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    • 1. 发明授权
    • Polyurethane spray systems having improved flame-retardant properties
    • 聚氨酯喷雾系统具有改进的阻燃性能
    • US5567763A
    • 1996-10-22
    • US290624
    • 1994-08-15
    • Sanjeev MadanPeter K. Hyde-Smith
    • Sanjeev MadanPeter K. Hyde-Smith
    • C08G18/66C08K3/00C08K3/38
    • C08G18/6685C08K3/0058C08G2150/50
    • This invention relates to a flame-retardant polyurethane spray system prepared by mixing at an isocyanate index of from 90 to 120(A) an isocyanate composition containing(a) an organic polyisocyanate, and(b) 0 to 50 wt. %, relative to the organic polyisocyanate, of a halogen-containing organic flame retardant; and(B) an isocyanate-reactive composition containing(a) 10 to 80 wt. % of an isocyanate-reactive compound having a molecular weight of 400 to 10,000 and functionality of 2 to 7;(b) 1 to 50 wt. % of an isocyanate-reactive compound having a molecular weight less than 399 and functionality of 2 to 6;(c) 0 to 15 wt. % of an isocyanate-reactive tertiary amine polyether having a molecular weight of 100 to 1000;(d) 5 to 55 wt. % of a flame retardant other than a halogen-containing organic flame retardant, optionally in combination with a halogen-containing organic flame retardant, with the proviso that the weight ratio of the total amount of halogen-containing organic flame retardant in (A) and (B) to the amount of other flame retardants in (B) is from 0.4 to 1.5;(e) 0.01 to 1.5 wt. % of an organic metal catalyst or a mixture thereof with a tertiary amine catalyst; and(f) 0 to 15 wt. % of additives, wherein the quantities of components (B)(a) to (B)(f) are relative to the total amount of components (B)(a) to (B)(e).The invention further relates to a method for spray application of such flame-retardant polyurethane systems and to the resultant polyurethanes.
    • 本发明涉及通过在异氰酸酯指数为90-120(A)下混合含有(a)有机多异氰酸酯的异氰酸酯组合物和(b)0-50重量% 相对于有机多异氰酸酯的含卤有机阻燃剂的%; 和(B)异氰酸酯反应性组合物,其含有(a)10〜80重量% %的分子量为400至10,000且官能度为2至7的异氰酸酯反应性化合物; (b)1〜50wt。 %的分子量小于399且官能度为2至6的异氰酸酯反应性化合物; (c)0〜15wt。 %的分子量为100〜1000的异氰酸酯反应性叔胺聚醚; (d)5〜55wt。 含卤素有机阻燃剂以外的阻燃剂的%,任选地与含卤素的有机阻燃剂组合,条件是(A)中的含卤素的有机阻燃剂的总量与 (B)与(B)中其他阻燃剂的量为0.4〜1.5; (e)0.01〜1.5重量% %的有机金属催化剂或其与​​叔胺催化剂的混合物; 和(f)0〜15wt。 %的添加剂,其中组分(B)(a)至(B)(f)的量相对于组分(B)(a)至(B)(e)的总量。 本发明还涉及这种阻燃聚氨酯体系和所得聚氨酯的喷涂方法。
    • 2. 发明授权
    • Method for the repair of existing manholes using elastomeric materials
    • 使用弹性体材料修复现有检修孔的方法
    • US5405218A
    • 1995-04-11
    • US878943
    • 1992-05-05
    • Peter K. Hyde-Smith
    • Peter K. Hyde-Smith
    • E02D29/12E03F5/02
    • E03F5/024E02D29/12E02D29/124E02D29/125E03F5/02E03F5/025
    • This invention relates to a method of repairing existing manholes and similar structures by applying a fast-curing elastomeric material using spray techniques whereby a homogeneous, non-porous, and monolithic coating or lining is formed. The fast-curing elastomeric material can be applied directly to existing concrete, brick, tile, mortar, and metal surfaces normally found in sewer manholes and catch basins, sewer and drainage pipes, parking decks, bridge piers and footings, holding ponds, bridge trusses, culverts, gratings, and the like and does not require any formwork. The elastomeric coatings provide effective surface protection against wear, corrosion, and water infiltration and can be applied in a single operation to horizontal, vertical, and overhead surfaces. The elastomeric materials are prepared by initiating the reaction of an isocyanate-terminated compound or polymer with an amine-terminated polymer or an aliphatic or aromatic diamine immediately before applying the elastomeric material to the surface to be coated. Preferably the reactive components (i.e., isocyanate-containing and amine-containing materials) are mixed directly in the spray gun used to apply the elastomeric material.
    • 本发明涉及通过使用喷雾技术应用快速固化的弹性体材料来修复现有的人孔和类似结构的方法,由此形成均匀的,无孔的和整体的涂层或衬里。 快速固化的弹性材料可以直接应用于现有的混凝土,砖瓦,砂浆和金属表面,通常位于下水道人孔和捕集池,下水道和排水管,停放甲板,桥墩和基座,持有池塘,桥桁架 ,涵洞,格栅等,不需要任何模板。 弹性体涂层提供有效的表面防护,防止磨损,腐蚀和水分渗透,并且可以在单个操作中应用于水平,垂直和顶部表面。 在将弹性体材料施加到待涂覆的表面之前,通过引发异氰酸酯封端的化合物或聚合物与胺封端的聚合物或脂族或芳族二胺的反应来制备弹性体材料。 优选地,反应性组分(即,含异氰酸酯和含胺材料)直接混合在用于施加弹性体材料的喷枪中。
    • 3. 发明授权
    • Method for the repair of existing manholes using elastomeric materials
    • 使用弹性体材料修复现有检修孔的方法
    • US5415499A
    • 1995-05-16
    • US138786
    • 1993-10-19
    • Peter K. Hyde-SmithYeara Houvras
    • Peter K. Hyde-SmithYeara Houvras
    • E02D29/12E03F5/02
    • E03F5/024E02D29/12E02D29/124E02D29/125E03F5/02E03F5/025
    • This invention relates to a method of repairing existing manholes and similar structures by applying a fast-curing elastomeric material using spray techniques whereby a homogeneous, non-porous, and monolithic coating or lining is formed. The fast-curing elastomeric material can be applied directly to existing substrates, which may comprise of concrete, brick, tile, mortar, and metal surfaces normally found in sewer manholes and catch basins, sewer and drainage pipes, parking decks, bridge piers and footings, holding ponds, bridge trusses, culverts, gratings, and the like and does not require any formwork. More preferably, the substrate surfaces are first cleaned and primed to improve the bond of elastomeric coating to the substrate. The most preferred primer is an aqueous solution of silane, preferably containing 10% to 30% silane. The elastomeric coatings provide effective surface protection against water infiltration, wear, and corrosion and can be applied in a single operation to horizontal, vertical, and overhead surfaces. The elastomeric materials are prepared by initiating the reaction of an isocyanate-terminated compound or polymer with an amine-terminated polymer or an aliphatic or aromatic diamine immediately before applying the elastomeric material to the surface to be coated. Preferably the reactive component (i.e., isocyante-containing and amine-containing materials) are mixed directly in the spray gun used to apply the elastomeric material.
    • 本发明涉及通过使用喷雾技术应用快速固化的弹性体材料来修复现有的人孔和类似结构的方法,由此形成均匀的,无孔的和整体的涂层或衬里。 快速固化的弹性体材料可以直接施加到现有的基材上,这些基材可以包括通常在下水道检修孔和捕集池,下水道和排水管,停车场,桥墩和脚下的混凝土,砖,瓦,砂浆和金属表面 ,持有池塘,桥梁桁架,涵洞,格栅等,不需要任何模板。 更优选地,首先清洁和引发基底表面以改善弹性体涂层与基底的结合。 最优选的底漆是硅烷的水溶液,优选含有10%至30%的硅烷。 弹性体涂层提供有效的表面防护,防止水渗入,磨损和腐蚀,并且可以在单个操作中应用于水平,垂直和顶部表面。 在将弹性体材料施加到待涂覆的表面之前,通过引发异氰酸酯封端的化合物或聚合物与胺封端的聚合物或脂族或芳族二胺的反应来制备弹性体材料。 优选地,反应性组分(即含异氰酸酯和含胺材料)直接混合在用于施加弹性体材料的喷枪中。