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1. 发明授权

US4238609A Production of ampho-ionic compounds 失效
标题翻译：两性离子化合物的生产
公开(公告)号：US4238609A
公开(公告)日：1980-12-09
申请号：US966045
申请日：1978-12-04
申请人： Ryuzo Mizuguchi , Atsushi Takahashi , Shinichi Ishikura , Akimitsu Uenaka
发明人： Ryuzo Mizuguchi , Atsushi Takahashi , Shinichi Ishikura , Akimitsu Uenaka
IPC分类号： C07D213/20 , C07D295/088 , C07C137/00
CPC分类号： C07D213/20 , C07D295/088
摘要： Ampho-ionic compounds of the formula ##STR1## wherein, for example, R is CH.sub.2 .dbd.C(CH.sub.3)--COOCH.sub.2 --, R.sub.2 is hydrogen and B.sup..sym. is --N.sup..sym. --(CH.sub.3).sub.2 C.sub.12 H.sub.25, are prepared by reacting an oxirane compound with sulfur dioxide and a tertiary amine. These ampho-ionic compounds are useful as, for example, surfactants.
摘要翻译：其中例如R为CH 2 = C（CH 3）-COOCH 2 - ，R 2为氢且B（+）为-N（+） - （CH 3）2 C 12 H 25的二价离子化合物由使环氧乙烷化合物与二氧化硫和叔胺反应。这些两性离子化合物可用作例如表面活性剂。

2. 发明授权

US4116912A Aqueous resin dispersion and thermosetting paint composition containing same 失效
标题翻译：含水树脂分散体和含有它的热固性涂料组合物
公开(公告)号：US4116912A
公开(公告)日：1978-09-26
申请号：US753086
申请日：1976-12-21
申请人： Ryuzo Mizuguchi , Atsushi Takahashi , Shinichi Ishikura
发明人： Ryuzo Mizuguchi , Atsushi Takahashi , Shinichi Ishikura
IPC分类号： C08F2/16 , C08F212/14 , C08F220/34 , C08F220/60 , C08L61/28 , C08L61/24
CPC分类号： C08F212/14 , C08F220/34 , C08F220/60 , Y10T428/31688 , Y10T428/31895 , Y10T428/31957 , Y10T428/31964
摘要： A thermosetting coating composition which comprises an aqueous resin dispersion obtained by polymerization of a polymerizable monomer having an ampho-ionic structure with any other polymerizable monomer being copolymerizable therewith and an amino plast resin, and which can afford a hardened coating film having an excellent durability at a relatively low temperature within a short period of time.
摘要翻译：一种热固性涂料组合物，其包含通过将具有两性离子结构的可聚合单体与可与其共聚的任何其它可聚合单体和氨基塑料树脂聚合而获得的水性树脂分散体，并且其可以提供具有优异耐久性的硬化涂膜在短时间内相对较低的温度。

3. 发明授权

US4481150A Process for preparing hydroxyalkylaminosulfonic acids 失效
标题翻译：制备羟烷基氨基磺酸的方法
公开(公告)号：US4481150A
公开(公告)日：1984-11-06
申请号：US412977
申请日：1982-08-27
申请人： Keizou Ishii , Ryuzo Mizuguchi , Shinichi Ishikura , Tamotsu Yoshioka
发明人： Keizou Ishii , Ryuzo Mizuguchi , Shinichi Ishikura , Tamotsu Yoshioka
IPC分类号： C07C309/14 , C07C143/02
CPC分类号： C07C309/14
摘要： A process for preparing hydroxyalkylaminosulfonic acids which comprises reacting a hydroxyalkylamine of the formula: ##STR1## wherein R.sub.1 is a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, and R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, or a lower alkyl group, with an alkali metal salt of an .alpha.,.beta.-unsaturated sulfonic acid of the formula: ##STR2## wherein R.sub.3 is a hydrogen atom or a methyl group and M is an alkali metal, followed by elimination of the alkali metal to give a hydroxyalkylaminosulfonic acid of the formula: ##STR3## wherein R.sub.1 and R.sub.3 are each as defined above and R.sub.2 ' is a hydrogen atom, a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, a lower alkyl group or a group of the formula: ##STR4## wherein R.sub.3 is as defined above.
摘要翻译：一种制备羟烷基氨基磺酸的方法，其包括使下式的羟烷基胺反应：其中R1是在烷基链中任选含有-O-或-COO-的C1-C20羟基烷基，R2是氢原子，在烷基链或低级烷基中任选含有-O-或-COO-的C1-C20羟烷基，与下式的α，β-不饱和磺酸的碱金属盐反应：（III））其中R3是氢原子或甲基，M是碱金属，然后除去碱金属，得到下式的羟烷基氨基磺酸：其中R 1和R 3各自如上所定义，和 R2'是氢原子，在烷基链中任选地含有-O-或-COO-的C 1 -C 20羟基烷基，低级烷基或下式的基团：其中R 3如上所定义。

4. 发明授权

US4461870A High solid coating composition containing novel microparticles of crosslinked copolymer including amphoionic groups 失效
标题翻译：含有包含两性基团的交联共聚物的新颖微粒的高固体涂料组合物
公开(公告)号：US4461870A
公开(公告)日：1984-07-24
申请号：US460878
申请日：1983-01-25
申请人： Kazunori Kanda , Keizou Ishii , Katsuaki Kida , Shinichi Ishikura , Ryuzo Mizuguchi
发明人： Kazunori Kanda , Keizou Ishii , Katsuaki Kida , Shinichi Ishikura , Ryuzo Mizuguchi
IPC分类号： C08G12/34 , C08G59/14 , C08G59/40 , C09D167/00 , C09D201/00 , C08L75/00 , C08L67/08
CPC分类号： C09D167/00 , C08G12/34 , C08G59/14 , C08G59/4064 , C09D201/00
摘要： A high solid coating composition comprising(A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to,(B) a volatile organic liquid diluent in which the polymer (A) is carried,(C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and(D) a crosslinking agent dissolved in the diluent (B),which is characterized in that the microparticles (C) are composed of crosslinked copolymer of .alpha.,.beta.-ethylenically unsaturated monomers carrying thereon a resinous portion having an amphoionic group of the formula: ##STR1## wherein R is a member selected from optionally substituted alkylene having 1 to 6 carbon atoms and phenylene group and Y is --COOH or --SO.sub.3 H.
摘要翻译：一种高固体涂料组合物，其包含（A）具有能够与交联剂（D）反应的官能团的成膜聚合物，以下称为（B）其中聚合物（A）为其中的挥发性有机液体稀释剂携带（C）平均直径为0.02〜40微米的聚合物微粒，其不溶于成膜聚合物（A）和稀释剂（B）的组合，并保持在其中的稳定的分散状态，和（D）溶解在稀释剂（B）中的交联剂，其特征在于，微粒（C）由α，β-烯键式不饱和单体的交联共聚物组成，所述α，β-烯属不饱和单体带有具有下式的两性基团的树脂部分：其中R是选自具有1-6个碳原子的任意取代的亚烷基和亚苯基，Y是-COOH或-SO 3 H的成员。

5. 发明授权

US4215028A Thermosetting resin, and its production and use 失效
标题翻译：热固性树脂，其生产和使用
公开(公告)号：US4215028A
公开(公告)日：1980-07-29
申请号：US927038
申请日：1978-07-24
申请人： Ryuzo Mizuguchi , Atushi Takahashi , Shinichi Ishikura , Akimitsu Uenaka
发明人： Ryuzo Mizuguchi , Atushi Takahashi , Shinichi Ishikura , Akimitsu Uenaka
IPC分类号： C08F16/00 , C08F2/16 , C08F16/14 , C08F20/00 , C08F20/32 , C08F20/34 , C08F20/52 , C08F26/00 , C08F26/06 , C08F246/00 , C09D125/00 , C09D129/00 , C09D133/04 , C09D133/14 , C08F220/04 , C08F220/06
CPC分类号： C08F246/00 , C09D133/14 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31909
摘要： A thermosetting resin of self cross-linking type which is prepared by polymerization of at least one polymerizable monomer having an ampho-ion structure, at least one polymerizable monomer containing an oxirane group and at least one other monomer and can afford a hardened film or article of good physical properties when cross-linked.
摘要翻译：一种自交联型热固性树脂，其通过至少一种具有两性离子结构的可聚合单体，至少一种含有环氧乙烷基团的可聚合单体和至少一种其它单体的聚合而制备，并且可以提供硬化膜或制品交联时具有良好的物理性能。

6. 发明授权

US4309327A Polymeric resin from ethylenic amino, sulfonic monomers 失效
标题翻译：聚合树脂由乙烯基氨基，磺酸单体组成
公开(公告)号：US4309327A
公开(公告)日：1982-01-05
申请号：US82585
申请日：1979-10-09
申请人： Shinichi Ishikura , Ryuzo Mizuguchi , Keizou Ishii , Tamotu Yoshioka
发明人： Shinichi Ishikura , Ryuzo Mizuguchi , Keizou Ishii , Tamotu Yoshioka
IPC分类号： C08F12/14 , C08F16/14 , C08L61/20 , C09D133/14 , C09D157/12 , C08F228/00
CPC分类号： C09D157/12 , C08F12/14 , C08F16/14 , C09D133/14 , C08L61/20 , Y10T428/31692
摘要： A coating composition comprising as a main component a polymeric resin obtained by solution polymerization of at least one of polymerizable amino acid compounds of either one of the formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each hydrogen, methyl or ethyl, R.sub.5 is hydrogen or C.sub.1 -C.sub.20 alkyl optionally having --SO--, --COO-- or --O-- therein, R.sub.6 is C.sub.1 -C.sub.12 alkylene optionally substituted with --OH, --SH or --SR.sub.7 (R.sub.7 being C.sub.1 -C.sub.4 alkyl) and/or optionally substituted with C.sub.1 -C.sub.4 alkyl or phenylene optionally substituted with C.sub.1 -C.sub.4 alkyl and A is --COOH or --SO.sub.3 H, and ##STR2## wherein R.sub.8, R.sub.9 and R.sub.10 are each hydrogen or C.sub.1 -C.sub.6 alkyl, R.sub.11 is hydrogen or C.sub.1 -C.sub.20 alkyl optionally having --SO--, --COO-- or --O-- therein, or a group of the formula: ##STR3## (R.sub.8, R.sub.9 and R.sub.10 being each as defined above), R.sub.12 is C.sub.2 -C.sub.12 alkylene optionally substituted with C.sub.1 -C.sub.6 alkyl or phenylene optionally substituted with C.sub.1 -C.sub.4 alkyl, and A is as defined above, with or without at least one of other polymerizable monomers.
摘要翻译：一种涂料组合物，其包含作为主要组分的聚合物树脂，该聚合物树脂通过以下任一下式的可聚合的氨基酸化合物的溶液聚合获得：其中R1，R2，R3和R4各自为氢，甲基或乙基，R 5为氢或任选具有-SO - ， - COO-或-O-的C 1 -C 20烷基，R 6为任选被-OH，-SH或-SR 7取代的C 1 -C 12亚烷基（R 7为C 1 -C 4烷基）和/或任选被任选被C 1 -C 4烷基取代的C 1 -C 4烷基或亚苯基取代，并且A是-COOH或-SO 3 H，且其中R 8，R 9和R 10各自为氢或C 1 -C 6烷基，R 11为氢或任选具有-SO - ， - COO-或-O-的C 1 -C 20烷基，或下式的基团：R 8，R 9和R 10各自如上所述，R 12为C 2 任选被C 1 -C 6烷基取代的-C 12亚烷基或任选被C 1 -C 4烷基取代的亚苯基，A如上所定义，具有或不具有至少一种其它可聚合单体。

7. 发明授权

US4294740A Process for preparing acrylic resin emulsions 失效
标题翻译：制备丙烯酸树脂乳液的方法
公开(公告)号：US4294740A
公开(公告)日：1981-10-13
申请号：US143923
申请日：1980-04-23
申请人： Ryuzo Mizuguchi , Shinichi Ishikura , Keizou Ishii , Tamotu Yoshioka
发明人： Ryuzo Mizuguchi , Shinichi Ishikura , Keizou Ishii , Tamotu Yoshioka
IPC分类号： C08F2/22 , C08F2/24 , C08F255/02
CPC分类号： C08F2/24 , C08F255/023
摘要： A process for preparing a substantially lump free acrylic resin emulsion by emulsion polymerization of one or more acrylic monomers in water in the presence or absence of an emulsifier or a dispersing agent, wherein the polymerization is carried out in the presence a water-insoluble resin which is immiscible with the acrylic resin in the emulsion and has a softening or melting point of 20.degree. C. or higher.
摘要翻译：在存在或不存在乳化剂或分散剂的情况下通过一种或多种丙烯酸单体在水中的乳液聚合制备基本上无块状的丙烯酸树脂乳液的方法，其中聚合在水不溶性树脂存在下进行，其中与乳液中的丙烯酸树脂不混溶，并且具有20℃以上的软化点或熔点。

8. 发明授权

US4468493A High solid coating composition containing novel microparticles of crosslinked copolymer containing amphoionic groups 失效
标题翻译：含有含有两性基团的交联共聚物的新型微粒的高固体涂料组合物
公开(公告)号：US4468493A
公开(公告)日：1984-08-28
申请号：US460877
申请日：1983-01-25
申请人： Shinichi Ishikura , Kazunori Kanda , Katsuaki Kida , Ryuzo Mizuguchi
发明人： Shinichi Ishikura , Kazunori Kanda , Katsuaki Kida , Ryuzo Mizuguchi
IPC分类号： C09D5/00 , C08F246/00 , C08G12/34 , C08G59/14 , C08G59/40 , C09D133/02 , C09D167/00 , C09D167/08 , C09D201/00 , C08L75/06 , C08L61/28
CPC分类号： C09D167/00 , C08G12/34 , C08G59/14 , C08G59/4064 , C09D201/00
摘要： A high solid coating composition comprising(A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to,(B) a volatile organic liquid diluent in which the polymer (A) is carried,(C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and(D) a crosslinking agent dissolved in the diluent (B), which is characterized by the fact that the microparticles (C) are composed of crosslinked copolymer obtained by copolymerizing at least one of the polymerizable amino acid compounds of the formula: ##STR1## with other polymerizable .alpha.,.beta.-ethylenically unsaturated monomers, at least part of which is crosslinking monomer.
摘要翻译：一种高固体涂料组合物，其包含（A）具有能够与交联剂（D）反应的官能团的成膜聚合物，以下称为（B）其中聚合物（A）为其中的挥发性有机液体稀释剂携带（C）平均直径为0.02〜40微米的聚合物微粒，其不溶于成膜聚合物（A）和稀释剂（B）的组合，并保持在其中的稳定的分散状态，和（D）溶解在稀释剂（B）中的交联剂，其特征在于，所述微粒（C）由通过使下式的可聚合氨基酸化合物中的至少一种共聚得到的交联共聚物构成：＆lt; IMAGE 与其他可聚合的α，β-烯键式不饱和单体，其中至少一部分是交联单体。

9. 发明授权

US4582651A Process for preparing hydroxyalkylaminosulfonic acids 失效
标题翻译：制备羟烷基氨基磺酸的方法
公开(公告)号：US4582651A
公开(公告)日：1986-04-15
申请号：US599823
申请日：1984-04-13
申请人： Keizou Ishii , Ryuzo Mizuguchi , Shinichi Ishikura , Tamotsu Yoshioka
发明人： Keizou Ishii , Ryuzo Mizuguchi , Shinichi Ishikura , Tamotsu Yoshioka
IPC分类号： A61K31/38 , A61K31/40 , A61K31/415 , C07D207/16 , C07D231/06 , C07C143/02 , C07C101/30
CPC分类号： C07D231/06 , A61K31/38 , A61K31/40 , A61K31/415 , C07D207/16 , Y10S516/05 , Y10S516/91
摘要： A process for preparing hydroxyalkylaminosulfonic acids which comprises reacting a hydroxyalkylamine of the formula: ##STR1## wherein R.sub.1 is a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, and R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, or a lower alkyl group, with an alkali metal salt of an .alpha.,.beta.-unsaturated sulfonic acid of the formula: ##STR2## wherein R.sub.3 is a hydrogen atom or a methyl group and M is an alkali metal, followed by elimination of the alkali metal to give a hydroxyalkylaminosulfonic acid of the formula: ##STR3## wherein R.sub.1 and R.sub.3 are each as defined above and R.sub.2 ' is a hydrogen atom, a C.sub.1 -C.sub.20 hydroxyalkyl group optionally containing --O-- or --COO-- in the alkyl chain, a lower alkyl group or a group of the formula: ##STR4## wherein R.sub.3 is as defined above.
摘要翻译：一种制备羟烷基氨基磺酸的方法，其包括使下式的羟烷基胺反应：其中R1是在烷基链中任选含有-O-或-COO-的C1-C20羟基烷基，R2是氢原子，在烷基链或低级烷基中任选含有-O-或-COO-的C1-C20羟烷基，与下式的α，β-不饱和磺酸的碱金属盐反应：（III））其中R3是氢原子或甲基，M是碱金属，然后除去碱金属，得到下式的羟烷基氨基磺酸：其中R 1和R 3各自如上所定义，和 R2'是氢原子，在烷基链中任选地含有-O-或-COO-的C 1 -C 20羟基烷基，低级烷基或下式的基团：其中R 3如上所定义。

10. 发明授权

US4530946A Resinous emulsion comprising microparticles for coating use and preparation thereof 失效
标题翻译：包含用于涂布的微粒和其制备的树脂乳液
公开(公告)号：US4530946A
公开(公告)日：1985-07-23
申请号：US585595
申请日：1984-03-02
申请人： Kazunori Kanda , Keizou Ishii , Katsuaki Kida , Shinichi Ishikura , Ryuzo Mizuguchi
发明人： Kazunori Kanda , Keizou Ishii , Katsuaki Kida , Shinichi Ishikura , Ryuzo Mizuguchi
IPC分类号： C08G12/34 , C08G59/14 , C08G59/40 , C09D167/00 , C09D201/00 , C08L63/10
CPC分类号： C09D167/00 , C08G12/34 , C08G59/14 , C08G59/4064 , C09D201/00
摘要： A resinous emulsion is prepared by copolymerizing .alpha.,.beta.-ethylenically unsaturated monomers and a crosslinking monomer which is at least difunctional, in an aqueous medium in the presence of a resin having an amphoionic group of the formula: ##STR1## wherein R represents substituted or unsubstituted C.sub.1 -C.sub.6 alkylene or phenylene and Y is --COOH or --SO.sub.3 H, or in the presence of a resin having the above said amphoionic group and a polymerizable .alpha.,.beta.-unsaturated bonding. The thus obtained emulsion is useful for the obtainment of crosslinked polymer microparticles to be incorporated in a high solid coating composition or for the preparation of aqueous coating composition because of having contained no harmful emulsifier or surfactant.
摘要翻译：在具有下式的两性基团的树脂的存在下，在水性介质中共聚α，β-烯属不饱和单体和至少二官能的交联单体制备树脂乳液，其中R表示取代或未取代的C1-C6亚烷基或亚苯基，Y为-COOH或-SO3H，或在具有上述所述两性基团的树脂和可聚合α，β-不饱和键的存在下。由此获得的乳液可用于获得掺入高固体涂料组合物中的交联聚合物微粒或由于不含有害乳化剂或表面活性剂而制备水性涂料组合物。

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