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1. 发明授权

US08273431B2 Polyamide resin composition 有权
标题翻译：聚酰胺树脂组合物
公开(公告)号：US08273431B2
公开(公告)日：2012-09-25
申请号：US12302335
申请日：2007-05-31
申请人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
发明人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
IPC分类号： B32B1/02 , B32B1/08
CPC分类号： C08K5/0008 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/60 , C08K3/22 , C08K3/36 , C08K5/098 , C08L77/00 , C08L77/06 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/139 , Y10T428/31725 , Y10T428/31728 , Y10T428/31736 , Y10T428/3175 , Y10T428/31757
摘要： A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an α,ω-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.
摘要翻译：聚酰胺树脂组合物含有至少含有聚酰胺（X）和碳原子数为10〜50的脂肪酸金属盐的树脂成分，并含有任意的添加剂（A）和/或添加剂（B）。聚酰胺（X）通过含有70摩尔％以上的间苯二甲胺和含有70摩尔％以上的α，ω-直链脂肪族二羧酸的二羧酸成分的二胺成分的熔融缩聚得到。添加剂（A）是选自由碳原子数为8〜30的脂肪酸和碳原子数2〜10的二胺得到的二酰胺化合物，由脂肪酸得到的二酯化合物，具有8至30个碳原子的碳原子和具有2至10个碳原子的二醇和表面活性剂，并且所述添加剂（B）是选自金属氢氧化物，金属乙酸盐，金属醇盐，金属碳酸盐和脂肪酸。

2. 发明授权

US08940379B2 Polyamide resin composition 有权
标题翻译：聚酰胺树脂组合物
公开(公告)号：US08940379B2
公开(公告)日：2015-01-27
申请号：US13439577
申请日：2012-04-04
申请人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
发明人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
IPC分类号： B32B1/02 , C08K3/36 , B32B27/08 , C08K5/00 , C08L77/00 , C08K5/098 , B32B27/34 , C08K3/22 , C08L77/06 , B32B1/08
CPC分类号： C08K5/0008 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/60 , C08K3/22 , C08K3/36 , C08K5/098 , C08L77/00 , C08L77/06 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/139 , Y10T428/31725 , Y10T428/31728 , Y10T428/31736 , Y10T428/3175 , Y10T428/31757
摘要： A polyamide resin composition contains a resin component containing at least a polyamide, a fatty acid metallic salt having from 10 to 50 carbon atoms, and an additive. The polyamide is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an α,ω-linear aliphatic dicarboxylic acid. The additive is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant.
摘要翻译：聚酰胺树脂组合物含有至少含有聚酰胺，10〜50个碳原子的脂肪酸金属盐和添加剂的树脂成分。通过含有70摩尔％以上的间苯二甲胺和含有70摩尔％以上的α，ω-直链脂肪族二羧酸的二羧酸成分的二胺成分的熔融缩聚得到聚酰胺。所述添加剂是选自由碳原子数为8〜30的脂肪酸得到的二酰胺化合物和碳原子数为2〜10的二胺的至少一种化合物，由具有8个碳原子的脂肪酸得到的二酯化合物至30个碳原子和具有2至10个碳原子的二醇和表面活性剂。

3. 发明申请

US20120258268A1 POLYAMIDE RESIN COMPOSITION 审中-公开
标题翻译：聚酰胺树脂组合物
公开(公告)号：US20120258268A1
公开(公告)日：2012-10-11
申请号：US13439577
申请日：2012-04-04
申请人： Ryoji OTAKI , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
发明人： Ryoji OTAKI , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
IPC分类号： B32B27/08 , B32B27/34 , B32B1/02 , C08L77/12 , C08K5/20 , C08K5/56 , C08L77/10 , B32B27/36 , C08K5/1535
CPC分类号： C08K5/0008 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/60 , C08K3/22 , C08K3/36 , C08K5/098 , C08L77/00 , C08L77/06 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/139 , Y10T428/31725 , Y10T428/31728 , Y10T428/31736 , Y10T428/3175 , Y10T428/31757
摘要： A polyamide resin composition contains a resin component containing at least a polyamide, a fatty acid metallic salt having from 10 to 50 carbon atoms, and an additive. The polyamide is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an α,ω-linear aliphatic dicarboxylic acid. The additive is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant.
摘要翻译：聚酰胺树脂组合物含有至少含有聚酰胺，10〜50个碳原子的脂肪酸金属盐和添加剂的树脂成分。通过含有70摩尔％以上的间苯二甲胺和含有70摩尔％以上的α，ω-直链脂肪族二羧酸的二羧酸成分的二胺成分的熔融缩聚得到聚酰胺。所述添加剂是选自由碳原子数为8〜30的脂肪酸得到的二酰胺化合物和碳原子数为2〜10的二胺的至少一种化合物，由具有8个碳原子的脂肪酸得到的二酯化合物至30个碳原子和具有2至10个碳原子的二醇和表面活性剂。

4. 发明申请

US20090239013A1 POLYAMIDE RESIN COMPOSITION 有权
标题翻译：聚酰胺树脂组合物
公开(公告)号：US20090239013A1
公开(公告)日：2009-09-24
申请号：US12302335
申请日：2007-05-31
申请人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
发明人： Ryoji Otaki , Jun Mitadera , Tomonori Kato , Tomomichi Kanda
IPC分类号： B32B1/02 , B32B27/34 , B32B27/36 , B32B27/32 , B32B27/08 , C08K5/20 , C08K5/098 , C08L77/06
CPC分类号： C08K5/0008 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/60 , C08K3/22 , C08K3/36 , C08K5/098 , C08L77/00 , C08L77/06 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/139 , Y10T428/31725 , Y10T428/31728 , Y10T428/31736 , Y10T428/3175 , Y10T428/31757
摘要： A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an α,ω-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.
摘要翻译：聚酰胺树脂组合物含有至少含有聚酰胺（X）和碳原子数为10〜50的脂肪酸金属盐的树脂成分，并含有任意的添加剂（A）和/或添加剂（B）。聚酰胺（X）通过含有70摩尔％以上的间苯二甲胺和含有70摩尔％以上的α，ω-直链脂肪族二羧酸的二羧酸成分的二胺成分的熔融缩聚得到。添加剂（A）是选自由碳原子数为8〜30的脂肪酸和碳原子数2〜10的二胺得到的二酰胺化合物，由脂肪酸得到的二酯化合物，具有8至30个碳原子的碳原子和具有2至10个碳原子的二醇和表面活性剂，并且所述添加剂（B）是选自金属氢氧化物，金属乙酸盐，金属醇盐，金属碳酸盐和脂肪酸。

5. 发明申请

US20070049680A1 Resin compositions, intercalates, nanocomposites and laminates prepared with aromatic polyamide and polyphenoxy polymers 失效
标题翻译：用芳族聚酰胺和聚苯氧基聚合物制备的树脂组合物，嵌入剂，纳米复合材料和层压材料
公开(公告)号：US20070049680A1
公开(公告)日：2007-03-01
申请号：US11216692
申请日：2005-08-31
申请人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
发明人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
IPC分类号： C08K9/04
CPC分类号： C08J5/005 , B32B27/08 , B32B27/16 , B32B27/20 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/306 , B32B2307/54 , B32B2307/5825 , B32B2307/702 , B32B2307/7242 , B32B2307/7265 , B32B2439/70 , B82Y30/00 , C08J3/005 , C08J2377/06 , C08K9/04 , C08K2201/011 , C08L71/00 , C08L77/00 , C08L77/06 , C08L2666/14
摘要： A resin composition comprising melt blending a polyamide resin such as nylon MXD6 with a polyphenoxy resin. The polyamide resin and the polyphenoxy resin may be combined prior to or after melting and can be sandwiched between two PET layers in a perform mold to form an article capable of blow molding to form a container with improved delamination resistance. Also, intercalated layered materials are prepared by co-intercalation of an onium ion, an aromatic polyamide oligomer or polymer, e.g., nylon MXD6, and a polyphenoxy oligomer or polymer between the planar layers of a swellable layered material, such as a phyllosilicate, preferably a smectite clay. The co-intercalated layered materials are combined with the aromatic polyamide and polyphenoxy resin to form a nanocomposite composition for sandwiching between PET layers to form containers having improved delamination resistance.
摘要翻译：一种树脂组合物，其包括将聚酰胺树脂如尼龙MXD6与聚苯氧树脂熔融共混。聚酰胺树脂和聚苯氧树脂可以在熔融之前或之后组合，并且可以在执行模具中夹在两个PET层之间以形成能够吹塑以形成具有改善的耐分层性的容器的制品。另外，嵌层的层状材料通过在可溶胀的层状材料如页硅酸盐的平坦层之间共同嵌入鎓离子，芳族聚酰胺低聚物或聚合物，例如尼龙MXD6和聚苯氧基低聚物或聚合物来制备，优选蒙皂石粘土共嵌层层状材料与芳族聚酰胺和聚苯氧树脂结合形成纳米复合组合物，用于夹层在PET层之间以形成具有改善的耐分层性的容器。

6. 发明授权

US07053171B2 Production method of polyamide 有权
标题翻译：聚酰胺的生产方法
公开(公告)号：US07053171B2
公开(公告)日：2006-05-30
申请号：US10849027
申请日：2004-05-20
申请人： Ryoji Otaki , Tomomichi Kanda
发明人： Ryoji Otaki , Tomomichi Kanda
IPC分类号： C08G69/08 , C08G69/26
CPC分类号： C08G69/26 , C08G69/28 , C08L29/04 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/04
摘要： In the production method of the present invention, the polyamide is produced by the polycondensation of a diamine component and a dicarboxylic acid component comprising a straight-chain α,ω-aliphatic dicarboxylic acid and an aromatic dicarboxylic acid. The dicarboxylic acid component is first made into a suspension phase of the solid aromatic dicarboxylic acid in a molten straight-chain α,ω-aliphatic dicarboxylic acid. A part of the diamine component is added while the reaction system is in the suspension phase. Then, the reaction system is made into a homogeneous molten phase, to which the rest of the diamine component is added. Finally, the reaction system is kept at temperatures within a specific range to complete the polycondensation.
摘要翻译：在本发明的制造方法中，通过二胺成分和包含直链α，ω-脂族二羧酸和芳族二羧酸的二羧酸成分的缩聚制备聚酰胺。首先将二羧酸组分制成固体芳族二羧酸在熔融的直链α，ω-脂族二羧酸中的悬浮相。当反应体系处于悬浮相时，加入一部分二胺组分。然后，将反应体系制成均匀的熔融相，加入剩余的二胺组分。最后，将反应体系保持在特定范围内，以完成缩聚反应。

7. 发明申请

US20090277858A1 Multilayer Bottle 有权
标题翻译：多层瓶
公开(公告)号：US20090277858A1
公开(公告)日：2009-11-12
申请号：US12158504
申请日：2006-12-21
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B65D23/00
CPC分类号： B32B27/36 , B32B1/02 , B32B27/28 , B32B27/34 , B65D1/0215 , C08L77/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L2666/02
摘要： There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an α,ω-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.
摘要翻译：提供了包括由热塑性聚酯树脂制成的最外层和最内层的多层瓶，以及插入在最外层和最内层之间的至少一个阻挡层。阻挡层含有至少两种成分，包括通过将含有间苯二甲胺作为主要成分的二胺成分与含有α，ω-直链脂族二羧酸为主要成分的二羧酸成分缩聚得到的聚酰胺，以及具有比聚酰胺低的分子量。多层瓶几乎不会在冲击或滴落时发生分层，因此不需要具有较少的不规则形状或较少弯曲的形状以防止分层，并且还具有大的设计选择自由度。

8. 发明申请

US20090120900A1 MULTI-LAYERED BOTTLE 有权
标题翻译：多层瓶
公开(公告)号：US20090120900A1
公开(公告)日：2009-05-14
申请号：US11994660
申请日：2006-07-06
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B65D90/02
CPC分类号： B65D1/0215 , B32B7/02 , B32B27/36 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： There is provided a multilayer bottle comprising a barrel portion including an outermost layer, an innermost layer and at least one barrier layer interposed between the outermost layer and the innermost layer, which satisfies the requirements represented by the following formulae (1) to (3) at the same time: OTR≦0.2 cc·mm/(m2·day·atm) (1) where OTR represents an average oxygen transmission rate of the barrier layer of the barrel portion; 20≦(Average degree of orientation of barrier layer of barrel portion)≦45; and (2) 0≦b/a≦100≦200 (3) where “a” represents an average thickness (μm) of the barrier layer of the barrel portion; and “b” represents an average thickness (μm) of the barrier layer of a bottom portion of the bottle. The multilayer bottle is free from delamination owing to impact upon dropping even when the bottle is formed with irregularities and bends and therefore exhibits a large freedom of design choice.
摘要翻译：提供了一种多层瓶，其包括筒状部分，其包括最外层，最内层和插入在最外层和最内层之间的至少一个阻挡层，其满足由下式（1）至（3）表示的要求，同时：<？in-line-formula description =“In-line Formulas”end =“lead”？> OTR <= 0.2 cc.mm/(m2.day.atm）（1）<？in-line -formulae description =“In-line Formulas”end =“tail”？>其中OTR表示筒部分的阻挡层的平均氧气透过率; <？in-line-formula description =“在线公式”end =“lead”？> 20 <=（筒部阻挡层的平均取向度）<= 45; 和（2）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> 0 < = b / a <= 100 <= 200（3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中“a”表示阻挡层的平均厚度（mum）的桶部分; “b”表示瓶的底部的阻挡层的平均厚度（mum）。即使当瓶形成不规则和弯曲时，多层瓶也不会因为落下的冲击而脱层，因此表现出大的设计自由度。

9. 发明授权

US07927678B2 Multilayer bottle 有权
标题翻译：多层瓶
公开(公告)号：US07927678B2
公开(公告)日：2011-04-19
申请号：US12158504
申请日：2006-12-21
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B32B27/08
CPC分类号： B32B27/36 , B32B1/02 , B32B27/28 , B32B27/34 , B65D1/0215 , C08L77/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L2666/02
摘要： There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an α,ω-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.
摘要翻译：提供了包括由热塑性聚酯树脂制成的最外层和最内层的多层瓶，以及插入在最外层和最内层之间的至少一个阻挡层。阻隔层含有至少两种成分，包括通过使含有间苯二甲胺作为主要成分的二胺组分与含有α，ω-线性脂族二羧酸作为主要成分的二羧酸组分缩聚获得的聚酰胺，以及具有比聚酰胺低的分子量。多层瓶几乎不会在冲击或滴落时发生分层，因此不需要具有较少的不规则形状或较少弯曲的形状以防止分层，并且还具有大的设计选择自由度。

10. 发明授权

US07619024B2 Resin compositions, intercalates, nanocomposites and laminates prepared with aromatic polyamide and polyphenoxy polymers 失效
标题翻译：用芳族聚酰胺和聚苯氧基聚合物制备的树脂组合物，嵌入剂，纳米复合材料和层压材料
公开(公告)号：US07619024B2
公开(公告)日：2009-11-17
申请号：US11216692
申请日：2005-08-31
申请人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
发明人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
IPC分类号： C08J5/10 , C08K3/34
CPC分类号： C08J5/005 , B32B27/08 , B32B27/16 , B32B27/20 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/306 , B32B2307/54 , B32B2307/5825 , B32B2307/702 , B32B2307/7242 , B32B2307/7265 , B32B2439/70 , B82Y30/00 , C08J3/005 , C08J2377/06 , C08K9/04 , C08K2201/011 , C08L71/00 , C08L77/00 , C08L77/06 , C08L2666/14
摘要： A resin composition comprising melt blending a polyamide resin such as nylon MXD6 with a polyphenoxy resin. The polyamide resin and the polyphenoxy resin may be combined prior to or after melting and can be sandwiched between two PET layers in a perform mold to form an article capable of blow molding to form a container with improved delamination resistance. Also, intercalated layered materials are prepared by co-intercalation of an onium ion, an aromatic polyamide oligomer or polymer, e.g., nylon MXD6, and a polyphenoxy oligomer or polymer between the planar layers of a swellable layered material, such as a phyllosilicate, preferably a smectite clay. The co-intercalated layered materials are combined with the aromatic polyamide and polyphenoxy resin to form a nanocomposite composition for sandwiching between PET layers to form containers having improved delamination resistance.
摘要翻译：一种树脂组合物，其包括将聚酰胺树脂如尼龙MXD6与聚苯氧树脂熔融共混。聚酰胺树脂和聚苯氧树脂可以在熔融之前或之后组合，并且可以在执行模具中夹在两个PET层之间以形成能够吹塑以形成具有改善的耐分层性的容器的制品。另外，嵌层的层状材料通过在可溶胀的层状材料如页硅酸盐的平坦层之间共同嵌入鎓离子，芳族聚酰胺低聚物或聚合物，例如尼龙MXD6和聚苯氧基低聚物或聚合物来制备，优选蒙皂石粘土共嵌层层状材料与芳族聚酰胺和聚苯氧树脂结合形成纳米复合组合物，用于夹层在PET层之间以形成具有改善的耐分层性的容器。

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