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1. 发明授权

US5112689A Composite particle 失效
标题翻译：复合颗粒
公开(公告)号：US5112689A
公开(公告)日：1992-05-12
申请号：US447511
申请日：1989-12-07
申请人： Tasaburo Ueno , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Naoya Yabuuchi
发明人： Tasaburo Ueno , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Naoya Yabuuchi
IPC分类号： C08J3/12 , C09D5/03 , G03G9/087
CPC分类号： C09D5/03 , G03G9/08791 , G03G9/08795 , G03G9/08797 , Y10T428/2991 , Y10T428/2998
摘要： The invention relates to a composite particle comprising 2 to 98% by weight of a base resin having softending point of -10.degree. to 120.degree. C. and a number average molecular weight of 600 or more and 98 to 2% by weight of an anisotropic crystalline polymer having a phase transition point of 60.degree. to 230.degree. C. and a number average molecular weight of 600 to 10,000 and capable for forming an anisotropic molten phase, the polymer having the specific structure in which a repeating unit of the formula:A--X--B (I)(wherein 100 to 50 mol % of A stands for defined mesogenic group, 0 to 50 mole % of A is p-phenylene, m-phenylene or trans-1,4-cyclohexylene, B is a defined spacer group, and X is ester bond, carbonate bond, amide bond, urethane bond or urea bond, and a repeating unit of the formula:R (II)in which R stands for bivalent to hexavalent hydrocarbon residue, are connected, in any successive orders and in a weight ratio of (I)/(II)=99.9/0.1 to 60/40, with each other through ester bond, carbonate bond, amide bond, urethane bond or urea bond, and end portions are occupied by a functional group as hydroxyl, carboxyl and the like. The composition particle is useful as powder coating, dry toner and the like.

2. 发明授权

US5070161A Heat-latent, cationic polymerization initiator and resin compositions containing same 失效
公开(公告)号：US5070161A
公开(公告)日：1991-12-03
申请号：US356903
申请日：1989-05-25
申请人： Shinji Nakano , Hiroharu Ohsugi , Yasuhiko Nakae , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Takeshi Endo
发明人： Shinji Nakano , Hiroharu Ohsugi , Yasuhiko Nakae , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Takeshi Endo
IPC分类号： C07D213/20 , C07D213/61 , C07D213/84 , C08F4/20 , C08F4/42 , C08G59/68 , C08G65/10 , C08G85/00 , C08K5/19 , C08K5/3432
CPC分类号： C07D213/20 , C07D213/61 , C07D213/84 , C08G59/686 , C08G65/105 , C08G85/00 , C08K5/19 , C08K5/3432
摘要： Benzyl pyridinium or ammonium salts of a non-nucleophilic anion are useful as a cationic polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.

3. 发明授权

US5248809A Process for preparing a polymerizable compound having both polymerizable double bond and hydroxyl group 失效
标题翻译：制备具有两个可聚合的双键和羟基的聚合物的方法
公开(公告)号：US5248809A
公开(公告)日：1993-09-28
申请号：US432873
申请日：1989-11-07
申请人： Ryozo Takagawa , Hisaki Tanabe , Yoshio Eguchi , Koichi Tsutsui
发明人： Ryozo Takagawa , Hisaki Tanabe , Yoshio Eguchi , Koichi Tsutsui
IPC分类号： C07C233/20 , C08F20/28 , C08F20/58 , C08F299/04 , C08G63/08 , C08G63/685 , C09D151/00
CPC分类号： C08G63/6852 , C07C233/20 , C08F20/28 , C08F20/58 , C08F299/0485 , C08G63/08 , C09D151/003
摘要： A process for preparing a polymerizable compound of the formula: ##STR1## or a polymerizable compound of the formula: ##STR2## is provided. These formed compounds are useful for the preparation of an acrylic resin which is low in viscosity and capable of forming a coating with excellent flexibility, weather resistance and water resistance.

4. 发明授权

US5306806A Thermosetting polyester resin and powder coating resinous composition containing the same 失效
标题翻译：热固性聚酯树脂和粉末涂料含有相同的树脂组合物
公开(公告)号：US5306806A
公开(公告)日：1994-04-26
申请号：US560226
申请日：1990-07-20
申请人： Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi
发明人： Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi
IPC分类号： C08G63/185 , C08G63/672 , C09D167/02 , C08G63/00
CPC分类号： C09D167/02 , C08G63/185 , C08G63/672
摘要： The invention concerns a thermosetting polyester resin capable of forming an anisotropic molten phase comprising a repeating unit of the formula: A-X-B alone, or a combination of the repeating unit of the formula: A-X-B and the repeating unit of the formula: R, adjoining two repeating units being connected each other through an ester bond, in which A represents a mesogenic group defined in the specification, B is a spacer group defined in the specification, X is an ester bond, and R represents a bivalent to hexavalent aliphatic, aromatic or alicyclic hydrocarbon residue, the end bondings of the connected repeating units being occupied by OH, COOH or their reactive derivatives and the sum of the resinous acid value and the OH value being 10 to 200.The invention also provides a powder coating resinous composition containing the abovesaid resin.
摘要翻译：本发明涉及一种能够形成各向异性熔融相的热固性聚酯树脂，其包含下式的重复单元：单独的AXB，或下式的重复单元：AXB和式R的重复单元的组合：邻接两个重复的单元通过酯键彼此连接，其中A表示说明书中定义的介晶基团，B是说明书中定义的间隔基团，X是酯键，R代表二价至六价的脂族，芳族或脂环族烃残基，所连接的重复单元的末端键合被OH，COOH或它们的活性衍生物占据，并且树脂酸值和OH值的总和为10〜200。本发明还提供了含有上述物质的粉末涂料树脂组合物树脂。

5. 发明授权

US4978777A Novel polymerizable vinyl monomers and vinyl resins prepared therefrom 失效
标题翻译：由其制备的新型可聚合乙烯基单体和乙烯基树脂
公开(公告)号：US4978777A
公开(公告)日：1990-12-18
申请号：US180072
申请日：1988-04-11
申请人： Ryozo Takagawa , Hisaki Tanabe , Koji Asakura , Mitsuo Yamada , Hiroharu Ohsugi , Ryuzo Mizuguchi , Yoshio Eguchi
发明人： Ryozo Takagawa , Hisaki Tanabe , Koji Asakura , Mitsuo Yamada , Hiroharu Ohsugi , Ryuzo Mizuguchi , Yoshio Eguchi
IPC分类号： C07C67/24 , C07C69/54 , C08F220/28
CPC分类号： C08F220/28 , C07C67/24 , C07C69/54
摘要： A polymerizable vinyl monomer represented by the formula: ##STR1## wherein R represents a hydrogen atom or methyl group and n is a real number of 3 to 100, and preparation thereof. The vinyl monomer is useful for the preparation of vinyl resin which is highly reactive in crosslinking with a hardener and capable of resulting in a coating of resilient, tough and flexible nature.

6. 发明授权

US4891419A Modified polyester resin composition containing isonanoic acid and a cyclic ester 失效
标题翻译：含有异壬酸和环状酯的改性聚酯树脂组合物
公开(公告)号：US4891419A
公开(公告)日：1990-01-02
申请号：US119834
申请日：1987-11-12
申请人： Ryozo Takagawa , Hisaki Tanabe , Koichi Inoue , Hirotoshi Umemoto
发明人： Ryozo Takagawa , Hisaki Tanabe , Koichi Inoue , Hirotoshi Umemoto
IPC分类号： C08G63/48 , C08G63/46 , C08G63/60 , C09D167/00 , C09D167/08
CPC分类号： C08G63/60 , C09D167/00
摘要： A modified polyester resin composition for coating use comprising a polyester resin modified with 5 to 30% by weight of the total solid of a branched fatty acid having 8 and more carbon atoms and with 5 to 30% by weight of the total solid of a cyclic ester represented by the formula: ##STR1## wherein R represents an alkylene group having 4 to 10 carbon atoms, the resin having a hydroxyl value of 70 to 300. The present resin composition is specifically useful as resinous vehicle in a top coat composition for plastic and other substrates.
摘要翻译：一种涂料用改性聚酯树脂组合物，其包含用5至30重量％的具有8个或更多个碳原子的支链脂肪酸的总固体和5至30重量％总固体的环状由下式表示的酯：其中R表示具有4-10个碳原子的亚烷基，该树脂的羟值为70〜300。本发明的树脂组合物特别可用作塑料用面漆组合物中的树脂载体和其他底物。

7. 发明授权

US4810758A Resinous composition for coating use, which is excellent in weather resistance and in low temperature curing properties, its preparation and coating composition containing the same 失效
标题翻译：其耐候性和低温固化性优异的涂料用树脂组合物及其制备方法和含有它们的涂料组合物
公开(公告)号：US4810758A
公开(公告)日：1989-03-07
申请号：US25281
申请日：1987-03-12
申请人： Hisaki Tanabe , Ryozo Takagawa , Hirotoshi Umemoto
发明人： Hisaki Tanabe , Ryozo Takagawa , Hirotoshi Umemoto
IPC分类号： C09D201/00 , C09D167/00 , C09D201/08 , C08F20/00
CPC分类号： C09D201/08 , C09D167/00
摘要： A resinous composition for coating use which is excellent in weather resistance and in low temperature curing properties, comprising a resin having resinous acid value based on carboxyl groups derived from its constituting tetrachlorophthalic acid of 2 to 8, a resinous acid value based on sulfonic acid groups derived from its constituting sulfophthalic acid of 0.5 to 5, and a functional group capable of reacting with a crosslinking agent to be compounded with the resin. The present resin is useful, in the combination form with a crosslinking agent, as a resinous vehicle of a coating composition which is excellent in curing properties, weather resistance, pigment dispersibility and storage stability and is specifically useful as an intermediate or top coat paint for automobile bodies or the like.
摘要翻译：一种耐候性和低温固化性优异的涂料用树脂组合物，其含有树脂酸值基于其构成的四氯邻苯二甲酸的羧基为2-8的树脂酸值，基于磺酸基的树脂酸值衍生自其构成的0.5〜5的间苯二甲酸，以及能够与与树脂配混的交联剂反应的官能团。本树脂与交联剂的组合形式可用作固化性，耐候性，颜料分散性和储存稳定性优异的涂料组合物的树脂载体，并且特别适用于作为中间或面漆涂料汽车车身等。

8. 发明授权

US5066722A Heat-latent curing catalyst and resin compositions containing the same 失效
标题翻译：热固化固化催化剂和含有它的树脂组合物
公开(公告)号：US5066722A
公开(公告)日：1991-11-19
申请号：US485897
申请日：1990-03-01
申请人： Shinji Nakano , Hiroharu Ohsugi , Satoshi Urano , Masamichi Furukawa , Ryozo Takagawa , Yoshio Eguchi , Takeshi Endo
发明人： Shinji Nakano , Hiroharu Ohsugi , Satoshi Urano , Masamichi Furukawa , Ryozo Takagawa , Yoshio Eguchi , Takeshi Endo
IPC分类号： C07C211/63 , C07C211/64 , C07C215/40 , C07C215/66 , C07C217/58 , C07C309/30 , C07C309/31 , C07D213/20 , C07D213/84 , C08G59/68 , C08K5/42 , C08L61/28 , C08L63/00 , C09D133/06 , C09D143/04 , C09D201/10
CPC分类号： C07D213/20 , C07C211/63 , C07C211/64 , C07C215/40 , C07C215/66 , C07C217/58 , C07C309/30 , C07C309/31 , C07D213/84 , C08G59/686 , C08G59/687 , C08K5/42 , C08L61/28 , C08L63/00 , C09D133/066 , C09D143/04 , C09D201/10
摘要： Benzylpyridinium or benzylammonium salts of a benzenesulfonate anion are useful as a proton-donating curing catalyst ion a resinous system capable of curing in the presence of such a catalyst. The catalyst is characterized by its heat-latent nature and thus does not impair the storage stability of the resinous system at an ambient temperature.

9. 发明授权

US5208289A Curing resin composition and its cured product 失效
标题翻译：固化树脂组合物及其固化产品
公开(公告)号：US5208289A
公开(公告)日：1993-05-04
申请号：US675620
申请日：1991-03-27
申请人： Mitsuhiro Takarada , Yuji Yoshikawa , Kenji Yamamoto , Hiroharu Ohsugi , Atsushi Ohgaki , Ryozo Takagawa
发明人： Mitsuhiro Takarada , Yuji Yoshikawa , Kenji Yamamoto , Hiroharu Ohsugi , Atsushi Ohgaki , Ryozo Takagawa
IPC分类号： C08L33/06 , C08G59/00 , C08K5/5419 , C08L33/04 , C08L63/00 , C08L67/00 , C08L67/02 , C08L83/04 , C08L83/05 , C08L101/02 , C09D133/04 , C09D163/00 , C09D183/05
CPC分类号： C08K5/5419 , C08L101/02
摘要： This invention discloses a curing resin composition comprising (a) an organic resin containing no less than 2 alkenyl groups per molecule, and having a number average molecular weight of 500-100,000. (b) an organohydrogen-polysiloxane containing no less than 2 Si--H bonds per molecule, and (c) a platinum catalyst. It is desired that the organic resin of component (a) is at least one type chosen from acrylic, polyester and epoxy. The preferable amount of component (b) is such that there are 0.8-4 hydrogen atoms bonded to silicon atoms per alkenyl group of component (a).

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