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1. 发明授权

US09441087B2 Fluoropolymer composition 有权
公开(公告)号：US09441087B2
公开(公告)日：2016-09-13
申请号：US13878030
申请日：2011-10-13
申请人： Serena Carella , Mattia Bassi , Paolo Toniolo , Julio A. Abusleme , Stefano Mortara
发明人： Serena Carella , Mattia Bassi , Paolo Toniolo , Julio A. Abusleme , Stefano Mortara
IPC分类号： C08K3/22 , B29D99/00 , C08K5/00 , C08J5/18 , B32B27/06 , B32B27/32
CPC分类号： C08K3/22 , B29D99/00 , B32B27/06 , B32B27/322 , B32B2439/00 , C08J5/18 , C08J2327/12 , C08K5/005 , Y10T29/49002 , Y10T29/49623 , Y10T428/25 , C08L27/12
摘要： A thermoplastic fluoropolymer composition comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE), said polymer having a heat of fusion of at most 35 J/g and from 0.05 to 5% by weight, based on weight of said semi-crystalline polymer (A), of particles of at least one inorganic UV blocker compound, said particles having an average particle size of 1 to 150 nm, said composition being suitable for manufacturing UV-opaque films having outstanding transparency and haze properties.

2. 发明申请

US20130192755A1 Multilayer assembly 审中-公开
标题翻译：多层装配
公开(公告)号：US20130192755A1
公开(公告)日：2013-08-01
申请号：US13877792
申请日：2011-10-12
申请人： Serena Carella , Mattia Bassi , Stefano Mortara , Paolo Toniolo , Julio A. Abusleme
发明人： Serena Carella , Mattia Bassi , Stefano Mortara , Paolo Toniolo , Julio A. Abusleme
IPC分类号： B32B27/08
CPC分类号： B32B27/08 , B32B27/20 , B32B27/304 , B32B2250/03 , B32B2250/246 , B32B2250/40 , B32B2264/102 , B32B2307/412 , B32B2307/71 , B32B2307/712 , B32B2457/12 , H01L31/0481 , Y02E10/50 , Y10T156/10 , Y10T428/257 , Y10T428/259 , Y10T428/265 , Y10T428/31544
摘要： A multilayer assembly comprising a first inner layer (L1) made from a first composition (C1), said first composition (C1) comprising at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and a second outer layer (L2) made from a second composition, said second composition (C2) being free from TiO2-containing additives, said second composition (C2) comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer (A) having a heat of fusion of at least 35 J/g.
摘要翻译：一种多层组件，包括由第一组合物（C1）制成的第一内层（L1），所述第一组合物（C1）包含至少一种包含衍生自乙烯（E）和氯三氟乙烯（CTFE）的重复单元的聚合物，并且至少一钛化合物和由第二组合物制成的第二外层（L2），所述第二组合物（C2）不含TiO 2添加剂，所述第二组合物（C2）包含至少一种半结晶聚合物（A），其包含衍生自乙烯和至少一种选自三氟氯乙烯（CTFE），四氟乙烯（TFE）及其混合物的含氟单体，所述半结晶聚合物（A）具有至少35J / g的熔化热。

3. 发明申请

US20130202878A1 Fluoropolymer composition 有权
标题翻译：含氟聚合物组成
公开(公告)号：US20130202878A1
公开(公告)日：2013-08-08
申请号：US13878030
申请日：2011-10-13
申请人： Serena Carella , Mattia Bassi , Paolo Toniolo , Julio A. Abusleme , Stefano Mortara
发明人： Serena Carella , Mattia Bassi , Paolo Toniolo , Julio A. Abusleme , Stefano Mortara
IPC分类号： C08K3/22 , B29D99/00
CPC分类号： C08K3/22 , B29D99/00 , B32B27/06 , B32B27/322 , B32B2439/00 , C08J5/18 , C08J2327/12 , C08K5/005 , Y10T29/49002 , Y10T29/49623 , Y10T428/25 , C08L27/12
摘要： A thermoplastic fluoropolymer composition comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE), said polymer having a heat of fusion of at most 35 J/g and from 0.05 to 5% by weight, based on weight of said semi-crystalline polymer (A), of particles of at least one inorganic UV blocker compound, said particles having an average particle size of 1 to 150 nm, said composition being suitable for manufacturing UV-opaque films having outstanding transparency and haze properties.
摘要翻译：一种热塑性含氟聚合物组合物，其包含至少一种包含衍生自乙烯和三氟氯乙烯（CTFE）和四氟乙烯（TFE）中的至少一种的重复单元的半结晶聚合物（A），所述聚合物具有至多35J / g的熔融热和0.05至5重量％的所述半结晶聚合物（A）的重量，至少一种无机UV阻断剂化合物的颗粒，所述颗粒的平均粒径为1-150nm，所述组合物是合适的用于制造具有优异的透明性和雾度特性的不透紫外线膜。

4. 发明授权

US09006565B2 Opaque fluoropolymer composition comprising white pigments for photovoltaic elements of solar cells 有权
标题翻译：不透明的含氟聚合物组合物包含用于太阳能电池的光伏元件的白色颜料
公开(公告)号：US09006565B2
公开(公告)日：2015-04-14
申请号：US13123958
申请日：2009-10-15
申请人： Julio A. Abusleme , Mattia Bassi , Régis Faig , Paolo Toniolo
发明人： Julio A. Abusleme , Mattia Bassi , Régis Faig , Paolo Toniolo
IPC分类号： H01L31/04 , H01L31/048 , C08L27/12 , C08L27/16 , C08K3/00 , C08K3/22 , C08L27/18
CPC分类号： H01L31/048 , C08K3/013 , C08K3/22 , C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , H01L31/0481 , Y02E10/50 , Y10T428/3154 , C08L2666/04
摘要： A fluoropolymer composition having a total luminous transmittance (TT) of less than 15%, when measured according to ASTM D1003 on a sample having a thickness of about 50 μm, said composition comprising: at least one hydrogen-containing fluoropolymer [polymer (A)]; from 5 to 80% by weight of (A) of at least one inorganic pigment [pigment (I)]; and from 1 to 99% by weight of (I) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad×sec−1 of less than 100 Pa×sec at a temperature of 280° C. [polymer (B)]. By adding polymer (B) to the composition based on polymer (A) it is advantageously possible to obtain an even dispersion of the pigment (I) so that a composition possessing outstanding opacity and still being processable under the form of films, so as to provide adequate mechanical properties, can be manufactured therefrom.
摘要翻译：在根据ASTM D1003对厚度为约50μm的样品测量时，总透光率（TT）小于15％的含氟聚合物组合物，所述组合物包含：至少一种含氢的含氟聚合物[聚合物（A） ]; （A）5至80重量％的至少一种无机颜料[颜料（I）]; 和1至99重量％的（I）至少一种每（卤）含氟聚合物，其选自在剪切速率为1rad×sec-1的动态粘度小于100Pa×sec的四氟乙烯（TFE）共聚物中在280℃的温度下进行。[聚合物（B）]。通过在基于聚合物（A）的组合物中加入聚合物（B），有利地可以获得颜料（I）的均匀分散体，使得具有优异的不透明性并且仍然可以在膜的形式下处理的组合物，以便提供足够的机械性能，可以由其制造。

5. 发明申请

US20110226333A1 Opaque fluoropolymer composition comprising white pigments for photovoltaic elements of solar cells 有权
标题翻译：不透明的含氟聚合物组合物包含用于太阳能电池的光伏元件的白色颜料
公开(公告)号：US20110226333A1
公开(公告)日：2011-09-22
申请号：US13123958
申请日：2009-10-15
申请人： Julio A. Abusleme , Mattia Bassi , Régis Faig , Paolo Toniolo
发明人： Julio A. Abusleme , Mattia Bassi , Régis Faig , Paolo Toniolo
IPC分类号： C08L27/18 , C08K3/30 , H01L31/0203
CPC分类号： H01L31/048 , C08K3/013 , C08K3/22 , C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , H01L31/0481 , Y02E10/50 , Y10T428/3154 , C08L2666/04
摘要： A fluoropolymer composition having a total luminous transmittance (TT) of less than 15%, when measured according to ASTM D1003 on a sample having a thickness of about 50 μm, said composition comprising: at least one hydrogen-containing fluoropolymer [polymer (A)]; from 5 to 80% by weight of (A) of at least one inorganic pigment [pigment (I)]; and from 1 to 99% by weight of (I) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad×sec−1 of less than 100 Pa×sec at a temperature of 280° C. [polymer (B)]. By adding polymer (B) to the composition based on polymer (A) it is advantageously possible to obtain an even dispersion of the pigment (I) so that a composition possessing outstanding opacity and still being processable under the form of films, so as to provide adequate mechanical properties, can be manufactured therefrom.
摘要翻译：在根据ASTM D1003对厚度为约50μm的样品测量时，总透光率（TT）小于15％的含氟聚合物组合物，所述组合物包含：至少一种含氢的含氟聚合物[聚合物（A） ]; （A）5至80重量％的至少一种无机颜料[颜料（I）]; 和1至99重量％的（I）至少一种每（卤）含氟聚合物，其选自在剪切速率为1rad×sec-1的动态粘度小于100Pa×sec的四氟乙烯（TFE）共聚物中在280℃的温度下进行。[聚合物（B）]。通过在基于聚合物（A）的组合物中加入聚合物（B），有利地可以获得颜料（I）的均匀分散体，使得具有优异的不透明性并且仍然可以在膜的形式下处理的组合物，以便提供足够的机械性能，可以由其制造。

6. 发明授权

US11441007B2 Fluoropolymer composition for multilayer assemblies 有权
公开(公告)号：US11441007B2
公开(公告)日：2022-09-13
申请号：US14131747
申请日：2012-07-10
申请人： Stefano Mortara , Julio A. Abusleme
发明人： Stefano Mortara , Julio A. Abusleme
IPC分类号： C08K3/22 , C08F214/22 , C08F20/06 , B29C48/21 , C09D127/16 , C08F14/22 , C08L27/16 , B32B27/30 , B32B27/36 , C08K3/30
摘要： The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.

7. 发明授权

US08642702B2 VDF polymer composition 有权
标题翻译： VDF聚合物组成
公开(公告)号：US08642702B2
公开(公告)日：2014-02-04
申请号：US13643339
申请日：2011-04-26
申请人： Julio A. Abusleme , Stefano Mortara
发明人： Julio A. Abusleme , Stefano Mortara
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08J5/18 , C08J2327/16 , C08L27/16 , C08L27/12 , C08L23/0892
摘要： The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.
摘要翻译：本发明涉及一种热塑性VDF聚合物组合物，其包含：至少一种包含至少85％摩尔衍生自VDF的重复单元的热塑性偏二氟乙烯（VDF）聚合物; 和至少一种乙烯/氯三氟乙烯（ECTFE）聚合物，其中所述ECTFE聚合物具有小于210℃的熔点，并且其含量相对于VDF聚合物的总重量为0.1-20重量％和ECTFE聚合物。本发明还涉及制备VDF聚合物的方法及其用于制造膜，特别是透明膜的用途。

8. 发明授权

US07262226B2 CTFE-based thermoprocessable compositions 有权
标题翻译：基于CTFE的热处理组合物
公开(公告)号：US07262226B2
公开(公告)日：2007-08-28
申请号：US10814339
申请日：2004-04-01
申请人： Julio A. Abusleme , Claudia Manzoni , Mattia Bassi
发明人： Julio A. Abusleme , Claudia Manzoni , Mattia Bassi
IPC分类号： C08J9/00 , C08F259/08
CPC分类号： C08J9/0061 , C08F259/08 , C08J2327/12 , C08J2427/00 , C08L27/12 , C08L27/18 , H01B3/441 , H01B3/443 , C08L2666/04
摘要： A thermoprocessable polymeric composition formed by ethylene/chlorotrifluoroethylene copolymers containing from 0.5 to 20% by moles of ethylene, optionally in combination with the chlorotrifluoroethylene homopolymer, wherein the composition contains in total from 90 to 99.5% by moles of chlorotrifluoroethylene and from 0.5-10% by moles of ethylene; said polymeric composition having a second melting temperature (TmII) higher than 185° C., preferably higher than 200° C.
摘要翻译：由乙烯/氯三氟乙烯共聚物形成的热可加工聚合物组合物，其含有0.5至20摩尔％的乙烯，任选与氯三氟乙烯均聚物组合，其中组合物含有总共90-99.5摩尔％的三氟氯乙烯和0.5-10％摩尔的乙烯; 所述聚合物组合物具有高于185℃，优选高于200℃的第二熔融温度（℃）。

9. 发明申请

US20140127434A1 FLUOROPOLYMER COMPOSITION FOR MULTILAYER ASSEMBLIES 审中-公开
标题翻译：多层组合物的氟聚合物组合物
公开(公告)号：US20140127434A1
公开(公告)日：2014-05-08
申请号：US14131747
申请日：2012-07-10
申请人： Stefano Mortara , Julio A. Abusleme
发明人： Stefano Mortara , Julio A. Abusleme
IPC分类号： C08K3/22 , B29C47/06 , C08K3/30
CPC分类号： C08K3/22 , B29C48/21 , C08K3/30 , Y10T29/49826 , Y10T428/1352 , Y10T428/1393 , Y10T428/31515 , Y10T428/3154
摘要： The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.
摘要翻译：本发明涉及一种组合物（C1），其包含：至少一种（甲基）丙烯酸改性的VDF聚合物[聚合物（A）]，其包含衍生自衍生自偏二氟乙烯（VDF）单体的重复单元和至少一种亲水（甲基））式（I）的丙烯酸单体（MA），其中R1，R2，R3彼此相同或不同的各自独立地为氢原子或C1-C3烃基，ROH为氢或C1- C5烃部分包含至少一个羟基; 相对于聚合物（A）的重量，不超过5重量％的至少一种无机UV阻断剂化合物，包含由所述组合物（C1）制成的一层的多层组件，涉及制备所述多层组件的方法和使用不同的使用领域，包括保护光伏组件。

10. 发明申请

US20130037754A1 VDF POLYMER COMPOSITION 有权
标题翻译： VDF聚合物组合物
公开(公告)号：US20130037754A1
公开(公告)日：2013-02-14
申请号：US13643339
申请日：2011-04-26
申请人： Julio A. Abusleme , Stefano Mortara
发明人： Julio A. Abusleme , Stefano Mortara
IPC分类号： C08L27/16 , C08L27/18 , B29C47/00 , H01B1/20 , B29C47/14 , C08L27/20 , C08K3/22
CPC分类号： C08J5/18 , C08J2327/16 , C08L27/16 , C08L27/12 , C08L23/0892
摘要： The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.
摘要翻译：本发明涉及一种热塑性VDF聚合物组合物，其包含：至少一种包含至少85％摩尔衍生自VDF的重复单元的热塑性偏二氟乙烯（VDF）聚合物; 和至少一种乙烯/氯三氟乙烯（ECTFE）聚合物，其中所述ECTFE聚合物具有小于210℃的熔点，并且其含量相对于VDF聚合物的总重量为0.1-20重量％和ECTFE聚合物。本发明还涉及制备VDF聚合物的方法及其用于制造膜，特别是透明膜的用途。

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