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1. 发明授权

US09745404B2 Resin molded article for automobile interior material 有权
公开(公告)号：US09745404B2
公开(公告)日：2017-08-29
申请号：US15306253
申请日：2015-04-23
申请人： SANYO CHEMICAL INDUSTRIES, LTD. , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Kenta Nose , Koichi Saito , Osami Yamada , Hiroyuki Ishii , Daisuke Taniguchi
IPC分类号： C08G18/42 , C08G18/12 , C08G18/30 , C08G18/38 , C08G18/66 , C08G18/73 , B29C41/00 , B29C41/18 , B29C41/36 , C08G18/28 , C08G18/32 , B29K75/00 , B29K105/00 , B29L31/30
CPC分类号： C08G18/4211 , B29C41/003 , B29C41/18 , B29C41/36 , B29K2075/00 , B29K2105/0094 , B29K2105/251 , B29K2995/0077 , B29K2995/0088 , B29L2031/30 , C08G18/12 , C08G18/2825 , C08G18/30 , C08G18/3206 , C08G18/3819 , C08G18/4202 , C08G18/4216 , C08G18/4238 , C08G18/6633 , C08G18/664 , C08G18/73 , C08G2140/00 , C08G18/3228
摘要： Provided is a resin molded article for an automobile interior material, the resin molded article achieving both resin strength permitting formation of a thin film, and crease resistance. This molded article is to be used in an automobile interior material, the resin molded article being obtained by slush-molding a powdered thermoplastic urethane urea resin composition (P) that satisfies (1)-(5) below, said resin composition (P) containing an additive and a thermoplastic urethane urea resin (U) obtained by reacting a high-molecular diol (a), a linear alkane diol (b), a monool (c), a diamine (d), and an organic diisocyanate (e): (1) (a) contains a specific polyester diol; (2) the weight of (b) is within a specific range relative to the total weight of (a)-(e); (3) the tensile strength of a film comprising (P) is 8.0 MPa or higher; (4) the storage modulus of (P) at 130° C. is 0.1-5.0 MPa; (5) the ratio of the storage modulus of (P) at 50° C. to the storage modulus at 23° C. by a specific measurement method is 50% or higher.

2. 发明授权

US09273188B2 Process for producing urethane resin particles for slush molding 有权
标题翻译：用于制造用于搪塑的聚氨酯树脂颗粒的方法
公开(公告)号：US09273188B2
公开(公告)日：2016-03-01
申请号：US14558338
申请日：2014-12-02
申请人： SANYO CHEMICAL INDUSTRIES, LTD.
发明人： Yasuhiro Tsudo , Masaki Inaba , Koichi Saito , Hideaki Saito , Takanori Yamamoto
IPC分类号： C08J3/20 , B29C41/18 , C08G18/73 , C08G18/10 , C08G18/12 , C08G18/42 , C08J3/12 , B29K75/00
CPC分类号： C08J3/203 , B29C41/18 , B29K2075/00 , C08G18/10 , C08G18/12 , C08G18/42 , C08G18/73 , C08J3/12 , C08J3/20 , C08J2375/00 , C08J2375/04
摘要： The present invention is urethane resin particles (C) for slush mold which contain a urethane resin (D) and an additive (N), wherein the particles have a shape factor SF1 of 101 to 200, a shape factor SF2 of 120 to 240, and a central particle diameter of 20 to 500 μm. It is preferred that the urethane resin (D) has a concentration of urea groups of 0.5 to 10% by weight, a total of the concentration of urethane groups and that of the urea groups of 4 to 20% by weight, a melting point of 160 to 260° C. and a glass transition temperature of −65 to 0° C.
摘要翻译：本发明是含有聚氨酯树脂（D）和添加剂（N）的用于糊模的聚氨酯树脂颗粒（C），其中颗粒的形状因子SF1为101〜200，形状因子SF2为120〜240，中心粒径为20〜500μm。优选聚氨酯树脂（D）的尿素基浓度为0.5〜10重量％，氨基甲酸酯基和尿素基的浓度的总和为4〜20重量％，熔点为 160〜260℃，玻璃化转变温度为-65〜0℃。

3. 发明申请

US20130261240A1 POLYURETHANE RESIN POWDER COMPOSITION FOR SLUSH MOLDING 审中-公开
标题翻译：聚氨酯树脂粉末组合物
公开(公告)号：US20130261240A1
公开(公告)日：2013-10-03
申请号：US13793179
申请日：2013-03-11
申请人： SANYO CHEMICAL INDUSTRIES, LTD. , CALSONIC KANSEI CORPORATION
发明人： Shu Yasuhara , Yasuhiro Tsudo , Koichi Saito , Masaaki Namiki , Naohito Jinnai , Shigeji Ichikawa , Masaaki Tamura
IPC分类号： C08L33/12 , C08L75/04
CPC分类号： C08L33/12 , C08G18/12 , C08G18/2825 , C08G18/4202 , C08G18/73 , C08G2140/00 , C08L33/14 , C08L75/04 , C08L2205/22 , C08L2312/00 , C08G18/3256
摘要： Provided is a polyurethane resin powder composition for slush molding from which an outer skin for an instrument panel can be produced, the outer skin not interfering with deployment of an airbag. More specifically, provided is a polyurethane resin powder composition (D) for slush molding comprising perfectly spherical thermoplastic polyurethane resin particles (A) obtained by reacting a polyester diol component (J) and a diisocyanate component (F), a plasticizer (B), and a vinyl-type copolymer fine particles (C) having a crosslinked structure, wherein the polyester diol component (J) comprises a polyester diol (J1) comprising an aromatic dicarboxylic acid (E) and ethylene glycol as essential constituent units, a ratio of volume average particle sizes of (A) and (C), (A):(C), is 200:1 to 2000:1, and an extent of surface coverage of a surface of (A) with (C) {Equation (1)} is 20 to 80%. [Expression 1] Extent of surface coverage (%)=[number of particles of (C)]×[average cross section area of one particle of (C)]/surface area of (A)×100 (1)
摘要翻译：本发明提供一种用于搪塑的聚氨酯树脂粉末组合物，由此可以制造用于仪表板的外皮，外皮不会妨碍气囊的展开。更具体地说，提供了一种用于搪塑的聚氨酯树脂粉末组合物（D），包括通过使聚酯二醇组分（J）和二异氰酸酯组分（F）反应获得的完全球形的热塑性聚氨酯树脂颗粒（A），增塑剂（B），和具有交联结构的乙烯基型共聚物微粒（C），其中所述聚酯二醇组分（J）包含包含芳族二羧酸（E）和乙二醇作为必要组分单元的聚酯二醇（J1），其比例为（A）和（C），（A）:( C）的体积平均粒径为200:1〜2000:1，（A）表面的覆盖程度为（C）{式 1）}为20〜80％。 [表达式1]表面覆盖度（％）= [（C）的颗粒数]×（（C）的一个粒子的平均截面积）/（A）×100（1）

4. 发明申请

US20150086770A1 PROCESS FOR PRODUCING URETHANE RESIN PARTICLES FOR SLUSH MOLDING 有权
标题翻译：生产用于硅胶模塑的URETHANE树脂颗粒的方法
公开(公告)号：US20150086770A1
公开(公告)日：2015-03-26
申请号：US14558338
申请日：2014-12-02
申请人： SANYO CHEMICAL INDUSTRIES, LTD.
发明人： Yasuhiro Tsudo , Masaki Inaba , Koichi Saito , Hideaki Saito , Takanori Yamamoto
IPC分类号： C08J3/20 , C08J3/12
CPC分类号： C08J3/203 , B29C41/18 , B29K2075/00 , C08G18/10 , C08G18/12 , C08G18/42 , C08G18/73 , C08J3/12 , C08J3/20 , C08J2375/00 , C08J2375/04
摘要： The present invention is urethane resin particles (C) for slush mold which contain a urethane resin (D) and an additive (N), wherein the particles have a shape factor SF1 of 101 to 200, a shape factor SF2 of 120 to 240, and a central particle diameter of 20 to 500 μm. It is preferred that the urethane resin (D) has a concentration of urea groups of 0.5 to 10% by weight, a total of the concentration of urethane groups and that of the urea groups of 4 to 20% by weight, a melting point of 160 to 260° C. and a glass transition temperature of −65 to 0° C.
摘要翻译：本发明是含有聚氨酯树脂（D）和添加剂（N）的用于糊模的聚氨酯树脂颗粒（C），其中颗粒的形状因子SF1为101〜200，形状因子SF2为120〜240，中心粒径为20〜500μm。优选聚氨酯树脂（D）的尿素基浓度为0.5〜10重量％，氨基甲酸酯基和尿素基的浓度的总和为4〜20重量％，熔点为 160〜260℃，玻璃化转变温度为-65〜0℃。

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