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    • 2. 发明授权
    • Fe-based amorphous metal alloy having a linear BH loop
    • 具有线性BH环的Fe基非晶态金属合金
    • US06749695B2
    • 2004-06-15
    • US10071990
    • 2002-02-08
    • Ronald J. MartisRyusuke Hasegawa
    • Ronald J. MartisRyusuke Hasegawa
    • H01F1153
    • H01F1/15341H01F1/15308
    • A metallic glass alloy ribbon consists essentially of about 70 to 87 atom percent iron. Up to about 20 atom percent of the iron is replaced by cobalt and up to about 3 atom percent of the iron is replaced by nickel, manganese, vanadium, titanium or molybdenum. About 13-30 atom percent of the element balance comprises a member selected from the group consisting of boron, silicon and carbon. The alloy is heat-treated at a sufficient temperature to achieve stress relief. A magnetic field applied during the heat-treatment causes the magnetization to point away from the ribbon's predetermined easy magnetization direction. The metallic glass exhibits linear DC BH loops with low ac losses. As such they are especially well suited for use in current/voltage transformers.
    • 金属玻璃合金带基本上由约70至87原子%的铁组成。 高达约20原子%的铁被钴取代,最多约3原子%的铁被镍,锰,钒,钛或钼代替。 约13-30原子%的元素余量包括选自硼,硅和碳的成员。 该合金在足够的温度下热处理以达到减轻应力。 在热处理期间施加的磁场使得磁化指向远离带的预定易磁化方向。 金属玻璃呈现出具有低交流损耗的线性DC BH环。 因此,它们特别适用于电流/电压互感器。
    • 5. 发明授权
    • Magnetic glassy alloys for electronic article surveillance
    • 用于电子物品监控的磁性玻璃状合金
    • US06475303B1
    • 2002-11-05
    • US09633058
    • 2000-08-08
    • Ryusuke HasegawaHoward H. LiebermannRonald J. Martis
    • Ryusuke HasegawaHoward H. LiebermannRonald J. Martis
    • H01F1153
    • C22C45/008C22F1/10G08B13/2442H01F1/15308H01F1/15316
    • A glassy metal alloy consists essentially of the formula CoaNibFecMdBeSifCg, where M is at least one element selected from the group consisting of Cr, Mo, Mn and Nb, “a-g” are in atom percent and the sum of “a-g” equals 100, “a” ranges from about 25 to about 60, “b” ranges from about 5 to about 45, “c” ranges from about 6 to about 12, “d” ranges from about 0 to about 3, “e” ranges from about 5 to 25, “f” ranges from about 0 to about 15 and “g” ranges from about 0 to 6, said alloy having a value of the saturation magnetostriction between −3 ppm and +3 ppm. The alloy can be cast by rapid solidification from the melt into ribbon, sheet or wire form. The alloy exhibits non-linear B—H hysteresis behavior in its as-cast condition. The alloy is further annealed with or without magnetic field at temperatures below said alloy's first crystallization temperature, having non-linear B—H hysteresis loops. The alloy is suited for use as a magnetic marker in electronic article surveillance systems utilizing magnetic harmonics.
    • 玻璃状金属合金主要由式CoaNibFecMdBeSifCg组成,其中M为选自Cr,Mo,Mn和Nb中的至少一种元素,“ag”为原子百分数,“ag”之和等于100, a“为约25至约60,”b“为约5至约45,”c“为约6至约12,”d“为约0至约3,”e“为约5 至25,“f”为约0至约15,“g”为约0至6,所述合金的饱和磁致伸缩值为-3ppm至+ 3ppm。 该合金可以通过快速凝固从熔体铸造成带状,片状或线状。 该合金在其铸态条件下表现出非线性的B-H滞后特性。 在低于所述合金的第一结晶温度的温度下,使用或不使用磁场进行退火合金,其具有非线性B-H磁滞回线。 该合金适用于利用磁谐波的电子物品监控系统中的磁标记。
    • 8. 发明授权
    • Integrated hybrid electronic article surveillance marker
    • 综合混合电子物品监控标记
    • US06696953B2
    • 2004-02-24
    • US09919252
    • 2001-07-31
    • An QiuRyusuke Hasegawa
    • An QiuRyusuke Hasegawa
    • G08B1314
    • G08B13/2411G08B13/242G08B13/2445G08B13/2448
    • Electronic article surveillance markers, methods for their production and for their use are disclosed. In one aspect there is provided an integrated deactivatable hybrid marker which can be used both in radio frequency and magnetic harmonic article surveillance systems. The harmonics generating element or elements of the marker are inserted into a RF resonant circuit as an active part of the circuit. The deactivation of the marker is accomplished by employing another element of high coercivity magnetic material. When placed in a RF interrogation field, the hybrid marker causes an increase in absorption of transmitted signal in order to reduce the signal in the receiving coil of the RF surveillance system. When placed in an interrogation zone of a magnetic harmonic article surveillance system, the marker generates high harmonics of the interrogating frequency that can be detected by the receiver of the surveillance system. In addition both the RF and harmonic functions of the hybrid marker can be deactivated by a single process. Further more, the use of conductive paste material to print the RF circuits is disclosed to achieve a low cost manufacturing process.
    • 公开了电子物品监视标记,其生产方法和用途。 在一个方面,提供了可以在射频和磁谐波物品监视系统中使用的集成的可去活化混合标记。 将谐波产生元件或标记的元件作为电路的有源部分插入到RF谐振电路中。 通过使用高矫顽力磁性材料的其它元件来实现标记的失活。 当放置在RF询问场中时,混合标记导致传输信号的吸收增加,以便减少RF监视系统的接收线圈中的信号。 当放置在磁谐波物品监视系统的询问区域时,标记产生可由监视系统的接收器检测的询问频率的高次谐波。 此外,混合标记的RF和谐波功能可以通过单个过程去激活。 此外,公开了使用导电糊材料来印刷RF电路以实现低成本的制造工艺。
    • 9. 发明授权
    • Metallic glass alloys for mechanically resonant marker surveillance
systems
    • 用于机械共振标记监视系统的金属玻璃合金
    • US5650023A
    • 1997-07-22
    • US465051
    • 1995-06-06
    • Ryusuke HasegawaRonald Martis
    • Ryusuke HasegawaRonald Martis
    • C22C45/02C22C45/00G08B13/24H01F1/153
    • G08B13/2408C22C45/00G08B13/2442H01F1/15308H01F1/15316H01F1/15341
    • A glassy metal alloy consists essentially of the formula Fe.sub.a Co.sub.b Ni.sub.c M.sub.d B.sub.c Si.sub.f C.sub.g, where "M" is at least one member selected from the group consisting of molybdenum, chromium and manganese, "a-g" are in atom percent, "a" ranges from about 30 to about 45, "b" ranges from about 4 to about 40, "c" ranges from about 5 to about 45, "d" ranges from about 0 to about 3, "3" ranges from about 10 to about 25, "f" ranges from about 0 to about 15 and "g" ranges from about 0 to about 2. The alloy can be cast by rapid solidification into ribbon, annealed to enhance magnetic properties, and formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically. Voltage amplitudes detected for the marker are high, and interference between surveillance systems based on mechanical resonance and harmonic re-radiance is virtually eliminated.
    • 玻璃状金属合金主要由式FeaCobNicMdBcSifCg组成,其中“M”为选自钼,铬和锰的至少一种,“ag”为原子百分数,“a”为约30至约45 ,“b”为约4至约40,“c”为约5至约45,“d”为约0至约3,“3”为约10至约25,“f”为 约0至约15,“g”的范围为约0至约2.该合金可以通过快速固化成带状,退火以提高磁性,并形成特别适用于磁机械致动的标记 文章监控系统。 有利地,标记的特征在于频率范围内的相对线性的磁化响应,其中谐波标记系统以磁性方式操作。 检测到的标记电压幅度很大,实际上消除了基于机械共振和谐波重新辐射的监视系统之间的干扰。
    • 10. 发明授权
    • Metallic glass alloys for mechanically resonant marker surveillance
systems
    • 用于机械共振标记监视系统的金属玻璃合金
    • US5628840A
    • 1997-05-13
    • US421094
    • 1995-04-13
    • Ryusuke Hasegawa
    • Ryusuke Hasegawa
    • C22C45/02C22C45/00G08B13/24H01F1/153
    • G08B13/2408C22C45/00G08B13/2442H01F1/15308H01F1/15316H01F1/15341
    • A glassy metal alloy consists essentially of the formula Fe.sub.a Co.sub.b Ni.sub.c M.sub.d B.sub.e Si.sub.f C.sub.g, where "M" is at least one member selected from the group consisting of molybdenum, chromium and manganese, "a-g" are in atom percent, "a" ranges from about 30 to about 45, "b" ranges from about 4 to about 40, "c" ranges from about 5 to about 45, "d" ranges from about 0 to about 3, "3" ranges from about 10 to about 25, "f" ranges from about 0 to about 15 and "g" ranges from about 0 to about 2. The alloy can be cast by rapid solidification into ribbon or otherwise formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically. Voltage amplitudes detected for the marker are high, and interference between surveillance systems based on mechanical resonance and harmonic re-radiance is virtually eliminated.
    • 玻璃状金属合金主要由式FeaCobNicMdBeSifCg组成,其中“M”为选自钼,铬和锰的至少一种,“ag”为原子百分数,“a”为约30至约45 ,“b”为约4至约40,“c”为约5至约45,“d”为约0至约3,“3”为约10至约25,“f”为 约0至约15,“g”的范围为约0至约2.合金可以通过快速固化成带状或以其它方式形成特别适用于磁机械致动物品监视系统的标记。 有利地,标记的特征在于频率范围内的相对线性的磁化响应,其中谐波标记系统以磁性方式操作。 检测到的标记电压幅度很大,实际上消除了基于机械共振和谐波重新辐射的监视系统之间的干扰。