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1. 发明申请

US20060131209A1 Integrated alkylation process using ionic liquid catalysts 有权
标题翻译：使用离子液体催化剂的综合烷基化方法
公开(公告)号：US20060131209A1
公开(公告)日：2006-06-22
申请号：US11021167
申请日：2004-12-21
申请人： Hye Kyung Timken , Saleh Elomari , Steve Trumbull , Robert Cleverdon
发明人： Hye Kyung Timken , Saleh Elomari , Steve Trumbull , Robert Cleverdon
IPC分类号： C10L1/04 , C07C2/56
CPC分类号： C10L1/06 , C10G29/205 , C10G50/00 , C10G2300/1081 , C10G2300/1088 , C10G2400/02
摘要： An integrated refining process for the production of high quality gasoline blending components from low value components is disclosed. In addition there is disclosed a method of improving the operating efficiency of a refinery by reducing fuel gas production and simultaneously producing high quality gasoline blending components of low volatility. The processes involve the alkylation of a refinery stream containing pentane with ethylene using an ionic liquid catalyst.
摘要翻译：公开了一种用于从低价值部件生产高质量汽油混合组分的综合精炼方法。此外，还公开了通过降低燃料气体生产并同时生产低挥发性的高品质汽油调和组分来提高炼油厂的运行效率的方法。该方法涉及使用离子液体催化剂烷基化含有乙烯的戊烷的精炼料流。

2. 发明申请

US20060135839A1 Alkylation process using chloroaluminate ionic liquid catalysts 有权
标题翻译：使用氯铝酸盐离子液体催化剂的烷基化方法
公开(公告)号：US20060135839A1
公开(公告)日：2006-06-22
申请号：US11021165
申请日：2004-12-21
申请人： Saleh Elomari , Steve Trumbull , Hye Kyung Timken , Robert Cleverdon
发明人： Saleh Elomari , Steve Trumbull , Hye Kyung Timken , Robert Cleverdon
IPC分类号： C07C2/58
CPC分类号： C10G29/205 , C07C2/58 , C10G50/00 , C07C9/16
摘要： A process for the production of a high quality gasoline blending components from refinery process streams by the alkylation of light isoparaffins with olefins using an ionic liquid catalyst is disclosed. The process includes reacting a refinery stream containing isopentane and/or isobutane with a refinery stream containing ethylene and/or propylene and butylenes under alkylation conditions in the presence of a chloroaluminate ionic liquid catalyst comprising a hydrocarbyl substituted pyridinium halide or a hydrocarbyl substituted imidazolium halide of the general formulas A and B, respectively. Where R=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a halide and preferably a chloride, and R1 and R2=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and where R1 and R2 may or may not be the same.
摘要翻译：公开了一种通过使用离子液体催化剂通过烯烃使轻质异链烷烃烷基化从炼厂工艺流中生产高品质汽油调和组分的方法。该方法包括在烷基化条件下，在氯铝酸盐离子液体催化剂存在下使包含异戊烷和/或异丁烷的炼油厂物流与含有乙烯和/或丙烯和丁烯的炼油厂物流反应，所述氯铝酸盐离子液体催化剂包含烃基取代的吡啶鎓卤化物或烃基取代的咪唑鎓卤化物分别是通式A和B。其中R = H，甲基，乙基，丙基，丁基，戊基或己基，X是卤化物，优选氯化物，R1和R2 = H，甲基，乙基，丙基，丁基，戊基或己基，其中R1和 R2可能或可能不一样。

3. 发明申请

US20050124485A1 Gasoline sulfur reduction in fluid catalytic cracking 有权
标题翻译：汽油硫化液流化催化裂化
公开(公告)号：US20050124485A1
公开(公告)日：2005-06-09
申请号：US11013708
申请日：2004-12-16
申请人： Arthur Chester , Hye Kyung Timken , Terry Roberie , Michael Ziebarth
发明人： Arthur Chester , Hye Kyung Timken , Terry Roberie , Michael Ziebarth
IPC分类号： C10G35/085 , B01J29/00 , B01J29/03 , B01J29/06 , B01J29/072 , B01J29/076 , B01J29/08 , B01J29/14 , B01J29/16 , B01J29/24 , B01J29/26 , B01J29/40 , B01J29/46 , B01J29/48 , B01J29/70 , B01J29/76 , B01J29/78 , B01J29/84 , B01J29/88 , C01B39/00 , C10G11/00 , C10G11/05 , C10G11/18 , C10G25/05 , C10G45/04 , C10G55/06
CPC分类号： C10G11/05 , B01J29/0308 , B01J29/0333 , B01J29/072 , B01J29/076 , B01J29/088 , B01J29/146 , B01J29/166 , B01J29/24 , B01J29/405 , B01J29/46 , B01J29/48 , B01J29/7057 , B01J29/7088 , B01J29/7615 , B01J29/7638 , B01J29/7676 , B01J29/7815 , B01J29/7838 , B01J29/7876 , B01J29/84 , B01J29/88 , B01J2229/42
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction additive comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve. The molecular sieve is normally a large pore size zeolite such as USY or zeolite beta or an intermediate pore size zeolite such as ZSM-5. The metal is normally a metal of Period 3 of the Periodic Table, preferably zinc or vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
摘要翻译：催化裂化过程的液体裂解产物，特别是裂化汽油的硫含量通过使用包含多孔分子筛的硫还原添加剂而减少，该多孔分子筛在孔结构内部含有高于零的氧化态的金属的筛子。分子筛通常是大孔的沸石，例如USY或沸石β或中等孔径的沸石如ZSM-5。金属通常是元素周期3的金属，优选锌或钒。硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

4. 发明授权

US08772035B2 Process for controlling ionic liquid catalyst activity by titration 有权
标题翻译：通过滴定控制离子液体催化剂活性的方法
公开(公告)号：US08772035B2
公开(公告)日：2014-07-08
申请号：US13008662
申请日：2011-01-18
申请人： Hye Kyung Timken , Annie T. Pathiparampil
发明人： Hye Kyung Timken , Annie T. Pathiparampil
IPC分类号： G01N31/00 , G01N31/10 , G01N31/16 , B01J27/125 , B01J27/06 , B01J31/00
CPC分类号： G01N31/10 , B01J27/06 , B01J27/125 , B01J31/00 , B01J31/0284 , B01J31/40 , C07C2/58 , C10G11/02 , C10G29/06 , C10G29/205 , C10G50/00 , G01N31/16 , Y02P20/584 , Y10T436/145555 , C07C9/16
摘要： A process for determining ionic liquid catalyst deactivation including (a) collecting at least one sample of an ionic liquid catalyst; (b) hydrolyzing the at least one sample to provide at least one hydrolyzed sample; (c) titrating the at least one hydrolyzed sample with a basic reagent to determine a volume of the basic reagent necessary to neutralize a Lewis acid species of the ionic liquid catalyst; and (d) calculating the acid content of the at least one sample from the volume of basic reagent determined in step (c) is described. Processes incorporating such a process for determining ionic liquid catalyst deactivation are also described. These processes are an alkylation process, a process for controlling ionic liquid catalyst activity in a reaction producing by-product conjunct polymers, and a continuous process for maintaining the acid content of an ionic liquid catalyst at a target acid content in a reaction producing by-product conjunct polymers.
摘要翻译：一种用于测定离子液体催化剂失活的方法，包括（a）收集至少一种离子液体催化剂样品; （b）水解所述至少一种样品以提供至少一种水解样品; （c）用碱性试剂滴定至少一种水解样品以确定中和离子液体催化剂的路易斯酸物质所需的碱性试剂的体积; 并且（d）描述从步骤（c）中确定的碱性试剂的体积计算至少一种样品的酸含量。还描述了结合这种用于确定离子液体催化剂失活的方法的方法。这些方法是烷基化方法，用于控制产生副产物结合聚合物的反应中的离子液体催化剂活性的方法，以及在反应生成副产物的反应中将离子液体催化剂的酸含量保持在目标酸含量的连续方法，产品结合聚合物。

5. 发明申请

US20120325724A1 RECOVERY OF ALKYL CHLORIDE ADSORBTION CAPACITY BY BASIC SOLUTION TREATMENT OF SPENT ADSORBENT 审中-公开
标题翻译：通过基本溶液处理氯化钠吸附容量来回收吸附剂
公开(公告)号：US20120325724A1
公开(公告)日：2012-12-27
申请号：US13169695
申请日：2011-06-27
申请人： Michael S. Driver , Hye Kyung Timken
发明人： Michael S. Driver , Hye Kyung Timken
IPC分类号： C10G25/12 , B01J38/64
CPC分类号： B01J31/0284 , C10G25/00 , C10G25/12 , C10G29/205 , C10G29/26 , C10G2300/1081 , C10G2300/1088 , C10G2300/4018 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： Processes for the rejuvenation of a spent adsorbent, wherein the adsorption capacity of the spent adsorbent may be repeatedly restored by treating the spent adsorbent with a basic solution and subsequent adsorbent activation, thereby allowing a plurality of adsorption cycles using a single adsorbent sample. Processes for ionic liquid catalyzed hydrocarbon conversion and hydrocarbon product purification are also disclosed.
摘要翻译：废吸附剂的再生方法，其中可以通过用碱性溶液处理废吸附剂和随后的吸附剂活化来重复地恢复废吸附剂的吸附能力，从而允许使用单个吸附剂样品的多个吸附循环。还公开了用于离子液体催化的烃转化和烃产物纯化的方法。

6. 发明申请

US20110183423A1 PROCESS FOR CONTROLLING IONIC LIQUID CATALYST ACTIVITY BY TITRATION 有权
标题翻译：控制离子液体催化剂活性的方法
公开(公告)号：US20110183423A1
公开(公告)日：2011-07-28
申请号：US13008662
申请日：2011-01-18
申请人： Hye Kyung Timken , Annie T. Pathiparampil
发明人： Hye Kyung Timken , Annie T. Pathiparampil
IPC分类号： G01N31/16
CPC分类号： G01N31/10 , B01J27/06 , B01J27/125 , B01J31/00 , B01J31/0284 , B01J31/40 , C07C2/58 , C10G11/02 , C10G29/06 , C10G29/205 , C10G50/00 , G01N31/16 , Y02P20/584 , Y10T436/145555 , C07C9/16
摘要： A process for determining ionic liquid catalyst deactivation including (a) collecting at least one sample of an ionic liquid catalyst; (b) hydrolyzing the at least one sample to provide at least one hydrolyzed sample; (c) titrating the at least one hydrolyzed sample with a basic reagent to determine a volume of the basic reagent necessary to neutralize a Lewis acid species of the ionic liquid catalyst; and (d) calculating the acid content of the at least one sample from the volume of basic reagent determined in step (c) is described. Processes incorporating such a process for determining ionic liquid catalyst deactivation are also described. These processes are an alkylation process, a process for controlling ionic liquid catalyst activity in a reaction producing by-product conjunct polymers, and a continuous process for maintaining the acid content of an ionic liquid catalyst at a target acid content in a reaction producing by-product conjunct polymers.
摘要翻译：一种用于测定离子液体催化剂失活的方法，包括（a）收集至少一种离子液体催化剂样品; （b）水解所述至少一种样品以提供至少一种水解样品; （c）用碱性试剂滴定至少一种水解样品以确定中和离子液体催化剂的路易斯酸物质所需的碱性试剂的体积; 并且（d）描述从步骤（c）中确定的碱性试剂的体积计算至少一种样品的酸含量。还描述了结合这种用于确定离子液体催化剂失活的方法的方法。这些方法是烷基化方法，用于控制产生副产物结合聚合物的反应中的离子液体催化剂活性的方法，以及在反应生成副产物的反应中将离子液体催化剂的酸含量保持在目标酸含量的连续方法，产品结合聚合物。

7. 发明申请

US20120167766A1 Process for the separation of carbon dioxide from flue gas 有权
标题翻译：从烟道气中分离二氧化碳的方法
公开(公告)号：US20120167766A1
公开(公告)日：2012-07-05
申请号：US12930207
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, JR. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, JR. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： B01D53/18 , B01D53/14
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1481 , B01D2252/103 , B01D2252/30 , B01D2258/0233 , B01D2258/025 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A process and system for separating CO2 from a flue gas stream is disclosed. The process involves (a) contacting a flue gas stream containing water vapor and CO2 with an ionic absorbent under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-absorbent complex; wherein the ionic absorbent comprises a cation and an anion comprising an amine moiety; and (b) recovering a gaseous product having a reduced CO2 content.
摘要翻译：公开了一种用于从烟道气流中分离CO 2的方法和系统。该方法包括（a）在吸收条件下使含有水蒸气和CO 2的烟道气与离子吸收剂接触，以从烟道气流吸收至少一部分CO 2并形成CO 2吸收复合物; 其中所述离子吸收剂包含阳离子和包含胺部分的阴离子; 和（b）回收具有降低的CO 2含量的气态产物。

8. 发明申请

US20050124490A1 Homogeneous modified-alumina fischer-tropsch catalyst supports 有权
标题翻译：均相改性氧化铝费 - 托催化剂载体
公开(公告)号：US20050124490A1
公开(公告)日：2005-06-09
申请号：US10728641
申请日：2003-12-05
申请人： Hye Kyung Timken
发明人： Hye Kyung Timken
IPC分类号： B01J21/12 , B01J23/40 , B01J23/74 , B01J23/745 , B01J23/75 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/03 , C01F7/02 , C01F7/34 , C10G2/00
CPC分类号： B01J23/40 , B01J21/12 , B01J23/74 , B01J23/745 , B01J23/75 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0045 , B01J37/036 , C01F7/02 , C01F7/34 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C10G2/33 , C10G2/332
摘要： A homogeneous, amorphous catalyst support comprising a modifying-metal-oxide and a base-metal oxide, the catalyst support having a Surface to Bulk modifying-metal/base-metal atomic ratio of from about 0.6 to about 1.3 and exhibiting an X-ray diffraction having broader line width and lower intensity than is exhibited by the base-metal oxide is disclosed. More specifically, a homogeneous, amorphous silica-modified-Alumina catalyst support useful in the Fischer-Tropsch process is disclosed. A silica-modified-Alumina catalyst support of the present invention maintains the desirable properties of alumina and exhibits higher resistance to acid than unmodified alumina.
摘要翻译：包含改性金属氧化物和贱金属氧化物的均匀的无定形催化剂载体，所述催化剂载体具有约0.6至约1.3的表面与体系改性金属/碱金属原子比，并显示X射线公开了具有比基础金属氧化物显示的更宽的线宽度和更低的强度的衍射。更具体地，公开了用于费 - 托方法的均匀的无定形二氧化硅改性的氧化铝催化剂载体。本发明的二氧化硅改性氧化铝催化剂载体保持氧化铝的期望性能，并且比未改性的氧化铝显示出更高的耐酸性。

9. 发明授权

US09180403B2 Aqueous solutions of amine functionalized ionic compounds for carbon capture processes 有权
标题翻译：用于碳捕获过程的胺官能化离子化合物的水溶液
公开(公告)号：US09180403B2
公开(公告)日：2015-11-10
申请号：US12930208
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： C07C211/62 , C07C211/63 , C07C211/64 , B01D53/14
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D53/78 , B01D2252/204 , B01D2252/2056 , B01D2252/30 , B01D2252/502 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： An aqueous ionic absorbent solution is disclosed containing (a) about 15 wt. % to about 80 wt. % of one or more diluents, based on the total weight of the aqueous ionic absorbent solution; and (b) an ionic absorbent containing a cation and an anion comprising an amine moiety.
摘要翻译：公开了一种含水离子吸收剂溶液，其包含（a）约15重量％％至约80wt。％的一种或多种稀释剂，基于含水离子吸收剂溶液的总重量; 和（b）含有阳离子和含有胺部分的阴离子的离子吸收剂。

10. 发明授权

US08911539B2 Process for the separation of carbon dioxide from flue gas 有权
标题翻译：从烟道气中分离二氧化碳的方法
公开(公告)号：US08911539B2
公开(公告)日：2014-12-16
申请号：US12930207
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： B01D53/14 , B01D53/18
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1481 , B01D2252/103 , B01D2252/30 , B01D2258/0233 , B01D2258/025 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A process and system for separating CO2 from a flue gas stream is disclosed. The process involves (a) contacting a flue gas stream containing water vapor and CO2 with an ionic absorbent under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-absorbent complex; wherein the ionic absorbent comprises a cation and an anion comprising an amine moiety; and (b) recovering a gaseous product having a reduced CO2 content.
摘要翻译：公开了一种用于从烟道气流中分离CO 2的方法和系统。该方法包括（a）在吸收条件下使含有水蒸气和CO 2的烟道气与离子吸收剂接触，以从烟道气流吸收至少一部分CO 2并形成CO 2吸收复合物; 其中所述离子吸收剂包含阳离子和包含胺部分的阴离子; 和（b）回收具有降低的CO 2含量的气态产物。

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