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1. 发明申请

US20170267812A1 Process to Prepare a Polyester Polymer Composition Comprising a Polyester Polymer Having Furanic Units and a Polyester Polymer Composition Obtainable Thereby and the Use Thereof 审中-公开
公开(公告)号：US20170267812A1
公开(公告)日：2017-09-21
申请号：US15478984
申请日：2017-04-04
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Philip Nising , Francesca Tancini , David Pfister , Giuseppe Storti , Massimo Morbidelli
IPC分类号： C08G63/78 , C08G63/83 , C08G63/84 , B29C49/00 , C08G63/91 , B29C45/00 , B29C47/00 , C08G63/181 , C08G63/85
CPC分类号： C08G63/78 , B29C45/0001 , B29C48/022 , B29C49/0005 , B29K2067/00 , C08G63/181 , C08G63/83 , C08G63/84 , C08G63/85 , C08G63/916 , C08L67/02
摘要： A polyester polymer composition having a polyester polymer with furanic units as well as a process to prepare this polyester polymer composition are herein described. The process includes the step of reacting a cyclic polyester oligomer in the presence of a catalyst in a ring-opening polymerization reaction with a reaction temperature and a reaction time sufficient to yield a polyester polymer having furanic units. The present invention further provides a method of use of this polyester polymer composition in extrusion, injection molding, or blow molding.

2. 发明授权

US10059799B2 Method for stabilizing a condensed phase composition including a cyclic ester in a process of manufacturing a polyester or of lactide 有权
公开(公告)号：US10059799B2
公开(公告)日：2018-08-28
申请号：US15510917
申请日：2015-08-19
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Hans-Peter Brack , Francesca Tancini , Yingchuan Yu
IPC分类号： C08G63/02 , C08G63/85 , C08G63/08
CPC分类号： C08G63/78 , C08G63/08 , C08G63/85 , C08G63/90
摘要： A method for stabilizing a condensed phase composition in a process of manufacturing a polyester from cyclic ester monomer comprising the steps of devolatilizing a reaction mixture, which contains i) at least one polymerizable cyclic ester, ii) at least one catalyst and optionally at least one initiator, to produce a vapor stream and a molten residue, wherein the vapor stream includes mainly i) the at least one polymerizable cyclic ester and ii) the at least one catalyst and/or the at least one initiator and/or a reaction product or a residue of the at least one catalyst and/or the at least one initiator and condensing the vapor stream to form the condensed phase composition, wherein at least one polymerization inhibitor is added as stabilizer to the reaction mixture and/or to the condensed phase composition in an amount so that the degree of conversion of the polymerizable cyclic ester in the condensed phase composition is not more than 15%, wherein the degree of conversion is 100▪(c0−CF)/c0, wherein c0 is the initial concentration of the cyclic ester in the condensed phase composition obtained by the condensation of the vapor stream and CF is the concentration of the cyclic ester in the condensed phase composition after addition of 150 ppm of tin octoate as catalyst and of 100 mmol/kg of ethyl-hexanol as initiator to the condensed phase composition and a subsequent heat treatment of condensed phase composition under inert atmosphere conditions for 12 hours at 160° C.

3. 发明授权

US09725558B2 Process to prepare a cyclic oligomer and a cyclic oligomer obtainable thereby 有权
公开(公告)号：US09725558B2
公开(公告)日：2017-08-08
申请号：US14773480
申请日：2013-11-27
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Philip Nising , Francesca Tancini , David Pfister , Giuseppe Storti , Massimo Morbidelli
IPC分类号： C08G63/91 , C08G63/78 , C08G63/181 , C08G63/16
CPC分类号： C08G63/916 , C08G63/16 , C08G63/181 , C08G63/78
摘要： A process to prepare a cyclic polyester oligomer composition having a cyclic polyester oligomer having furanic units, includes the step of reacting a monomer component, for example, 2,5-furan dicarboxylic acid and, for example, ethylene glycol, in a ring closing oligomerization at a reaction temperature and reaction time, for example, at 100° C. to 350° C. for 30 to 600 minutes to obtain a cyclic polyester oligomer having furanic units. The process yields a cyclic polyester oligomer composition which can be used in further ring-opening polymerization reactions to produce a polyester polymer. The cyclic polyester oligomer composition has a cyclic polyester oligomer having furanic units and less than 5% linear oligomeric polyester species in the composition.

4. 发明授权

US10377853B2 Process to prepare a polyester polymer composition comprising a polyester polymer having furanic units and a polyester polymer composition obtainable thereby and the use thereof 有权
公开(公告)号：US10377853B2
公开(公告)日：2019-08-13
申请号：US15478984
申请日：2017-04-04
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Philip Nising , Francesca Tancini , David Pfister , Giuseppe Storti , Massimo Morbidelli
IPC分类号： C08G63/78 , C08G63/181 , B29C48/00 , C08G63/83 , C08G63/84 , C08G63/85 , C08L67/02 , B29C45/00 , B29C49/00 , C08G63/91 , B29K67/00
摘要： A process to prepare a polyester polymer composition comprising a polyester polymer having furanic units is disclosed. The process comprises a step of ring-opening polymerization of a cyclic polyester oligomer, which comprises residue of furandicarboxylic acid and a diol, in the presence of a catalyst in order to yield a polyester polymer having furanic units. The polyester polymer composition obtainable by the process, wherein the polyester polymer composition comprises a polyester polymer having furanic units and a cyclic polyester oligomer in a concentration of less than 5 wt % of the composition. The use of the polyester polymer composition in extrusion, injection molding, or blow molding are also disclosed.

5. 发明申请

US20160017093A1 A Process to Prepare a Cyclic Oligomer and a Cyclic Oligomer Obtainable Thereby 有权
标题翻译：制备环状低聚物和由此获得的环状低聚物的方法
公开(公告)号：US20160017093A1
公开(公告)日：2016-01-21
申请号：US14773480
申请日：2013-11-27
申请人： SULZER CHEMTECH AG
发明人： Liborio Ivano Costa , Philip Nising , Francesca Tancini , David Pfister , Giuseppe Storti , Massimo Morbidelli
IPC分类号： C08G63/91 , C08G63/16
CPC分类号： C08G63/916 , C08G63/16 , C08G63/181 , C08G63/78
摘要： A process to prepare a cyclic polyester oligomer composition comprising a cyclic polyester oligomer having furanic units is disclosed. The process comprises the step of reacting a monomer component in the presence of an optional catalyst and/or optional organic base in a ring closing oligomerization step under conditions of a reaction temperature and reaction time sufficient to yield a cyclic polyester oligomer having furanic units. The invention further relates to a cyclic polyester oligomer composition obtainable by said process, wherein the cyclic polyester oligomer composition comprises a cyclic polyester oligomer of structure Y1 or Y2 having furanic units, wherein the composition contains less than 5%, preferably 3, most preferably 1 weight % of linear oligomeric polyester species in the composition. The present invention further relates also to the use of said cyclic polyester oligomer composition in the production of a polyester polymer.
摘要翻译：公开了一种制备包含具有呋喃单元的环状聚酯低聚物的环状聚酯低聚物组合物的方法。该方法包括在反应温度和反应时间足以产生具有呋喃单元的环状聚酯低聚物的条件下，在闭环低聚步骤的任选催化剂和/或任选的有机碱存在下使单体组分反应的步骤。本发明还涉及通过所述方法获得的环状聚酯低聚物组合物，其中环状聚酯低聚物组合物包含具有呋喃单元的结构Y1或Y2的环状聚酯低聚物，其中组合物含有小于5％，优选3，最优选1 组合物中线性低聚物种的重量百分比。本发明还涉及所述环状聚酯低聚物组合物在聚酯聚合物的制备中的用途。

6. 发明授权

US10066054B2 Continuous method for manufacturing a polyester from cyclic ester monomer 有权
公开(公告)号：US10066054B2
公开(公告)日：2018-09-04
申请号：US15510859
申请日：2015-09-03
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Hans-Peter Brack , Francesca Tancini , Yingchuan Yu
IPC分类号： C08G63/02 , C08G63/78 , C08G63/08 , C08G63/90
摘要： A process of manufacturing a polyester from cyclic ester monomer comprises the steps of: a) providing a cyclic ester, b) polymerizing the cyclic ester in the presence of a catalyst and optionally an initiator in a reactor to form a reaction mixture comprising polyester and unreacted cyclic ester, wherein after the polymerization at least one polymerization inhibitor is added to the reaction mixture, wherein the polymerization inhibitor is selected from the group consisting of monoimines, diimines, mono alkyl phosphates according to the formula RPO4H2, wherein R is a C6-16 linear, branched or cyclic alkyl group, di alkyl phosphates according to the formula R2PO4H, wherein each R is independently a C6-16 linear, branched or cyclic alkyl group or a combination thereof, and phosphate esters according to the general formula (I) wherein at least one of R′, R″ and R″′ has the general structure as in general formula (II) wherein n>0 and Q is independently a C1-16 linear, branched or substituted alkyl group, and R is independently an H or linear, branched, cyclic or substituted alkyl group or a phenyl group derivative, and wherein any of R′, R″ and R″′ not having the general structure as in general formula (II) is independently an H or a linear, branched, cyclic or substituted alkyl group or a phenyl group derivative.

7. 发明申请

US20170240700A1 A Method for Stabilizing a Condensed Phase Composition Including a Cyclic Ester in a Process of Manufacturing a Polyester or of Lactide 审中-公开
公开(公告)号：US20170240700A1
公开(公告)日：2017-08-24
申请号：US15510917
申请日：2015-08-19
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Hans-Peter Brack , Francesca Tancini , Yingchuan Yu
IPC分类号： C08G63/85 , C08G63/08
CPC分类号： C08G63/78 , C08G63/08 , C08G63/85 , C08G63/90
摘要： A method for stabilizing a condensed phase composition in a process of manufacturing a polyester from cyclic ester monomer comprising the steps of devolatilizing a reaction mixture, which contains i) at least one polymerizable cyclic ester, ii) at least one catalyst and optionally at least one initiator, to produce a vapor stream and a molten residue, wherein the vapor stream includes mainly i) the at least one polymerizable cyclic ester and ii) the at least one catalyst and/or the at least one initiator and/or a reaction product or a residue of the at least one catalyst and/or the at least one initiator and condensing the vapor stream to form the condensed phase composition, wherein at least one polymerization inhibitor is added as stabilizer to the reaction mixture and/or to the condensed phase composition in an amount so that the degree of conversion of the polymerizable cyclic ester in the condensed phase composition is not more than 15%, wherein the degree of conversion is 100▪ (c0−CF)/c0, wherein c0 is the initial concentration of the cyclic ester in the condensed phase composition obtained by the condensation of the vapor stream and CF is the concentration of the cyclic ester in the condensed phase composition after addition of 150 ppm of tin octoate as catalyst and of 100 mmol/kg of ethyl-hexanol as initiator to the condensed phase composition and a subsequent heat treatment of condensed phase composition under inert atmosphere conditions for 12 hours at 160° C.

8. 发明申请

US20170240697A1 A Continuous Method for Manufacturing a Polyester from Cyclic Ester Monomer 审中-公开
公开(公告)号：US20170240697A1
公开(公告)日：2017-08-24
申请号：US15510859
申请日：2015-09-03
申请人： Sulzer Chemtech AG
发明人： Liborio Ivano Costa , Hans-Peter Brack , Francesca Tancini , Yingchuan Yu
IPC分类号： C08G63/78 , C08G63/90 , C08G63/08
CPC分类号： C08G63/78 , C08G63/08 , C08G63/85 , C08G63/90
摘要： A process of manufacturing a polyester from cyclic ester monomer comprises the steps of: a) providing a cyclic ester, b) polymerizing the cyclic ester in the presence of a catalyst and optionally an initiator in a reactor to form a reaction mixture comprising polyester and unreacted cyclic ester, wherein after the polymerization at least one polymerization inhibitor is added to the reaction mixture, wherein the polymerization inhibitor is selected from the group consisting of monoimines, diimines, mono alkyl phosphates according to the formula RPO4H2, wherein R is a C6-16 linear, branched or cyclic alkyl group, di alkyl phosphates according to the formula R2PO4H, wherein each R is independently a C6-16 linear, branched or cyclic alkyl group or a combination thereof, and phosphate esters according to the general formula (I) wherein at least one of R′, R″ and R″′ has the general structure as in general formula (II) wherein n>0 and Q is independently a C1-16 linear, branched or substituted alkyl group, and R is independently an H or linear, branched, cyclic or substituted alkyl group or a phenyl group derivative, and wherein any of R′, R″ and R″′ not having the general structure as in general formula (II) is independently an H or a linear, branched, cyclic or substituted alkyl group or a phenyl group derivative.

9. 发明申请

US20160002397A1 A Process to Prepare a Polyester Polymer Composition Comprising a Polyester Polymer Having Furanic Units and a Polyester Polymer Composition Obtainable Thereby and the use Thereof 审中-公开
标题翻译：一种制备聚酯聚合物组合物的方法，该聚酯组合物包含具有可获得的呋喃单元和聚酯聚合物组合物的聚酯聚合物及其用途
公开(公告)号：US20160002397A1
公开(公告)日：2016-01-07
申请号：US14772477
申请日：2013-11-27
申请人： SULZER CHEMTECH AG
发明人： Liborio Ivano Costa , Philip Nising , Francesca Tancini , David Pfister , Giuseppeü Storti , Massimo Morbidelli
IPC分类号： C08G63/78 , B29C49/00 , B29C47/00 , B29C45/00 , C08G63/85 , C08G63/91
CPC分类号： C08G63/78 , B29C45/0001 , B29C48/022 , B29C49/0005 , B29K2067/00 , C08G63/181 , C08G63/83 , C08G63/84 , C08G63/85 , C08G63/916 , C08L67/02
摘要： A process to prepare a polyester polymer composition comprising a polyester polymer having furanic units is disclosed. The process comprises the step of reacting a cyclic polyester oligomer in the presence of a catalyst in a ring-opening polymerization step under conditions of a reaction temperature and reaction time sufficient to yield a polyester polymer having furanic units. The invention further relates to a polyester polymer composition obtainable by said process, wherein the polyester polymer composition comprises a polyester polymer having furanic units and a cyclic polyester oligomer comprising either structure Y1 or Y2, preferably in a concentration of less than 5 wt %, more preferably less than 1, more preferably less than 0.5 in the composition. The present invention further relates also to the use of said polyester polymer composition in extrusion, injection molding, or blow molding.
摘要翻译：公开了一种制备包含具有呋喃单元的聚酯聚合物的聚酯聚合物组合物的方法。该方法包括在反应温度和反应时间足以产生具有呋喃单元的聚酯聚合物的条件下，在开环聚合步骤的催化剂存在下使环状聚酯低聚物反应的步骤。本发明还涉及通过所述方法获得的聚酯聚合物组合物，其中聚酯聚合物组合物包含具有呋喃单元的聚酯聚合物和包含结构Y1或Y2的环状聚酯低聚物，优选浓度小于5wt％，更多优选小于1，更优选小于0.5。本发明还涉及所述聚酯聚合物组合物在挤出，注射成型或吹塑中的用途。

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