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1. 发明授权

US5110961A Catalytic process for the synthesis of an alcohol, new metal complexes and process for the synthesis of these complexes 失效
标题翻译：用于合成醇，新金属络合物的催化方法和合成这些复合物的方法
公开(公告)号：US5110961A
公开(公告)日：1992-05-05
申请号：US628389
申请日：1990-12-14
申请人： Serge Lecolier , Andre Mortreux , Francis Petit , Henri Samain
发明人： Serge Lecolier , Andre Mortreux , Francis Petit , Henri Samain
IPC分类号： B01J31/20 , C01G51/00 , C07B41/02 , C07B41/04 , C07B41/12 , C07B43/04 , C07B61/00 , C07C41/03 , C07C43/23 , C07C67/26 , C07C69/02 , C07C69/76 , C07C69/78 , C07C69/88 , C07C213/04 , C07C215/02 , C07C215/42 , C25B1/00 , C25B3/04
CPC分类号： C07C41/03 , B01J31/20 , C01G51/006 , C07B41/02 , C07C213/04 , C25B1/00 , B01J2231/48 , B01J2531/27 , B01J2531/42 , B01J2531/44 , B01J2531/845 , C01P2006/60 , C07C2101/14
摘要： The invention relates to a catalytic process for the synthesis of an alcohol by reaction of an epoxide with a nucleophilic compound containing a labile hydrogen, such as an alcohol, a phenol, a primary amine or a carboxylic acid.The catalyst is a metal complex of general formula (I)[M[Co(CO).sub.4 ].sub.2 ].sub.x in which x is equal to 1 or 2 and M denotes tin, lead and cadmium.The reaction preferably takes place in the presence of carbon monoxide.This process makes it possible to increase the yield and the selectivity of the reaction and the stereoselectivity for alcohol in the case of which the hydroxyl formed is attached to the least hindered carbon atom of the epoxide.The invention also relates to the new complexes of formula (I) in which x equals 2.It also relates to a process for the electrosynthesis of these new compounds by electroreduction of Co.sub.2 (CO).sub.8 in an organic solvent medium in a cell in which the anode consists of the metal M, followed by isolation of the complex, the temperature of the reaction mixture and that at which the complex is isolated being lower than 25.degree. C.
摘要翻译：本发明涉及通过环氧化物与含有不稳定氢的亲核化合物如醇，伯胺或羧酸的反应合成醇的催化方法。催化剂是通式（I）[M [Co（CO）4] 2] x的金属络合物，其中x等于1或2，M表示锡，铅和镉。反应优选在一氧化碳的存在下进行。在使环氧化物的最少受阻碳原子附着了羟基的情况下，可以提高反应的收率和选择性以及醇的立体选择性。本发明还涉及式（I）的新的配合物，其中x等于2.它还涉及通过在有机溶剂介质中电还原Co2（CO）8来电解这些新化合物的方法，其中细胞中阳极由金属M组成，然后分离复合物，反应混合物的温度和复合物的分离温度低于25℃。

2. 发明授权

US5214205A Process for the preparation of acetic anhydride from methyl formate 失效
标题翻译：从甲基丙烯酸制备乙酸酐的方法
公开(公告)号：US5214205A
公开(公告)日：1993-05-25
申请号：US868186
申请日：1992-04-14
申请人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
发明人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
IPC分类号： B01J31/20 , B01J31/24 , C07B61/00 , C07C51/12 , C07C51/56 , C07C53/12
CPC分类号： C07C53/12 , C07C51/56
摘要： The invention relates to a process for the preparation of acetic anhydride, characterized in that a gas containing essentially CO, at a pressure of at least 1 MPa, is reacted with methyl formate in the presence ofa) a rhodium-based catalyst,b) two iodine-containing promoters of different kind, successively ionic and covalent, andc) an N-substituted cyclic amide as solvent.
摘要翻译：本发明涉及一种制备乙酸酐的方法，其特征在于在a）铑基催化剂存在下，使基本上含有至少1MPa压力的CO的气体与甲酸甲酯反应，b）两种不同种类的含碘促进剂，连续离子和共价，和c）N-取代的环状酰胺作为溶剂。

3. 发明授权

US5574116A Process for the preparation of a catalyst for the polymerization of olefins 失效
标题翻译：制备烯烃聚合催化剂的方法
公开(公告)号：US5574116A
公开(公告)日：1996-11-12
申请号：US214691
申请日：1994-03-18
申请人： Karel Bujadoux , Jean-Michel Brusson , Francis Petit , Andre Mortreux
发明人： Karel Bujadoux , Jean-Michel Brusson , Francis Petit , Andre Mortreux
IPC分类号： C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： A process is disclosed for the polymerization of olefins, using (i) a catalyst and (ii) an organometallic activator from Groups I, II or III of the Periodic Table at temperatures between 20.degree. and 250.degree. C., and pressure up to 200 bar, in solution, or in suspension in an inert liquid hydrocarbon, at temperatures between 160.degree. and 350.degree. C., under pressures of between 400 and 3000 bar, in a continuous manner in a reactor where the mean residence time of the catalyst is between 1 and 150 seconds. The catalyst comprises at least one titanium compound, at least one halogen-containing organoaluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihaloalkane. The titanium compound is essentially a titanium (III) compound, the total content of titanium (II) and titanium (IV) being less than or equal to 15% of the total content of titanium. The catalyst is obtained by a process comprising, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihaloalkane by means of a molar excess of at least one halogen-containing organoaluminum compound, in the absence of an ether, and, in a second step, the addition to the reaction mixture of a compound which forms a magnesium halide in situ without supplementary reduction of the titanium compound obtained in the first step. Molar ratios of the .alpha.,.omega.-dihaloalkane, the titanium compound, halogen-containing organoaluminum, and the compound which forms a magnesium halide in situ are also described.
摘要翻译：公开了一种用于烯烃聚合的方法，其使用（i）催化剂和（ii）在20℃至250℃之间的元素周期表第I，II或III族的有机金属活化剂，压力高达200 在惰性液体烃中，160-150℃的温度下，在400-3000巴的压力下，在反应器中连续地在惰性液体烃中悬浮或悬浮，其中催化剂的平均停留时间为 1到150秒之间。催化剂包含至少一种钛化合物，至少一种含卤素的有机铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物，钛（II）和钛（IV）的总含量小于或等于钛总含量的15％。该催化剂是通过一种方法获得的，该方法包括在第一步骤中，通过摩尔过量的至少一种含卤素的有机铝化合物在α，ω-二卤代烷烃中还原钛（IV）化合物，醚，并且在第二步中，在没有补充还原第一步中获得的钛化合物的情况下向原位形成镁卤化物的化合物的反应混合物加入。还描述了α，ω-二卤代烷烃，钛化合物，含卤素的有机铝和原位形成卤化镁的化合物的摩尔比。

4. 发明授权

US5194676A Catalyst and process for the synthesis of saturated carboxylic esters 失效
标题翻译：用于饱和羧酸酯合成的催化剂和方法
公开(公告)号：US5194676A
公开(公告)日：1993-03-16
申请号：US674745
申请日：1991-03-26
申请人： Yves Castanet , Christophe Legrand , Andre Mortreux , Francis Petit
发明人： Yves Castanet , Christophe Legrand , Andre Mortreux , Francis Petit
IPC分类号： B01J27/13 , B01J31/02 , C07B61/00 , C07C67/303 , C07C67/38 , C07C69/24
CPC分类号： C07C69/24 , C07C67/38
摘要： Saturated carboxylic esters are produced from alkyl formate and an olefin, without the presence of substantial amounts of carbon monoxide, at a temperature of 120.degree. to 280.degree. C., under a pressure of 1 to 3,000 bars, in the presence of a catalyst based on ruthenium coordinated by ligands selected from carbon monoxide, halogen atoms and amines, and in the presence of an amide as a solvent. The catalyst is selected from catalysts consisting essentially of RuCl.sub.3.3H.sub.2 O; catalysts consisting essentially of the combination of an RuCl.sub.3.3H.sub.2 O together with at least one stabilizer selected from iodine, covalent iodides and quaternary ammonium halides; catalysts comprising Ru.sub.3 (CO).sub.12 together with at least one stabilizer such as is mentioned above; and catalysts selected from RuI.sub.3, [RuCl.sub.2 (CO).sub.3 ].sub.2, Ru(NH.sub.3).sub.6 Cl.sub.3 and [Ru(NH.sub.3).sub.5 Cl]Cl.sub.2, comprising, where appropriate, in addition, at least one stabilizer such as is mentioned above.
摘要翻译：在120至280℃的温度下，在1至3,000巴的压力下，在催化剂基的存在下，将饱和羧酸酯由甲酸烷基酯和烯烃生产，而不存在大量的一氧化碳在由选自一氧化碳，卤素原子和胺的配体和在作为溶剂的酰胺存在下配位的钌上。催化剂选自基本上由RuCl 3·3H 2 O组成的催化剂; 基本上由RuCl 3·3H 2 O与至少一种选自碘，共价碘化物和季铵卤化物的稳定剂的组合组成的催化剂; 包含Ru 3（CO）12的催化剂以及如上所述的至少一种稳定剂; 以及选自RuI 3，[RuCl 2（CO）3] 2，Ru（NH 3）6 Cl 3和[Ru（NH 3）5 Cl] Cl 2的催化剂，在适当的情况下还包括至少一种如上所述的稳定剂。

5. 发明授权

US5068014A Catalytic composition for the polymerization of olefins and its process of preparation 失效
标题翻译：用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5068014A
公开(公告)日：1991-11-26
申请号：US369229
申请日：1989-06-22
申请人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
发明人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
IPC分类号： C08F4/60 , C08F4/62 , C08F4/642 , C08F4/655 , C08F10/00
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译：制备烯烃聚合催化组合物的方法。在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物。钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

6. 发明授权

US5356848A Catalytic composition for the polymerization of olefins and its process of preparation 失效
标题翻译：用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5356848A
公开(公告)日：1994-10-18
申请号：US117319
申请日：1993-09-07
申请人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
发明人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
IPC分类号： C08F4/60 , C08F4/62 , C08F4/642 , C08F4/655 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译：制备烯烃聚合催化组合物的方法。在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物。钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

7. 发明授权

US5210202A Chiral phosphorous compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效
标题翻译：手性磷化合物，其制备方法及其在催化对映选择性合成反应中的应用
公开(公告)号：US5210202A
公开(公告)日：1993-05-11
申请号：US811673
申请日：1991-12-23
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： Chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphinoxy radical of the formula W=OP (R).sub.2, in which R is a hydrocarbon radical selected from the group consisting of alkyl, aryl, and cycloalkyl radicals, wherein the ligand is selected from the group consisting of:those of the formula ##STR1## those of the forumula ##STR2## those of the formula ##STR3## those of the formula ##STR4##
摘要翻译：包含至少一个胺基团和至少一个式W = OP（R）2的二烃基次膦基的手性含磷配体，其中R是选自烷基，芳基和环烷基的烃基，其中该配体选自：式（I）的化合物（I）的化合物的组合（II）的那些式

8. 发明授权

US5099077A Chiral phosphorus compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效
标题翻译： CHIRAL PHOSPHORUS化合物，其制备方法及其应用于催化合成反应的应用
公开(公告)号：US5099077A
公开(公告)日：1992-03-24
申请号：US398539
申请日：1989-10-11
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： A method of using a chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphioxy radical of the formula W=OP (R).sub.2 ; from the group consisting of:those of the formula ##STR1## those of the formula ##STR2## those of the formula ##STR3## those of the formula ##STR4## in a hydrogenation reaction for the synthesis of optically active organic compounds comprising reacting at least one organic compound that does not possess a center of asymmetry with (A), on the one hand, at least one transition metal complex of the formula MZq in which M is a metal in group VIII of the Periodic Classification, q is the coordination number of the metal M, and Z is an atom or molecule capable of complexing the metal M and (B), on the other hand, at least one ligand L.

9. 发明授权

US5024983A Catalyst system, process for its preparation and its application to the manufacture of aldehydes 失效
标题翻译：催化剂体系，其制备方法及其在制醛中的应用
公开(公告)号：US5024983A
公开(公告)日：1991-06-18
申请号：US323718
申请日：1989-03-15
申请人： Eric Paumard , Sylvain Mutez , Andre Mortreux , Francis Petit
发明人： Eric Paumard , Sylvain Mutez , Andre Mortreux , Francis Petit
IPC分类号： B01J31/18 , B01J31/24 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00
CPC分类号： B01J31/188 , B01J31/2409 , C07C45/50 , B01J2231/321 , B01J2531/828
摘要： The catalyst system is characterized in that it comprises:at least one platinum complex of formula LPtX.sub.2 in which L is an organic compound containing at least two phosphorus atoms capable of coordinating platinum and X is a halogen atom, andat least one combination formed between iron and an alkene carbonate, the alkene group preferably containing from 2 to 6 carbon atoms.The process for its preparation is characterized in that at least one combination formed between iron adn the alkene carbonate is reacted with at least one platinum complex of formula LPtX.sub.2 in at least one solvent for the said complex, at a temperature of between 10.degree. C. and the boiling point of the said solvent. The combination of iron and of an alkene carbonate may be formed by electrochemical reduction.Application of the catalyst system to the manufacture of aldehydes by hydroformylation of an organic compound containing ethylenic unsaturation, consisting in reacting the said organic compound with a mixture of carbon monoxide and hydrogen in the presence of an effective quantity of the said catalyst system, at a temperature of between 10.degree. and 300.degree. C. and at a pressure of between 10 and 350 bars.
摘要翻译：该催化剂体系的特征在于它包括：至少一种式LPtX2的铂络合物，其中L是含有能配位铂的至少两个磷原子的有机化合物，X是卤素原子，并且在铁和烯烃碳酸酯，烯烃基团优选含有2至6个碳原子。其制备方法的特征在于，在碳酸甲酯之间形成的至少一种组合与至少一种式LPtX2的铂络合物在所述络合物的至少一种溶剂中在10℃的温度下反应。和所述溶剂的沸点。铁和碳酸烯烃的组合可以通过电化学还原形成。在有效量的所述催化剂体系的存在下，将所述有机化合物与一氧化碳和氢气的混合物反应，所述有机化合物含有烯属不饱和基团的加成甲酰化将所述催化剂体系应用于醛的制备中，温度在10℃至300℃之间，压力在10至350巴之间。

10. 发明授权

US5492983A Catalysts and process for the preparation of catalysts which may be used for the polymerization of ethylene 失效
标题翻译：用于制备可用于乙烯聚合的催化剂的催化剂和方法
公开(公告)号：US5492983A
公开(公告)日：1996-02-20
申请号：US244679
申请日：1994-06-07
申请人： Xavier Olonde , Karel Bujadoux , Andre Mortreux , Francis Petit, deceased
发明人： Xavier Olonde , Karel Bujadoux , Andre Mortreux , Francis Petit, deceased
IPC分类号： C08F4/42 , C08F4/54 , C08F4/62 , C08F10/00 , C08F10/02 , C08F4/14
CPC分类号： C08F10/02 , Y02P20/544
摘要： This catalyst consists of the reaction product, with at least one organomagnesium compound and/or organolithium compound R.sup.1 Li (R.sup.1 =alkyl) or ArLi (Ar=phenyl or benzyl), of the reaction product of (Cp).sub.2 MX.sub.2 Li(OR.sub.2).sub.2 (M=lanthanide, Sc, Y; (Cp)=optionally substituted cyclopentadienyl; and R=alkyl), with at least one bidentate ligand, such as .beta.-diketone or .beta.-keto imine CZ.sub.3 COCHZCDCZ.sub.3, Z selected from halogen, alkyl and H, D=O, NH or NR.sup.3 (R.sup.3 =alkyl or aryl); and phosphorus ylid R.sup.2.sub.3 P.dbd.CA--CO--R.sup.2, R.sup.2 chosen from alkyl and aryl; A=alkyl or H. It advantageously takes the form of a solution at least partially containing an aromatic hydrocarbon. The process for the polymerization of ethylene may be carried out at 20.degree.-250.degree. C. at a pressure which may range up to approximately 200 bars, in solution or in suspension in an at least C.sub.6 inert hydrocarbon or may be carried out continuously, in at least one autoclave or tubular reactor, at 150.degree.-300.degree. C., at 400-2000 bars, the reaction medium being in the supercritical state.
摘要翻译： PCT No.PCT / FR93 / 00996 Sec。 371日期：1994年6月7日 102（e）日期1994年6月7日PCT提交1993年10月8日PCT公布。第WO94 / 09044号公报该催化剂由（Cp）的反应产物与至少一种有机镁化合物和/或有机锂化合物R1Li（R1 =烷基）或ArLi（Ar =苯基或苄基）组成，具有至少一个二齿配位体，例如β-二酮或β-酮亚胺CZ 3 COCHZCDCZ 3，Z选自：（2）M 2镧（OR 2）2（M =镧系元素，Sc，Y;（Cp）=任选取代的环戊二烯基; R = 卤素，烷基和H，D = O，NH或NR 3（R 3 =烷基或芳基）; 和磷叶立德R23P = CA-CO-R2，R2选自烷基和芳基; A =烷基或H.它有利地是至少部分含有芳族烃的溶液的形式。乙烯聚合的方法可以在20-250℃下进行，压力范围可达200巴，溶液中或在至少C6惰性烃中的悬浮液中，或连续进行，在至少一个高压釜或管式反应器中，在150-300℃，400-2000巴条件下，反应介质处于超临界状态。

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