suitable for high energy density applications. The present invention also concerns the general use of redox active compounds and electrochemically addressable electrode systems containing similar components which are suitable for use in the electrochemical cell.
摘要翻译：本发明涉及在电解质中含有电化学氧化还原活性化合物的锂可再充电电化学电池。电池由两个室组成，其中阴极室包含阴极锂插入材料和电解质中的一种或多种p型氧化还原活性化合物; 阳极室包含阳极锂插入材料和电解质中的一种或多种n型氧化还原活性化合物。这两个隔室由分离器分开，氧化还原活性化合物仅限于每个隔间。这种可充电电化学电池适用于高能量密度应用。本发明还涉及氧化还原活性化合物和包含适用于电化学电池的类似成分的电化学可寻址电极系统的一般用途。

3. 发明申请

US20100068621A1 NANOTUBE WIRING 有权
标题翻译： NANOTUBE接线
公开(公告)号：US20100068621A1
公开(公告)日：2010-03-18
申请号：US12445128
申请日：2007-10-18
申请人： Ivan Exnar , Shaik Mohammed Zakeeruddin , Michael Gratzel , Ladislav Kavan
发明人： Ivan Exnar , Shaik Mohammed Zakeeruddin , Michael Gratzel , Ladislav Kavan
IPC分类号： H01M4/60 , H01M4/02
CPC分类号： H01M10/0525 , H01M2/1673 , H01M4/0416 , H01M4/13 , H01M4/136 , H01M4/139 , H01M4/36 , H01M4/362 , H01M4/5825 , H01M4/60 , H01M4/625 , Y10S977/75
摘要： This invention concerns a novel method for surface derivatization of electrode materials for Li-ion batteries. The derivatization is based on adsorption of a composite assembly consisting of amphiphilic redox active molecule attached to single walled carbon nanotube (SWCNT). Its role consists in the enhancement of electronic conductivity of electrode materials, such as phosphate olivines, without requesting any significant increase of the electrode volume and mass. The SWCNT is linked to the redox molecule via non-covalent or covalent interaction with the hydrophobic part of the molecule or electrostatic interaction. The hydrophilic part of the molecule serves as the anchoring site for surface modification of the electrode active material. The redox potential of the molecule is close to the redox potential of the electrode active material. The adsorbed assembly of redox-molecule & SWCNT thus improves the charge transfer from a current collector to the electrode active material.
摘要翻译：本发明涉及用于锂离子电池的电极材料的表面衍生化的新方法。衍生化基于由连接到单壁碳纳米管（SWCNT）的两亲性氧化还原活性分子组成的复合组件的吸附。其作用在于提高诸如磷酸橄榄石之类的电极材料的电子传导性，而不需要电极体积和质量的显着增加。 SWCNT通过与分子的疏水部分或静电相互作用的非共价或共价相互作用与氧化还原分子连接。分子的亲水部分用作电极活性材料的表面改性的锚定位点。分子的氧化还原电位接近电极活性物质的氧化还原电位。因此，氧化还原分子和SWCNT的吸附组件改善了从集电器到电极活性材料的电荷转移。

4. 发明授权

US08097361B2 Nanotube wiring 有权
标题翻译：纳米管接线
公开(公告)号：US08097361B2
公开(公告)日：2012-01-17
申请号：US12445128
申请日：2007-10-18
申请人： Ivan Exnar , Shaik Mohammed Zakeeruddin , Michael Gratzel , Ladislav Kavan
发明人： Ivan Exnar , Shaik Mohammed Zakeeruddin , Michael Gratzel , Ladislav Kavan
IPC分类号： H01M4/60 , H01M4/13 , D01F9/12
CPC分类号： H01M10/0525 , H01M2/1673 , H01M4/0416 , H01M4/13 , H01M4/136 , H01M4/139 , H01M4/36 , H01M4/362 , H01M4/5825 , H01M4/60 , H01M4/625 , Y10S977/75
摘要： This invention concerns a novel method for surface derivatization of electrode materials for Li-ion batteries. The derivatization is based on adsorption of a composite assembly consisting of amphiphilic redox active molecule attached to single walled carbon nanotube (SWCNT). Its role consists in the enhancement of electronic conductivity of electrode materials, such as phosphate olivines, without requesting any significant increase of the electrode volume and mass. The SWCNT is linked to the redox molecule via non-covalent or covalent interaction with the hydrophobic part of the molecule or electrostatic interaction. The hydrophilic part of the molecule serves as the anchoring site for surface modification of the electrode active material. The redox potential of the molecule is close to the redox potential of the electrode active material. The adsorbed assembly of redox-molecule & SWCNT thus improves the charge transfer from a current collector to the electrode active material.
摘要翻译：本发明涉及用于锂离子电池的电极材料的表面衍生化的新方法。衍生化基于由连接到单壁碳纳米管（SWCNT）的两亲性氧化还原活性分子组成的复合组件的吸附。其作用在于提高诸如磷酸橄榄石之类的电极材料的电子传导性，而不需要电极体积和质量的显着增加。 SWCNT通过与分子的疏水部分或静电相互作用的非共价或共价相互作用与氧化还原分子连接。分子的亲水部分用作电极活性材料的表面改性的锚定位点。分子的氧化还原电位接近电极活性物质的氧化还原电位。因此，氧化还原分子和SWCNT的吸附组件改善了从集电器到电极活性材料的电荷转移。

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