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1. 发明申请

US20110065948A1 Nanosized Copper Catalyst Precursors For The Direct Synthesis Of Trialkoxysilanes 有权
标题翻译：用于直接合成三烷氧基硅烷的纳米铜催化剂前体
公开(公告)号：US20110065948A1
公开(公告)日：2011-03-17
申请号：US12950445
申请日：2010-11-19
申请人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
发明人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
IPC分类号： C07F7/04
CPC分类号： C07F7/025 , B01J23/72
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 60 nanometers, preferably from about 0.1 to about 30 nanometers, and most preferably from about 0.1 to about 15 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
摘要翻译：本发明提供了在直接合成式HSi（OR）3的三烷氧基硅烷中使用纳米尺寸铜，纳米尺寸铜氧化物，纳米尺寸氯化铜，其它纳米铜盐及其混合物作为催化铜的来源的方法，其中R为含有1〜6个碳原子的烷基。本发明的纳米尺寸的铜，纳米尺寸的氧化铜，纳米尺寸的氯化铜，其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约60纳米，优选为约0.1至约30纳米，最优选约0.1至约15纳米。催化铜的纳米化来源提供了硅上催化位点的高分散性，有助于高反应速率，高选择性和高硅转化率。与常规实践相比，本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

2. 发明授权

US08513449B2 Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes 有权
标题翻译：用于直接合成三烷氧基硅烷的纳米铜催化剂前体
公开(公告)号：US08513449B2
公开(公告)日：2013-08-20
申请号：US12950445
申请日：2010-11-19
申请人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
发明人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
IPC分类号： C07F7/04
CPC分类号： C07F7/025 , B01J23/72
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 60 nanometers, preferably from about 0.1 to about 30 nanometers, and most preferably from about 0.1 to about 15 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
摘要翻译：本发明提供了在直接合成式HSi（OR）3的三烷氧基硅烷中使用纳米尺寸铜，纳米尺寸铜氧化物，纳米尺寸氯化铜，其它纳米铜盐及其混合物作为催化铜的来源的方法，其中R为含有1〜6个碳原子的烷基。本发明的纳米尺寸的铜，纳米尺寸的氧化铜，纳米尺寸的氯化铜，其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约60纳米，优选为约0.1至约30纳米，最优选约0.1至约15纳米。催化铜的纳米化来源提供了硅上催化位点的高分散性，有助于高反应速率，高选择性和高硅转化率。与常规实践相比，本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

3. 发明授权

US07858818B2 Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes 有权
标题翻译：用于直接合成三烷氧基硅烷的纳米铜催化剂前体
公开(公告)号：US07858818B2
公开(公告)日：2010-12-28
申请号：US11804952
申请日：2007-05-21
申请人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
发明人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Mereigh , Chi-Lin O'Young , Hua Yu
IPC分类号： C07F7/04
CPC分类号： C07F7/025 , B01J23/72
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 60 nanometers, preferably from about 0.1 to about 30 nanometers, and most preferably from about 0.1 to about 15 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
摘要翻译：本发明提供了在直接合成式HSi（OR）3的三烷氧基硅烷中使用纳米尺寸铜，纳米尺寸铜氧化物，纳米尺寸氯化铜，其它纳米铜盐及其混合物作为催化铜的来源的方法，其中R为含有1〜6个碳原子的烷基。本发明的纳米尺寸的铜，纳米尺寸的氧化铜，纳米尺寸的氯化铜，其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约60纳米，优选为约0.1至约30纳米，最优选约0.1至约15纳米。催化铜的纳米化来源提供了硅上催化位点的高分散性，有助于高反应速率，高选择性和高硅转化率。与常规实践相比，本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

4. 发明授权

US07087100B2 Preparation of nanosized copper and copper compounds 有权
公开(公告)号：US07087100B2
公开(公告)日：2006-08-08
申请号：US09974503
申请日：2001-10-09
申请人： Kenrick M. Lewis , Hua Yu , Regina Nelson Eng , Sabrina R. Cromer , Chi-Lin O'Young , Abellard T. Mereigh
发明人： Kenrick M. Lewis , Hua Yu , Regina Nelson Eng , Sabrina R. Cromer , Chi-Lin O'Young , Abellard T. Mereigh
IPC分类号： B22F9/30 , C22B15/00 , C22B23/00 , C22B25/00
CPC分类号： B82Y30/00 , B22F1/0018 , B22F9/24 , B22F2001/0033 , B22F2001/0037 , C01B13/14 , C01B13/185 , C01G1/02 , C01G3/02 , C01P2004/10 , C01P2004/20 , C01P2004/40 , C01P2004/53 , C01P2004/62 , C01P2004/64 , C01P2006/60
摘要： The present invention is a process for producing nanosized metal compounds. The preferred product is nanosized copper, nanosized copper (I) oxide, and nanosized copper (II) oxide. The process includes heating a copper metal precursor in a hydrocarbon preferably selected from alkylated benzenes, polyaromatic hydrocarbons, paraffins and/or naphthenic hydrocarbons. The heating is desirably at a temperature and time effective to convert, for example, the copper metal precursor to nanosized copper (II) oxide, nanosized copper (I) oxide and/or nanosized copper metal. Separation of the hydrocarbon is then performed. Recovering the solid product and recycle/reuse of the recovered hydrocarbon in subsequent preparations of nanosized metal and metal oxides may be performed. The nanosized metal oxides of the invention may additionally be converted to nanosized metal salts by reaction with the appropriate acids while dispersed in the hydrocarbons.

5. 发明授权

US07495120B2 Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes 有权
标题翻译：用于直接合成三烷氧基硅烷的纳米铜催化剂前体
公开(公告)号：US07495120B2
公开(公告)日：2009-02-24
申请号：US11975787
申请日：2007-12-17
申请人： Kenrick M. Lewis , Regina Nelson Eng , Sabrina R. Cromer , Abellard T. Mereigh , Chi-Lin O'Young
发明人： Kenrick M. Lewis , Regina Nelson Eng , Sabrina R. Cromer , Abellard T. Mereigh , Chi-Lin O'Young
IPC分类号： C07F7/04
CPC分类号： C07F7/025
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 600 nanometers, preferably from about 0.1 to about 500 nanometers, and most preferably from about 0.1 to about 100 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
摘要翻译：本发明提供了在直接合成式HSi（OR）3的三烷氧基硅烷中使用纳米尺寸铜，纳米尺寸铜氧化物，纳米尺寸氯化铜，其它纳米铜盐及其混合物作为催化铜的来源的方法，其中R为含有1〜6个碳原子的烷基。本发明的纳米尺寸的铜，纳米尺寸的氧化铜，纳米尺寸的氯化铜，其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约600纳米，优选为约0.1至约500纳米，最优选约0.1至约100纳米。催化铜的纳米化来源提供了硅上催化位点的高分散性，并且有助于高反应速率，高选择性和高硅转化率。与常规实践相比，本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

6. 发明授权

US07339068B2 Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes 有权
公开(公告)号：US07339068B2
公开(公告)日：2008-03-04
申请号：US09974092
申请日：2001-10-09
申请人： Kenrick M. Lewis , Regina Nelson Eng , Sabrina R. Cromer , Abellard T. Mereigh , Chi-Lin O'Young
发明人： Kenrick M. Lewis , Regina Nelson Eng , Sabrina R. Cromer , Abellard T. Mereigh , Chi-Lin O'Young
IPC分类号： C07F7/04
CPC分类号： C07F7/025
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 600 nanometers, preferably from about 0.1 to about 500 nanometers, and most preferably from about 0.1 to about 100 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.

7. 发明申请

US20080103323A1 Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes 有权
标题翻译：用于直接合成三烷氧基硅烷的纳米铜催化剂前体
公开(公告)号：US20080103323A1
公开(公告)日：2008-05-01
申请号：US11804952
申请日：2007-05-21
申请人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Merelgh , Chi-Lin O'Young , Hua Yu
发明人： Sabrina R. Cromer , Regina Nelson Eng , Kenrick M. Lewis , Abellard T. Merelgh , Chi-Lin O'Young , Hua Yu
IPC分类号： C07F7/02
CPC分类号： C07F7/025 , B01J23/72
摘要： The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR)3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 60 nanometers, preferably from about 0.1 to about 30 nanometers, and most preferably from about 0.1 to about 15 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.
摘要翻译：本发明提供了在式HSi（OR）3的三烷氧基硅烷的直接合成中使用纳米尺寸铜，纳米尺寸铜氧化物，纳米尺寸氯化铜，其它纳米铜盐及其混合物作为催化铜的来源的方法其中R是包含1至6个碳原子的烷基。本发明的纳米尺寸的铜，纳米尺寸的氧化铜，纳米尺寸的氯化铜，其他的纳米级铜盐及其混合物的平均粒度范围为约0.1至约60纳米，优选为约0.1至约30纳米，最优选约0.1至约15纳米。催化铜的纳米化来源提供了硅上催化位点的高分散性，有助于高反应速率，高选择性和高硅转化率。与常规实践相比，本发明的纳米尺寸铜催化剂前体允许使用显着降低的铜含量。

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