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    • 1. 发明授权
    • Process for the continuous preparation of unsaturated polyesters
    • 连续制备不饱和聚酯的方法
    • US3911048A
    • 1975-10-07
    • US42034873
    • 1973-11-29
    • SIR SOC ITALIANA RESINE SPA
    • VARGIU SILVIOPASSALENTI BEPPINONISTRI UGO
    • C08G63/00C08G63/52C08G63/78C08G63/22
    • C08G63/52C08G63/785
    • Process for the continuous preparation of unsaturated polyesters, comprising bringing olefinically unsaturated dicarboxylic acids or their anhydrides, if desired, together with saturated dicarboxylic acids of their anhydrides (dicarboxylic acid component) and dihydric alcohols, if desired, together with higher polyhydric alcohols (alcohol component) into contact in molar ratios of from about 1.5:1 to 1.95:1 in a first reaction phase, operating at a temperature of from about 100* to 160*C and with residence times of from about 5 to 40 minutes to cause the formation of a corresponding half-ester; adding to the half-ester formed a further quantity of the alcohol component in such a way as to give a molar ratio of the dicarboxylic acid component to the total amount of the alcohol component in the range of from about 0.87:1 to 0.97:1; bringing about the polyesterification in a second reaction phase by treating the product obtained in at least two separate and successive stages, which are operated at decreasing pressure values in the range of from about 5 atmospheres to atmospheric pressure, for times of about 2 to 8 hours, and at temperatures of from about 100* to 220*C, the temperature in said stages not differing by more than about 10*C, and the water formed during the polyesterification being eliminated from each of the said stages; evaporating the residual water and the excess of the alcohol component from the polyesterification product obtained with operation at pressures below atmospheric pressure.
    • 连续制备不饱和聚酯的方法,包括如果需要,将烯属不饱和二羧酸或其酸酐与其酸酐(二羧酸组分)和二元醇的饱和二羧酸一起,连同更高级的多元醇(醇组分 )在第一反应相中的摩尔比为约1.5:1至1.95:1的摩尔比,在约100至160℃的温度和约5-40分钟的停留时间下进行接触以引起形成 的相应的半酯; 向半酯中加入另外量的醇组分,使得二羧酸组分与醇组分的总量的摩尔比在约0.87:1至0.97:1的范围内 ; 通过将在至少两个分开的和连续的阶段中获得的产物处理在第二反应阶段中进行聚酯化,其在约5个大气压至大气压的压力值下操作约2至8小时 在约100℃至220℃的温度下,所述阶段的温度不超过约10℃,并且在每个所述阶段中消除在聚酯化期间形成的水; 从低于大气压的压力下操作获得的聚酯化产物中蒸发残余水和过量的醇组分。