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    • 4. 发明申请
    • NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
    • 非电解电解质二次电池
    • US20130101899A1
    • 2013-04-25
    • US13806020
    • 2011-06-06
    • Tetsuya KajitaHiroo TakahashiRyuichi KasaharaJiro IriyamaTatsuji Numata
    • Tetsuya KajitaHiroo TakahashiRyuichi KasaharaJiro IriyamaTatsuji Numata
    • H01M4/485H01M10/04H01M4/525
    • H01M4/485H01M4/131H01M4/133H01M4/134H01M4/525H01M10/04Y10T29/49108
    • There is provided a nonaqueous electrolyte secondary battery having high capacity in which the reduction in the capacity of the battery due to the irreversible capacity in the first charge and discharge is suppressed using a high capacity positive electrode. The nonaqueous electrolyte secondary battery according to the exemplary embodiment includes a positive electrode and a negative electrode including at least one negative electrode active material selected from the group consisting of Si, a Si oxide and carbon, wherein the positive electrode includes a positive electrode active material including an oxide capable of absorbing and releasing lithium and a transition metal oxide, the transition metal oxide being represented by Li2MO2 (wherein M is at least one of Cu and Ni) and including a square-planar coordination MO4 structure, the square-planar coordination MO4 structure forming a one-dimensional chain which shares an edge formed by two opposing oxygen atoms, wherein the relation Z≦Y is satisfied provided that Y represents the first charge capacity of the negative electrode, and Z represents the first charge capacity of the positive electrode.
    • 提供了一种高容量的非水电解质二次电池,其中使用高容量正极抑制了由于第一次充放电中的不可逆容量引起的电池容量的降低。 本实施方式的非水电解质二次电池包括正极和负极,所述正极和负极具有选自由Si,Si氧化物和碳组成的组中的至少一种负极活性物质,其中所述正极包含正极活性物质 包括能够吸收和释放锂的氧化物和过渡金属氧化物,所述过渡金属氧化物由Li2MO2(其中M是Cu和Ni中的至少一种)表示,并且包括正方形协调MO4结构,所述正方形配位 形成共享由两个相对的氧原子形成的边缘的一维链的MO4结构,其中满足关系Z @ Y,其中Y表示负极的第一充电容量,Z表示正极的第一充电容量 电极。
    • 7. 发明授权
    • Lithium secondary battery and control system therefor, and method for detecting state of lithium secondary battery
    • 锂二次电池及其控制系统,以及锂二次电池的状态检测方法
    • US09018916B2
    • 2015-04-28
    • US13811837
    • 2011-07-20
    • Jiro IriyamaTetsuya KajitaDaisuke KawasakiRyuichi KasaharaTatsuji Numata
    • Jiro IriyamaTetsuya KajitaDaisuke KawasakiRyuichi KasaharaTatsuji Numata
    • H02H3/24G01R31/36H01M4/485H01M10/44H01M10/48G06F17/15H02J7/00
    • H01M10/48G01R31/362G01R31/3648G06F17/15H01M4/485H01M10/44H02J7/00H02J7/007Y02E60/122Y02P70/54
    • There is provided a control system for a lithium secondary battery that can quantitatively sense a deterioration state inherent in a lithium secondary battery using silicon oxide as a negative electrode active material, that is, the nonuniform reaction state of a negative electrode. A control system for a lithium secondary battery including a positive electrode, a negative electrode using silicon oxide as a negative electrode active material, and a lithium reference electrode having a reference potential with respect to the negative electrode includes measurement means for measuring a voltage V of the negative electrode with respect to the lithium reference electrode and a discharge capacity Q of the lithium secondary battery during discharge of the lithium secondary battery; generation means for generating a V-dQ/dV curve representing a relationship between dQ/dV, which is a proportion of an amount of change dQ in the discharge capacity Q to an amount of change dV in the voltage V, and the voltage V; calculation means for calculating an intensity ratio of two peaks appearing on the V-dQ/dV curve for two voltage values in the voltage V; and sensing means for sensing a state of the negative electrode utilizing the intensity ratio.
    • 提供了一种锂二次电池的控制系统,其可以使用氧化硅作为负极活性物质,即负极的不均匀的反应状态来定量地感测锂二次电池固有的劣化状态。 一种锂二次电池的控制系统,包括正电极,使用氧化硅作为负电极活性材料的负极和相对于负电极具有参考电位的锂参比电极,包括用于测量电压V的电压V的测量装置 相对于锂参考电极的负极和锂二次电池放电期间的锂二次电池的放电容量Q; 用于产生表示作为放电容量Q中的变化量dQ与电压V中的变化量dV的比例的dQ / dV与电压V之间的关系的V-dQ / dV曲线的生成装置; 用于计算在V-dQ / dV曲线上出现的两个电压在电压V中的两个电压值的强度比的计算装置; 以及感测装置,用于利用强度比来感测负极的状态。