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    • 2. 发明授权
    • Composition, adhesive and aqueous emulsion
    • 组合物,粘合剂和水性乳液
    • US5308910A
    • 1994-05-03
    • US903449
    • 1992-06-24
    • Ken YukiMasato NakamaeHitoshi MaruyamaTatsuaki Hattori
    • Ken YukiMasato NakamaeHitoshi MaruyamaTatsuaki Hattori
    • C08G18/62C08G18/63C09J175/00C08L29/04
    • C08G18/636C08G18/6229C08G18/633C09J175/00C08G2170/80
    • There is disclosed a composition which comprises an aqueous emulsion selected from (A-1) aqueous emulsion comprising a dispersoid which comprises a vinyl ester polymer (1) and a copolymer a (meth)acrylic ester and a primary hydroxyl group-containing ethylenically unsaturated monomer (2), the polymer (1) being present principally in the central part of the dispersoid, the copolymer (2) having a glass transition temperature of lower than 50.degree. C. an being present principally in the peripheral part thereof; and a dispersant comprising a vinyl alcohol polymer and (A-2) aqueous emulsion comprising a dispersoid which comprises a copolymer of a hydrophobic unsaturated monomer such as (meth)acrylic ester and a primary hydroxyl group-containing ethylenically unsaturated monomer; and a dispersant comprising a vinyl alcohol polymer having a mercapto group at an end thereof and a (B) polyvalent isocyanate compound. Disclosed also are an adhesive comprising the aforementioned composition and a wooden product which is joined by the use of the adhesive. The above-disclosed adhesive is excellent in initial adhesivity, adhesive strength, water resistance and so forth.
    • 公开了一种组合物,其包含选自(A-1)水性乳液的水乳液,其包含分散质,其包含乙烯基酯聚合物(1)和共聚物(甲基)丙烯酸酯和含伯羟基的烯属不饱和单体 (2)中,聚合物(1)主要存在于分散质的中心部分,共聚物(2)的玻璃化转变温度低于50℃,主要在其周边部分存在; 以及包含乙烯醇聚合物和(A-2)水性乳液的分散剂,其包含分散质,其包含疏水性不饱和单体如(甲基)丙烯酸酯和含伯羟基的烯属不饱和单体的共聚物; 和包含末端具有巯基的乙烯醇聚合物和(B)多价异氰酸酯化合物的分散剂。 还公开了包含上述组合物的粘合剂和通过使用粘合剂连接的木制品。 上述粘合剂的初始粘合性,粘合强度,耐水性等优异。