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1. 发明授权

US06176937B1 Process for treating a metal surface with an acidic solution containing hydrogen peroxide and a stabilizer 失效
标题翻译：用含有过氧化氢和稳定剂的酸性溶液处理金属表面的方法
公开(公告)号：US06176937B1
公开(公告)日：2001-01-23
申请号：US09531601
申请日：2000-03-20
申请人： Sarah J. Colgan , Neil J. Sanders , Colin F. McDonogh
发明人： Sarah J. Colgan , Neil J. Sanders , Colin F. McDonogh
IPC分类号： C23G100
CPC分类号： C23G1/086 , C01B15/037 , C23F3/06 , C23G1/08 , C23G1/103 , Y10S134/902
摘要： Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolved metals such as iron, copper or titanium. A method is provided wherein stabilization can be achieved by employing a combination of a) a hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.
摘要翻译：用于金属表面处理的过氧化氢水性酸性溶液遭受由溶解的金属如铁，铜或钛引起的过氧化氢分解速率的升高。提供了一种方法，其中通过采用以下组合来实现稳定化：a）羟基苯甲酸，优选对羟基苯甲酸; b）水溶助极性磺酸，优选对甲苯磺酸; 和c）疏水性烷芳基磺酸，优选十二烷基苯磺酸。

2. 发明授权

US6126755A Metal surface treatment solutions and process 失效
标题翻译：金属表面处理方法及工艺
公开(公告)号：US6126755A
公开(公告)日：2000-10-03
申请号：US284023
申请日：1999-05-25
申请人： Sarah J. Colgan , Neil J. Sanders , Colin F. McDonogh
发明人： Sarah J. Colgan , Neil J. Sanders , Colin F. McDonogh
IPC分类号： C01B15/037 , C23F1/28 , C23F3/06 , C23G1/02 , C23G1/08
CPC分类号： C23G1/086 , C01B15/037 , C23F3/06 , C23G1/08 , C23G1/103 , Y10S134/902
摘要： Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolution of metals such as iron, copper, or titanium. Stabilization can be achieved by employing a combination of a) hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.
摘要翻译： PCT No.PCT / GB97 / 02725 Sec。 371日期1999年5月25日 102（e）日期1999年5月25日PCT提交1997年10月6日PCT公布。公开号WO98 / 15674 日期1998年4月16日用于金属表面处理的过氧化氢水性酸性溶液由于金属如铁，铜或钛的溶解而引起的过氧化氢分解速率增加。稳定化可以通过以下方法实现：a）羟基苯甲酸，优选对羟基苯甲酸; b）水溶助极性磺酸，优选对甲苯磺酸; 和c）疏水性烷芳基磺酸，优选十二烷基苯磺酸。

3. 发明授权

US5429812A Manufacture of peroxidic compositions 失效
标题翻译：过氧化物组合物的制造
公开(公告)号：US5429812A
公开(公告)日：1995-07-04
申请号：US70376
申请日：1993-06-08
申请人： Colin F. McDonogh , Neil J. Sanders
发明人： Colin F. McDonogh , Neil J. Sanders
IPC分类号： C01B15/06 , C01B20060101 , C01B17/98
CPC分类号： C01B15/06
摘要： Production of peroxomonosulphuric acid (Caro's acid) by reaction between concentrated hydrogen peroxide and sulphuric acid solutions can be impaired substantially when substoichiometric amounts of sulphuric acid are employed.The problem is ameliorated or removed by first forming a body of sulphuric acid-rich fluid (usually the smaller volume) and thereafter introducing into that body of fluid the hydrogen peroxide solution (usually the larger volume). The reaction mixture progressively becomes sulphuric acid-lean. The body of fluid is advantageously either concentrated sulphuric acid itself, or a premix formed by reaction between hydrogen peroxide and at least an equimolar amount of sulphuric acid. The process is particularly suitable for making Caro's acid when from 0.02 to 0.5 moles of sulphuric acid is employed per mole of hydrogen peroxide.
摘要翻译： PCT No.PCT / GB91 / 02138 Sec。 371日期：1993年6月8日 102（e）日期1993年6月8日PCT 1991年12月3日PCT PCT。公开号WO92 / 11200 日期：1992年7月9日。当使用亚化学计量的硫酸时，通过浓缩的过氧化氢和硫酸溶液之间的反应生产过氧硫酸（卡罗酸）。通过首先形成一个富含硫酸的流体（通常较小的体积），然后将该过氧化氢溶液（通常较大的体积）引入该体内的流体来改善或去除该问题。反应混合物逐渐变成贫硫酸。流体本身有利地是浓硫酸本身或由过氧化氢和至少等摩尔量的硫酸之间的反应形成的预混合物。当每摩尔过氧化氢使用0.02至0.5摩尔硫酸时，该方法特别适用于制备Caro酸。

4. 发明授权

US5364549A Hydrogen peroxide solutions 失效
标题翻译：过氧化氢溶液
公开(公告)号：US5364549A
公开(公告)日：1994-11-15
申请号：US768538
申请日：1991-09-23
申请人： Colin F. McDonogh
发明人： Colin F. McDonogh
IPC分类号： C23F1/28 , C23F3/06 , C23G1/08 , C09K13/06 , B44C1/22 , C01B15/01
CPC分类号： C23F1/28 , C23F3/06 , C23G1/086
摘要： It would be desirable to replace nitric acid based solutions for surface treating steels and like materials with a sulphuric acid based solution containing hydrogen peroxide, but such replacement solutions lose hydrogen peroxide rapidly through mainly iron-induced decomposition.A surface treatment solution that is based on sulphuric acid and hydrogen peroxide, but has improved stability, contains an effective amount in combination of hydrofluoric acid, are hydroxybenzoic acid and an N-alkoxyphenyl-acetamide. Preferably, the hydroxybenzoic acid is para-hydroxybenzoic acid and the N-alkoxyphenyl-acetamide is N-(4-ethoxyphenyl)-acetamide. It is preferable to employ a saturated solution of each of the two latter components, and this can achieved practically and simply by adding the solid components in the shape of a block or blocks which maintain the saturated solution over an extended period of time.
摘要翻译： PCT No.PCT / GB90 / 01450 Sec。 371日期1991年9月23日 102（e）1991年9月23日PCT PCT 1990年9月20日PCT公布。出版物WO91 / 05079 日期为1991年4月18日。希望用含有过氧化氢的硫酸溶液替代用于表面处理钢和类似材料的硝酸溶液，但是这种替代溶液主要通过铁诱导的分解而快速失去过氧化氢。羟基苯甲酸和N-烷氧基苯基 - 乙酰胺是以硫酸和过氧化氢为基础但稳定性提高的表面处理溶液含有氢氟酸的有效量。优选地，羟基苯甲酸是对羟基苯甲酸，N-烷氧基苯基 - 乙酰胺是N-（4-乙氧基苯基） - 乙酰胺。优选使用后两种组分中的每一种的饱和溶液，并且可以通过将固体组分以保持饱和溶液的形式的固体组分延长一段时间来实现和简单地实现。

5. 发明授权

US5304360A Peroxoacid manufacture 失效
标题翻译：过氧酸制造
公开(公告)号：US5304360A
公开(公告)日：1994-04-19
申请号：US769803
申请日：1991-10-02
申请人： John R. G. Lane , Colin F. McDonogh , Stephen E. Woods
发明人： John R. G. Lane , Colin F. McDonogh , Stephen E. Woods
IPC分类号： B01J14/00 , B01J19/24 , C01B15/06 , C01B17/98 , C01B17/48
CPC分类号： B01J19/2415 , C01B15/06 , B01J2219/00094 , B01J2219/00164
摘要： Conventional plant to produce peroxomonosulphuric acid (Caro's acid) is large and emphasises extensive cooling, so that it is awkward to transport, can be cumbersome to install beside existing plant and can suffer from relatively expensive capital and/or running costs.In the present invention, Caro's acid is generated continuously in relatively small plant adiabatically, by introducing concentrated hydrogen peroxide into a stream of concentrated sulphuric acid in a reaction chamber dimensioned so that the throughput is very fast. In particularly suitable embodiments, the reaction chamber is annular at the points of introduction of the reagents, its width being greater in the vicinity of the hydrogen peroxide inlet than in the vicinity of the sulphuric acid inlet. The hydrogen peroxide inlet is preferably angled backwardly so that its encounter angle with the sulphuric acid stream is over 90.degree. to about 165.degree..
摘要翻译：生产过氧硫酸（Caro's acid）的传统工厂很大，并且强调大量的冷却，因此运输是尴尬的，安装在现有工厂旁边可能很麻烦，并且可能遭受相对昂贵的资金和/或运行成本。在本发明中，通过将浓缩的过氧化氢引入反应室中的浓硫酸流中，绝热地在相对较小的植物中连续生成Caro酸，其尺寸使得生产量非常快。在特别合适的实施方案中，反应室在试剂引入点处是环形的，其宽度在过氧化氢入口附近比在硫酸入口附近更大。过氧化氢入口优选地向后倾斜，使得其与硫酸流的碰撞角超过90度至约165度。

6. 发明授权

US4770808A Stabilization of metal-containing hydrogen peroxide solutions 失效
标题翻译：含金属过氧化氢溶液的稳定化
公开(公告)号：US4770808A
公开(公告)日：1988-09-13
申请号：US899895
申请日：1986-08-25
申请人： Colin F. McDonogh , David B. Mobbs
发明人： Colin F. McDonogh , David B. Mobbs
IPC分类号： C01B15/037 , C23C22/06 , C23C22/77 , C23F3/06 , C23G1/00 , C23G1/02
CPC分类号： C23F3/06 , C01B15/037 , C23G1/02
摘要： Unless aqueous acidic hydrogen peroxide solutions are stabilized, an excessive rate of decomposition of hydrogen peroxide precludes their use for treatment of metal surfaces, such as of copper and copper alloys, during which use substantial concentrations of decomposition catalysts build-up in solution. Regular monitoring of the solutions for residual stabilizer content would demand sophisticated analytical equipment beyond the reach of many users.The invention provides a stabilizer in the form of a block of sparingly soluble material, whereby monitoring can be simply and readily effected visually or by a simple electrical or mechanical detection system. For copper/copper alloys preferred stabilizers are p-hydroxybenzoic acid and triphenyl carbinol.
摘要翻译：除非水性酸性过氧化氢溶液稳定，否则过氧化氢分解速度过高会阻止其用于处理金属表面，如铜和铜合金，在此期间，溶液中会堆积大量的分解催化剂。定期监测残留稳定剂含量的解决方案将需要复杂的分析设备，超出许多用户的范围。本发明提供了一种易溶性材料块形式的稳定剂，从而可以通过目视或简单的电或机械检测系统简单且容易地进行监测。对于铜/铜合金，优选的稳定剂是对羟基苯甲酸和三苯基甲醇。

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