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1. 发明申请

US20180312649A1 HYBRID FLUOROPOLYMER COMPOSITES 审中-公开
公开(公告)号：US20180312649A1
公开(公告)日：2018-11-01
申请号：US16028152
申请日：2018-07-05
申请人： SOLVAY SA , COMMISSARIAT A L ' ENERGIE ATOMIQUE ET AUX ENERGIES AL TERNATIVES
发明人： Jean-Baptiste DUCROS , Aurelie LAVIE-CAMBOT , Lionel PICARD , Olivier PRAS , Helene ROUAULT , Christine HAMON , Julio A. ABUSLEME
IPC分类号： C08J5/22 , C08G18/62 , H01M10/0565 , H01M10/0525 , H01G11/56 , H01G11/06 , C08G18/71
CPC分类号： C08J5/2237 , C08F214/225 , C08G18/6229 , C08G18/6279 , C08G18/718 , C08J2327/22 , H01G11/06 , H01G11/56 , H01M10/0525 , H01M10/0565 , H01M2300/0082 , Y02E60/13 , C08F220/20 , C08F214/285
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a process for manufacturing said fluoropolymer hybrid organic/inorganic composite and films and membranes thereof and to uses of said fluoropolymer hybrid organic/inorganic composite and films and membranes thereof in various applications.

2. 发明申请

US20190252657A1 FLUOROPOLYMER MEMBRANE FOR ELECTROCHEMICAL DEVICES 审中-公开
公开(公告)号：US20190252657A1
公开(公告)日：2019-08-15
申请号：US16310412
申请日：2017-06-13
申请人： SOLVAY SA , COMMISSARIAT A L' ENERGIE ATOMIQUE ET AUX ENERGIES AL TERNATIVES
发明人： Julio A. ABUSLEME , Marc-David BRAIDA , Christine HAMON , Hélène ROUAULT , Djamel MOURZAGH , Gaëlle BESNARD , Daniel TOMASI
IPC分类号： H01M2/14 , H01M2/16 , H01M10/0525 , H01M4/66 , C08F20/06 , C08F14/22 , B01D69/14 , B01D71/32
CPC分类号： H01M2/145 , B01D67/0079 , B01D69/148 , B01D71/32 , C08F14/22 , C08F20/06 , C08F214/225 , C08J5/225 , C08J2327/16 , H01M2/166 , H01M4/668 , H01M10/0525 , H01M2004/028 , H01M2004/029
摘要： The present invention pertains to a membrane for an electrochemical device, to a process for manufacturing said membrane and to use of said membrane in a process for manufacturing an electrochemical device.

3. 发明申请

US20210408574A1 FLUOROPOLYMER HYBRID COMPOSITE 有权
公开(公告)号：US20210408574A1
公开(公告)日：2021-12-30
申请号：US17297028
申请日：2019-12-16
申请人： SOLVAY SA , Politecnico di Torino
发明人： Alberto FRACHE , Silvia SANTANGELETTA , Daniele BATTEGAZZORE , Julio A. ABUSLEME , Christine HAMON , Giambattista BESANA , Ségolène BRUSSEAU
IPC分类号： H01M10/056
摘要： The invention pertains to a process for the manufacture of a polymer electrolyte based on a fluoropolymer hybrid organic/inorganic composite, to a polymer electrolyte obtained thereof and to uses of said polymer electrolyte and membranes obtained therefrom in various applications, especially in electrochemical and in photo-electrochemical applications.

4. 发明申请

US20160204405A1 SOLID COMPOSITE FLUOROPOLYMER SEPARATOR 审中-公开
标题翻译：固体复合荧光聚合物分离器
公开(公告)号：US20160204405A1
公开(公告)日：2016-07-14
申请号：US14911356
申请日：2014-08-05
申请人： SOLVAY SA
发明人： Christine HAMON , Milena STANGA , Riccardo PIERI
IPC分类号： H01M2/14 , H01M10/0525 , H01M2/16
摘要： The present invention pertains to a process for manufacturing a solid composite separator, said process comprising the following steps: (i) providing a liquid composition [composition (L)] comprising, preferably consisting of: at least one fluoro-polymer [polymer (F)] comprising one or more backbone chains, said backbone chains comprising recurring units derived from at least one fluorinated monomer [monomer (F)], and one or more side functional groups selected from the group consisting of —O—Rx and —C(O)O—Rx groups, wherein Rx is a hydrogen atom or a C1-C5 hydrocarbon group comprising at least one hydroxyl group, optionally, at least one metal compound of formula (I) [compound (M)]: X4-mAYm wherein X is a hydrocarbon group, optionally comprising one or more functional groups, m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, and Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, at least one inorganic filler [filler (I)], and a liquid medium [medium (L)]; (ii) providing a porous substrate layer made from one or more sets of polymer fibres [substrate (P)]; (iii) applying the composition (L) onto the substrate (P) thereby providing a wet substrate (P) [substrate (P—W)]; (iv) drying and then, optionally, curing the substrate (P—W) provided in step (iii) thereby providing a solid composite separator; and (v) optionally, submitting to compression the solid composite separator provided in step (iv). The present invention also pertains to the solid composite separator obtainable by said process and to use of the solid composite separator in electrochemical devices.
摘要翻译：本发明涉及一种制备固体复合隔板的方法，所述方法包括以下步骤：（i）提供液体组合物[组合物（L）]，其包含，优选由以下组成：至少一种氟聚合物[聚合物（F ）包含一个或多个主链，所述主链包含衍生自至少一种氟化单体[单体（F）]的重复单元和一个或多个选自-O-Rx和-C（ O）O-Rx基团，其中Rx是氢原子或包含至少一个羟基的C 1 -C 5烃基，任选地至少一种式（I）金属化合物[化合物（M）]：X4-mAYm其中 X是任选包含一个或多个官能团的烃基，m是1至4的整数，A是选自Si，Ti和Zr的金属，Y是选自以下的可水解基团：的烷氧基，酰氧基等乙氧基，至少一种无机填料[填料（I）]和液体介质[介质（L）]; （ii）提供由一组或多组聚合物纤维[基材（P）]制成的多孔基材层; （iii）将组合物（L）施加到基材（P）上，从而提供湿底材（P）[基材（P-W）]; （iv）干燥，然后任选地固化步骤（iii）中提供的底物（P-W），从而提供固体复合隔膜; 和（v）任选地，将步骤（iv）中提供的固体复合隔膜进行压缩。本发明还涉及通过所述方法获得的固体复合隔膜和在电化学装置中使用固体复合隔膜。

5. 发明申请

US20200321618A1 FLEXIBLE BATTERY 审中-公开
公开(公告)号：US20200321618A1
公开(公告)日：2020-10-08
申请号：US16310409
申请日：2017-06-13
申请人： SOLVAY SA , COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
发明人： Hélène ROUAULT , Gaëlle BESNARD , Léo MERCHAT , Jérémie SALOMON , Julio A. ABUSLEME , Marc-David BRAIDA , Christine HAMON
IPC分类号： H01M4/66 , H01M4/04 , H01M10/0525 , H01M4/58
摘要： The present invention pertains to a flexible electrode, to a process for the manufacture of said flexible electrode and to uses of said flexible electrode in electrochemical devices, in particular in secondary batteries.

6. 发明申请

US20190233599A1 FLUOROPOLYMER FILM 审中-公开
公开(公告)号：US20190233599A1
公开(公告)日：2019-08-01
申请号：US16312272
申请日：2017-06-01
申请人： SOLVAY SA , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人： Christine HAMON , Julio A. ABUSLEME , Aurélie GUYOMARD-LACK , Jean LE BIDEAU , Dominique GUYOMARD , Bernard LESTRIEZ
IPC分类号： C08J5/18 , H01M10/0565 , H01M10/0525 , H01M10/0568 , H01G11/56 , H01G11/52 , H01G9/20 , H01G9/00 , G02F1/1516
CPC分类号： C08J5/18 , B32B27/304 , B32B27/322 , C08F214/225 , C08J2327/16 , G02F1/15165 , H01G9/0036 , H01G9/2009 , H01G11/06 , H01G11/52 , H01G11/56 , H01M10/0525 , H01M10/0565 , H01M10/0568 , H01M2300/0025 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02E60/13
摘要： The invention pertains to a process for the manufacture of a fluoropolymer film, to the fluoropolymer film obtainable therefrom and to use of said fluoropolymer film in electrochemical and photo-electrochemical devices.

7. 发明申请

US20180371194A1 FLUOROPOLYMER HYBRID COMPOSITE 审中-公开
公开(公告)号：US20180371194A1
公开(公告)日：2018-12-27
申请号：US15777092
申请日：2016-11-16
申请人： SOLVAY SA
发明人： Julio A. ABUSLEME , Matteo LAVASELLI , Christine HAMON , Alberto FRACHE , Giambattista BESANA , Giovanni CAMINO , Ségolène BRUSSEAU
IPC分类号： C08J5/22 , C08L71/02 , H01M2/16 , H01M2/14
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a film comprising said fluoropolymer hybrid organic/inorganic composite and to uses of said film in various applications, in particular in electrochemical and in photo-electrochemical applications.

8. 发明申请

US20170073483A1 HYBRID FLUOROPOLYMER COMPOSITES 审中-公开
标题翻译：混合氟聚合物复合材料
公开(公告)号：US20170073483A1
公开(公告)日：2017-03-16
申请号：US15309354
申请日：2015-05-06
申请人： SOLVAY SA , COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
发明人： Jean-Baptiste DUCROS , Aurelie LAVIE-CAMBOT , Lionel PICARD , Olivier PRAS , Helene ROUAULT , Christine HAMON , Julio A. ABUSLEME
IPC分类号： C08J5/22 , H01G11/06 , H01G11/56 , H01M10/0525 , H01M10/0565
CPC分类号： C08J5/2237 , C08F214/225 , C08G18/6229 , C08G18/6279 , C08G18/718 , C08J2327/22 , H01G11/06 , H01G11/56 , H01M10/0525 , H01M10/0565 , H01M2300/0082 , Y02E60/13 , C08F220/20 , C08F214/285
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a process for manufacturing said fluoropolymer hybrid organic/inorganic composite and films and membranes thereof and to uses of said fluoropolymer hybrid organic/inorganic composite and films and membranes thereof in various applications.
摘要翻译：本发明涉及含氟聚合物杂化有机/无机复合材料，涉及制造所述含氟聚合物杂化有机/无机复合材料及其膜及其膜的方法，以及所述含氟聚合物杂化有机/无机复合材料及其膜和膜在各种应用中的用途。

9. 发明申请

US20160160392A1 FLUOROPOLYMER FIBRE 审中-公开
标题翻译：荧光纤维
公开(公告)号：US20160160392A1
公开(公告)日：2016-06-09
申请号：US14905443
申请日：2014-07-15
申请人： SOLVAY SA
发明人： Julio A. ABUSLEME , Giambattista BESANA , Mattia BASSI , Christine HAMON , Chiara GUALANDI , Maria Letizia FOCARETE , Andrea ZUCCHELLI
IPC分类号： D01F6/32 , H01M10/0525 , D02J1/00 , B01D71/32 , D04H1/4318 , D01D5/00 , H01M2/16
CPC分类号： D01F6/32 , B01D67/0079 , B01D71/32 , B01D71/76 , C08F214/18 , D01D5/003 , D01D5/0038 , D01F1/10 , D01F6/48 , D02J1/00 , D04H1/4318 , D04H1/728 , D10B2321/042 , D10B2321/08 , D10B2401/06 , D10B2401/061 , D10B2401/16 , D10B2505/00 , D10B2505/04 , H01M2/162 , H01M2/1686 , H01M10/052 , H01M10/0525
摘要： The present invention pertains to a process for manufacturing one or more fluoropolymer fibres, said process comprising the following steps: (i) providing a liquid composition [composition (C1)] comprising: —at least one fluoropolymer comprising at least one hydroxyl end group [polymer (FOH)L and—a liquid medium comprising at least one organic solvent [solvent (S)]; (ii) contacting the composition (C1) provided in step (i) with at least one metal compound [compound (M)] of formula (I) here below: X4-mAYm (I) wherein X is a hydrocarbon group, optionally comprising one or more functional groups, m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, and Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, thereby providing a liquid composition [composition (C2)]; (iii) submitting to at least partial hydrolysis and/or polycondensation the composition (C2) provided in step (ii) thereby providing a liquid composition [composition (C3)] comprising at least one fluoropolymer hybrid organic/inorganic composite; (iv) processing the composition (C3) provided in step (iii) by electrospinning thereby providing one or more fluoropolymer fibres; (v) drying the fluoropolymer fibre(s) provided in step (iv); and (vi) optionally, submitting to compression the fluoropolymer fibre(s) provided in step (v) at a temperature comprised between 50° C. and 300° C. The invention also pertains to a process for the manufacture of said fluoropolymer fibre(s) and to uses of said fluoropolymer fibre(s) in various applications.
摘要翻译：本发明涉及制造一种或多种含氟聚合物纤维的方法，所述方法包括以下步骤：（i）提供液体组合物[组合物（C1）]，其包含： - 至少一种包含至少一个羟基端基的含氟聚合物[ 聚合物（FOH）L和包含至少一种有机溶剂[溶剂（S）]的液体介质; （ⅱ）将步骤（ⅰ）中提供的组合物（C1）与下式的式（I）的至少一种金属化合物[化合物（M））接触：X4-mAYm（I）其中X是烃基，任选包括一个或多个官能团，m是1至4的整数，A是选自Si，Ti和Zr的金属，Y是选自烷氧基，酰氧基的可水解基团和羟基，从而提供液体组合物[组合物（C2）]; （iii）使步骤（ii）中提供的组合物（C2）至少部分水解和/或缩聚，从而提供包含至少一种含氟聚合物杂化有机/无机复合材料的液体组合物[组合物（C3）]; （iv）通过静电纺丝处理步骤（iii）中提供的组合物（C3），从而提供一种或多种含氟聚合物纤维; （v）干燥步骤（iv）中提供的含氟聚合物纤维; 和（vi）任选地，在50℃和300℃之间的温度下压缩步骤（v）中提供的含氟聚合物纤维。本发明还涉及制备所述含氟聚合物纤维的方法（以及所述含氟聚合物纤维在各种应用中的用途。

10. 发明申请

US20150372274A1 SEPARATOR COATED WITH POLYMER AND CONDUCTIVE SALT AND ELECTROCHEMICAL DEVICE USING THE SAME 审中-公开
标题翻译：使用聚合物和导电盐和电化学装置的分离器
公开(公告)号：US20150372274A1
公开(公告)日：2015-12-24
申请号：US14646560
申请日：2013-11-20
申请人： SOLVAY SA
发明人： Christine HAMON , Riccardo PIERI , Shilei CHEN , Marc-David BRAIDA , Jean-Francois MOUSSET
IPC分类号： H01M2/16 , H01M2/14
CPC分类号： H01M2/1686 , H01M2/145 , H01M2/1626 , H01M2/1653 , H01M10/0525
摘要： The present invention provides method for manufacturing a coated separator for use in an electrochemical device, comprising the steps of: (i) providing a separator having two surfaces; (ii) applying a coating composition [composition (C)] on at least one surface of the separator, the composition (C) comprising a polymer [polymer (P)] and at least one electrolyte salt [salt (E)] of formula (a), A+B− (a) wherein A+ indicates an ion selected from alkaline metal cations or a combination thereof, and B″ indicates an ion selected from anions or a combination thereof, so as to obtain a coating layer onto said surface; and (ii) drying the coating layer so as to obtain a coated separator, wherein the polymer (P) is a vinylidene fluoride (VdF) polymer and comprises recurring units derived from at least one comonomer (C), said comonomer (C) being different from vinylidene fluoride (VdF), and wherein the polymer (P) comprises recurring units derived from at least one (meth)acrylic monomer (MA). Further, the present provides a separator for use in an electrochemical device, said separator being coated on at least one surface thereof a coating comprising a polymer (P) and at least one salt (E) as described above, wherein said coating is characterized by: a dry thickness of from about 0.1 to 10 μm; a weight between 5 and 100% of the weight of the un-coated separator; or being substantially solvent free. Moreover, the present invention provides a method for producing an electrochemical device using the coated separator as described above.
摘要翻译：本发明提供一种用于制造用于电化学装置的涂覆分离器的方法，包括以下步骤：（i）提供具有两个表面的分离器; （ii）将涂料组合物[组合物（C）]涂布在隔膜的至少一个表面上，包含聚合物[聚合物（P）]和至少一种式（I）的电解质盐[盐（E）（a）中，A + B-（a）其中A +表示选自碱金属阳离子或其组合的离子，B“表示选自阴离子或其组合的离子，从而在所述表面上获得涂层 ; 和（ⅱ）干燥该涂层从而得到涂覆的隔膜，其中聚合物（P）是偏二氟乙烯（VdF）聚合物，并且包含衍生自至少一种共聚单体（C）的重复单元，所述共聚单体（C）为不同于偏氟乙烯（VdF），并且其中聚合物（P）包含衍生自至少一种（甲基）丙烯酸单体（MA）的重复单元。此外，本发明提供了一种用于电化学装置的隔板，所述隔膜在其至少一个表面上涂覆有如上所述的包含聚合物（P）和至少一种盐（E）的涂层，其中所述涂层的特征在于：干燥厚度为约0.1至10μm; 重量在未涂覆分离器重量的5至100％之间; 或基本上无溶剂。此外，本发明提供一种如上所述的使用涂覆隔板的电化学装置的制造方法。

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