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1. 发明授权

US5726222A Microcapsule-type curing agent, method for producing the same, thermosetting resin composition, prepreg and fiber reinforced composite material 失效
标题翻译：微胶囊型固化剂，其制备方法，热固性树脂组合物，预浸料和纤维增强复合材料
公开(公告)号：US5726222A
公开(公告)日：1998-03-10
申请号：US838443
申请日：1997-04-07
申请人： Ryuji Sawaoka , Shinji Kouchi , Toshio Muraki
发明人： Ryuji Sawaoka , Shinji Kouchi , Toshio Muraki
IPC分类号： C08J3/24 , C08K9/10 , C12N1/21 , C12N15/31 , C12N15/52 , C12N15/63 , C12N15/70
CPC分类号： C08J3/241 , C08J5/24 , C08K9/10 , Y10S525/936
摘要： Disclosed is a microcapsule-type curing agent comprising (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin dissolvable to the thermosetting resin by heating. The microcapsule-type curing agent is formed as a particle-like material in which the component (A) is coated with a layer whose main constituent is the component (B) and the mean particle diameter of which is in the range of 0.1 to 20 .mu.m. By using the microcapsule-type curing agent, a thermosetting resin composition and a prepreg which are good in storage stability at a room temperature and excellent in thermal resistance of a cured product made therefrom can be obtained. Further, a fiber reinforced composite material obtained using this thermosetting resin composition is excellent in curing uniformity and thermal resistance.
摘要翻译：公开了一种微胶囊型固化剂，其包含（A）热固性树脂用固化剂和（B）通过加热可溶解于热固性树脂的热塑性树脂。微胶囊型固化剂形成为其中组分（A）涂覆有主要成分为组分（B）的层并且其平均粒径在0.1至20范围内的颗粒状材料亩通过使用微胶囊型固化剂，可以得到在室温下的保存稳定性好，由其制成的固化物的耐热性优异的热固性树脂组合物和预浸料坯。此外，使用这种热固性树脂组合物获得的纤维增强复合材料具有优异的固化均匀性和耐热性。

2. 发明授权

US5589523A Microcapsule-type curing agent, method for producing the same, thermosetting resin composition, prepreg and fiber reinforced composite material 失效
标题翻译：微胶囊型固化剂，其制备方法，热固性树脂组合物，预浸料和纤维增强复合材料
公开(公告)号：US5589523A
公开(公告)日：1996-12-31
申请号：US468445
申请日：1995-06-06
申请人： Ryuji Sawaoka , Shinji Kouchi , Toshio Muraki
发明人： Ryuji Sawaoka , Shinji Kouchi , Toshio Muraki
IPC分类号： C08J3/24 , C08K9/10 , C12N1/21 , C12N15/31 , C12N15/52 , C12N15/63 , C12N15/70
CPC分类号： C08J3/241 , C08J5/24 , C08K9/10 , Y10S525/936
摘要： Disclosed is a microcapsule curing agent including (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin. The microcapsule curing agent is formed as a particle-like material in which component (A) is coated with a layer whose main constituent is component (B) and the mean particle diameter of which is in the range of 0.1 to 20 .mu.m. By using the microcapsule curing agent, a thermosetting resin composition and a prepreg which exhibit good storage stability at room temperature and are excellent in thermal resistance for cured products made therefrom can be obtained. A fiber reinforced composite material obtained using the thermosetting resin composition is excellent in curing uniformity and thermal resistance.
摘要翻译：公开了一种微胶囊固化剂，其包含（A）热固性树脂用固化剂和（B）热塑性树脂。微胶囊固化剂形成为其中组分（A）涂覆有主要成分为组分（B）的层并且其平均粒径在0.1-20μm范围内的颗粒状材料。通过使用微胶囊固化剂，可以获得在室温下显示良好的储存稳定性并且由其制备的固化产物的耐热性优异的热固性树脂组合物和预浸料坯。使用该热固性树脂组合物得到的纤维增强复合材料的固化均匀性和耐热性优异。

3. 发明授权

US5599612A Woven carbon fiber fabric 失效
标题翻译：编织碳纤维织物
公开(公告)号：US5599612A
公开(公告)日：1997-02-04
申请号：US408730
申请日：1995-03-22
申请人： Toshio Muraki , Masazumi Tokunou , Ryuji Sawaoka , Masahiko Hayashi , Toshiaki Higashi , Tokuo Tazaki
发明人： Toshio Muraki , Masazumi Tokunou , Ryuji Sawaoka , Masahiko Hayashi , Toshiaki Higashi , Tokuo Tazaki
IPC分类号： C08J3/24 , C08J5/06 , C08J5/24 , B32B7/00
CPC分类号： C08J3/242 , C08J5/06 , C08J5/24 , C08J2363/00 , Y10S428/902 , Y10T428/30 , Y10T428/31511 , Y10T442/2008 , Y10T442/2098 , Y10T442/2951
摘要： A prepreg precursor including a carbon fiber woven fabric having applied to the fabric between about 0.5 to about 10 wt % of a stabilizer material for stabilizing the structural form of the fabric. Prepregs can then be produced using the woven fabric. Undesired settlement of matrix resin from the surface of the woven fabric is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of surface resin.
摘要翻译：一种包括碳纤维织物的预浸料前体，该碳纤维织物已经在织物上施加约0.5至约10重量％的用于稳定织物结构形式的稳定剂材料。然后可以使用织造织物制备预浸料。因此防止了从机织织物表面出现的不希望的基质树脂沉降。因此，与使用常规机织织物制备的预浸料相比，通过使用本发明的织物制备的预浸料可以长期保持其粘性，并且可以用于生产平滑性优异而不缺乏表面的纤维增强复合材料树脂。

4. 发明授权

US5151322A Thermoplastic composite plate material and products molded from the same 失效
标题翻译：热塑复合板材及其制品
公开(公告)号：US5151322A
公开(公告)日：1992-09-29
申请号：US440367
申请日：1989-11-22
申请人： Yukitane Kimoto , Kohzou Murata , Toshio Muraki
发明人： Yukitane Kimoto , Kohzou Murata , Toshio Muraki
IPC分类号： B29B11/16 , B29C45/00 , B29C45/02 , B29C70/06 , B29C70/14 , B29C70/46 , B29K101/12 , B29K105/06 , C08J5/24 , F02F7/00
CPC分类号： B29C70/46 , B29C45/0005 , B29C45/02 , B29C70/14 , B29L2031/322 , F02F7/006 , Y10T428/249945 , Y10T428/249946 , Y10T428/249947 , Y10T428/30 , Y10T428/31623
摘要： A thermoplastic composite plate material having a quasi isotropy comprises a thermoplastic resin having a melt viscosity of 1,000-15,000 poise and strip pieces each constructed of unidirectionally orientated reinforcing fibers and each having the specific dimensions of the thickness, the width, the length and the ratio of the width and the length thereof. The strip pieces are randomly distributed in plane parallel to a surface of the composite plate material. Since the composite plate material has good quasi-isotropic and high mechanical properties such as flexural strength, flexural modulus and impact strength, a composite product having good quasi-isotropic and high mechanical properties can be obtained by using the composite plate materials. Moreover, since the composite plate material has a good fittability, a composite product having a complicated shape can be easily molded.

5. 发明授权

US06267920B1 Hydrostatic compression method for producing a fancy log from a primary wood 失效
标题翻译：用于从原木生产花式木材的静压压缩方法
公开(公告)号：US06267920B1
公开(公告)日：2001-07-31
申请号：US08929651
申请日：1997-09-16
申请人： Tamio Arakawa , Akihiko Ito , Toshio Muraki , Masako Sakurai
发明人： Tamio Arakawa , Akihiko Ito , Toshio Muraki , Masako Sakurai
IPC分类号： B29C4310
CPC分类号： B27K5/001 , B27K3/15 , B27K5/06 , B27M1/02
摘要： A hydrostatic compression method for producing a fancy log with a decorative and complicated external appearance from a primary wood. In the method, a primary wood having a water content adjusted in the range of 10-80 wt % is brought into a softened state, then the softened wood is compressed with hydrostatic pressure by means of liquid as pressurizing medium. Next, the compressed wood is treated with a fixation means to fix the compressed state. The fixation means can be a shaping jig, a mold, heating in a particular temperature range conducted while constraining the volume relation of compressed wood, cooling down below the softening point of the wood while under pressure, compact-packing together with hard particles into a vessel followed by heating, or a primary wood is chemically treated to form a localized wood-plastics composite before applying hydrostatic compression.
摘要翻译：一种用于从原木生产具有装饰性和复杂外观的花式木材的静水压缩方法。在该方法中，将水分调节在10-80重量％范围内的初级木材进入软化状态，然后通过作为加压介质的液体以静水压力压缩软化木材。接下来，用固定装置处理压缩木材以固定压缩状态。定影装置可以是成形夹具，模具，在限制压缩木材的体积关系的同时进行的特定温度范围的加热，在压力下冷却到低于木材的软化点，与硬颗粒一起压实成为然后加热，或者在施加静水压力之前，对原木进行化学处理以形成局部的木塑复合材料。

6. 发明授权

US06250350B1 Method of impregnating wood with liquid 失效
标题翻译：用液体浸渍木材的方法
公开(公告)号：US06250350B1
公开(公告)日：2001-06-26
申请号：US08937472
申请日：1997-09-25
申请人： Toshio Muraki , Masahiro Funato , Akiko Hoshino , Tamio Arakawa
发明人： Toshio Muraki , Masahiro Funato , Akiko Hoshino , Tamio Arakawa
IPC分类号： B27M100
CPC分类号： B27K3/163 , B27K3/08 , B27K3/15 , Y10T428/249925 , Y10T428/2904
摘要： A method of impregnating wood with liquid puts the wood in a pressure vessel, immerses the wood in the liquid contained in the pressure vessel, pressurizes the liquid to compress the wood while keeping the temperature of the wood at or above the softening point of the wood, and reduces pressure in the pressure vessel so that the wood may cause volume relaxation in the liquid and be impregnated with the liquid.
摘要翻译：用液体浸渍木材的方法将木材放入压力容器中，将木材浸入包含在压力容器中的液体中，对液体加压以压缩木材，同时将木材的温度保持在木材的软化点或高于木材的软化点，并且降低压力容器中的压力，使得木材可能导致液体中的体积松弛并且被液体浸渍。

7. 发明授权

US4323639A Photosensitive polyamide resin composition 失效
标题翻译：光敏聚酰胺树脂组合物
公开(公告)号：US4323639A
公开(公告)日：1982-04-06
申请号：US202381
申请日：1980-07-24
申请人： Kazumasa Chiba , Keiichi Egawa , Toshio Muraki
发明人： Kazumasa Chiba , Keiichi Egawa , Toshio Muraki
IPC分类号： G03F7/037 , G03C1/68
CPC分类号： G03F7/037
摘要： A photosensitive resin composition comprising a polyamide containing 10 to 70% by weight of a polyoxyethylene segment or poly(oxyethylene/oxypropylene) copolymer segment having a number average molecular weight of from 150 to 1,500 in its molecular chain, and a photopolymerizable unsaturated compound. This composition exhibits excellent flexibility and water- and alcohol-developability, and results in a printing plate exhibiting excellent transparency, toughness and printing durability.
摘要翻译：一种感光性树脂组合物，其包含含有10〜70重量％的分子链中数均分子量为150〜1500的聚氧乙烯链段或聚（氧乙烯/氧丙烯）共聚物链段的聚酰胺和光聚合性不饱和化合物。该组合物显示出优异的柔软性和水和醇显影性，并且导致显示出优异的透明性，韧性和印刷耐久性的印刷版。

8. 发明授权

US4380622A Process for producing aliphatic copolyesteramide, an aliphatic copolyesteramide and tubing molded therefrom 失效
标题翻译：脂肪族共聚酯酰胺的制造方法，脂肪族共聚酯酰胺及其成型管
公开(公告)号：US4380622A
公开(公告)日：1983-04-19
申请号：US387334
申请日：1982-06-11
申请人： Kazumasa Chiba , Kazuhiko Kobayashi , Toshio Muraki
发明人： Kazumasa Chiba , Kazuhiko Kobayashi , Toshio Muraki
IPC分类号： C08G69/44 , C08G63/44 , C08G69/00
CPC分类号： C08G69/44
摘要： The aliphatic copolyesteramide having high degree of polymerization, is prepared by heating a mixture of (A) ester-forming components comprising (a) aliphatic diols and (b) aliphatic dicarboxylic acids and (B) amide-forming components comprising at least one component selected from the group consisting of (a) aliphatic .omega.-aminocarboxylic acids and (b) equimolar salt of (.alpha.) aliphatic diamines and (.beta.) aliphatic dicarboxylic acids, at temperatures of about 150.degree. to 260.degree. C., substantially under an atmospheric pressure, in the presence of catalyst and in the substantially absence of water, and subsequently heating the resulting esterified product at temperatures of about 200.degree. to 300.degree. C. under a reduced pressure. The obtained copolyesteramide can be formed into various molded articles, such as tubing, having excellent flexibility, toughness, shapability, chemical resistance, heat resistance, hydrolysis resistance and fatigue resistance.
摘要翻译：具有高聚合度的脂肪族共聚酯酰胺通过加热（A）成酯组分的混合物来制备，所述组分包含（a）脂肪族二醇和（b）脂族二羧酸和（B）含有至少一种所选成分的酰胺形成组分从（a）脂肪族ω-氨基羧酸和（b）（α）脂族二胺和（β）脂族二羧酸的等摩尔盐组成的组，在约150℃至260℃的温度下，基本上在大气压在催化剂存在下并且基本上不存在水的情况下，然后在减压下在约200℃至300℃的温度下加热得到的酯化产物。所获得的共聚酯酰胺可以形成为具有优异的柔韧性，韧性，成形性，耐化学性，耐热性，耐水解性和耐疲劳性的各种模制品如管材。

9. 发明授权

US4290935A Highly rigid polyamide composition 失效
标题翻译：高刚性聚酰胺组合物
公开(公告)号：US4290935A
公开(公告)日：1981-09-22
申请号：US88386
申请日：1979-10-25
申请人： Toshio Muraki
发明人： Toshio Muraki
IPC分类号： C08G69/14 , C08G69/16 , C08L77/02 , C08K5/20
CPC分类号： C08G69/16 , C08G69/14 , C08L77/02
摘要： A highly rigid poly-.epsilon.-caproamide composition containing about 50 to 5000 ppm of barium combined with the poly-.epsilon.-caproamide, and having a .gamma.-type crystal ratio of about 0.3 to 0.7 is disclosed. The polyamide has improved rigidity without loss of other advantageous mechanical properties of poly-.epsilon.-caprolactam. By addition of an aluminum compound, the rigidity of the composition can be further improved. A bisamide compound may be added to provide excellent mold release without harming the mechanical properties of the composition.
摘要翻译：公开了一种高刚性聚ε-己内酰胺组合物，其含有约50-5000ppm的钡与聚ε-己酰胺结合，并具有约0.3至0.7的γ型晶体比。聚酰胺具有改善的刚性，而不损失聚ε-己内酰胺的其它有利的机械性能。通过添加铝化合物，可以进一步提高组合物的刚性。可以加入双酰胺化合物以提供优异的脱模而不损害组合物的机械性能。

10. 发明授权

US3940373A Copolyamide of caprolactam 失效
标题翻译：己内酰胺共聚酰胺
公开(公告)号：US3940373A
公开(公告)日：1976-02-24
申请号：US455056
申请日：1974-03-27
申请人： Toshio Muraki , Yasuo Miura , Hiroshi Kodama
发明人： Toshio Muraki , Yasuo Miura , Hiroshi Kodama
IPC分类号： C08G69/00 , C08G69/36 , C08L77/00 , C08G69/14 , C08G69/46
CPC分类号： C08G69/36
摘要： A novel copolyamide is obtained by copolymerizing a three-component system comprising .epsilon.-caprolactam; a salt of hexamethylenediamine and adipic acid; and a salt of 1,3-cyclohexanebis (methylamine) and adipic acid, in the specified proportions shown in the drawing.The copolyamide is easily soluble in lower aliphatic alcohols and has good transparency. Solutions of the copolyamide in alcohol have superior stability.
摘要翻译：通过共聚包含ε-己内酰胺的三组分体系获得新型共聚酰胺; 六亚甲基二胺和己二酸的盐; 和1,3-环己烷二甲酸（甲胺）和己二酸的盐，按照图中所示的规定比例。

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