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1. 发明授权

US5070161A Heat-latent, cationic polymerization initiator and resin compositions containing same 失效
公开(公告)号：US5070161A
公开(公告)日：1991-12-03
申请号：US356903
申请日：1989-05-25
申请人： Shinji Nakano , Hiroharu Ohsugi , Yasuhiko Nakae , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Takeshi Endo
发明人： Shinji Nakano , Hiroharu Ohsugi , Yasuhiko Nakae , Hisaki Tanabe , Ryozo Takagawa , Yoshio Eguchi , Koichi Tsutsui , Takeshi Endo
IPC分类号： C07D213/20 , C07D213/61 , C07D213/84 , C08F4/20 , C08F4/42 , C08G59/68 , C08G65/10 , C08G85/00 , C08K5/19 , C08K5/3432
CPC分类号： C07D213/20 , C07D213/61 , C07D213/84 , C08G59/686 , C08G65/105 , C08G85/00 , C08K5/19 , C08K5/3432
摘要： Benzyl pyridinium or ammonium salts of a non-nucleophilic anion are useful as a cationic polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.

2. 发明授权

US5066722A Heat-latent curing catalyst and resin compositions containing the same 失效
标题翻译：热固化固化催化剂和含有它的树脂组合物
公开(公告)号：US5066722A
公开(公告)日：1991-11-19
申请号：US485897
申请日：1990-03-01
申请人： Shinji Nakano , Hiroharu Ohsugi , Satoshi Urano , Masamichi Furukawa , Ryozo Takagawa , Yoshio Eguchi , Takeshi Endo
发明人： Shinji Nakano , Hiroharu Ohsugi , Satoshi Urano , Masamichi Furukawa , Ryozo Takagawa , Yoshio Eguchi , Takeshi Endo
IPC分类号： C07C211/63 , C07C211/64 , C07C215/40 , C07C215/66 , C07C217/58 , C07C309/30 , C07C309/31 , C07D213/20 , C07D213/84 , C08G59/68 , C08K5/42 , C08L61/28 , C08L63/00 , C09D133/06 , C09D143/04 , C09D201/10
CPC分类号： C07D213/20 , C07C211/63 , C07C211/64 , C07C215/40 , C07C215/66 , C07C217/58 , C07C309/30 , C07C309/31 , C07D213/84 , C08G59/686 , C08G59/687 , C08K5/42 , C08L61/28 , C08L63/00 , C09D133/066 , C09D143/04 , C09D201/10
摘要： Benzylpyridinium or benzylammonium salts of a benzenesulfonate anion are useful as a proton-donating curing catalyst ion a resinous system capable of curing in the presence of such a catalyst. The catalyst is characterized by its heat-latent nature and thus does not impair the storage stability of the resinous system at an ambient temperature.

3. 发明授权

US4829132A Resinous composition containing polyester resin, for coating use 失效
标题翻译：含有聚酯树脂的树脂组合物，用于涂料用途
公开(公告)号：US4829132A
公开(公告)日：1989-05-09
申请号：US88531
申请日：1987-08-21
申请人： Hirotoshi Umemoto , Hisaki Tanabe , Shinji Nakano
发明人： Hirotoshi Umemoto , Hisaki Tanabe , Shinji Nakano
IPC分类号： C08G63/199 , C08G63/16 , C08G63/20 , C08G63/48 , C08G63/91 , C09D167/00
CPC分类号： C08G63/48 , C08G63/20 , C09D167/00
摘要： Resinous composition for use in coating comprising a hexahydrophthalic acid or anhydride thereof whose acidic groups are capable of developing a resinous acid value and etherified aminoformaldehyde resin. This resinous composition is characterized by possessing all the advantages of oil-free polyester resin compositions such as good weather resistance mechanical properties in the coating, interlaminar adhesion and the like, and furthermore the composition inter alia, has excellent weather resistance because of its modification with saturated alicyclic acids and the curing properties are enhanced because of the control of the acidic groups which develops a resinous acid value. The invention also provides a coating composition, containing as a vehicle, the aforementioned resinous composition.
摘要翻译： PCT No.PCT / JP83 / 00294 Sec。 371日期：1984年5月2日 102（e）日期1984年5月2日PCT提交1983年9月2日PCT公布。公开号WO84 / 00972 日期为1984年3月15日。用于涂料的含有组合物的组合物，其包含其酸性基团能够显现树脂酸值和醚化的氨基甲醛树脂的六氢邻苯二甲酸或其酸酐。该树脂组合物的特征在于具有无油聚酯树脂组合物的所有优点，例如涂层中的耐候性机械性能，层间粘合性等，此外，组合物由于其改性而具有优异的耐候性，饱和脂环酸并且由于控制产生树脂酸值的酸性基团而提高了固化性能。本发明还提供一种包含作为载体的上述树脂组合物的涂料组合物。

4. 发明授权

US4563492A Resinous composition which is useful for the dispersion difficulty dispersible coloring matter 失效
标题翻译：可用于分散难分散色素的树脂组合物
公开(公告)号：US4563492A
公开(公告)日：1986-01-07
申请号：US574963
申请日：1984-01-30
申请人： Hirotoshi Umemoto , Hisaki Tanabe , Akihiro Kanakura , Shinji Nakano
发明人： Hirotoshi Umemoto , Hisaki Tanabe , Akihiro Kanakura , Shinji Nakano
IPC分类号： C09D161/20 , C08G18/08 , C08G63/685 , C09D161/32 , C09D167/00 , C09D175/00 , C09D175/04 , C09D175/06 , C09D201/02 , C08L67/08 , C08K5/34
CPC分类号： C09D161/32 , C08G18/0833 , C08G63/685 , C09D167/00
摘要： A resinous composition for coating use comprising an amphoteric resin having an acidic resinous component and a basic component of a basic compound, and an amino-formaldehyde resin etherified with monohydric alcohol having 1 to 4 carbon atoms and/or isocyanate compound, which is characterized by the fact that the basic component of a said amphoteric resin consists of a basic compound whose titration midpoint potential in non-aqueous potentiometric titration, when incorporated into the resin, is less than 450 mV, and the basicity of the amphoteric resin is within the range of 1.0.times.10.sup.-2 to 1.0 m mol/g solid. This composition can exhibit excellent pigment dispersibility and is useful as resinous vehicle for a coating composition to be used as a top coat for automobile bodies and the like.
摘要翻译：一种涂料用树脂组合物，其包含具有酸性树脂成分和碱性化合物碱性成分的两性树脂和与1〜4个碳原子的一元醇醚化的氨基甲醛树脂和/或异氰酸酯化合物，其特征在于，所述两性树脂的基本成分由在非水电位滴定中的滴定中点电位（当结合到树脂中）小于450mV的碱性化合物组成时，两性树脂的碱度在为1.0×10 -2〜1.0m mol / g固体。该组合物可以表现出优异的颜料分散性，并且可用作用作汽车车身等的顶涂层的涂料组合物的树脂载体。

5. 发明授权

US4535128A Polycarboxylic-alkyleneimine resinous composition and coating composition containing same 失效
标题翻译：聚羧酸 - 亚烷基亚胺树脂组合物和含有它们的涂料组合物
公开(公告)号：US4535128A
公开(公告)日：1985-08-13
申请号：US567314
申请日：1983-12-30
申请人： Hirotoshi Umemoto , Hisaki Tanabe , Shinji Nakano
发明人： Hirotoshi Umemoto , Hisaki Tanabe , Shinji Nakano
IPC分类号： C08F8/30 , C08G18/08 , C08G63/88 , C08G63/91 , C09D133/04 , C09D167/00 , C09D167/08 , C09D201/02 , C09D201/08 , C08L61/28
CPC分类号： C09D201/08 , C08G18/0823 , C09D167/00
摘要： A resinous composition for coating use comprising a resin obtained by the reaction of base resin having as essential groups, both carboxyl groups derived from a polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV in a state capable of developing a resinous acid value and a functional group reactive with a crosslinking agent, and an alkyleneimine compound in an amount equivalent to resinous acid value of 0.01 to 50, the resinous acid value based on said polycarboxylic acid in the final composition being 2 to 50.This is useful for the preparation of a coating composition having improved curing property, storage stability and time color stability.
摘要翻译：一种用于涂料用途的树脂组合物，其包含通过基本树脂作为必要基团反应获得的树脂，两个来自多元羧酸的羧基，其在非水电位滴定中的滴定中点电位大于-300mV，形成树脂酸值和与交联剂反应的官能团，以及相当于树脂酸值为0.01〜50的烯丙基亚胺化合物，最终组合物中所述多元羧酸的树脂酸值为2-50。这对于制备具有改进的固化性能，储存稳定性和时间颜色稳定性的涂料组合物是有用的。

6. 发明授权

US4578436A Coating resinous composition containing saturated alicyclic acid modified amphoteric polyester resin 失效
标题翻译：含有饱和脂环酸改性两性聚酯树脂的树脂组合物
公开(公告)号：US4578436A
公开(公告)日：1986-03-25
申请号：US608698
申请日：1984-05-02
申请人： Hirotoshi Umemoto , Hisaki Tanabe , Akihiro Kanakura , Shinji Nakano
发明人： Hirotoshi Umemoto , Hisaki Tanabe , Akihiro Kanakura , Shinji Nakano
IPC分类号： C08G63/199 , C08G63/16 , C08G63/20 , C08G63/48 , C08G63/685 , C08G63/91 , C09D167/00 , C08F20/00
CPC分类号： C09D167/00 , C08G63/20 , C08G63/48
摘要： A novel resinous composition used for coating comprising an amphoteric polyester resin whose acidic groups are capable of developing a resinous acid value are controlled in kind and are modified with saturated alicyclic acids and etherified amino-formaldehyde resins. This resinous composition is characterized by having all of the advantages possessed by oil-free polyester resin compositions in respect to weather resistance, the mechanical properties of the coating, interlaminar adhesion and the like, and furthermore, are excellent, inter alia, weather resistance because of be modified with saturated alicyclic acids. Also the curing properties are improved because of the control of the acidic groups and because the resins are amphoteric, they are compatible with melamine resins and have excellent pigment dispersibility. The invention also provides a coating composition containing as a vehicle, the abovementioned resinous composition.
摘要翻译： PCT No.PCT / JP83 / 00293 Sec。 371日期：1984年5月2日 102（e）日期1984年5月2日PCT提交1983年9月2日PCT公布。公开号WO84 / 00971 1984年3月15日。用于涂层的新型树脂组合物，其包含两性聚酯树脂，其酸性基团能够显现出树脂酸值，并以饱和脂环酸和醚化氨基甲醛树脂进行改性。该树脂组合物的特征在于具有无油聚酯树脂组合物在耐候性，涂层的机械性能，层间粘合性等方面具有的所有优点，此外，由于耐候性特别优异，因为被饱和脂环酸改性。由于酸性基团的控制，固化性能得到改善，并且由于树脂是两性的，它们与三聚氰胺树脂相容并且具有优异的颜料分散性。本发明还提供了含有作为载体的上述树脂组合物的涂料组合物。

7. 发明授权

US4501863A Polycarboxylic acid resinous composition, its preparation and coating composition containing the same 失效
标题翻译：聚羧酸树脂组合物，其制备方法和含有该组合物的涂料组合物
公开(公告)号：US4501863A
公开(公告)日：1985-02-26
申请号：US567313
申请日：1983-12-30
申请人： Hirotoshi Umemoto , Hisaki Tanabe , Mitsuo Yamada , Shinji Nakano
发明人： Hirotoshi Umemoto , Hisaki Tanabe , Mitsuo Yamada , Shinji Nakano
IPC分类号： C08G63/00 , C08G18/08 , C08G63/12 , C08G63/78 , C08L33/04 , C08L61/20 , C08L61/28 , C09D133/04 , C09D161/20 , C09D161/28 , C09D167/00 , C09D167/02 , C09D175/04 , C09D201/00 , C09D201/02 , C09D201/08 , C08F283/00 , C08G63/76 , C08L61/00
CPC分类号： C09D201/08 , C08G18/0823 , C09D167/00
摘要： A resinous composition for coating use comprising a resin having a resinous acid value derived from polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV under the state capable of developing resinous acid value of 2 to 50 and having a functional group reactive with a crosslinking agent, and preparation thereof.The composition is useful for the preparation of coating composition having improved curing property.
摘要翻译：一种用于涂料的树脂组合物，其包含树脂，其树脂酸值源自多元羧酸，其在非水电位滴定中的滴定中点电位大于-300mV，在能够发挥树脂酸值为2-50的状态下，并具有与交联剂反应的官能团及其制备。该组合物可用于制备具有改进的固化性能的涂料组合物。

8. 发明授权

US4976785A Paint resin 失效
标题翻译：油漆树脂
公开(公告)号：US4976785A
公开(公告)日：1990-12-11
申请号：US309894
申请日：1989-02-14
申请人： Shinji Nakano , Koichi Tsutsui , Shoji Ikeda , Yoji Hirasawa
发明人： Shinji Nakano , Koichi Tsutsui , Shoji Ikeda , Yoji Hirasawa
IPC分类号： C09D7/45 , C09D17/00
CPC分类号： C09D7/02 , C09D17/00
摘要： Disclosed is a paint resin prepared by reacting an aluminum chelate compound with a resin having an active hydrogen bonded to an electrophilic atom or atomic group, and/or epoxy group.
摘要翻译：公开了通过铝螯合化合物与具有键合到亲电子原子或原子团的活性氢的树脂和/或环氧基团而制备的涂料树脂。

9. 发明授权

US5399695A Method for the synthesis of quaternary ammonium salts 失效
标题翻译：季铵盐的合成方法
公开(公告)号：US5399695A
公开(公告)日：1995-03-21
申请号：US45531
申请日：1993-04-09
申请人： Shinji Nakano , Takao Morimoto , Takeshi Endo
发明人： Shinji Nakano , Takao Morimoto , Takeshi Endo
IPC分类号： C07C209/60 , C07C211/64 , C07C217/58 , C07D213/20 , C07C211/27 , C07F9/92
CPC分类号： C07D213/20 , C07C209/60 , C07C211/64 , C07C217/58
摘要： Provided is a convenient method for synthesizing quaternary ammonium salts which are useful as curing catalysts for one-part thermosetting resin compositions which maintain storage stability at room temperature. The ammonium salts are synthesized by direct reaction of a benzyl alcohol or a benzyl alkyl ether optionally having on the benzene ring and/or at .alpha.-position one or more substituent groups inert to the intended reaction, with a corresponding strong-acid salt of a tertiary amine.
摘要翻译：提供合成季铵盐的方便方法，其可用作在室温下保持储存稳定性的一部分热固性树脂组合物的固化催化剂。铵盐通过苯甲醇或任选在苯环上和/或α位上一个或多个对预期反应呈惰性的取代基的苯甲醇或苄基烷基醚与相应的强酸盐叔胺。

10. 发明授权

US5349067A Method for the synthesis of quaternary ammonium salts 失效
标题翻译：季铵盐的合成方法
公开(公告)号：US5349067A
公开(公告)日：1994-09-20
申请号：US45540
申请日：1993-04-09
申请人： Shinji Nakano , Takao Morimoto , Takeshi Endo
发明人： Shinji Nakano , Takao Morimoto , Takeshi Endo
IPC分类号： C07D213/79 , C07C209/60 , C07C211/64 , C07D213/20 , C07D213/84 , C07D211/10 , C07D211/18 , C07D211/26
CPC分类号： C07D213/20 , C07D213/84
摘要： Provided is a convenient method for the synthesis of quaternary ammonium sulfonate compounds which are useful as curing catalysts for one-part thermosetting resin compositions which maintain storage stability at room temperature. The compounds are synthesized by subjecting in one step a benzyl alcohol optionally having on the benzene ring and/or the .alpha.-position one or more substituent groups to reaction with a corresponding tertiary amine and an organic sulfonic acid chloride.
摘要翻译：提供了合成季铵磺酸盐化合物的方便方法，其可用作在室温下保持储存稳定性的一部分热固性树脂组合物的固化催化剂。所述化合物通过一步法将在苯环上和/或α位上的一个或多个取代基任选地含有苄醇与相应的叔胺和有机磺酰氯反应来合成。

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